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Turning Pollution Into Cash | Earth Wise     

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Power plants and other industrial facilities are a major source of carbon emissions.  There are a variety of techniques under development to prevent those emissions by capturing them rather than releasing them into the atmosphere.  All of them add costs to the functioning of the facility.  A good way to offset those costs is to convert the emissions into useful products, ideally making it profitable to capture emissions.

Engineers at the University of Cincinnati have developed an electrochemical system that converts carbon dioxide into ethylene, which is a chemical used in a wide range of manufacturing.  Ethylene has sometimes been called “the world’s most important chemical”.  It is used in many kinds of plastics, textiles, and the rubber found in tires and insulation. It is also used in heavy industry such as steel and cement plants as well as in the oil and gas industry.

The Cincinnati process is a two-stage cascade reaction that converts carbon dioxide to carbon monoxide and then into ethylene.  It is based on the underlying principle of the plug-flow reactor that is used for variety of production applications.  The study, published in the journal Nature Catalysis, demonstrates that the process has high ethylene selectivity – meaning that it effectively isolates the desired compound – as well as high productivity – meaning that it makes a lot of it.  The system will take more time to become truly economical, but the researchers are continuing to make progress on that front with improved catalysts.

The researchers believe that this technique can reduce carbon emissions and make a profit doing it.  Power plants and other facilities emit a lot of carbon dioxide.  With this process, it may be possible to capture it and produce a valuable chemical.

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Conversion process turns pollution into cash

Photo, posted February 27, 2018, courtesy of Cyprien Hauser via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wastewater As A Freshwater Source | Earth Wise

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Water covers three-quarters of our planet, but freshwater – the water we drink, bathe in, and irrigate crops with – comprises only 3% of the world’s water and much of that is frozen in glaciers or otherwise unavailable.  Nearly 3 billion people suffer from water scarcity for at least some of the year.

Natural freshwater sources – lakes, rivers, and groundwater – are under stress from the effects of climate change and from the increasing demands of city populations.  The wastewater treatment plants in large cities represent a significant potential water source provided that sustainable and economical technologies to produce it can be developed.

Researchers at Lehigh University in Pennsylvania have patented an innovative ion exchange desalination process that is a legitimate candidate to transform wastewater into usable water.

Existing large-scale desalination systems make use of semipermeable reverse osmosis membranes that require an energy source to run the system.  The Lehigh process, which they call HIX-Desal, harnesses the unique chemistry of carbon dioxide to take the place of the energy used in reverse osmosis systems. 

Tests of the new system show that the salinity of treated wastewater can be reduced by more than 60% by the HIX-Desal process without requiring any reverse osmosis.  At an Allentown, Pennsylvania water treatment plant where the system was tested, the researchers estimated that using the system could save about a million kWh per day in electricity usage, enough energy to power 94 homes for a year.

With this system, waste carbon dioxide from landfills or turbine exhaust can be used to desalinate municipal wastewater.  It could be the basis of a circular economy.

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Desalination tech uses CO2 to tap into municipal wastewater as alternative freshwater source

Photo, posted November 28, 2020, courtesy of Richard Ricciardi via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Better Ways To Make Bioplastics | Earth Wise

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The world produces over 300 million tons of plastics each year, mostly produced from petroleum.  The environmental consequences are substantial and there is a critical need to replace as much of that plastic production with biodegradable plastics as possible.  Thus, there is global research aimed at making bioplastics more economical and as environmentally friendly as possible.

Researchers at Texas A&M University have developed an improved approach for making bioplastics from corn stubble, grasses, and mesquite agricultural production.  Apart from the obvious environmental benefits of having biodegradable plastics, producing bioplastics from common agricultural waste would create new revenue streams for farmers as well as the people who transport harvested feedstock and byproduct crops to refinery operations.

The key to bioplastic production is the efficient extraction and use of lignin, the organic polymer that is the primary structural support material in most plants.  The new research takes five conventional pretreatment technologies for plant materials and modifies them to produce both biofuel and plastics together at a lower cost.  The new method is called “plug-in preconditioning processes of lignin” and it can be directly and economically added into current biorefineries.  The process is designed to integrate dissolving, conditioning, and fermenting lignin, extracting energy from it and making it easily adaptable to biorefinery designs.

The so-called bioeconomy currently supports some 286,000 jobs.  Innovation is the key to achieving more widespread use of biodegradable plastic.  With improved economics of so-called lignocellulosic biorefineries, there can be new avenues to use agricultural waste to produce biodegradable plastics.

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‘Plugging in’ to produce environmentally friendly bioplastics

Photo, posted November 5, 2015, courtesy of Kathryn Faith via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Getting Value From Plastic Waste | Earth Wise

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To date, the world has produced more than five billion tons of plastic and is making more all the time.  Based on the way things are currently done, most of that will end up in landfills or in the natural environment.  By 2050, the amount of plastic is expected to exceed 13 billion tons.   This is one of the world’s biggest environmental problems.

Recently, an international collaboration by universities and institutions in the UK, China, and Saudi Arabia has developed a method of converting plastic waste into hydrogen gas and high-value solid carbon.

The technique was achieved with a new type of catalysis that uses microwaves to activate catalyst particles that effectively strip hydrogen from plastic polymers.  The work was recently published in the journal Nature Catalysis and details how the researchers mixed mechanically pulverized plastic particles with a microwave-susceptor catalyst of iron oxide and aluminum oxide.  That mixture was then subjected to microwave treatment and yielded a large volume of hydrogen gas and a residue of carbonaceous material, most of which was identified as carbon nanotubes.

The process is more rapid than most methods for dealing with plastic waste and can extract over 97% of the hydrogen in plastic without producing any carbon dioxide emissions. 

The new method represents an attractive potential solution to the problem of plastic waste.  Instead of polluting the planet, plastics could become a valuable feedstock for producing clean hydrogen fuel as well as valuable carbon materials.  Proponents of the so-called hydrogen economy have continued to seek a green and economical way to produce hydrogen.  This new work might be just what they are looking for.

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Turning plastic waste into hydrogen and high-value carbons

Photo, posted April 21, 2007, courtesy of Redwin Law via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

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There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy.  Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen.  But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it.  The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants.  This membrane is an essential part of pairing the two photosystems.  It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes.  Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Oman’s Rocks

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There is growing interest in the idea of capturing and storing carbon dioxide.  Reducing the amount of it we are putting into the atmosphere is essential for limiting the effects of climate change, but even eliminating emissions entirely is not enough because the CO2 already there stays in the atmosphere for decades or more.

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New Energy Goals For New York

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Since 2015, New York has had in place an energy plan aimed at building a clean, resilient and cost-effective energy system for the state.  A key part of that plan is to reduce greenhouse gas emissions by 40% from 1990 levels by the year 2030.  Another major goal is to have 50% of the state’s electricity produced from renewable sources by the same year.

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Fuel From Greenhouse Gases

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Carbon dioxide and methane are the two greenhouse gases that are having the greatest impact on the global climate.  There are basically three ways to prevent them from getting into the atmosphere:  don’t emit them, trap them and store them away, or turn them into something useful.

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