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Turning Carbon Into Stone | Earth Wise

January 31, 2023 By EarthWise Leave a Comment

A start-up company in Oman called 44.01 was recently awarded a $1.2 million Earthshot Prize by Prince William of the U.K. The company, whose name corresponds to the molecular weight of carbon dioxide, is working on speeding up natural chemical reactions that take carbon from the air and lock it into solid mineral form.

The company’s location in Oman is no random occurrence. The mountains of northern Oman and along the coast of the United Arab Emirates are the site of a huge block of oceanic crust and upper mantle that was thrust upward some 96 million years ago. The tilted mass of rock is over 200 miles long and is the largest surface exposure of the Earth’s mantle in the world.

This type of rock, called peridotite, is rich in olivine and pyroxene, which react with water and carbon dioxide to form calcium-based minerals like serpentine and calcite that permanently lock in carbon. Other kinds of rock also are capable of carbon-storing mineralization, but this mantle rock is the most effective for the purpose. It only exists at the Earth’s surface in a few places, including Papua New Guinea and some spots in California and Oregon.

The 44.1 company is planning to use solar-powered direct air capture devices to remove CO₂ from the air, use it to produce carbonated water, and inject the water into the reactive rocks. The company will operate a couple of pilot systems during 2023. Ultimately, the company believes it can scale up the process to be able to permanently sequester as much as a billion tons of CO₂ a year by the year 2040 without needing to inject the gas into deep caverns or find other places to store it.

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With Major Prize, a Project to Turn Carbon Emissions to Stone Gains Momentum

Photo, posted August 10, 2018, courtesy of JM McBeth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fertilizing The Ocean | Earth Wise

January 23, 2023 By EarthWise Leave a Comment

There are a variety of schemes for removing carbon dioxide from the atmosphere. Some require advanced and generally not-very-well developed technology. Others, such as planting vast numbers of trees, are nature-based but are daunting with respect to the scale to which they need to take place in order to be truly effective.

Researchers at the Pacific Northwest National Laboratory in Richland, Washington have been examining the scientific evidence for seeding the oceans with iron-rich engineered fertilizer in order to feed phytoplankton. Phytoplankton are microscopic plants that are a key part of the ocean ecosystem.

Phytoplankton take up carbon dioxide as they grow. In nature, nutrients from the land end up in the ocean through rivers and from blowing dust. These nutrients fertilize the plankton. The idea is to augment these existing processes to increase the growth of phytoplankton. As they eventually die, they sink deep into the ocean, taking the excess carbon with them.

The researchers argue that engineered nanoparticles could provide highly controlled nutrition that is specifically tuned for different ocean environments. Surface coatings could help the particles attach to plankton. Some could be engineered with light-absorbing properties, allowing plankton to consume and use more carbon dioxide.

Analysis of over 100 published studies showed that numerous non-toxic, abundant, and easy-to-create metal-oxygen materials could safely enhance plankton growth. According to the researchers, the proposed fertilization would simply speed up a natural process that already sequesters carbon in a form that could remove it from the atmosphere for thousands of years. They argue that given the current trends in the climate, time is of the essence for taking action.

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Fertilizing the Ocean to Store Carbon Dioxide

Photo, posted August 2, 2007, courtesy of Kevin McCarthy via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Better Way To Capture Carbon | Earth Wise

April 29, 2022 By EarthWise Leave a Comment

The goal of carbon capture and storage technology is to remove carbon dioxide from the atmosphere and safely store it for the indefinite future. There are existing industrial facilities that capture carbon dioxide from concentrated sources – like the emissions from power plants. The technology currently captures and stores only about a tenth of a percent of global carbon emissions.

Most existing CCS technologies use chemical binders to trap carbon dioxide quickly and efficiently, but they are extraordinarily energy intensive as well as expensive.

Researchers at the University of Colorado Boulder have developed a new tool that could lead to more efficient and cheaper ways to capture carbon dioxide directly out of the air. The tool predicts how strong the bond will be between carbon dioxide and a candidate molecule for trapping it – that is, a binder. This new electrochemical diagnostic tool can be used to identify suitable molecular candidates for capturing carbon dioxide from everyday air.

Current carbon capture technologies are very expensive at the scale required to be able to turn the captured CO2 into useful substances, such as carbonates – which are an ingredient in cement – or formaldehyde or methanol, which can be used as fuels. Making useful materials out of the captured CO2 is an important way to offset the cost of capturing it that merely storing it away does not permit.

The new electrochemical analytical tool developed by the Colorado researchers offers the potential for identifying binders that will be more efficient and less expensive, thereby making direct air carbon capture a realistic part of the efforts to address climate change.

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New method could lead to cheaper, more efficient ways to capture carbon

Photo, posted October 25, 2015, courtesy of Frans Berkelaar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Direct Air Capture | Earth Wise

October 15, 2021 By EarthWise Leave a Comment

There is a lot of interest in carbon capture and sequestration (or CCS) in the context of trapping the carbon dioxide emissions from power plants and industrial facilities. The fossil fuel industry is especially enthusiastic about the potential for continuing to burn fuels without harming the environment. Apart from the technical challenges, there is the looming problem of CCS adding significant costs to power generation that is already losing the economic battle to renewable sources.

Direct air capture is a different matter. This is the idea of actively taking CO2 out of the atmosphere. This already happens by natural means such as sequestering it in soil or forests. But there is considerable work going on aimed at developing technology to capture atmospheric carbon dioxide in massive quantities.

This September marks the opening of a new project called “Orca” in Iceland, which will, for the time being, be the largest direct air capture system in the world. Once it is running around the clock, Orca will remove up to 4,000 metric tons of CO2 from the atmosphere each year.

Even larger DAC plants – one in the southwestern U.S and another in Scotland – are planned to come online in the next few years.

Ultimately, the question is whether direct air capture is feasible at large enough scale and affordable cost. The numbers are daunting. Society releases over 30 billion metric tons of carbon dioxide into the atmosphere each year. Removing significant amounts of that with DAC technology is an enormous challenge. Eliminating emissions remains the most practical way to mitigate the effects of climate change.

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The Dream of Carbon Air Capture Edges Toward Reality

Photo, posted November 10, 2017, courtesy of Governor Jay and First Lady Trudi Inslee via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Wood Into Plastic | Earth Wise

May 4, 2021 By EarthWise Leave a Comment

Plastic pollution is particularly pernicious because plastics can take hundreds of years to degrade in the environment. For this reason, researchers across the globe search for ways to shift from petrochemical plastics to ones that are biodegradable.

Producing biodegradable plastics is challenging both from the standpoint of the methods needed and from the results obtained. Producing them often requires toxic chemicals and can be very expensive. The materials that emerge often do not have the durability and strength of conventional plastics and can be unstable when exposed to moisture.

Researchers at the Yale School of the Environment have developed a process of decomposing the porous matrix of natural wood into a slurry that can be formed into a biodegradable plastic. The material shows high mechanical strength, stability when holding liquids, and is resistant to the effects of ultraviolet light. Along with all these favorable properties, the material can be recycled or safely biodegraded in the natural environment.

The slurry mixture is created by taking wood powder – a processing residue usually discarded in lumber mills – and deconstructing it with a biodegradable and recyclable solvent. The resulting mixture has a high solid content and high viscosity and can be casted and rolled without breaking.

The researchers conducted a comprehensive life cycle assessment to test the environmental impacts of the bioplastic compared with conventional plastics. Sheets of it were buried in soil and observed to fracture after two weeks and completely degrade after three months. The material can also be broken back down into the slurry by mechanical stirring.

The remaining topic to investigate is the potential impact on forests if the manufacturing of this bioplastic is scaled up.

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Turning wood into plastic

Photo, posted October 12, 2016, courtesy of the US Forest Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

30 Million Solar Homes | Earth Wise

March 29, 2021 By EarthWise Leave a Comment

A national coalition made up of more than 230 organizations has launched an initiative called the 30 Million Solar Homes campaign. The goal is to add enough rooftop and community solar energy to power 30 million homes across the U.S. over the next five years. That would be the equivalent of one in four American households.

The major focus of the 30 Million Solar Homes initiative is to rapidly and massively scale programs that help low-income families benefit from solar power. The coalition lists 15 federal policy initiatives including making solar tax incentives more equitable, providing more reliable low-income energy assistance through solar energy, supplementing low-income weatherization assistance with solar energy, and specifically funding solar projects in marginalized communities.

The federal government spends billions of dollars every year to help families to pay their energy costs, but these efforts only serve less than a fifth of the eligible population. Funding rooftop and community solar access for these households would provide long-term financial relief and reduce the need for annual energy bill assistance.

The more than 230 organizations in the coalition represent organizations focused on energy equity, climate, business, environment, faith, and public health. The coalition estimates that executing the plan would create three million good-paying jobs, lower energy bills by at least $20 billion a year, and reduce total annual greenhouse gas emissions by 1.5%.

Over the coming months, the campaign will seek to educate lawmakers and the Biden-Harris Administration about the benefits of distributed solar energy. The vision outlined by the coalition is an ambitious one to say the least.

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30 Million Solar Homes

Supporters of 30MSH

Photo, posted May 20, 2009, courtesy of Solar Trade Association via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Dangers Of Negative Emissions Technologies | Earth Wise

September 28, 2020 By EarthWise Leave a Comment

Reducing carbon emissions is not easy and there are plenty of people who don’t even want to try for various reasons, generally related to their perceived economic interests and convenience. As a result, there is a great deal of interest in so-called negative emissions technologies or NETs. These are methods for removing carbon dioxide from the atmosphere. Even the UN Intergovernmental Panel on Climate Change assumes that NETs will play a role in mitigating the effects of climate change and meeting international goals.

The most widely studied approaches to negative emissions technology are bioenergy with carbon capture and storage – which entails growing crops for fuel, and then capturing and burying the CO2 produced from burning the fuel; planting more forests; and direct air capture, which involves actually pulling CO2 out of the air and storing it – probably underground.

A new study published in Nature Climate Change points out that none of these technologies has even been tried at the demonstration scale, much less at the massive levels required to make a dent in current CO2 emissions.

Their analysis of the biofuel and reforestation strategies show that each would take up vast land and water resources already needed for agriculture and nature. Air capture uses less water than the other two approaches, but still uses quite a bit and even more energy, which if supplied by fossil fuels, would offset the benefits of carbon capture.

Negative emissions technologies may well play an important role in combating climate change, but it is essential that we understand what the consequences will be from implementing them. We need to know the pitfalls that could arise. It would be a major mistake to simply count on NETs to be some kind of silver bullet.

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Remove CO2 from the air? Don’t bet on it before examining costs, researchers say

Photo, posted January 11, 2008, courtesy of Al Pavangkanan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Solar On Commercial Buildings | Earth Wise

September 17, 2020 By EarthWise Leave a Comment

The United States installed 3.6 gigawatts of photovoltaic solar capacity in the first quarter of this year to reach a total installed capacity of 81.4 GW. That is enough to power about 16 million American homes. More than 2/3 of that capacity has been installed during the past five years.

There has been a boom in solar installations in recent years and, until the Covid-19 pandemic stuck, 2020 was expected to be the biggest year yet. Now the unprecedented health, social, and economic conditions in our country creates great uncertainty in such forecasts.

Nevertheless, the opportunities for growth in solar power continue to be substantial. A new report from the energy research firm Wood Mackenzie looked at the prospects for using the roof space of commercial buildings for solar power.

Currently, just 3.5% of commercial buildings in the U.S. have solar panels on their roofs. Another 1% of those buildings are attached to solar projects located off-site. The report looked at how many buildings are potential targets for solar projects.

After accounting for buildings that are too small or that use too little electricity to make solar power a worthwhile investment, the report estimated that 70% of commercial buildings in the U.S. – amounting to some 600,000 sites – are candidates for solar installations. Doing this would provide 145 GW of new solar capacity, which is nearly twice as much as currently exists in this country.

Commercial solar installations have their own unique logistical and financial challenges. While utility solar can scale to lower costs and residential solar has financing opportunities, commercial solar has neither. But ultimately, it represents an important opportunity for our future energy system.

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U.S. Commercial Rooftops Hold 145 Gigawatts of Untapped Solar Potential

Photo, posted June 25, 2014, courtesy of Rob Baxter via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Better Paint For Cooler Buildings | Earth Wise

August 20, 2020 By EarthWise 2 Comments

A research team led by scientists at UCLA have developed a super-white paint that reflects as much as 98% of incoming heat from the sun. Such paint, if used on rooftops and other parts of buildings, could have a major impact on reducing the costs of keeping buildings cool.

Passive daytime radiative cooling is a well-known method to keep buildings cooler. By having building surfaces reflect sunlight and radiate heat into space, building temperatures can be significantly lowered. This in turn cuts down on air conditioner use and associated carbon emissions.

A roof painted white will result in lower indoor temperatures than a darker roof. But a white roof will do even more: it can reject heat at infrared wavelengths that are invisible to our eyes. This results in even more radiative cooling.

The best performing white paints currently available reflect about 85% of incoming solar radiation. The rest is absorbed by materials in the paint. The new research has identified simple modifications in paint ingredients that lead to a major increase in reflectivity.

Current reflective white paints use titanium dioxide, which absorbs UV radiation and therefore heats up under sunlight. The researchers studied replacing it with other substances such as barite – an artist’s pigment – or with powdered Teflon, both of which allow the paint to reflect more of the sun’s radiation.

Many cities are encouraging the use of cool-roof technologies on new buildings. Using the most reflective coatings possible on rooftops, if applied on a sufficiently large scale, could have a real impact on climate change as well as saving significant amounts of energy used for running air conditioners in buildings.

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UCLA-led Team Develops Ways to Keep Buildings Cool with Improved Super White Paints

Photo, posted August 15, 2012, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture As Big Business

December 26, 2019 By EarthWise Leave a Comment

Removing greenhouse gasses from the atmosphere is an essential part of the overall effort to achieve zero net carbon emissions and stabilize the climate. Since we have not been able to reduce emissions fast enough to do the job, it is important to find ways to pull carbon dioxide out of the atmosphere.

There are many ways to do it, but they tend to be rather expensive and, so far, the need to mitigate climate change does not seem to provide sufficient incentive. A new study by researchers at UCLA, the University of Oxford, and five other institutions, analyzed the possibility of creating a large global industry based on capturing carbon dioxide and turning it into commercial products.

The study investigated the potential future scale and cost of 10 different ways to use carbon dioxide, including in fuels and chemicals, plastics, building materials, soil management, and forestry. The study looked at processes using carbon dioxide captured from waste products that are produced by burning fossil fuels as well as by simply capturing it directly from the atmosphere. The study also looked at processes that use carbon dioxide captured biologically by photosynthesis.

The conclusions of the study were that on average each of the ten utilization pathways could use about half a billion tons of carbon dioxide that would otherwise escape into the atmosphere. Thus, theoretically, these various pathways could take more than five billion tons of CO2 out of the atmosphere. Currently, fossil fuel combustion emits about 40 billion tons of carbon dioxide.

The authors of the study stress that there is no silver bullet in the fight against climate change. It will require multiple approaches – including CO2 removal for industrial use – to make real progress

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Carbon dioxide capture and use could become big business

Photo, posted September 18, 2015, courtesy of Tony Webster via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Natural Gas Processing

December 4, 2019 By EarthWise Leave a Comment

Qatar, a small country in the Middle East with a population of about 2.5 million has the highest per capita income of any country in the world. This is largely a result of being one of the world’s top producers of natural gas. The upshot of that is that the tiny country has the dubious honor of being the world’s leading emitter of CO2 per capita.

Texas A&M University has a campus in Qatar and researchers there in collaboration with colleagues at the main campus in College Station, Texas have developed a new reactor technology that can help Qatar process its wealth of natural gas while reducing the country’s carbon footprint.

The technology processes natural gas and captured CO2 to produce both syngas – which is a valuable precursor for many products – and high-quality carbon nanotubes, all without releasing CO2 into the atmosphere.

Natural gas reforming is a process by which syngas – a feedstock for liquid hydrocarbons and ultraclean fuels- is produced. The process requires lots of heat and emits CO2. The new technology adds a novel CARGEN (or CARbon GENerator) reactor that advances the natural gas reforming process and includes a catalyst that captures the CO2 emissions and produces nanotubes. The reactor can be driven by either electric or solar power, eliminating the need to burn fuel that ordinarily results in more carbon emissions.

The result is that Qatar’s CO2 emissions would be converted into two products that are important to its economy. In particular, carbon nanotubes are very expensive and extremely versatile, and can be used to manufacture products such as computers and other high-quality materials.

The next step for the researchers is to partner with industry collaborators to further scale up the technology.

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Qatar Researchers Develop Natural Gas Processing Technology That Could Reduce Qatar’s Carbon Footprint

Photo, posted September 30, 2012, courtesy of Jimmy Baikovicius via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Jet Fuels

May 9, 2019 By EarthWise Leave a Comment

The global aviation industry uses a whole lot of fuel: more than 5 million barrels a day. It is an incredibly energy-intensive industry and almost all of its energy comes from petroleum-based fuels.

While other large energy sectors such as electric power, ground transportation and commercial buildings have well-defined pathways to adopting renewable energy sources, the aviation industry does not have such a straightforward way to make a transition to sustainability. Electrifying planes using batteries or fuel cells is very challenging for a number of reasons, notably the weight restrictions on aircraft. So liquid biofuels as replacements for petroleum-based fuels remain the most promising approach.

A new study at the Lawrence Berkeley National Laboratory concludes that sustainable plant-based biofuels could provide a competitive alternative to conventional petroleum fuels if current development and scale-up initiatives are successful.

Multidisciplinary teams based at the Department of Energy’s Joint BioEnergy Institute are focused on optimizing each stage of the bio-jet fuel production process. This includes bioengineering ideal source plants and developing methods for efficiently isolating the carbohydrates in non-food biomass that bacteria can digest and bioconvert into fuel molecules.

The critical issue is cost. The theoretical cost of bio-jet fuel has come down dramatically in recent years but is still around $16 a gallon. The cost of standard jet fuel is about $2.50 a gallon. So, the real challenge is bridging that gap.

Reducing the cost of the fuel could come both from the material and process improvements that are underway as well as by finding ways to turn the leftover lignin residuals from the bioconversion process into valuable chemicals.

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