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An eco-friendly detergent

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Household products such as laundry detergents and dishwasher tablets are an indispensable part of everyday life, but such products contain all sorts of chemicals that have undesirable properties.  Many are difficult to break down when they enter the environment, and some add nutrients that trigger environmentally harmful algal blooms.   The ingredient lists for even what are described as environmentally friendly cleansing products can be filled with lots of polysyllabic chemicals with unknown potential impacts.  Detergents made from harmless stuff are often difficult to make, hard to rinse off, and sometimes potentially damaging to fabrics.

Researchers at Tianjin University in China have developed an environmentally friendly detergent made of tiny wood fibers and corn protein that removes stains from clothes and dishes as well as commercial products.

The researchers combined cellulose nanofibers from wood with zein protein, which is taken from corn, to produce an emulsion.  The cellulose can attract and repel water and can form emulsions and attract various kinds of stains.  The zein protein helps to stabilize the emulsion and trap oils.

They tested the new detergent by cleaning cotton cloth and dishes stained with ink, chili oil, and tomato paste.  They compared the results against commercial laundry detergent and dish soap.  Their new detergent was somewhat less effective than the commercial products when used at 1% concentration but was more effective when used at a 5% concentration. 

The results suggest that this natural detergent could be an efficient, cost-effective, and sustainable alternative to the synthetic cleaning agents that currently dominate the market.

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Researchers create eco-friendly detergent from wood fiber and corn protein

Photo, posted July 31, 2009, courtesy of Mei Anne Mendoza via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Are today’s refrigerants safe?

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Refrigeration is based on heat transfer mediums that absorb heat from the area being cooled and transfer it to the outside environment.

The earliest refrigerants were dangerous substances like ammonia.  In the 1930s, chlorofluorocarbons (CFCs) like Freon became the standard refrigerant for use in refrigeration systems and even in aerosol cans.  When these substances were found to be depleting the earth’s ozone layer, the Montreal Protocol dictated their phaseout and by the mid-1990s, CFCs were largely replaced by hydrofluorocarbons (HFCs).

HFCs don’t deplete the ozone layer, but they were eventually determined to be potent greenhouse gases, thousands of times more planet-warming than carbon dioxide.   As a result, the global phaseout of HFCs began in 2016, and have been increasingly replaced by hydrofluoroolefins (HFOs), which are considered a more environmentally-friendly alternative to all their predecessors.

Trying to not be surprised by additional unpleasant discoveries about refrigerants, researchers are studying the potential environmental impacts of HFOs.  Researchers at the University of New South Wales in Australia have found that HFOs can break down in the atmosphere and that some small amounts of the resultant products are in fact fluoroforms, which are the HFC with the greatest global warming potential and can stay in the atmosphere for up to 200 years.

That only a small amount of HFC gets into the atmosphere is good, but nevertheless it reveals that the consequences of replacing widely-used chemicals are not a simple matter to determine.

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Are our refrigerants safe? The lingering questions about the chemicals keeping us cool

Photo, posted July 19, 2021, courtesy of Vernon Air Conditioning via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fertilizer from thin air

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Ammonia is one of the largest-volume synthetic chemicals produced in the world. Globally, manufacturing plants produce about 200 million tons of it each year.  About 70% of ammonia is used to produce fertilizers.

Most ammonia is produced using the Haber-Bosch process, which converts hydrogen and nitrogen into ammonia.  The process is energy-hungry, running at over 900 degrees Fahrenheit, and therefore results in lots of greenhouse gas emissions – about 1% of the world’s annual CO2 emissions.

Researchers at Stanford University and King Fahd University in Saudi Arabia have developed a prototype device that can produce ammonia using wind energy to draw air through a mesh.  The method allows sustainable production of ammonia using the nitrogen in the air.

The process gets nitrogen from the air along with hydrogen from water vapor.  A mesh coated with catalysts facilitates the necessary chemical reactions.  The process operates at room temperature and standard atmospheric pressure, eliminating the need  for the high temperatures and high pressures of the Haber-Bosch process.

In principle, farmers could run a portable device onsite, eliminating the need to purchase and ship fertilizer from a manufacturer. 

The device is two or three years away from being market ready.  The developers are designing increasingly large mesh systems to produce greater quantities of ammonia.  Ammonia has more uses beyond fertilizers including its use as an energy carrier that can store and transport energy more efficiently than hydrogen gas.

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New device produces critical fertilizer ingredient from thin air, cutting carbon emissions

Photo, posted September 2, 2013, courtesy of Chafer Machinery via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Thermal batteries for heavy industry

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Heavy industries like cement, steel, chemicals, and paper require large amounts of heat and, for the most part, that heat comes from burning fossil fuels.  Other sectors of the economy have been making progress in reducing carbon emissions, but heavy industry has not found easy answers for supplying the heat it needs for manufacturing.

Researchers at MIT have developed a way to supply heat that only uses electricity, which in principle can come from carbon-free sources.  The idea is to use thermal batteries.  These are basically an electrically conductive equivalent of ceramic firebricks, which have been used to store heat for centuries in fireplaces and ovens.

A spinout company called Electrified Thermal Solutions has demonstrated that its firebricks can store heat efficiently for hours and release it by heating air or gas up to 3,272 degrees Fahrenheit. 

The firebrick arrays are contained in insulated, off-the-shelf metal boxes.  The standard system can collect and release about 5 megawatts of energy and store about 25 megawatt-hours.  The thermal battery can run hotter and last longer than any other electric heating solution on the market.

Using this technology can be a way to take advantage of the low cost of electricity in off-peak hours.  In the so-called wind belt in the middle of the U.S., electricity prices can even be negative at times.  Using the firebrick technology – called the Joule Hive Thermal Battery – it can be possible to provide industrial heating capability at very competitive prices, and that doesn’t even factor in the positive climate impact.

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Decarbonizing heavy industry with thermal batteries

Photo, posted April 19, 2019, courtesy of Hans M. via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Politics and plastic

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The world currently produces nearly half a billion tons of plastic each year.  This is more than twice the amount it produced 20 years ago.  Half of all plastics ever manufactured have been made in the past 20 years.  Plastic waste is everywhere.  About eight million tons of plastic waste escapes into the ocean each year.

Environmental groups have urged nations to adopt a legally binding treaty to address the ever-growing problem of plastic pollution. The United Nations climate conference in South Korea last month took up the issue of reaching agreement on such a treaty.  At what was supposed to be the final round of talks on the topic, delegates could not bridge wide differences on what such a treaty should contain.

The main bone of contention was whether the treaty should include limits on plastic production itself.  Saudi Arabia, Russia, Kuwait, and other oil-producing countries opposed any curbs on plastic production.   They also opposed the phase-out of harmful chemicals used in the production of plastic.

The Saudi delegation claimed that if the issue of plastic pollution is addressed, there should be no problem with producing plastics.  They said the problem is pollution itself, not plastics.  They proposed a focus on improving recycling and waste management.

Of course, preventing plastic pollution from occurring is an extremely challenging thing to do.  Delegates from countries pushing for a wide-ranging treaty – led by Rwanda – were unwilling to accept a toothless theory lacking real constraints on the plastics industry.

As the conference ended, delegates said that they would reconvene in future months to try again to produce a treaty.  No date or place has been announced.

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Nations Fail to Reach an Agreement on Plastic Pollution

Photo, posted February 4, 2023, courtesy of Ingrid Taylar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

PFAS and groundwater

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Per- and polyfluoroalkyl chemicals, more commonly known as PFAS, are a family of human-made chemicals that have been manufactured and used in a variety of industries since the 1940s.  They provide water-resistance, oil-resistance, dirt-resistance, and corrosion-resistance to a wide range of products, including food wrappers and packaging, clothing, dental floss, nonstick cookware, textiles, and electronics.

Exposure to PFAS has been linked to birth defects, thyroid disease, liver disease, kidney disease, and cancer.  These chemicals do not break down in the environment and therefore, over time, become concentrated in plants, animals, and people. 

According to a new first-of-its kind study by scientists at the U.S. Geological Survey, more than 20% of the U.S. population could be drinking groundwater contaminated with PFAS.  The study, which was recently published in the journal Science, found that those living in the Eastern U.S. are particularly likely to be exposed.

The study is the first to report national estimates of PFAS in untreated groundwater that supplies drinking water to private and public wells. The USGS research also provides the first estimate of the total number of Americans – anywhere from 71 to 95 million – who might be exposed to this contamination.

The researchers note that their estimates merely measure the existence of PFAS – before the water has undergone any treatment or filtering – meaning that, while they may be present, they may be at very low levels. 

To find a link to the detailed USGS map showing the probability of PFAS groundwater contamination in your region, visit our website: EarthWiseRadio.org.

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PFAS in US Groundwater Interactive Dashboard

Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

Photo, posted January 12, 2008, courtesy of Andrew Kraker via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fertilizers from wastewater sludge

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Sewage sludge is the mud-like residue that is produced as a byproduct during wastewater treatment.  In the U.S., sewage sludge is referred to as biosolids after it’s been treated.  The term is meant to distinguish the higher quality, treated sludge from raw sludge and from sludge that contains large quantities of environmental pollutants. 

However, according to a new study by researchers from Johns Hopkins University, fertilizers manufactured from the sludgy leftovers of wastewater treatment processes can still contain traces of potentially hazardous organic chemicals.

The research, which was recently published in the journal Environmental Science & Technology, provides one of the most comprehensive looks at the chemical composition of biosolids across the country. 

Biosolids do contain valuable organic matter and nutrients, including nitrogen and phosphorus.  According to the U.S. Environmental Protection Agency, more than half of the 3.76 million tons of biosolids produced in the U.S. in 2022 fertilized agricultural lands, golf courses, and other landscaped areas.

In the study, the research team screened 16 samples of biosolids from wastewater treatment facilities in nine U.S. and three Canadian cities. The researchers then created lists of the chemicals found in each sample.  They found 92 common compounds that were present in 80% or more of the samples.  The researchers cross-referenced those 92 compounds against the EPA’s CompTox Chemical Dashboard to identify which chemicals were most likely to pose threats to human health or the environment.

The findings could help the EPA identify which organic compounds to investigate further and which chemical contaminants may need government regulation. 

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Team Aims to Improve Safety of Fertilizers Made from Wastewater Sludge

Photo, posted November 2, 2011, courtesy of Susana Secretariat via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Biofuel refineries and toxic pollution

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There have been decades of government support for renewable, crop-based fuels – primarily corn ethanol.  In fact, it is a required component of gasoline sold in this country.  The biofuels industry has long claimed ethanol to be a clean, greener alternative to petroleum. 

There have been arguments all along that the environmental benefits of corn ethanol are dubious at best because of the energy required to produce the stuff.  There are also issues related to burning a food crop instead of feeding it to people and that the conversion of grasslands and forests to produce it releases massive amounts of carbon.

Recently, another serious concern has emerged.  A new review of industry data has found that the country’s biofuel refineries, mostly located in the Midwest, produce large amounts of toxic air pollutants, in some cases ever more than from their petroleum counterparts.

Emissions data from the country’s 275 ethanol, biodiesel, and renewable diesel plants revealed that they release carcinogenic formaldehyde as well as other potentially dangerous substances including acetaldehyde, hexane, and acrolein.  In 2022, biofuel refineries released 12.9 million pounds of hazardous air pollutants, compared to 14.9 million pounds emitted by oil refineries, and the biofuel plants actually emitted more of the four chemicals just mentioned than petroleum refineries did.

The broad use of crop ethanol is the result of intensive industry lobbying.  Ethanol plants are even exempt from some air pollution permitting requirements.  Perhaps the time has come to revisit its pervasive and mandated use.

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Biofuel Refineries Are Releasing Toxic Air Pollutants in Farm Communities Across the US

Photo, posted February 27, 2021, courtesy of Sue Thompson via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Forever chemicals in water

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So-called forever chemicals are pervasive in a wide range of products.  These are man-made substances called per- and polyfluoroalkyls or PFAS.  They get their unfortunate nickname because the chemical bonds in them are so strong that the compounds don’t break down for hundreds or even thousands of years.

PFAS compounds are used in makeup, dental floss, nonstick pans, food wrappers, pesticides, stain-resistant fabrics and carpets, firefighting foams, and more.  High level exposure to some of these chemicals has been linked to a variety of health problems include high cholesterol, liver and immune system damage, pregnancy problems, and kidney and testicular cancer.

A recent study published in the journal Nature Geoscience has found that PFAS chemicals are showing up in water around the world.  The study looked at more than 45,000 water samples and found that about 31% of ground water tested that wasn’t even near any obvious source of PFAS contamination had levels of the chemicals that are considered harmful to human health by the EPA.  About 16% of surface water samples – streams, rivers, ponds, and lakes – also not near any known source, had similar hazardous PFAS levels.

The EPA has now imposed strict new drinking water limits for six types of PFAS.  Going forward, water systems are required to monitor for these chemicals and remove them if they are found above allowable levels.  The new rules make the United States one of the strictest countries in the world in terms of regulating PFAS in water.

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EPA puts limits on ‘forever chemicals’ in drinking water

Photo, posted May 5, 2020, courtesy of Brandon Shaw via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pesticides and beeswax

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Honey bee colonies in the United States have experienced annual population declines since 2006.  Commercial beekeepers have reported honey bee colony loss rates averaging 30% each winter, which is startling when compared to historical loss rates of just 10-15%.  According to the USDA, there are many factors contributing to this decline, including parasites, pests, diseases, pesticides, and a phenomenon called Colony Collapse Disorder, in which worker bees abandon a hive and leave behind the queen.

According to a new study by researchers from Cornell University, beeswax in managed honey bee hives contains a variety of pesticide, herbicide, and fungicide residues.  Because bees reuse wax over years, these harmful chemicals can accumulate inside hives, exposing current and future generations of bees to long-term toxicity. 

The study, which was recently published in the Journal of Veterinary Diagnostic Investigation, adds that humans may also be exposed to these pesticides through contaminated honey, pollen, and beeswax (which is used in certain soaps, lotions, and cosmetics).  However, the amounts in these products are unlikely to pose a major threat to human health.

Pesticides get into the beeswax when bees feast on the nectar and pollen of plants that have been treated with the chemicals. According to the researchers, understanding which contaminants are impacting domestic honey bee populations could help better protect them and other pollinators, including birds, bats, wild bees, and other insects.

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Pesticides detected in beeswax

Photo, posted November 22, 2008, courtesy of Andrew Rivett via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Detecting dangerous chemicals with plants

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Researchers at University of California Riverside have been studying how to enable plants to sense and react to a chemical in the environment without damaging their ability to function in all other respects.  Why do this?  The idea is to be able to use plants as environmental sensors that can detect the presence of harmful substances.

The impetus for the work is presence of a protein in plants that senses a plant hormone called abscisic acid (or ABA) that helps plants acclimate to environmental changes.  During drought, plants produce ABA causing the plant to produce ABA receptor proteins that close pores in its leaves and stems, keeping in moisture.

The UCR researchers demonstrated that these ABA receptor proteins can be trained to bind to chemicals other than ABA.  This ability enabled them to create sensors for many chemicals, including banned pesticides.

In their recent publication, they demonstrated a green plant that turns bright red in the presence of azinphos-ethyl, a banned pesticide.  The goal is to easily detect chemicals in the environment from a distance.  A field of these plants would provide an obvious visual indicator of the use of a banned pesticide.  The researchers also demonstrated the ability to turn a variety of yeast into a sensor that could respond to two different chemicals at the same time.

Ultimately, it would be extremely valuable to design plants that sense dozens of chemicals to they could be used as living sensors that persist for years and provide environmental information.  The sensor plants are not being grown commercially at this time.  That will require regulatory approvals that are likely to take years.  But the discovery opens up real possibilities.

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Plants transformed into detectors of dangerous chemicals

Photo, posted August 29, 2013, courtesy of the United Soybean Board via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Hydrogen hubs

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The Infrastructure Investment and Jobs Act of 2021 earmarked $7 billion in federal funding aimed at accelerating the commercial-scale deployment of hydrogen as well as driving down its cost.  Clean hydrogen is considered to be a key technology for cleaning up hard-to-decarbonize industrial sectors like refining, chemicals, and heavy-duty transport. 

On October 13th, the Department of Energy named seven regional clean hydrogen hubs which will provide clean hydrogen production, storage, delivery, and end-use components.  The so-called H2Hubs are expected to collectively produce three million metric tons of hydrogen annually. 

One selected project is the Appalachian Hydrogen Hub that includes West Virginia, Ohio, Kentucky, and Pennsylvania.  Another is the California Hydrogen Hub, that will produce hydrogen exclusively from renewable energy and biomass.  Then there is the Gulf Coast Hydrogen Hub, centered in the Houston, Texas region.  A fourth hub is the Heartland Hydrogen Hub, which includes Minnesota, North Dakota, and South Dakota.  A fifth hub is the Mid-Atlantic Hydrogen Hub, that includes Pennsylvania, Delaware, and New Jersey.  The sixth is the Midwest Hydrogen Hub that includes Illinois, Indiana, and Michigan.  Finally, there is the Pacific Northwest Hydrogen Hub that includes Washington, Oregon, and Montana.

Each of these hubs involve multiple partner organizations in their regions and each has specific goals and strategies. The seven centers are located all around the country and are intended to jumpstart a national network of clean hydrogen producers, consumers, and connective infrastructure.

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Hydrogen hubs have arrived. Here are the big winners of the $7 billion sweepstakes

Photo, posted August 17, 2010, courtesy of David Stanley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pollution From Tires | Earth Wise

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A few years ago, researchers investigating massive deaths of coho salmon in West Coast streams discovered that the water contained particles from vehicle tires.  The cause of the fish mortality turned out to be a chemical called 6PPD that is added to tires to prevent cracking and degradation.  The mystery was solved, but so far, the chemical continues to be used by all major tire manufacturers and is found on roads and in waterways around the world.

Worse still, the acute toxicity of 6PPD and the chemicals that it transforms into when exposed to ground-level ozone is only the tip of the tire pollution iceberg.  Tire rubber contains more than 400 chemicals and compounds, many of which are carcinogenic. 

About 2 billion tires are sold across the globe each year and that number is expected to reach 3.4 billion by 2030.  Tires are made from about 20% natural rubber and 24% synthetic rubber, which requires about 4 gallons of petroleum per tire.  Hundreds of other ingredients – including steel, fillers, heavy metals like copper, cadmium, lead, and zinc – make up the rest.

Tire wear particles are emitted continually as vehicles travel.  They range in size from visible pieces of rubber or plastic to microparticles.  Research has shown that a car’s four tires collectively emit half a trillion ultrafine particles per mile driven.  These particles are small enough to be breathed into the lungs and can travel throughout the body and even cross the blood-brain barrier.  Particle pollution from tires exceeds that from tailpipes.

Tire pollution is a huge problem that is just starting to receive the attention it deserves.

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Road Hazard: Evidence Mounts on Toxic Pollution from Tires

Photo, posted June 22, 2018, courtesy of Tony Webster via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Paper Cups Are Not So Great | Earth Wise

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The environmental cost of plastic waste is a highly visible global issue.  The response has been a growing effort to replace plastic items with alternative materials.  One very visible change of this sort has been the replacement of plastic cups with paper cups at coffee shops.  But a new study at the University of Gothenburg in Sweden has found that this solution has problems of its own.

Researchers studied the effects of disposable cups in the environment on the larvae of the butterfly mosquito.  They placed disposable cups made from different materials in wet sediment and water for a few days and observed how the chemicals leached from the cups affected the growth of the larvae.  It turned out that all of the different kinds of cups had negative effects.  The concern is not specifically about mosquito larvae; it is the fact that more environmentally friendly drinking cups are still potentially harmful to living things.

Paper is neither fat nor water resistant, so paper cups need to be treated with a surface coating.  The most common coating is polylactide, which is a type of bioplastic.  It is generally considered to be biodegradable, but the study shows that it can still be toxic.  Bioplastics still contain many different chemicals and the potential toxicity of each of them is not well known.

The UN is trying to develop a binding agreement by the world’s countries to end the spread of plastics in society and nature.  For such an agreement to be effective, the plastics industry will need to clearly report what chemicals all products contain, including such mostly invisible products as the coating on paper drinking cups.

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Paper cups are just as toxic as plastic cups

Photo, posted October 23, 2016, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Better Plastic Recycling | Earth Wise

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Many of us are careful to put our plastic trash into the appropriate recycling bins hoping that we are helping to stem the global tide of plastic waste.  But many plastics are not recyclable at all and recycling those that are is not even always a good thing.  Breaking down plastics can generate polluting microplastics that are themselves a major environmental problem.  And perhaps the biggest problem for recycling efforts is that they are not cost effective and generally incur huge losses.

Chemical engineers at the University of Wisconsin-Madison recently published a study in the journal Nature outlining a new technique for turning low-value waste plastic into high-value industrial chemicals. 

The technique makes use of two existing chemical processing techniques.  The first is pyrolysis, which is high-temperature heating in an oxygen-free environment.  Heating waste plastic in this way produces pyrolysis oil, a liquid mix of various compounds that includes large amounts of olefins.  Olefins are simple hydrocarbons that are a central building block of many chemicals and polymers.  Olefins are most often produced by energy-intensive processes like steam cracking of petroleum. 

The UW-Madison process takes the olefins and subjects them to a process called homogenous hydroformylation catalysis, which converts them into aldehydes, which can then be further reduced into important industrial chemicals. 

The payoff is that the process can take waste plastics, which are only worth about $100 a ton, and turn them into high-value chemicals worth $1,200-$6,000 a ton.  If the process can be optimized and otherwise made ready for industrial-scale use, it would be a real game-changer in the battle against plastic waste.

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New recycling process could find markets for ‘junk’ plastic waste

Photo, posted September 16, 2015, courtesy of Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Decontaminating Drinking Water | Earth Wise

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At least two billion people around the world often drink water that is contaminated with disease-causing microbes.  Waterborne diseases are responsible for two million deaths each year, mostly among children under the age of five.

There are various ways to decontaminate water, including chemicals that can themselves produce toxic byproducts as well as using ultraviolet light, which takes fairly long to disinfect the water and requires a source of electricity. 

Scientists at Stanford University and the SLAC National Accelerator Laboratory have recently invented a low-cost, recyclable powder that kills thousands of waterborne bacteria every second when the water containing it is exposed to ordinary sunlight.  The discovery of this ultrafast disinfectant could be a tremendous benefit to the nearly 30% of the world’s population with no reliable access to safe drinking water.

The new disinfectant is a harmless metallic powder that works by absorbing both ultraviolet and high-energy visible light from the sun.  It consists of nano-sized flakes of aluminum oxide, molybdenum sulfide, copper, and iron oxide.  The key innovation is that when these four metallic ingredients are immersed in water, they all function together by reacting with the surrounding water and generating chemicals that quickly kill bacteria. The chemicals themselves don’t last long.  They quickly break down in the water leaving completely safe drinking water.

The nontoxic powder is recyclable.  It can be removed from water with a magnet.  It can also be reused at least 30 times.  Apart from its uses in less developed parts of the world, it could be valuable for hikers and backpackers who want to drink water from natural sources of unknown quality.

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New nontoxic powder uses sunlight to quickly disinfect contaminated drinking water

Photo, posted February 27, 2013, courtesy of Petras Gagilas via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

The Upper Atmosphere Is Cooling | Earth Wise

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The part of the atmosphere closest to the Earth’s surface has been warming since the Industrial Revolution.  This warming is associated with increasing amounts of carbon dioxide as well as other human-made chemicals that have been changing the makeup of the atmosphere. Climate change is generally thought about in terms of the lowest regions of the atmosphere – known as the troposphere – where our weather happens.

But climate models also predict that another result of the changes to the makeup of the atmosphere is that most of the atmosphere up higher will get dramatically colder.  The same gases that are warming the bottom few miles of air are cooling the much greater expanses above that extend to the edge of space.

Recent satellite data has confirmed the accuracy of these models and provide further confirmation of the human fingerprint of climate change. The natural variability of weather that complicates climate models does not play a role in the upper atmosphere.

In the higher levels of the atmosphere, the effects of increasing levels of carbon dioxide are quite different.  In the thinner air up there, the heat trapped and re-emitted by CO2 does not bump into other molecules creating warming.  Instead, it escapes to space.  Combined with the trapping of heat at lower levels, the result is a rapid cooling of the upper atmosphere.

There are potential problems associated with the cooling upper atmosphere including that it is contracting.  The result is that the crowd of manmade objects in low orbit remains there longer, and there is a potential increased degradation of the ozone layer. 

The changes we are making to the atmosphere are having significant effects from the surface of the earth to the edge of space.

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The Upper Atmosphere Is Cooling, Prompting New Climate Concerns

Photo, posted August 18, 2021, courtesy of Arek Socha via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pulling Carbon Dioxide Out Of Seawater | Earth Wise

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The world’s largest sink for carbon dioxide from the atmosphere is the ocean.  The world’s oceans soak up 30-40% of all the gas produced by human activities.  Dissolving carbon dioxide in water produces carbonic acid.   This is the reason that oceans are becoming increasingly acidic, which is causing serious damage to ocean ecosystems.

There are many efforts underway aimed at directly removing carbon dioxide from the air as a way to mitigate the effects of ongoing emissions.  But another possibility is to remove CO2 directly from ocean water.  Existing methods for doing it involve the use of expensive membranes and complex chemicals. The economics of such methods are quite unfavorable.

Recently, a team of researchers at MIT has identified what they claim is a truly efficient and inexpensive removal mechanism. It involves a reversible process based on membrane-free electrochemical cells.  Electrodes in the cells release protons that are introduced to seawater which drive the release of carbon dioxide dissolved in the water. The carbon dioxide can be collected and the processed water ends up being alkaline.

Running this process at a site that is already collecting seawater – such as at a desalination plant – would be an effective way to collect carbon dioxide as well as help mitigate ocean acidification.

Once the carbon dioxide is removed from the water, it still needs to be disposed of, just as is the case for other carbon removal processes.  It could be turned into useful chemicals or it could be stored in underground caverns.  But this approach is fairly unique in that the carbon dioxide has already been captured by the ocean.  The issue remains what to do with it.

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How to pull carbon dioxide out of seawater

Photo, posted January 19, 2016, courtesy of Judy Dean via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Spiders And Pest Control | Earth Wise

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Climate change facilitates the spread of invasive pest species by expanding their habitable environment ranges.  In conventional agriculture, farmers depend on chemical pesticides to control agricultural pests.  But 99% of all synthetic chemicals, including pesticides, are made from fossil fuels, and turning petrochemicals into pesticides requires massive amounts of energy.  These chemical pesticides also pollute the air and water, and destroy biodiversity by killing many non-target species as well.  

According to new research led by scientists from the University of Portsmouth in the U.K., groups of spiders could be used as an environmentally-friendly way to protect crops against agricultural pests.  The study, which was recently published in the journal Insects, suggests that web-building groups of spiders can be used to control populations of the tomato leafminer moth, a devastating pest of commercially important crops like tomatoes and potatoes.

The research team explored the use of tropical tent spiders for this pest control.  They are found in colonies around the world, and their range overlaps with regions of moth infestations, including Mediterranean Europe, Africa, Asia, and the Middle East.

In lab settings, different types of prey were introduced to colonies of spiders of varying body sizes.  The research team found that the larger spiders built larger webs and caught more prey, including tomato leafminer moths and fruit flies.   

Tropical tent spiders could be an effective and climate-friendly way to control flying insect pests.  However, more research is needed to ensure that these spiders don’t negatively impact crop pollination by also catching pollinators.

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Using spiders as environmentally-friendly pest control

Photo, posted June 10, 2018, courtesy of Lies Van Rompaey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Mosquito Magnets | Earth Wise

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We’ve all probably had the experience of being in the great outdoors with other people and having some of them being nearly devoured by mosquitoes while others didn’t get bitten at all.  It seemed like some people are mosquito magnets while others just aren’t the insects’ cup of tea, so to speak.

There have been various theories proposed over the years including such things as it being a question of blood type, or it having to do with how close one’s blood vessels are to their skin surface.

A new study by the Howard Hughes Medical Institute and the Rockefeller University has uncovered what appears to be the real explanation.  According to the paper published in the journal Cell, certain body odors are the deciding factor.  Every person has a unique scent profile associated with different chemicals present on their skin.  The researchers found that people whose skin produces high levels of carboxylic acids are the most attractive to mosquitos.

The researchers collected scent samples from participants by having them wear silk stockings on their arms for six hours.  The nylons were then cut into pieces and the pieces exposed to mosquitos.  After several months of head-to-head battles between various nylon samples, the study clearly demonstrated that the samples from subjects with higher levels of carboxylic acids in the skin were far more attractive to mosquitos.

Humans produce the substance at much higher levels than other animals.  There is little one can do about their own levels.  Changing one’s diet or what soap they use doesn’t seem to make a difference. 

Perhaps researchers can come up with some method of breaking down carboxylic acids in the skin in the future.  Until such time, there are really people who are mosquito magnets.

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Some People Really Are Mosquito Magnets, and They’re Stuck That Way

Photo, posted September 4, 2014, courtesy of James Gathany / Centers for Disease Control via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

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