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Better Zinc Batteries | Earth Wise

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The rapid growth of wind and solar power continues to drive a global quest for new battery technologies that can be used to store the energy generated by these sources when the sun isn’t shining, and the wind isn’t blowing.

For the most part, current battery energy storage systems use lithium-ion batteries – the same sort of batteries found in cellphones and electric vehicles.  There are many other battery chemistries, but they mostly have shortcomings in performance, economy, or longevity. 

Batteries store electricity in the form of chemical energy and chemical reactions convert that energy into electrical energy. Every battery has two electrodes:  the anode, from which electrons flow into external circuits, and the cathode, which receives electrons from the external circuit.  The electrolyte is the chemical medium through which the electrons flow.

One technology that has great potential is zinc-based batteries.  Zinc itself is a metal that is safe and abundant.  Batteries based on it are energy dense. However, zinc batteries have faced the challenge of having a short cycle life.  The batteries end up plating zinc on their anodes and battery performance degrades. 

A team of researchers at Oregon State University and three other universities have recently developed a new electrolyte for zinc batteries that raises the efficiency of the zinc metal anode to nearly 100% – actually slightly better than lithium-ion batteries.

Zinc batteries have a number of potential advantages over lithium-ion.  The new hybrid electrolyte developed by the researchers is non-flammable, cost-effective, and has low environmental impact.  Lithium-ion batteries rely on the supplies of relatively rare metals that are often difficult and environmentally harmful to obtain. 

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Researchers develop electrolyte enabling high efficiency of safe, sustainable zinc batteries

Photo, posted May 13, 2017, courtesy of Jeanne Menjoulet via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Distributed Wind Energy | Earth Wise

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When we think about wind power, we are usually talking about increasingly giant windfarms – either on land or offshore – that produce power on a utility scale.  But there is also distributed wind energy, which refers to wind technologies in locations that directly support individuals, communities, and businesses.  

Distributed wind can be so-called behind-the-meter applications that directly offset retail electricity usage much as rooftop solar installations do.  It can also be front-of-the-meter applications where the wind turbines are connected to the electricity distribution system and supplies energy on a community scale.  Distributed wind installations can range from a several-hundred-watt little turbine that powers telecommunications equipment to a 10-megawatt community-scale energy facility. As of 2020, there were nearly 90,000 distributed wind turbines in the U.S. with a total capacity of about 1 GW.

A study by the National Renewable Energy Laboratory has estimated the potential for distributed wind energy in the U.S.   According to the new analysis, the country has the ability to profitably provide nearly 1,400 GW of distributed wind energy capacity. 

Entire regions of the country have abundant potential. The regions with the best economic prospects have a combination of high-quality wind, relatively high electricity rates, and good siting availability.  Overall, the Midwest and Heartland regions had the highest potential especially within agricultural land.

Realizing this outcome for distributed wind will require improved financing and performance to lower costs, relaxation of siting requirement to open up more land for wind development, and continued investment tax credits and the use of net metering.

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U.S. has potential for 1,400 GW distributed wind energy, NREL finds

Photo, posted January 3, 2009, courtesy of skyseeker via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Colorful Solar Panels | Earth Wise

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More and more buildings and public spaces are incorporating solar panels and not only just on rooftops.  Some buildings are incorporating power-generating structures all over their facades.

Using solar panels in this way puts some design constraints on buildings because solar panels are typically a deep black color.  This is because solar panels need to absorb light and making them any other color decreases their ability to do so and generate power.  But the problem is that people don’t necessarily want a black building.

One alternative to traditional solar panel design is to use structural sources of color that include microscopic shapes that only reflect specific light frequencies, like the scales on butterfly wings.  But this approach generally leads to iridescence – which might not be what is wanted – and is often quite expensive to implement.

A team of researchers at a university in Shanghai has now demonstrated a way to give solar panels color that is easy and inexpensive to apply and that does not reduce their ability to produce energy efficiently.

The technique involves spraying a thin layer of a material called a photonic glass onto the surface of solar cells.  The photonic glass is made of a thin, disorderly layer of dielectric microscopic zinc sulfide spheres.  Even though most light can pass through the photonic glass, certain colors are reflected back, depending on the sizes of the spheres.  By varying that size, the researchers created solar panels that were blue, green, or purple with only a very small drop in solar panel efficiency.

The solar panels made this way maintained their color and performance under durability testing.  With this new technology, there may soon be colorful solar panels on our buildings.

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Colorful solar panels could make the technology more attractive

Photo, posted December 15, 2021, courtesy of Pete via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A New “Wonder Material” | Earth Wise

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Graphene is a form of carbon made of single-atom-thick layers. It has many remarkable properties and researchers around the world continue to investigate its use in multiple applications.

In 2019, a new material composed of single-atom-thick layers was produced for the first time.  It is phosphorene nanoribbons or PNRs, which are ribbon-like strands of two-dimensional phosphorous.  These materials are tiny ribbons that can be a single atomic layer thick and less than 100 atoms wide but millions of atoms long.  They are comparable in aspect ratio to the cables that span the Golden Gate Bridge.   Theoretical studies have predicted how PNR properties could benefit all sorts of devices, including batteries, biomedical sensors, thermoelectric devices, nanoelectronics, and quantum computers. 

As an example, nanoribbons have great potential to create faster-charging batteries because they can hold more ions than can be stored in conventional battery materials.

Recently, for the first time, a team of researchers led by Imperial College London and University College London researchers has used PNRs to significantly improve the efficiency of a device.  The device is a new kind of solar cell, and it represents the first demonstration that this new wonder material might actually live up to its hype.

The researchers incorporated PNRs into solar cells made from perovskites.  The resultant devices had an efficiency above 21%, which is comparable to traditional silicon solar cells.  Apart from the measured results, the team was able to experimentally verify the mechanism by which the PNRs enhanced the improved efficiency.

Further studies using PNRs in devices will allow researchers to discover more mechanisms for how they can improve performance.

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‘Wonder material’ phosphorene nanoribbons live up to hype in first demonstration

Photo, posted October 6, 2010, courtesy of Alexander AlUS / CORE-Materials via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Smart Roof | Earth Wise

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Scientists at the Lawrence Berkeley Laboratory have developed an all-season smart roof coating that can keep homes warm during the winter and cool during the summer, and the coating does not consume any gas or electricity.

Existing cool roof systems consist of reflective coatings, membranes, shingles, or tile that lower house temperatures by reflecting sunlight as well as emitting some of the absorbed solar heat away from the roof as infrared radiation.  The problem with such systems is that they continue to radiate heat during the winter, which actually drives up heating costs.

The new material is called a temperature-adaptive radiative coating or TARC.  It enables energy savings by automatically turning off the radiative cooling in the winter.  TARC reflects about 75% of sunlight year-round, but its thermal emittance is high when the temperature is warm – promoting heat loss to the sky – but decreases in cooler weather, helping to retain the heat in a building.

The researchers produced thin-film TARC material that looks like Scotch tape that could be affixed to a surface like a rooftop.  They applied the material to a balcony alongside a sample of commercial dark roof material and a sample of commercial white roof material.

In experiments simulating 15 different climate zones across the US, they found that the TARC material outperforms existing roof coatings for energy savings in 12 out of the 15 zones, particularly in regions with wide temperature variations between day and night, such as in the San Francisco Bay Area, or between winter and summer, such as New York City.

The researchers believe that installing TARC coatings on roofs would save the average U.S. household about 10% in utility costs.

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New Smart-Roof Coating Enables Year-Round Energy Savings

Photo, posted May 18, 2017, courtesy of Damian Gadal via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Batteries On Wheels | Earth Wise

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Transportation accounts for nearly a quarter of the direct carbon dioxide emissions coming from burning fuel.  As a result, electrification of transport is one of the major ways we can reduce emissions.  Increasing the number of electric vehicles over time is essential for meeting emissions targets.

But electric vehicles have the potential to do more than deliver emissions reduction; they can also provide other energy services.

More and more electric cars provide over 200 miles of driving range, but most cars are actually driven no more than 30 miles a day.  As a result, the fleet of electric cars represents a huge bank of energy stored in battery packs and mostly sitting around unused.  This presents an opportunity to leverage this resource.

Car battery packs could be used to absorb excess renewable energy generated in the middle of the day (for example from solar installations) or at night (from wind farms) and potentially then to export stored energy to power homes and support the grid.  This energy system is known as V2G, or vehicle-to-grid technology.

The University of Queensland in Australia has launched a unique international trial to see if the spare battery capacity in vehicles could be used for these purposes.  The university has partnered with Teslascope, which is an online analytics platform used by Tesla owners to track the performance of their cars.  Tesla owners wishing to be part of the study authorize the collection of their data and, in turn, receive a free 12-month subscription to the Teslascope service.  The study will collect data from Tesla owners in Australia, the US, Canada, Norway, Sweden, Germany, and the UK.

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Can EV spare battery capacity support the grid?

Photo, posted February 8, 2009, courtesy of City of St Pete via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Grid-Scale Battery Storage is on the Rise | Earth Wise

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Driven by steeply falling prices and improving technology, grid-scale battery storage systems are seeing record growth in the U.S. and around the world. Battery storage is a way to overcome one of the biggest obstacles to renewable energy:  the cycling between oversupply when the sun shines or the wind blows, and shortage when the sun sets or the wind drops.  Storing excess energy in battery banks can smooth imbalances between supply and demand.

In California, a 300-megawatt lithium-ion battery plant is being readied for operation with another 100 megawatts to come online in 2021.  The system will be able to power roughly 300,000 California homes for four-hour periods when energy demand outstrips supply.  It will be the world’s largest battery system for a while until even larger systems in Florida and in Saudi Arabia come online.

Nationwide, a record 1.2 gigawatts of storage were installed last year and that number is projected to jump dramatically over the next five years to nearly 7.5 gigawatts in 2025.

The price tag for utility-scale battery storage in the U.S. has plummeted, dropping nearly 70% just between 2015 and 2018.  Prices are expected to drop by a further 45% over the next decade.  Battery performance has continued to improve dramatically with increased power capacity and the ability to store and discharge energy over ever-longer periods of time. 

Favorable energy policies including renewable energy mandates coupled with continued price drops will drive the widespread expansion of battery energy storage.

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In Boost for Renewables, Grid-Scale Battery Storage Is on the Rise

Photo, posted November 17, 2016, courtesy of Steve Ryan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Better Paint For Cooler Buildings | Earth Wise

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A research team led by scientists at UCLA have developed a super-white paint that reflects as much as 98% of incoming heat from the sun.  Such paint, if used on rooftops and other parts of buildings, could have a major impact on reducing the costs of keeping buildings cool.

Passive daytime radiative cooling is a well-known method to keep buildings cooler.  By having building surfaces reflect sunlight and radiate heat into space, building temperatures can be significantly lowered.  This in turn cuts down on air conditioner use and associated carbon emissions.

A roof painted white will result in lower indoor temperatures than a darker roof.  But a white roof will do even more:  it can reject heat at infrared wavelengths that are invisible to our eyes.  This results in even more radiative cooling.

The best performing white paints currently available reflect about 85% of incoming solar radiation.  The rest is absorbed by materials in the paint.  The new research has identified simple modifications in paint ingredients that lead to a major increase in reflectivity.

Current reflective white paints use titanium dioxide, which absorbs UV radiation and therefore heats up under sunlight.  The researchers studied replacing it with other substances such as barite – an artist’s pigment – or with powdered Teflon, both of which allow the paint to reflect more of the sun’s radiation. 

Many cities are encouraging the use of cool-roof technologies on new buildings.  Using the most reflective coatings possible on rooftops, if applied on a sufficiently large scale, could have a real impact on climate change as well as saving significant amounts of energy used for running air conditioners in buildings.

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UCLA-led Team Develops Ways to Keep Buildings Cool with Improved Super White Paints

Photo, posted August 15, 2012, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Second Life For Electric Car Batteries | Earth Wise

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The number of electric cars around the world is growing steadily.  Battery technology continues to improve and the battery packs in the cars can have a long life.  Generally, the batteries are considered to require replacement only when their range has dropped below 80% of its original value.  Many are warranted to last for 8 to 10 years or more than 100,000 miles.  Some seem to do much better than that.

But however long it takes, there will eventually be a wave of used batteries whose performance is no longer deemed sufficient for vehicle use.  A new study, published in the journal Applied Energy, looked at the application of used vehicle batteries as backup storage for grid-scale solar photovoltaic installations where they could perform for more than a decade in this less demanding role.

The study looked at the economics of several scenarios including running a solar farm with no battery back up, running the same farm with brand-new batteries, and running the farm with a battery array made of repurposed vehicle batteries.

They found that the used EV battery array, if managed properly, could be a good, profitable investment provided that the batteries cost less than 60% of their original price.  They looked at the technical issues of screening batteries and combining batteries from different cars to work together.  They also looked at the economics of removing batteries from cars, collecting them, checking them over, and repackaging them.

Overall, they found that reusing vehicle batteries could ultimately meet half the forecasted demand for renewable energy backup storage over the next 10 years and would be both a technical and an economic success story.

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Solar energy farms could offer second life for electric vehicle batteries

Photo, posted June 10, 2011, courtesy of Nick Ares via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Strategies To Promote Green Products | Earth Wise

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Green products are environmentally-friendly products with features that are less harmful to people and the planet.  For instance, green products may require fewer resources to produce, consume less energy, contain non-toxic ingredients, or create fewer emissions.  Some examples include biodegradable waste bags, LED light bulbs, low-flow shower heads, organic cotton clothing, and reusable coffee cups and water bottles.  

But according to new research from two universities in the United Kingdom, companies looking to promote their latest environmentally-friendly product should actually downplay its greenness if they want consumers to buy it.

The study, by researchers from the University of East Anglia and the University of Leeds, found advertising that highlights a product’s green attributes can lead consumers to associate it with weak performance.  The findings, which were recently published in the Journal of Advertising, indicate that companies should downplay a product’s green qualities and instead promote it on more traditional aspects.

An example of these two distinct advertising strategies – green emphasis versus green understatement – can be found in the auto industry.  Car manufacturer Toyota prominently highlights the low emissions and low fuel consumption features of the Prius, employing what the researchers term as ‘explicit signals’.  In contrast, automaker Tesla reduces the prominence of its green attributes, focusing instead on its cars’ acceleration, handling, and other performance-related characteristics.  This is known as the ‘implicit signals’ marketing approach.

After conducting two experiments, the research team found that the implicit, rather than explicit, marketing approach about greenness leads to higher performance evaluations and purchase intent.

Consumers appear more likely to engage in pro-social actions when it’s accompanied by some form of personal benefit. 

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Highlighting product greenness may put consumers off buying

Photo, posted December 21, 2019, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

New Membranes For Carbon Capture

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Drastically reducing the amount of carbon dioxide being emitted into the atmosphere is an essential goal in the effort to mitigate the effects of climate change.  While the ultimate solution is to avoid combustion of fossil fuels by the use of clean alternative energy sources, that transition will take time – possibly more time than we have.  As a result, there is a great deal of effort underway to develop techniques for capturing the carbon emitted by fossil fuel combustion and either recycling it or storing it.

There are multiple ways to capture carbon emissions, but the ultimate goal is to find a technique that is both inexpensive and scalable.  One promising technique involves the use of high-performance membranes, which are filters that can specifically pick out CO2 from a mix of gases, such as those coming out of a factory smokestack.

Scientists at a Swiss laboratory have now developed a new class of high-performance membranes that exceeds the targeted performance for carbon capture by a significant margin.  The membranes are based on single-layer graphene with a selective layer thinner than 20 nanometers – only about 40 atoms thick. The membranes are highly tunable in terms of chemistry, meaning that they can be designed to capture specific molecules.

The membranes are highly permeable – meaning that they don’t impede gas flow too much – but highly selective.  The CO2/N2 separation factor is 22.5, which means that 22.5 times more nitrogen can get through the membrane than carbon dioxide.

The work is just at the laboratory stage at this point, but it is a very promising step towards developing a practical scheme for keeping carbon dioxide from escaping from power-plant and factory smokestacks.

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Next-gen membranes for carbon capture

Photo, posted December 28, 2010, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Another Way To Make Solar Cells

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Millions of rooftops now contain solar panels and the majority of the solar cells that make up those panels today are made from silicon.  Silicon solar cells require expensive, multi-step processing conducted at very high temperatures in special clean room facilities.  Despite these complications, the price of solar panels has continued to drop dramatically over the years.

But even as the price of solar cells gets lower and lower, there are still widespread efforts to find even better ways to make them.   One of those ways is with perovskite solar cells.  Perovskites are materials with a characteristic crystal structure and are quite common in nature.  Perovskites can be formed with a wide range of elements and can exhibit a variety of properties.

They were first used to make solar cells about 10 years ago and those first cells were unimpressive in most respects.  However, there has been steady progress since that time.  The potential advantages of perovskite solar cells are that they can be made from low-cost materials and can be manufactured using liquid chemistry, a far cheaper process than what is used to make silicon cells.

Researchers at MIT and several other institutions have recently published the results of research on how to tailor the composition of perovskite solar cells to optimize their properties.   What used to be a trial-and-error process can now become much more engineered and should lead to perovskite solar cells with performance that could exceed that of silicon cells.

Silicon solar panels are a huge, worldwide industry and displacing them in favor of an alternative technology is a tall order.  But if perovskite cells can be optimized for large-scale manufacturability, efficiency and durability, they could definitely give silicon a run for its money.

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Unleashing perovskites’ potential for solar cells

Photo courtesy of Ken Richardson/MIT.

Earth Wise is a production of WAMC Northeast Public Radio.

More Renewables Without Storage In Texas

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Texas has a Texas-sized appetite for electricity and relies most heavily on natural gas, coal and nuclear power to get it.  But in recent times, wind power has grown tremendously in the Lone Star State and it has already leapfrogged past nuclear power.  Coal could be the next domino to fall.

In the past few years, solar power has become competitive with wind in terms of price.  Texas is a large, coastal state in the sunny southwestern U.S. and has significant solar resources.  As a result, the amount of solar power in Texas is now growing rapidly.

In order for a combination of solar and wind power to address the bulk of electricity demand in Texas, there needs to be a way to provide reliability that these intermittent sources don’t necessarily provide.  Energy storage is a solution that ultimately is likely to be part of most electricity grids, but currently it is still expensive on a utility scale.

A new study from Rice University looked at the complementarity of solar and wind power in Texas.  Complementarity refers to balancing the output of solar and wind systems.  The peak performance of wind and solar occurs at very different times in different regions of the state.  The study suggests that the right mix of solar and wind systems in the right parts of Texas could provide a continuously reliable energy system.  On both a yearly and daily basis, wind and solar power resources in Texas complement each other in terms of peak performance.  It is a matter of locating the solar power and wind farms in the right places.

With the Texas solar industry really starting to boom, there is a real opportunity to integrate far more renewable energy into the Texas grid.

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More Renewables with Less Energy Storage: Texas Shows How

Photo, posted June 8, 2018, courtesy of Laura Lee Dooley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Battery That Eats Carbon Dioxide

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Fossil fuel-based power plants are increasingly considering the use of carbon capture technologies as a way to reduce emissions.  The biggest challenge to the wide-spread adoption of such technology is its energy cost, which of course equates to economic cost.  Present-day power plants equipped with carbon capture systems can use up to 30% of the electricity they generate just to power the capture, release, and storage of carbon dioxide.

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Using The Sun To Remove Ice

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Ice buildup can cause all sorts of problems ranging from performance issues to catastrophic failures.  For example, ice buildup can negatively impact things like airplanes, power lines, wind turbines, and the like.  Preventing this ice buildup typically requires energy-intensive heating systems or environmentally-harmful chemical sprays.

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Bacteria-Powered Solar Cell

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Commercially-available solar panels are composed of solar cells that are most often made from various forms of silicon.  Some panels use thin-film cells made from other semiconductor materials.  Solar cells utilize a property of semiconductors that allows them to convert light energy into electrical energy.

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Advantages Of Plug-In Hybrids

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Plug-in hybrid vehicles are ones that can run both on electricity provided by a power outlet as well as on gasoline.  There are many of them on the market these days built by quite a few car makers.  But these vehicles have an undeserved reputation as being the fig leaf of electric mobility.  Many environmental organizations and political decision-makers don’t consider them to be “real electric cars.”

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Delivery By Fuel Cell

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UPS recently announced a demonstration project that will put a prototype electric truck powered by a hydrogen fuel cell through the delivery company’s challenging paces.   Fuel cells have been used in some commercial vehicles to power auxiliary systems, but this is the first time that they will be used to propel a vehicle.

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