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Tracking down PFAS toxins

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PFAS – per- and polyfluoralkyl substances – are a group of organic compounds that have been extensively used to provide water-, oil-, and dirt-resistance to a wide range of products ranging from non-stick pans, clothing, and packaging to paint, car polish, and fire-suppressant foam.  Exposure to specific PFAS compounds is associated with multiple adverse health effects, including altered immune and thyroid function, liver disease, kidney disease, poor reproductive and developmental outcomes, and cancer.  PFAS compounds do not break down in the environment and therefore, over time, become concentrated in plants, animals, and people.

Government agencies such as the EPA in this country and the EU have set strict limits for allowable levels of PFAS in drinking water.  Testing water for the trace amounts of PFAS that constitute the limits is time-consuming and expensive and requires complex equipment and experienced personnel.

Researchers at MIT have now introduced a technique for making a portable, inexpensive test that can easily and selectively detect PFAS in water samples.  The test makes use of a special polymer containing fluorinated dye molecules that cause the polymer to fluoresce red.  If PFAS are present in the sample, they enter the polymer and displace the dye molecules and switches off the red fluorescence. 

The new technique is suitable for on-site detection in highly contaminated regions.  Detecting smaller concentrations can be achieved with sufficient precision after pre-concentrating the samples using the process of solid-phase extraction.

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Tracking down Environmental Toxins

Photo, posted October 16, 2021, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Removing Lead From Water With Beer Yeast | Earth Wise

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Lead and other heavy metals in water are a serious global problem that is worsening because of electronic waste and discharges from mining operations.  In the U.S., over 12,000 miles of waterways are impacted by mine-drainage water that is rich in heavy metals.

Lead in particular is highly toxic, especially to children.  The European Union established a standard for allowable lead in drinking water of only 5 parts per billion.  In the US, the EPA has declared that no level of lead at all is safe.

Researchers at MIT have recently discovered that inactive yeast can be effective as an inexpensive, abundant, and simple material for removing lead contamination from drinking water supplies.  The MIT study shows that the method works even at parts-per-billion levels of contamination.

The method is called biosorption, in which inactive biological material is used to remove heavy metals from water.  Previously, it has been studied at parts-per-million contaminant levels, but the MIT study shows that it works at much lower levels as well.

The team studied a type of yeast widely used in brewing.   The yeast cells used are inactive and desiccated and require no special care.  Such yeast is abundantly available as a waste product from beer brewing and various other fermentation-based industrial processes. 

The researchers estimate that to clean a water supply for a city the size of Boston would require about 20 tons of yeast a day, or 7,000 tons a year.  That seems like a lot, but one single brewery, the Boston Beer Company, generates 20,000 tons a year of surplus yeast that is no longer useful for fermentation.

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Could used beer yeast be the solution to heavy metal contamination in water?

Photo, posted September 5, 2017, courtesy of Allagash Brewing via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Harnessing The Smell Of Fear | Earth Wise

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Plant-eating insects present a major problem for farmers and home gardeners.  Aphids, for example, are a highly destructive pest to many crops.  Their large numbers and ability to transmit plant pathogens make them a persistent problem for growers.

Pesticides are chemical substances that are commonly used to prevent, destroy, repel or mitigate pests.  They include insecticides for insects, rodenticides for rodents, herbicides for weeds, and fungicides for microorganisms.  According to the U.S. Geological Survey, approximately one billion pounds of these chemicals are used in the United States every year.     

But pesticides can also contaminate soil, water, and other vegetation, as well as kill many non-target species.  Exposure to these chemicals is dangerous for human health. 

According to a new study, researchers from Pennsylvania State University have developed a way to bottle the “smell of fear” produced by predators in order to repel and disrupt pests naturally without the need for these harsh substances.  The researchers recently presented their findings at the American Chemical Society meeting.  

Aphids happen to be a favorite food of ladybugs. Aphids and other herbivorous insects will steer clear of fields and gardens if they smell predators nearby.  The researchers identified and extracted the volatile odor profile from ladybugs.  The researchers used the compounds to create a special odor blend that can be used in an essential oil diffuser to spread the scent across a garden or field. 

The research team plans to conduct field tests to see if the effects outside are similar to what was observed in the lab.  A natural and effective pest repellent would be a big win for people and the planet.  

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Protecting gardens and crops from insects using the ‘smell of fear’

Protecting gardens and crops from insects using the ‘smell of fear’ (YouTube)

Photo, posted May 10, 2011, courtesy of DM via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Disposable Masks And The Environment | Earth Wise

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The Covid-19 pandemic has made face masks and other personal protective equipment essential for healthcare workers.  Disposable N95 masks became the key requirement to help prevent the spread of the coronavirus.  But the wide use of these masks has both financial and environmental costs.

The pandemic is estimated to generate over 7,000 tons of medical waste each day and much of that is in the form of disposable masks.  Even though the pandemic has slowed down in many places, health care workers are continuing to wear masks most of the time.

A new study at MIT has looked at the financial and environmental cost of several different mask usage scenarios with an eye on trying to reduce the toll created by the continued need for using them.

If every health care worker in the US used a new N95 mask for each patient they encountered during the first six months of the pandemic, the total number of masks required would be over 7 billion, at a cost of over $6 billion and would generate 92,000 tons of waste (the equivalent of 252 Boeing 747 jets.)

Decontaminating regular N95 masks so that health care workers can wear them for more than one day could drop costs and environmental waste by at least 75% compared with using a new mask for every patient encounter. 

Fully reusable N95 masks could offer an even greater reduction in waste, but such masks are not yet commercially available.  MIT researchers are developing a reusable N95 mask made of silicone rubber that contains an N95 filter than can either be discarded or sterilized after use.  They have started a new company with the goal of commercializing the masks.

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The environmental toll of disposable masks

Photo, posted August 4, 2020, courtesy of the U.S. Navy / Mass Communication Specialist 3rd Class Jake Greenberg via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaning Up Diesel With Bacteria | Earth Wise

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Mothballed military outposts with piles of rusting oil drums are not an unusual sight in Greenland.  There are about 30 abandoned military installations in Greenland and diesel that was once used to operate generators and other machinery has, in many cases, seeped into the ground.

Removing tons of contaminated soil from these sites is incredibly resource-intensive involving the use of aircraft and ships, so it has not really been practical.  As a result, Danish Defense and the engineering company NIRAS instead conducted a five-year experiment to optimize the conditions for naturally occurring soil bacteria to break down the contaminating diesel.

The experiment was performed at Station 9117 Mestersvig, an abandoned military airfield on the coast of East Greenland.  Forty tons of diesel fuel contaminated the soil there.

The remediation method using bacteria is known as landfarming and has most often been applied in warmer climates around the world.  This was the first large-scale test under Arctic conditions.

Landfarming works by distributing contaminated soil in a thin layer, which is then plowed, fertilized, and oxygenated every year to optimize conditions for bacteria to degrade hydrocarbons.

The site was monitored by scientists from the University of Copenhagen, and they found that after five years, the bacteria had bioremediated as much as 82 percent of the 5,000 tons of contaminated soil on the site. 

Based on these results, it appears to be feasible for naturally occurring bacteria to be used to remediate contamination in all of the 30 deserted military installations in Greenland as well as in other Arctic sites contaminated by diesel pollution.

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Bacteria used to clean diesel-polluted soil in Greenland

Photo, posted September 6, 2013, courtesy of Maj. Matthew J. Sala/The U.S. Air National Guard via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Mollusks And Microplastics | Earth Wise

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Plastic debris comes in all different shapes and sizes, but pieces that are less than five millimeters in length are called microplastics.  Microplastics are everywhere, including in the food we eat, the water we drink, and the air we breathe.

Much of the oceanic microplastic pollution comes from the breakdown of plastic litter.  Another source of microplastic pollution is microbeads.  Microbeads, which are sometimes added to cleansing and exfoliating personal care products, pollute the environment when they get flushed down the drain.  

According to a new study by researchers at Hull York Medical School and the University of Hull in the U.K., mussels, oysters and scallops have the highest levels of microplastic contamination among seafood.  The research team examined 50 studies between 2014 and 2020 to determine the levels of microplastic contamination globally in fish and shellfish.  The team found that microplastic content was 0-10.5 microplastics per gram in mollusks, 0.1-8.6 microplastics per gram in crustaceans, and 0-2.9 microplastics per gram in fish.  

The researchers found that mollusks collected off the coasts of Asia were the most heavily contaminated with microplastics.  China, Australia, Canada, Japan and the United States are among the largest consumers of mollusks, followed by Europe and the U.K.

While the human health implications of consuming microplastics are not well understood, early evidence from other studies suggest they do cause harm. 

According to the research team, more data is needed from different parts of the world in order to better understand how microplastics vary between different oceans, seas, and waterways.

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Highest levels of microplastics found in molluscs, new study says

Photo, posted September 3, 2007, courtesy of Andrew Malone via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wildfires And Superfund Sites | Earth Wise

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Thousands of contaminated sites exist nationally due to hazardous waste being dumped, left out in the open, or otherwise improperly managed. These sites include manufacturing facilities, processing plants, landfills, and mining sites.  A Congressional act in 1980 established authority by the EPA to ultimately clean up these “Superfund” sites.

According to a government survey last year, 945 Superfund sites are vulnerable to hurricanes, flooding, sea level rise, increased precipitation, or wildfires, all of which are intensifying as the climate warms.   In particular, there are 245 sites vulnerable to wildfires and 68 of them have recently seen wildfires approach.

A comprehensive investigation by Inside Climate News, NBC News, and the Texas Observer has found that the threat presented by wildfires is exceeding authorities’ ability to adequately prepare and respond.  Fires at Superfund sites could release toxins ranging from acid mine drainage to radioactive smoke.

There have already been a number of close calls.  The 2013 Patch Springs Fire near Salt Lake City came within 10 miles of the Tooele Army Depot, a Superfund site with 902 ammunition bunkers along with soil and groundwater contaminated with hazardous chemicals.

The 2018 Carr Fire in Northern California over swept the Iron Mountain Mine Superfund site and threatened to release corrosive chemicals into the watershed.

For sites where no polluter can be made to pay and the EPA lacks cleanup funds, the agency will need to design protections that shield the sites from wildfires as long as the contamination remains. 

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Fueled by Climate Change, Wildfires Threaten Toxic Superfund Sites

Photo, posted July 26, 2018, courtesy of the Bureau of Land Management California via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Menace Of Abandoned Oil Wells | Earth Wise

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More than a century of oil and gas drilling has left behind millions of abandoned wells and many of them are leaching pollutants into the air and water.  Drilling companies continue to abandon even more wells as demand for oil diminishes and bankruptcies become more common.

Leaks from abandoned wells have long been known to be an environmental problem and a health hazard.  They have been linked to many instances of groundwater contamination and to dangerous fumes near homes and farms.

There have recently been efforts to track the amounts of methane leaching from abandoned oil and gas wells, and the figures in United States are alarming.  According to the most recent EPA report, more than 3.2 million abandoned oil and gas wells emitted a total of 281,000 tons of methane in 2018.  That is the climate-damage equivalent of consuming about 16 million barrels of crude oil, which is as much as the U.S. uses in a typical day.  According to the EPA, the actual amount could be as much as three times higher, because of incomplete data.   The agency believes that most of the methane comes from more than 2 million abandoned wells that were never properly plugged.

New York’s Department of Environmental Conservation has records of over 2,000 abandoned wells, but the state believes the actual number could be much higher.  This is a problem that won’t just go away.  Wells don’t leak for a year and then stop.  They can continue to leak for a century or more.  Cleaning up and plugging an abandoned well runs from $20,000 to $145,000, meaning that countrywide, cleaning up this environmental menace could cost somewhere between $60 billion and $435 billion.

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Special Report: Millions of abandoned oil wells are leaking methane, a climate menace

Photo, posted October 13, 2015, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Protecting Fresh Produce | Earth Wise

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Fresh fruits and vegetables can sometimes become contaminated by microorganisms during their long journey from fields to restaurants and grocery stores.  Contaminated produce can spoil other produce, which increases the number of fruits and vegetables in the supply chain that can cause illnesses. 

In order to prevent this cross-contamination between produce, researchers from Texas A&M University have designed a coating that can be applied to food-contact surfaces, like buckets, rollers, and conveyor belts.  The newly-created dual-function coating is both water-repellent and germicidal.  In other words, it can both repel and kill.  Without water, the researchers say bacteria can’t stick or multiply on surfaces, drastically reducing contamination.

To make this dual-function coating, the researchers chemically-attached a thin layer of silica to an aluminum sheet.  They then added a mixture of silica and lysozyme, a naturally-occurring germicidal protein found in egg whites and tears.  Together, the silica-aluminum and the silica-lysozyme formed microscopic bumps and crevices.  According to the research team, this rough texture, albeit microscopic, is the key to the coating’s superhydrophobic properties.  

The researchers tested the coating’s effectiveness at curbing the growth of two strains of disease-causing bacteria:  Salmonella and Listeria.  Upon review, the number of bacteria found on the dual-coating surfaces was 99.99% less than what was found on the uncoated surfaces. 

Despite the success in preventing bacterial spread, the research team said more research needs to be done to see how well the coating works for mitigating viral cross-contamination.  Since the coating would need to be reapplied after a certain amount of use, the researchers also plan to develop more permanent, dual-function coatings. 

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New dual-action coating keeps bacteria from cross-contaminating fresh produce

Photo, posted April 14, 2012, courtesy of U.S. Department of Agriculture via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Natural Habitats And Strawberry Farms | Earth Wise

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According to a new study led by researchers from the University of California – Davis, conserving natural habitat around strawberry fields can protect farmers’ yields, their bottom line, and the environment.  The study also suggests that conserving natural habitat in this way has no detectable threat to food safety. 

In this study, which was recently published in the journal Ecological Applications, the research team conducted surveys and experiments at 20 strawberry farms along California’s Central Coast.  This region is responsible for 43% of the nation’s strawberry production. 

The researchers found that strawberry farmers were better off with natural habitat, like forests, grasslands, wetlands, and shrubs, around their farms than without it.  According to the study’s models, adding natural habitat can reduce crop damage costs by 23%.  Removing natural habitat can increase costs by as much as 76%. 

Importantly, the strawberry farms with natural habitat surrounding them showed no signs of increased fecal contamination.  While bird feces were regularly encountered on the ground, only 2 of 10,000 strawberries examined show signs of direct fecal contamination.  Those contaminated berries would be discarded during the hand-harvesting process.   

These findings run contradictory to current best practice recommendations that support natural habitat removal around strawberry farms in order to decrease bird fecal contamination and crop damage.  These food safety requirements were a consequence of the deadly outbreak of E. coli in 2006, which was traced back to spinach grown in this region.   

It seems like our agricultural landscapes can both support and benefit from biodiversity. 

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Natural habitat around farms a win for strawberry growers, birds and consumers

Photo, posted June 16, 2011, courtesy of the USDA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Much More Microplastics In The Ocean | Earth Wise

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We’ve been hearing more and more about plastic contamination (microplastics) in the ocean.  It is pulled from the nostrils of sea turtles, found in Antarctic waters, and tracked in increasing quantities in sedimentary layers dating back to the 1940s.  A new study by researchers from the Scripps Institution of Oceanography suggests that there could be a million times more pieces of plastic in the ocean than previously estimated.

Oceanographers found that some of the tiniest countable microplastic particles in seawater occur at much higher concentrations than previously measured.  Apparently, the traditional way of counting marine microplastics most likely misses the smallest particles, and therefore underestimates the number of particles by a factor of anywhere from 10,000 to a million.

The new measurements estimate that the oceans may be contaminated by 8 million pieces of so-called mini-microplastics per cubic meter of water.  Earlier studies that only looked at larger pieces of plastic found only 10 pieces per cubic meter. 

Microplastic studies typically trawl or pull a fine net behind a ship to collect samples.  But the meshes previously used could only capture plastics as small as 333 microns.  The new study found plastic particles as small as 10 microns, which is less than the width of a human hair.

Plastics keep breaking down into smaller and smaller particles, but they are so chemically strong that their chemical bonds don’t break down. They remain bits of plastic.  Scientists are concerned that these particles can get small enough to enter the human bloodstream.  The potential effects on human health are not well known and not extensively studied.

The problem of plastics just keeps getting bigger.

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Microplastics a million times more abundant in the ocean than previously thought

Photo courtesy of UC San Diego.

Earth Wise is a production of WAMC Northeast Public Radio.

Road Salt Pollution

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Mirror Lake is a popular recreational lake located in the Village of Lake Placid.  It is the most developed lake within the Adirondack Park, which is a publicly protected area that is actually larger than Yellowstone, Yosemite, Glacier, and Grand Canyon National Parks combined.

New research has revealed that road salt runoff into Mirror Lake is preventing natural water turnover which poses a risk to the balance of its ecology.  The study, which was published in Lake and Reservoir Management, found that road salt runoff is preventing spring mixing of the water column.    This creates more anoxic water conditions, meaning there is less oxygen in the water, and limits the ability of the habitat to support the native lake trout. 

Mirror Lake is the first lake in the Adirondack Park to show an interruption in lake turnover due to road salt.  Many lakes in northern climes experience so-called “dimictic turnover”, which is a natural process where wind and less stratified water conditions of spring and fall allow mixing of the water column that redistribute oxygen and nutrients throughout the lake.  High levels of surface-water chloride introduced into the lake from road salt runoff inhibit the mixing of the water column.

The lack of mixing and oxygenation is bad news for fish species such as lake trout, which require cold, oxygenated water to survive.  It may also put the lake at a greater risk of algal blooms.

Mirror Lake is small, surrounded by concentrated development, and receives the direct discharge of stormwater.  So, it is particularly vulnerable to road salt contamination.  Other lakes elsewhere in New York may experience similar conditions.  The researchers are confident that natural turnover conditions could be restored to the lake if road salt application in the watershed is reduced.

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Road salt pollutes lake in one of the largest US protected areas, new study shows

Photo, posted January 5, 2018, courtesy of MTA of the State of NY via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

China And Rare Earth Mining

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Rare earth elements are a crucial part of much of modern technology.  Everything from computers to X-ray machines and aircraft engines needs one or more rare earth elements for magnets, lenses, and other functions.  The world’s tech giants such as Apple, Huawei, and Tesla depend on suppliers of rare earths.

Rare earth elements are not actually rare, but they are very expensive to extract in ways that are not extremely harmful to the environment.  China has been a major source of these elements since its rare earth mining industry took off in the 1990s.  The removal of rare earths from the earth’s crust, using a mix of water and chemicals, has caused extensive water and soil pollution.

Today, concrete leaching ponds and plastic-lined wastewater pools dot the hills of Southeast China.  Large wastewater ponds sit uncovered and open to the elements in many places.  Landslides or barrier failures can spill contaminated contents into waterways or groundwater.

Local and federal officials in China have started to shut down illegal and small-scale rare earth mining operations and have embarked on a cleanup of polluted sites.  The rare earth mining cleanup operation is part of wider efforts across China to address severe problems of water, air and soil pollution.

China’s Ministry of Industry and Information Technology estimated that the cleanup bill for southern Jiangxi Province could amount to more than $5 billion.  Many environmental experts and local officials say that the cost of the cleanup should not be shouldered by the Chinese government alone, but also by the rare earth industry and the global companies and consumers that benefit from rare earth technology.  As rare earth mining efforts start up elsewhere around the world, it is important not to repeat the mistakes made in China.

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China Wrestles with the Toxic Aftermath of Rare Earth Mining

Photo, posted April 21, 2019, courtesy of John Beans via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Antibiotics In The Environment

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Antibiotics make their way into the environment in many ways.  Sources of antibiotic pollution include the waste from large-scale animal farms and the wastewater from hospitals, municipalities, and antibiotic manufacturing.

A new study has discovered concentrations of antibiotics in some of the world’s rivers exceed safe levels by up to 300 times.  In the project, researchers looked for 14 commonly used antibiotics in rivers in 72 countries across six continents.  They found antibiotics at 65% of all the sites they examined. 

The antibiotic ciproflaxacin was the compound that most frequently exceeded safe levels, surpassing that threshold in 51 places. The antibiotic metronidazole exceeded safe levels by the biggest margin.  Concentrations of this antibiotic at one site in Bangladesh was 300 times greater than the safe level.  The most prevalent antibiotic was trimethoprim.  It was detected at 307 of the 711 sites. 

Some of the world’s most iconic rivers were sampled as a part of this study, including the Danube, Mekong, Seine, Thames, Tiber and Tigris. 

The project, which was led by the University of York, found that high-risk sites were often located near wastewater treatment systems, waste or sewage dumps, and in some areas of political unrest. 

Safe levels for antibiotics, which were recently established by the AMR Industry Alliance, range from 20,000 to 32,000 nanograms per liter depending on the compound. 

According to the research team, solutions to the problem of antibiotic contamination should include infrastructure investment, tighter regulation, and the remediation of already contaminated sites. 

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Antibiotics found in some of the world’s rivers exceed ‘safe’ levels, global study finds

Photo, posted October 7, 2013, courtesy of Nicola via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Problem Of Microplastics

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In recent years, there have been multiple reports of microplastic contamination seemingly everywhere:  in the ocean, in lakes and rivers, in beverages and foods, and in the bodies of birds, fish, and even people.  As the world tries to come to grips with this growing problem, there are many things that we simply don’t know.

Microplastics are usually formed by the breakdown of larger pieces of plastic.  Shopping bags and cups degrade into microplastics.  Microfiber clothing generates microplastics in washing machines.  And some manufacturers still intentionally add microplastics to personal care products like toothpaste and facial scrubs.

Technically, a microplastic is any piece of plastic measuring five millimeters in size down to one micron – which is one thousandth of a millimeter.  But there can be even smaller plastic particles classified as sub-microplastics and even nanoplastics.

A real concern is that it is not actually clear how dangerous microplastics are for living organisms.  We know that aquatic and terrestrial species – including humans – can and do absorb microplastic particles, but whether there is actual toxicity and the nature of any detrimental effects is not yet well understood.

Another real problem is that it is actually not easy to distinguish microplastics from other particles in a given sample.   When you are looking at a particle that is smaller than a millimeter in size, it is not easy to tell whether it is a grain of sand, a bit of cellulose from a plant, or a microplastic.  There are reliable and definitive ways to analyze samples for microplastics, but they are not as simple and commonplace as just looking through a microscope.

Microplastics are a rapidly growing problem and we don’t even really know how big and how bad the problem is.

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How dangerous is microplastic?

Photo, posted January 10, 2015, courtesy of Daria Nepriakhina via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

An Accidental Plastic Eater

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A couple of years ago, scientists in Japan discovered bacteria at a recycling plant that were breaking down a type of plastic called polyethylene terephthalate, or PET.  With the world facing a growing plastic pollution problem, British and American researchers began to study the enzyme that the bacteria were using to try to understand how it works.

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A Ton Of Plastic Per Person

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A study by the American Association for the Advancement of Science has produced an estimate of the total amount of plastic manufactured worldwide since the 1950s.  The researchers then measured that data against statistics on recycling, incineration and discard rates.  The results are sobering.

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Dioxane And Drinking Water

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A byproduct of plastics production, dioxane is a clear, synthetic, liquid solvent that easily mixes with water.  It’s frequently used in paint strippers, dyes, and varnishes, as well as shampoos and body washes – particularly those that are sudsy.  Dioxane doesn’t really biodegrade and is widely regarded as a contaminant.    

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