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Moisture swing carbon capture

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As the world grapples with limiting the amount of carbon dioxide in the atmosphere, there is a growing need to capture the carbon dioxide that is emitted as well as preventing it from being emitted in the first place.  Carbon capture can be accomplished at the source of emissions (such as power plants) or it can be done by taking it out of the atmosphere.  The latter is called “direct air capture”.

It is not at all clear whether direct air capture can be accomplished on a scale that would really make a difference and at an acceptable cost either in dollars or energy expended.  But if it can be done that way, it would be a major tool in combatting climate change.

Direct air capture technology generally makes use of sorbent materials whose capacity to capture carbon dioxide and later release it is a function of temperature.  The process requires significant amounts of energy to release the carbon dioxide that has been captured. 

New research from Northwestern University makes use of the “moisture-swing” technique which uses materials whose ability to capture and release carbon dioxide depends on humidity rather than temperature.  While it takes some amount of energy to humidify the volume of air containing the sorbent material, it is very small compared to temperature-driven systems. 

There are many groups working with moisture-swing technology, but the Northwestern Group has identified a number of new sorbent materials with superior properties.

The fundamental questions of scalability and cost remain, but moisture-swing is a promising approach to direct air capture.  If carbon dioxide can be pulled out of the atmosphere in large volumes, it can be concentrated and stored or converted into useful products.

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Pulling carbon dioxide right out of the air

Photo, posted May 15, 2020, courtesy of James Watt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cheaper Carbon Capture | Earth Wise

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As the years roll by without sufficient progress in reducing carbon dioxide emissions, the need for technologies that can capture CO2 from its sources or remove it from the air becomes stronger and stronger.  People have developed various ways to capture carbon dioxide, but to date, they generally suffer from some combination of being too costly or not being able to scale up to the necessary magnitude.

Scientists at the Pacific Northwest National Laboratory in Richland, Washington recently announced the creation of a new system that they claim is the least costly to date that captures carbon dioxide and turns it into a widely-used chemical: methanol.

Technologies that simply capture carbon dioxide that then needs to be stored in some secure location are difficult to implement from a cost perspective.  The PNNL researchers believe that turning CO2 into methanol can provide the financial incentive for widespread implementation.   Methanol can be used as a fuel, a solvent, or an important ingredient in plastics, paint, construction materials, and car parts.

The system is designed to be installed in fossil fuel-fired power plants as well as cement and steel plants.  Using a capture solvent developed by PNNL, the system grabs carbon dioxide molecules before they are emitted and converts them into methanol. Creating methanol from CO2 is nothing new, but capturing the carbon dioxide and converting into methanol in one continuously flowing system is new.

More work is needed to optimize and scale the process and it may be several years before it is ready for commercial deployment.

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Scientists Unveil Least Costly Carbon Capture System to Date

Photo, posted November 25, 2022, courtesy of Massachusetts Department of Environmental Conservation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon Capture In Wyoming | Earth Wise

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Wyoming produces about 40% of our country’s coal and many towns in the state were built because of and make their living from it.  With coal’s plummeting share in the nation’s electricity, there is a great deal of anxiety among residents of those towns.

As carbon dioxide levels in the atmosphere continue to climb, there is a growing sense that cutting emissions will not happen quickly enough and it will be necessary to pull the greenhouse gas out of the atmosphere.  The current long-term government climate strategy assumes that carbon removal will account for 6 to 8 percent of the nation’s greenhouse gas reductions by 2050.

The Inflation Reduction Act passed in August provides $3.5 billion to help build “direct air capture hubs” around the country, with an emphasis on fossil fuel-dependent communities such as many in Wyoming. 

The town of Rock Springs, Wyoming is home to the Jim Bridger Coal Plant. A company called CarbonCapture, Inc., is launching Project Bison, which will build a direct air capture facility outside of town that is set to begin operations next year.  It will initially capture 10,000 metric tons of CO2 per year but plans to expand that to 5 million tons a year by 2030. 

That would be far more than any current carbon capture plant can do. The largest plant in the world, located in Iceland, pulls in only about 4,000 metric tons a year.

There are many problems associated with carbon capture.  It uses up very large amounts of energy, possibly presents environmental problems, and is very expensive.  In short, the technology has a long way to go before becoming viable.  However, this may ultimately be another example where necessity is the mother of invention.

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Carbon Removal Is Coming to Fossil Fuel Country. Can It Bring Jobs and Climate Action?

Photo, posted July 22, 2012, courtesy of Max Phillips via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon Capture Booming | Earth Wise

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For the world to reach a state of net-zero emissions, it is going to require more than the ongoing transition to renewable energy sources.  There will also need to be efforts to capture the emissions from sources that can’t easily eliminate their pollution.  These include steel mills, cement plants, and other industrial sites.  At least for the foreseeable future,  a number of essential industries have no other viable path to deep decarbonization, and carbon capture and storage projects are the only promising strategy on hand.

Companies use CCS to filter emissions from fossil fuel power plants and industrial facilities and then bury the captured carbon underground, often in deep caverns.

Over the past 12 months, the pipeline for carbon capture and storage projects has grown by 44%.  This year, firms have announced 61 new CCS projects, bringing the total number of commercial projects in the global pipeline to 196, which includes about 30 that are already in operation.  Another 11 are under construction, and 153 are in development.

When all of these projects are completed, they will have the capacity to capture a total of about 270 million tons of carbon dioxide per year.  Estimates are that there need to be 1,400 million tons locked away each year to reach zero-emissions.  So, the existing project pipeline constitutes about 20% of what is ultimately needed.

The recently passed Inflation Reduction Act boosts tax incentives for carbon capture.  Analysts believe this could multiply U.S. deployment of the technology more than 10-fold.  Globally, it is expected that CCS will continue its rapid growth as countries ramp up investments in the technology.

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Carbon Capture Projects See Meteoric Growth in 2022

Photo, posted August 22, 2022, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

California Climate Legislation | Earth Wise

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At the end of its summer session, California’s state legislature passed five climate-related bills including ones that it had been unable to pass in previous sessions.  Taking all of these actions puts California in the position of blazing a trail for the country and the rest of world in taking aggressive action on climate issues.

One bill confirmed California’s goal of reaching net-zero emissions by 2045.  Another bill added interim-term targets to go along with the state’s goal of 100% renewable electricity by 2045.  It sets a target of 90% by 2030 and 95% by 2040.  That bill mandates that California state agencies use 100% clean energy by 2035, which is a decade earlier than the previous requirement.

A third bill requires the California Air Resources Board to determine steps and regulations for carbon-capture and storage projects at pollution hotspots like oil refineries.

A fourth bill requires the state to set goals for removing carbon dioxide from the atmosphere through natural means such as tree planting.

The California state budget includes a record-breaking $54 billion to be spent on climate programs over the next five years, including $6.1 billion toward electric vehicles, $14.8 billion towards public transit projects, more than $8 billion for electric grid stabilization, $2.7 billion towards preventing wildfires, and $2.8 billion towards managing drought.

California has been dealing with ongoing drought and numerous wildfires and is highly motivated to take decisive action in dealing with the climate crisis.  California’s environmental initiatives often result in comparable actions taken by other states.

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California Passes Massive Climate Legislation Package

Photo, posted March 16, 2019, courtesy of Raymond Shobe via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Cheap Material For Carbon Capture | Earth Wise

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The recently passed Inflation Reduction Act includes significant support for carbon capture technologies. Eliminating fossil fuel burning is essential for halting climate change, but in the interim, methods for capturing emissions of carbon dioxide and either storing it or turning it into usable products are increasingly necessary.

There are a variety of techniques being developed for carbon capture but at this point, none of them are commercially viable.  The best technique in use today involves piping flue gases through chemicals called liquid amines, which bind CO2.  The process requires large amounts of energy to release the bound carbon dioxide so it can be concentrated and stored.  As a result, it is complicated and expensive.

Researchers at UC Berkeley, Stanford, and Texas A&M University have developed a carbon capture method using melamine, which is an inexpensive polymer used to make Formica, as well as low-cost dinnerware, industrial coatings, and other plastics.  Porous melamine itself adsorbs CO2 to a limited extent.  But the researchers discovered that adsorption could be much improved by adding the chemical DETA (diethylenetriamine) to bind the CO2.  In addition, adding cyanuric acid increased the melamine pore size and radically improved CO2 capture efficiency even more.

The result is a material that is more efficient even than exotic carbon capture materials like metalorganic frameworks and is much cheaper and easier to make. The researchers aim to design equipment that can used in industrial facilities, attached to buildings and other structures, or even to the tailpipes of gas-powered vehicles.

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A simple, cheap material for carbon capture, perhaps from tailpipes

Photo, posted June 10, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture: Solution Or Band-Aid? | Earth Wise

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The idea of capturing the CO2 emissions from industry and locking them up is nothing new.  It’s been going on for decades in some places.  Norway’s state-owned oil company Equinor has been holing away a million tons of CO2 a year for a long time.  But overall, CCS – carbon capture and storage – has had very limited use.  As of last year, there were only about 30 large-scale projects in operation around the world, capturing only 0.1% of global emissions.

There is now growing interest in CCS and many new projects are underway.  A combination of rising carbon prices in Europe, tax breaks for CCS in the US, national net-zero targets, and the increasing need to ramp down global emissions are all driving rising CCS activities. 

While recent reports from the Intergovernmental Panel on Climate change still claim that it is possible to remain below 2 degrees Celsius of warming without using carbon capture, there is growing belief that it may be necessary given the present pace of the transition away from fossil fuels.

Two industries that together produce about 14% of global CO2 emissions are cement and steel.  These are both industries for which it is difficult to eliminate emissions regardless of the energy sources used. CCS may be the best approach to reducing their emissions.

But there is considerable pushback against CCS.  The concern is that CCS is primarily a way to delay decarbonization.  It encourages various industries to continue to use fossil fuels instead of shifting away from them.  Nonetheless, CCS no doubt has its place as part of the solution to climate change.

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Solution or Band-Aid? Carbon Capture Projects Are Moving Ahead

Photo, posted June 5, 2022, courtesy of Mark Dixon via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Primary Ways To Mitigate Climate Change | Earth Wise

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The most recent report issued by the Intergovernmental Panel on Climate Change states that the world must halt the increase in greenhouse gases within three years, reduce emissions by 43% in the next seven years, and eliminate them entirely by 2050.  Otherwise, there will likely be catastrophic and irreversible impacts on the climate.

With respect to achieving these reductions, the report emphasizes decarbonizing the energy sector through electrification by replacing fossil fuels anywhere and everywhere possible.  Where that isn’t yet practical – such as in shipping and aviation – the use of biofuels and hydrogen can provide a stopgap until battery technology becomes a viable alternative.

The economics of this approach continue to improve.  Since 2010, the cost of wind, solar, and batteries has declined by as much as 85%.  In many cases, costs have fallen below those of fossil fuels.  Nonetheless, the report stresses that continuing to provide national, state, and local incentives for using renewable energy is a key factor in achieving the necessary reductions.

However, reducing emissions will no longer be enough.  This is the first major IPCC report that states that man-made carbon dioxide removal strategies will be necessary to meet the goals of the Paris Climate Agreement.  So-called natural carbon storage options, like planting trees and using farming methods that sequester carbon in soil, are also important parts of the strategy.

It is up to governments, policymakers, and investors to implement the necessary changes to mitigate climate change.  There is lots of talk about it, but it will take concerted action to avoid increasingly dire consequences.

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Report highlights affordable, available ways to mitigate climate change now

Photo, posted September 8, 2007, courtesy of Kevin Dooley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Better Way To Capture Carbon | Earth Wise

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The goal of carbon capture and storage technology is to remove carbon dioxide from the atmosphere and safely store it for the indefinite future.  There are existing industrial facilities that capture carbon dioxide from concentrated sources – like the emissions from power plants.  The technology currently captures and stores only about a tenth of a percent of global carbon emissions.

Most existing CCS technologies use chemical binders to trap carbon dioxide quickly and efficiently, but they are extraordinarily energy intensive as well as expensive.

Researchers at the University of Colorado Boulder have developed a new tool that could lead to more efficient and cheaper ways to capture carbon dioxide directly out of the air.  The tool predicts how strong the bond will be between carbon dioxide and a candidate molecule for trapping it – that is, a binder.  This new electrochemical diagnostic tool can be used to identify suitable molecular candidates for capturing carbon dioxide from everyday air.

Current carbon capture technologies are very expensive at the scale required to be able to turn the captured CO2 into useful substances, such as carbonates – which are an ingredient in cement – or formaldehyde or methanol, which can be used as fuels.  Making useful materials out of the captured CO2 is an important way to offset the cost of capturing it that merely storing it away does not permit.

The new electrochemical analytical tool developed by the Colorado researchers offers the potential for identifying binders that will be more efficient and less expensive, thereby making direct air carbon capture a realistic part of the efforts to address climate change.

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New method could lead to cheaper, more efficient ways to capture carbon

Photo, posted October 25, 2015, courtesy of Frans Berkelaar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Safely Storing Carbon | Earth Wise

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As carbon dioxide levels continue to increase in the atmosphere and emissions reductions aren’t happening as fast as needed, there is growing interest in carbon capture and storage technologies.

The idea is to capture the CO2 emitted from industrial processes or from the burning of fossil fuels in power generation, and then permanently store it out of harm’s way.  There are several different types of sites where the CO2 might be stored.  Deep saline aquifers are particularly desirable for the purpose, but depleted hydrocarbon reservoirs are commonplace and relatively simple to use.  These are oil and gas wells that have been drained of their resources.

In many cases, CO2 has already been injected into these depleted wells as a means of enhanced oil recovery.  Therefore, such wells provide a unique opportunity to study what happens to carbon dioxide when it’s stored in these places.

Researchers from Oxford University recently published a paper in the journal Nature that compared the state of depleted wells with injected carbon dioxide to that of wells without the injected gas.  They found that nearly 3/4 of the CO2 was dissolved in the groundwater.  Unexpectedly, they also found that 13-19% of the carbon dioxide was converted into methane by methanogenic bacteria.  Methane is less soluble, less compressible, and less reactive than carbon dioxide.

Producing methane in these wells is therefore undesirable.  Deeper sites that have temperatures too high for the bacteria to thrive are much more suitable.  This research is important for identifying future carbon capture and storage sites and for designing long-term monitoring programs that are essential for low-risk, long-term carbon storage.

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Safer carbon capture and storage

Photo, posted November 6, 2015, courtesy of CL Baker via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture In Denmark | Earth Wise

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Denmark has pledged to reduce greenhouse gas emissions 70% by 2030 compared with 1990 levels. The country has also banned oil exploration in Danish waters and plans to phase out offshore drilling in the North Sea by 2050.

Instead of pumping oil from the North Sea, Denmark plans to capture CO2 and store it there.  To meet its climate goals, Denmark is investing $2.4 billion in a plan to capture carbon dioxide from its energy and industrial sectors and inject it into the seabed in geological formations that previously held oil and gas deposits.

The first North Sea carbon capture and storage facilities will be put into service in 2025 and will remove nearly half a million tons of emissions from the atmosphere each year.  The carbon dioxide will be captured from energy and industrial sectors such as waste incineration and cement production.

There are multiple carbon capture projects underway around the world.  Many are directed at so-called direct air capture, which is taking carbon dioxide out of the air once it is already there.  In Iceland, a project named “Orca” is extracting CO2 from the air and piping into a processing facility where it is mixed with water and diverted into a deep underground well.  Other large direct air capture plants are being built in the U.S. Southwest and in Scotland.

Whether capturing carbon from industrial operations or directly from the air ultimately makes environmental and economic sense remains to be seen.  What is driving the development of these technologies is the troubling math that reducing emissions is not happening fast enough to stave off the destructive effects of climate change that will result from global temperatures rising too much.

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Denmark bets on North Sea carbon capture to hit climate goals

Photo, posted July 2, 2018, courtesy of Ansgar Koreng via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Cement Manufacturing | Earth Wise

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Cement is the basic ingredient of concrete, which is the most widely used construction material in the world.  About 8% of global carbon dioxide emissions are associated with cement production.

More than half of these emissions come from making clinker, which is a major component of cement produced by heating ground limestone and clay to a temperature of over 2500 degrees Fahrenheit.  Some of the emissions come from burning fossil fuels to heat the materials, but much of them come from the chemical reaction that creates the clinker.

The Portland Cement Association, which represents 92% of US cement manufacturing capacity, has recently released its “Roadmap to Carbon Neutrality”, which lays out a plan to reach carbon net zero across the cement and concrete value chain by 2050.

The plan includes the greater use of alternative fuels to reduce emissions from energy use.  It also involves the adoption of newer versions of cement such as Portland limestone cement, which reduces CO2 levels.  The industry has already reduced emissions by some shifting to Portland limestone cement, but it still only represents a small fraction of cement production.

The most significant strategy would be the adoption of carbon capture, utilization, and storage (or CCUS) technologies.  The idea is to capture the CO2 generated in the production of clinker and inject it into the fresh concrete.  It would actually be permanently sequestered in the concrete and would not be released even if a structure is demolished in the future.

It will take a combination of technologies and initiatives for the cement industry to reduce its emissions.  Fortunately, the industry appears to be committed to that goal.

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US cement manufacturers release their road map to carbon neutrality by 2050

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Direct Air Capture | Earth Wise

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There is a lot of interest in carbon capture and sequestration (or CCS) in the context of trapping the carbon dioxide emissions from power plants and industrial facilities.  The fossil fuel industry is especially enthusiastic about the potential for continuing to burn fuels without harming the environment.  Apart from the technical challenges, there is the looming problem of CCS adding significant costs to power generation that is already losing the economic battle to renewable sources.

Direct air capture is a different matter.   This is the idea of actively taking CO2 out of the atmosphere.  This already happens by natural means such as sequestering it in soil or forests.  But there is considerable work going on aimed at developing technology to capture atmospheric carbon dioxide in massive quantities.

This September marks the opening of a new project called “Orca” in Iceland, which will, for the time being, be the largest direct air capture system in the world.  Once it is running around the clock, Orca will remove up to 4,000 metric tons of CO2 from the atmosphere each year.

Even larger DAC plants – one in the southwestern U.S and another in Scotland – are planned to come online in the next few years.

Ultimately, the question is whether direct air capture is feasible at large enough scale and affordable cost.  The numbers are daunting.  Society releases over 30 billion metric tons of carbon dioxide into the atmosphere each year.  Removing significant amounts of that with DAC technology is an enormous challenge.  Eliminating emissions remains the most practical way to mitigate the effects of climate change.

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The Dream of Carbon Air Capture Edges Toward Reality

Photo, posted November 10, 2017, courtesy of Governor Jay and First Lady Trudi Inslee via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture And The Infrastructure Bill | Earth Wise

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The trillion-dollar infrastructure bill contains a variety of provisions related to energy and the environment.  Among them is authorization for more than $12 billion for carbon capture technologies, including direct air capture and demonstration projects on coal, natural gas, and industrial plants and supporting carbon dioxide infrastructure.

Inclusion of this provision has largely been driven by energy companies, electrical utilities, and other industrial sectors.  The strongest proponents have been fossil fuel companies.  The reasons are fairly clear.

Support for carbon capture and storage (or CCS) technologies would yield billions of dollars for corporate polluters while allowing them to continue to burn fossil fuels.  To date, CCS technology has not progressed very far.  It is very expensive and has done little to reduce emissions. 

The strongest argument against directing significant resources into CCS for the power sector is that the plummeting costs of wind and solar energy have made renewable energy sources competitive with or cheaper than burning fossil fuels to generate electricity.  Adding expensive carbon capture equipment to a power plant only makes the economics of using fossil fuels worse.

The infrastructure bill does promote direct air capture technology, which is literally pulling carbon dioxide out of the air independent of any industrial activities generating it.  Given the world’s progress on reducing emissions, direct air capture technology may be an essential part of the global strategy to combat climate change.  If infrastructure funds largely go in that direction rather than for propping up fossil fuel companies, they may prove to be of great value.

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Fossil Fuel Companies Are Quietly Scoring Big Money for Their Preferred Climate Solution: Carbon Capture and Storage

Photo, posted March 15, 2021, courtesy of Michael Swan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Path To Net Zero | Earth Wise

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Reaching net zero emissions is both feasible and affordable, according to researchers at the Department of Energy’s Lawrence Berkeley National Laboratory, the University of San Francisco, and consulting firm Evolved Energy Research.   The researchers created a detailed model of the entire U.S. energy and industrial system to produce the first detailed, peer-reviewed study of how to achieve carbon neutrality by 2050.

The study analyzed multiple feasible technology pathways based on very different assumptions of remaining fossil fuel use, land use, consumer adoption, nuclear energy, and biofuel use.  What they had in common was increasing energy efficiency, transitioning to electric technologies, utilizing clean electricity (especially wind and solar power), and deploying small amounts of carbon capture technology.

The decarbonization of the U.S. energy system is an infrastructure transformation.  Getting to net zero by 2050 means adding many gigawatts of wind and solar power plants, new transmission lines, a fleet of electric cars and light trucks, millions of heat pumps to replace conventional furnaces and water heaters, and more energy-efficient buildings.

The various pathways studied have net costs between 0.2% and 1.2% of GDP, which is as little as $1 per person per day.  The cost variations come from various tradeoffs such as the amount of land given to solar and wind farms as well as the amount of new transmission infrastructure required. 

A key result of the study is that the actions required over the next 10 years are similar among all the pathways.   We need to increase the use of renewable energy and make sure that all new infrastructure, such as cars and buildings are low carbon.

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Getting to Net Zero – and Even Net Negative – is Surprisingly Feasible, and Affordable

Photo, posted July 12, 2010, courtesy of Tom Shockey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Dangers Of Negative Emissions Technologies | Earth Wise

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Reducing carbon emissions is not easy and there are plenty of people who don’t even want to try for various reasons, generally related to their perceived economic interests and convenience.  As a result, there is a great deal of interest in so-called negative emissions technologies or NETs.   These are methods for removing carbon dioxide from the atmosphere.  Even the UN Intergovernmental Panel on Climate Change assumes that NETs will play a role in mitigating the effects of climate change and meeting international goals.

The most widely studied approaches to negative emissions technology are bioenergy with carbon capture and storage – which entails growing crops for fuel, and then capturing and burying the CO2 produced from burning the fuel; planting more forests; and direct air capture, which involves actually pulling CO2 out of the air and storing it – probably underground. 

A new study published in Nature Climate Change points out that none of these technologies has even been tried at the demonstration scale, much less at the massive levels required to make a dent in current CO2 emissions. 

Their analysis of the biofuel and reforestation strategies show that each would take up vast land and water resources already needed for agriculture and nature.  Air capture uses less water than the other two approaches, but still uses quite a bit and even more energy, which if supplied by fossil fuels, would offset the benefits of carbon capture.

Negative emissions technologies may well play an important role in combating climate change, but it is essential that we understand what the consequences will be from implementing them.  We need to know the pitfalls that could arise.  It would be a major mistake to simply count on NETs to be some kind of silver bullet.

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Remove CO2 from the air? Don’t bet on it before examining costs, researchers say

Photo, posted January 11, 2008, courtesy of Al Pavangkanan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Carbon Capture Technique | Earth Wise

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Carbon dioxide emissions by electricity generating plants, fossil-fuel burning vehicles, and industry produce about 2/3 of the greenhouse gases driving climate change.  Without decreasing these emissions, the earth will continue to get warmer, sea levels will continue to rise, and the world will face more droughts, floods, wildfires, famine and conflict.

Electrification of vehicles and reliance upon renewable energy sources will ultimately drastically reduce the use of fossil fuels and the resultant emissions, but that transition may take too long to reverse the direction of climate change.  In the meantime, there is a great need to find effective and efficient ways to capture emissions from fossil fuel plants. 

Recent research at the University of California, Berkeley, Lawrence Berkeley National Laboratory, and ExxonMobil has developed a new technique for carbon capture.  The technique makes use of metal-organic framework (or MOF) technology.  An MOF, modified with nitrogen-containing amine molecules, captures CO2 and then low-temperature steam is used to flush out the CO2 either to be used or sequestered underground.

Experiments demonstrated the technique to have a six-times greater capacity for removing CO2 from the flue gas of a refinery than current amine-based technology.  It selectively removed 90% of the emitted CO2. 

There is a relatively limited market for captured CO2, so power plants using the capture technology would likely pump the CO2 into the ground, or otherwise sequester it.  The cost of doing this sort of emission scrubbing would have to be facilitated by government policies, such as carbon trading or a carbon tax, which would provide the necessary economic incentive for doing carbon capture and sequestration.

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New technique to capture CO2 could reduce power plant greenhouse gases

Photo courtesy of UC Berkeley.

Earth Wise is a production of WAMC Northeast Public Radio.

An Incentive For Carbon Capture | Earth Wise

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Convincing industries to reduce their carbon dioxide emissions has not been easy.  Many approaches have been debated, including carbon taxes, carbon tax-and-trade schemes, and passing a giant Green New Deal.  Most economists agree that putting a price on carbon is likely to be the most effective approach.

But there is already in place an adjustment to the US tax code that is more of a carrot than a stick.  It is a tax credit that is designed to make capturing CO2 a financial winner for a number of high-emitting industries.  The credit, called 45Q, was enacted in February 2018.

The 45Q credit earns industrial manufacturers $50 per metric ton of CO2 stored permanently or $35 per ton if the CO2 is put to use.  An earlier credit for capturing carbon dioxide was limited to only $20 per metric ton and was capped at 75 million tons.  Some large fossil fuel companies did make use of the earlier credit.

The new version does not have a cap, but to qualify, companies need to start constructing carbon-capture facilities within 7 years and have 12 years to claim their money.

Companies with emission-intensive operations are busy figuring out how to take advantage of the credit.  These include cement makers, steel and power plants, corn ethanol producers, and ammonia plants.

Because the credit mandates that companies start constructing their carbon-capture facilities within seven years, most companies will tend to rely on mature technologies.  But the tax credit should also drive demand for next-generation carbon-capture technologies, of which there are many under development.  Saving lots of money on taxes is likely to lure US companies to capture carbon dioxide.

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45Q, the tax credit that’s luring US companies to capture CO2

Photo, posted October 2, 2014, courtesy of Sask Power via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Storing CO2 Underground | Earth Wise

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Capturing the carbon dioxide emitted from power plants and factories and safely storing it so it can’t enter the atmosphere has long been an attractive and desirable goal.  Even though the use of renewable energy sources has been expanding rapidly, it will still be a long time before fossil fuel plants go away entirely.

The most widely considered method of carbon capture and storage is underground storage.  The idea is to send the carbon dioxide through a pipeline to a place where underground rock formations can store it safely and permanently.  Typically, it would be pumped deep underground – often more than half a mile down – and the site would be monitored to make sure the CO2 doesn’t leak back up to the atmosphere or into the water table.

A new study looked at how much carbon dioxide the suitable geological formations on Earth can store.  The conclusion of the study is that drilling about 12,000 carbon storage wells globally could provide enough capacity to store 6 to 7 billion tons of CO2 a year by 2050.  That is about 13% of global emissions.

Drilling 12,000 wells is equivalent to the amount of oil and gas drilling that has taken place just in the Gulf of Mexico over the last 70 years.  The study identified locations worldwide that could handle the pressures associated with storing injected carbon dioxide.

So far, less than two dozen projects exist that capture and store carbon dioxide from fossil fuel plants.  In total, these plants can capture about 36 million tons a year, which is far less than what is needed.  But the new study at least shows that finding places to put captured carbon is not a problem.

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Ample Geological Capacity Exists to Store Large Quantities of Captured CO2

Photo courtesy of Equinor.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture As Big Business

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Removing greenhouse gasses from the atmosphere is an essential part of the overall effort to achieve zero net carbon emissions and stabilize the climate.  Since we have not been able to reduce emissions fast enough to do the job, it is important to find ways to pull carbon dioxide out of the atmosphere.

There are many ways to do it, but they tend to be rather expensive and, so far, the need to mitigate climate change does not seem to provide sufficient incentive. A new study by researchers at UCLA, the University of Oxford, and five other institutions, analyzed the possibility of creating a large global industry based on capturing carbon dioxide and turning it into commercial products.

The study investigated the potential future scale and cost of 10 different ways to use carbon dioxide, including in fuels and chemicals, plastics, building materials, soil management, and forestry.  The study looked at processes using carbon dioxide captured from waste products that are produced by burning fossil fuels as well as by simply capturing it directly from the atmosphere.  The study also looked at processes that use carbon dioxide captured biologically by photosynthesis.

The conclusions of the study were that on average each of the ten utilization pathways could use about half a billion tons of carbon dioxide that would otherwise escape into the atmosphere.  Thus, theoretically, these various pathways could take more than five billion tons of CO2 out of the atmosphere.   Currently, fossil fuel combustion emits about 40 billion tons of carbon dioxide.

The authors of the study stress that there is no silver bullet in the fight against climate change.  It will require multiple approaches – including CO2 removal for industrial use – to make real progress

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Carbon dioxide capture and use could become big business

Photo, posted September 18, 2015, courtesy of Tony Webster via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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