methods

A Cheap Material For Carbon Capture | Earth Wise

September 12, 2022 By EarthWise Leave a Comment

The recently passed Inflation Reduction Act includes significant support for carbon capture technologies. Eliminating fossil fuel burning is essential for halting climate change, but in the interim, methods for capturing emissions of carbon dioxide and either storing it or turning it into usable products are increasingly necessary.

There are a variety of techniques being developed for carbon capture but at this point, none of them are commercially viable. The best technique in use today involves piping flue gases through chemicals called liquid amines, which bind CO2. The process requires large amounts of energy to release the bound carbon dioxide so it can be concentrated and stored. As a result, it is complicated and expensive.

Researchers at UC Berkeley, Stanford, and Texas A&M University have developed a carbon capture method using melamine, which is an inexpensive polymer used to make Formica, as well as low-cost dinnerware, industrial coatings, and other plastics. Porous melamine itself adsorbs CO2 to a limited extent. But the researchers discovered that adsorption could be much improved by adding the chemical DETA (diethylenetriamine) to bind the CO2. In addition, adding cyanuric acid increased the melamine pore size and radically improved CO2 capture efficiency even more.

The result is a material that is more efficient even than exotic carbon capture materials like metalorganic frameworks and is much cheaper and easier to make. The researchers aim to design equipment that can used in industrial facilities, attached to buildings and other structures, or even to the tailpipes of gas-powered vehicles.

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A simple, cheap material for carbon capture, perhaps from tailpipes

Photo, posted June 10, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wastewater And Ammonia | Earth Wise

October 22, 2021 By EarthWise Leave a Comment

Ammonia is the second most produced chemical in the world. More than half of it is used in agriculture to produce various kinds of fertilizer, to produce cotton defoliants that make cotton easier to pick, and to make antifungal agents for fruits. Globally, ammonia represents more than a $50 billion a year market.

Current methods to make ammonia require enormous amounts of heat – generated by burning fossil fuels – to break apart nitrogen molecules so that they can bind to hydrogen to form the compound. Ammonia production accounts for about 2% of worldwide fossil energy use and generates over 400 million tons of CO2 annually.

Engineers at the University of Illinois Chicago have created a solar-powered electrochemical reaction that uses wastewater to make ammonia and does it with a solar-to-fuel efficiency that is 10 times better than previous comparable technologies.

The process uses nitrate – which is one of the most common groundwater contaminates – to supply nitrogen and uses sunlight to power the reaction. The system produces nearly 100% ammonia with almost no hydrogen side reactions. No fossil fuels are needed, and no carbon dioxide or other greenhouse gases are produced. The new method makes use of a cobalt catalyst that selectively converts nitrate molecules into ammonia.

Not only is the reaction itself carbon-neutral, which is good for the environment, but if it is scaled up for industrial use, it will consume wastewater, thereby actually being good for the environment. The new process is the subject of a patent filing and the researchers are already collaborating with municipal corporations, wastewater treatment centers, and others in industry to further develop the system.

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Combining sunlight and wastewater nitrate to make the world’s No. 2 chemical

Photo, posted August 29, 2018, courtesy of Montgomery County Planning Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Floating Renewable Energy | Earth Wise

July 22, 2021 By EarthWise Leave a Comment

A team of researchers at Texas A&M University believes that the next generation of offshore energy could come in the form of a synergistic combination of multiple renewable energy generators installed on a floating offshore platform.

Their concept for the ocean renewable energy station comprises wind, wave, ocean current, and solar energy elements that could generate electricity for anything from a coastal or island community to a research lab or military unit. The station would be tethered to the sea bottom and could be used in locations where the water depth increases quickly, such as along the U.S. Pacific Coast or Hawaii.

Offshore wind is already commercially competitive, while wave-energy converters so far have been less cost-effective and only useful for specialized, smaller-scale applications. The proposed ocean renewable energy station would make use of multiple different methods of electricity generation and incorporate innovative smart materials in the wave energy converters that respond to changes in wave height and frequency and allow for more consistent power production.

Denmark is already building a huge multi-source, multi-purpose ocean energy island. This world’s first energy island will be 30 acres in area and serve as a hub for 200 giant offshore wind turbines generating 3 GW of electric power. It is the largest construction project in Danish history, and will cost an estimate $34 billion. As well as supplying other European countries with electricity, the goal is to use the new offshore island to produce green hydrogen from seawater, which can also be exported. Large battery banks on the island will store surplus electricity for use in times of high demand.

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Research Underway On Floating Renewable Energy Station

Photo, posted September 27, 2014, courtesy of Eric Gross via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Recycling Solar Panels | Earth Wise

October 1, 2020 By EarthWise Leave a Comment

It is inevitable that the things we make and use eventually outlive their useful lives and become waste that we have to deal with. Solar panels, despite their impressively long lifetime, can’t escape this general principle. As pioneering solar panels near the end of their 30-year electronic lives, they could well become the world’s next big wave of e-waste.

According to the International Renewable Energy Agency, nearly 90 million tons of solar panels will have reached their end of life by the year 2050, resulting in about 7 million tons of new solar e-waste per year.

Solar photovoltaic deployment has grown at unprecedented rates in recent years. The total global installed capacity is about 600 GW today; projections are that there will be 1,600 GW by 2030 and 4,500 GW by 2050.

Solar panels contain valuable materials, including silver and high-purity silicon. But current recycling procedures are not cost-effective. Only about 10% of panels are currently recycled in the U.S. The rest go to landfills or are shipped overseas to become another country’s problem.

Before solar waste becomes a major problem, the industry needs to better address the issue. Strategies include improving the design of panels to align with recycling capabilities as well as developing new recycling methods that can more efficiently extract and purify the valuable materials in the panels. Industry researchers are also looking into ways to repair and resell panels that are still in good condition and to repurpose old panels for less demanding functions like e-bike charging stations and housing complexes.

Like most things, solar panels do fail over time and with a rapidly growing number of them in the world, we need to figure out how to avoid them adding to the world’s problems.

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Solar Panels Are Starting to Die. Will We be Able to Recycle the E-Waste?

Photo, posted January 6, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A High-Tech Fire Alarm | Earth Wise

July 23, 2020 By EarthWise Leave a Comment

In recent years, wildfires have been a global problem, notably in California, Brazil, and Australia. It has become increasingly important to be able to respond to new fires as soon and as quickly as possible. Such response can make the task of extinguishing them easier, thereby reducing the amount of damage and the loss of property and life.

Traditional methods for detecting forest fires include satellite monitoring, ground patrols, and watch towers, all of which have high labor and financial costs but suffer from low efficiency. Remote sensing technologies are becoming increasingly common but rely on batteries for power, requiring servicing in remote locations to replace depleted batteries. Solar cells represent an alternative to batteries, but it is challenging to use them in forests because of shading and foliage coverage.

A team of researchers at Michigan State University has developed a remote forest fire detection and alarm system powered by nothing more than the movement of tree limbs in the wind. The device is known as an MC-TENG, which is an acronym for multilayered cylindrical triboelectric nanogenerator. The triboelectric effect is a phenomenon where certain materials become electrically charged when they separate from a second material with which they were previously in contact. In the new device, two cylindrical sleeves fit within one another – one anchored and the other free to slide. The device is tied to a tree branch and when the branch sporadically moves in the wind, electricity is generated and stored in a carbon-nanotube-based micro supercapacitor. This powers a sensing system that can continuously monitor environmental conditions without requiring any maintenance.

A combination of carbon monoxide and temperature sensors provides a high-tech fire alarm that can operate continuously in the most remote forest.

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Self-Powered Alarm Fights Forest Fires, Monitors Environment

Photo, posted August 3, 2012, courtesy of Lukas Schlagenhauf via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Building For Climate Change

May 13, 2019 By EarthWise Leave a Comment

The manifestations of climate change are creating increasingly familiar images: floodwaters rising up house windows, charred buildings in the wake of wildfires, and homes and businesses demolished by storm winds. As these sorts of calamities become ever more common, changes to how houses are built are going to be necessary.

How can homes become more resilient against severe and unpredictable weather?

Research at Carlton University’s Sprott School of Business looks at this issue.

As an example, houses can be framed and finished in certain ways that help protect them from wind and flooding. But such methods are currently only happening in the custom-build fringes of the housing sector. Widespread adoption will require, at the minimum, significant changes to building codes.

Revising building codes is not an easy matter. The codes themselves are highly technical and complex, and beyond that, the process Is often politicized.

Even simple things like hurricane ties, which are small pieces of hardware that prevent a roof from lifting during a severe wind are not now included in building codes. Insurance companies support their use as inexpensive protection for houses. But even though the overall cost is relatively minor, the building industry pushes back at the additional expense.

The need to reduce carbon emissions has created a push for sustainable housing. But the increasingly erratic weather means that houses also need resilience and adaptation. These features will inevitably add costs and incorporating them into building codes requires producing convincing business cases.

The U.S. experienced 394 natural catastrophe events last year costing $225 billion in damage. Finding ways to make homes and businesses more resilient is not just a good idea; it is essential.

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How to Start Weather-Proofing Homes for Unpredictable Weather

Photo, posted June 12, 2008, courtesy of U.S. Geological Survey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Jet Fuels

May 9, 2019 By EarthWise Leave a Comment

The global aviation industry uses a whole lot of fuel: more than 5 million barrels a day. It is an incredibly energy-intensive industry and almost all of its energy comes from petroleum-based fuels.

While other large energy sectors such as electric power, ground transportation and commercial buildings have well-defined pathways to adopting renewable energy sources, the aviation industry does not have such a straightforward way to make a transition to sustainability. Electrifying planes using batteries or fuel cells is very challenging for a number of reasons, notably the weight restrictions on aircraft. So liquid biofuels as replacements for petroleum-based fuels remain the most promising approach.

A new study at the Lawrence Berkeley National Laboratory concludes that sustainable plant-based biofuels could provide a competitive alternative to conventional petroleum fuels if current development and scale-up initiatives are successful.

Multidisciplinary teams based at the Department of Energy’s Joint BioEnergy Institute are focused on optimizing each stage of the bio-jet fuel production process. This includes bioengineering ideal source plants and developing methods for efficiently isolating the carbohydrates in non-food biomass that bacteria can digest and bioconvert into fuel molecules.

The critical issue is cost. The theoretical cost of bio-jet fuel has come down dramatically in recent years but is still around $16 a gallon. The cost of standard jet fuel is about $2.50 a gallon. So, the real challenge is bridging that gap.

Reducing the cost of the fuel could come both from the material and process improvements that are underway as well as by finding ways to turn the leftover lignin residuals from the bioconversion process into valuable chemicals.

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Bright Skies for Plant-Based Jet Fuels

Photo, posted March 28, 2009, courtesy of Yasuhiro Chatani via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Rare Earths From Mining Waste

May 3, 2019 By EarthWise Leave a Comment

The 17 rare earth elements have become important parts of much of modern technology. Despite their name, most of these elements are relatively plentiful in the earth’s crust, but because of their geochemical properties they are typically dispersed and not often found concentrated in minerals. As a result, economically exploitable ore deposits are uncommon. There are no significant sources in the U.S.

Rare earths play important roles in high-performance magnets, electric motors in vehicles, wind turbines, microphones and speakers, and in portable electronics like cell phones. As these applications become ever larger, the need for additional sources of rare earths increases.

Researchers at Idaho National Laboratory and Rutgers University have studied a method for extracting rare-earth elements from mining waste that could greatly increase the world’s supply of these valuable materials.

It turns out that large amounts of rare earths exist in phosphogypsum, a waste product from producing phosphoric acid from phosphate rock. The U.S. alone mined 28 million tons of phosphate rock in 2017. (Phosphoric acid is used in the production of fertilizers and other products).

The researchers estimate that more than a billion tons of phosphogypsum waste sits in piles at storage sites across the U.S. alone. World-wide, about 100,000 tons of rare earth elements per year end up in phosphogypsum waste. This compares to the total current world-wide production of rare earth oxides of 126,000 tons.

The researchers studied methods for extracting the elements from the waste. A method utilizing a common environmental bacterium showed great promise.

There are concerns about residual radioactivity and other environmental issues in dealing with the waste material, but the world’s supply of rare earth elements might become much greater based on this research.

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Critical Materials: Researchers Eye Huge Supply of Rare-Earth Elements from Mining Waste

Photo, posted June 19, 2015, courtesy of David Stanley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Speed Breeding Of Crops

January 4, 2019 By EarthWise Leave a Comment

A technique pioneered by NASA for the purpose of growing plants extra-terrestrially is now being applied here on earth to fast-track improvements in a range of crops. The technique, known as speed breeding, has been adapted for use by British and Australian researchers on a scale ranging from vast greenhouses to desktop growth chambers.

Speed breeding uses enhanced LED lighting and day-long regimes of up to 22 hours to optimize photosynthesis and promote rapid growth of crops. By speeding up the breeding cycle of plants,it is possible, for example, to grow six generations of wheat in a year compared with two generations using traditional breeding methods.

With shortened breeding cycles, genetic improvements such as yield gain, disease resistance and climate resistance can be fast-tracked in crops such as wheat, barley, chickpeas, various Brassica species, oil seed rape and peas.

The ability to do this in compact desktop chambers permits cutting-edge research to be performed inexpensively before being scaled up to large greenhouses.

Crop development is an increasingly important activity and speed breeding is increasingly attractive in light of the opposition in some quarters to modern gene-editing techniques to create GMO crops. Speed breeding allows crop improvements via anon-GMO route.

The new technique is already being applied in Australia, which is experiencing one of the worst droughts on record. It is being used to rapidly cycle genetic improvements to make crops more drought resilient.

Generation time in most plant species is a major bottleneck in applied research programs and breeding. Speed breeding can greatly reduce this bottleneck, allowing scientists to respond more quickly to emerging diseases, the changing climate and increased demand for specific plant traits.

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