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Solar Windows | Earth Wise

September 1, 2022 By EarthWise Leave a Comment

Solar windows are an attractive idea. It is very appealing to have the vertical surfaces on the outside of almost any building generate electricity. The challenge is to have a transparent window be able to function as an efficient-enough solar panel.

Most conventional solar panels use silicon solar cell technology, which is not based on a transparent material. Transparent solar cells use dye-sensitized technology, which has been the subject of research for decades but has yet to achieve widespread use.

Researchers at the University of Michigan have recently published work on a new process to manufacture solar windows that can be large (over six feet in each dimension) and efficient at electricity production.

The windows make use of dye-sensitized cells which are connected to lines of metal so small that they are invisible to the naked eye. The individual cells are fairly small but the connection technology allows the construction of large windows.

The solar window has an efficiency of 7%, meaning 7% of incoming sunlight energy is converted to electricity. The researchers believe that 10% efficiency should be attainable with their technology. Conventional solar panels have efficiencies of 15% or more.

However, the goal is not necessarily to compete with silicon solar panels. The real opportunity is to be able to generate electricity when rooftop solar is not practical or to produce additional electricity even when there is already a solar roof.

Going forward, the goals of solar window development are to increase efficiency and to reduce costs to where installing the windows is economically attractive. Estimates are that the windows currently would cost about twice as much as a conventional window but would pay for the difference in two to six years depending on such things as the level of sun exposure.

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Web Links

Inside Clean Energy: What’s Hotter than Solar Panels? Solar Windows.

Photo, posted April 17, 2017, courtesy of Shelby Bell via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Progress On Perovskite Solar Cells | Earth Wise

August 2, 2022 By EarthWise Leave a Comment

Perovskites are semiconductors with a specific crystal structure. Their properties make them well suited for making solar cells. They can be manufactured at room temperature, using much less energy than it takes to make the silicon-based solar cells widely used today. As a result, perovskite solar panels would be cheaper and more sustainable to produce. Manufacturing silicon solar cells takes a lot of energy because silicon is forged at around 3000 degrees Fahrenheit. In addition, perovskites can be made flexible and transparent, making it possible to use them in ways unavailable with silicon solar technology.

But unlike silicon, perovskites are very fragile. The early solar cells made from perovskites in 2009 and 2012 lasted for only minutes. Lots of potential, but little practicality.

Recently, Princeton Engineering researchers have developed the first perovskite solar cell with a commercially viable lifetime, which is a major breakthrough. The team projects that the device can perform above industry standards for about 30 years, which is much more than the 20 years designated as a viability threshold for commercial cells.

The research team has developed an ultra-thin capping layer between two of the layers of a perovskite solar cell. The layer is just few atoms thick but has been demonstrated to dramatically increase the durability of the device.

There is great potential for the new solar cell technology. It has efficiency to compete with silicon cells but can be tuned for specific applications and can be manufactured locally with low energy inputs. If successfully commercialized, the result will be solar panels that are cheaper, more efficient, and more flexible than what are available today.

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Once seen as fleeting, a new solar tech shines on and on

Photo, posted January 8, 2020, courtesy of David Baillot/UC San Diego Jacobs School of Engineering via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Red Hot Chili Solar Panels | Earth Wise

April 9, 2021 By EarthWise Leave a Comment

The majority of solar panels in use today are made from either single-crystal or polycrystalline silicon, the same stuff used to make the ubiquitous chips in computers, cell phones, and countless other devices. In addition, a growing fraction of solar panels utilize thin-film technology, which offers cost and flexibility advantages.

Monocrystal silicon still provides the highest efficiency and longest lifespan in commercially available panels, but the lower costs and some other features of thin-film solar panels are growing that market over time.

More recently, perovskite solar cell technology has been a source of great interest in the research community. Perovskites are a class of minerals with a specific crystalline structure that already have uses in various applications. As a solar cell material, perovskites offer the potential for converting more sunlight to electricity, being manufactured far more cheaply using no exotic or expensive materials, being more defect-tolerant, as well as a having number of other advantages. They also have the potential for having very high efficiency.

Recently, a group of researchers in China and Sweden published results of studies demonstrating that the addition of a novel ingredient has increased the efficiency of perovskite solar cells to nearly 22%, which is better than most commercial silicon solar cells. The ingredient is capsaicin, the chemical that gives chili peppers their spicy sting. Adding capsaicin expands the grains that make up the active material of the solar cell, allowing the more effective transport of electricity.

Why did the researchers think of adding the active ingredient of hot peppers to a solar cell in the first place? So far, they aren’t saying.

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Web Links

Solar panels capture more sunlight with capsaicin – the chemical that makes chili peppers spicy

Photo, posted August 16, 2019, courtesy of Pedro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Recycling Solar Panels | Earth Wise

October 1, 2020 By EarthWise Leave a Comment

It is inevitable that the things we make and use eventually outlive their useful lives and become waste that we have to deal with. Solar panels, despite their impressively long lifetime, can’t escape this general principle. As pioneering solar panels near the end of their 30-year electronic lives, they could well become the world’s next big wave of e-waste.

According to the International Renewable Energy Agency, nearly 90 million tons of solar panels will have reached their end of life by the year 2050, resulting in about 7 million tons of new solar e-waste per year.

Solar photovoltaic deployment has grown at unprecedented rates in recent years. The total global installed capacity is about 600 GW today; projections are that there will be 1,600 GW by 2030 and 4,500 GW by 2050.

Solar panels contain valuable materials, including silver and high-purity silicon. But current recycling procedures are not cost-effective. Only about 10% of panels are currently recycled in the U.S. The rest go to landfills or are shipped overseas to become another country’s problem.

Before solar waste becomes a major problem, the industry needs to better address the issue. Strategies include improving the design of panels to align with recycling capabilities as well as developing new recycling methods that can more efficiently extract and purify the valuable materials in the panels. Industry researchers are also looking into ways to repair and resell panels that are still in good condition and to repurpose old panels for less demanding functions like e-bike charging stations and housing complexes.

Like most things, solar panels do fail over time and with a rapidly growing number of them in the world, we need to figure out how to avoid them adding to the world’s problems.

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Web Links

Solar Panels Are Starting to Die. Will We be Able to Recycle the E-Waste?

Photo, posted January 6, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Concrete Production And Diminishing Coal Burning | Earth Wise

June 5, 2020 By EarthWise Leave a Comment

Coal burning is still one of the primary means of generating electricity in the United States, but its use is diminishing and doing so fairly rapidly. The coal burning process produces residual, incombustible materials. One of them is fly ash, which is composed of fine, glassy, rounded particles rich in silicon, aluminum, calcium, and iron oxides. Fly ash is captured from coal plant flue gas by precipitators and bag filters. It turns out that two-thirds of this fly ash is not dumped into landfills or impoundments, but rather is put to use.

Because of its chemical and physical characteristics, fly ash can substitute for a portion of portland cement in concrete. Using this byproduct material in making cement actually reduces its cost. Beyond cost, the addition of fly ash as a so-called supplementary cementitious material or SCM improves concrete’s long-term strength and reduces porosity and permeability. It reduces the risk of thermal cracking and provides good long-term mechanical properties.

The amount of fly ash used in concrete products increased by 5% between 2011 and 2017 while the amount produced dropped by 36%. Concrete production continues to increase steadily while fly ash production is steadily dropping.

Therefore, the concrete industry is looking for alternative sources of SCM. The most obvious is the approximately 1/3 of fly ash that hasn’t been used to make concrete. Much of that is landfilled or ponded onsite at power plants. So, opportunities exist for excavating or dredging and recovering these materials.

As coal burning goes away, concrete manufacturing needs to make some changes.

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Web Links

What Does the Changing Face of Electricity Production Mean for Concrete?

Photo, posted February 16, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Another Way To Make Solar Cells

March 21, 2019 By EarthWise Leave a Comment

Millions of rooftops now contain solar panels and the majority of the solar cells that make up those panels today are made from silicon. Silicon solar cells require expensive, multi-step processing conducted at very high temperatures in special clean room facilities. Despite these complications, the price of solar panels has continued to drop dramatically over the years.

But even as the price of solar cells gets lower and lower, there are still widespread efforts to find even better ways to make them. One of those ways is with perovskite solar cells. Perovskites are materials with a characteristic crystal structure and are quite common in nature. Perovskites can be formed with a wide range of elements and can exhibit a variety of properties.

They were first used to make solar cells about 10 years ago and those first cells were unimpressive in most respects. However, there has been steady progress since that time. The potential advantages of perovskite solar cells are that they can be made from low-cost materials and can be manufactured using liquid chemistry, a far cheaper process than what is used to make silicon cells.

Researchers at MIT and several other institutions have recently published the results of research on how to tailor the composition of perovskite solar cells to optimize their properties. What used to be a trial-and-error process can now become much more engineered and should lead to perovskite solar cells with performance that could exceed that of silicon cells.

Silicon solar panels are a huge, worldwide industry and displacing them in favor of an alternative technology is a tall order. But if perovskite cells can be optimized for large-scale manufacturability, efficiency and durability, they could definitely give silicon a run for its money.

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