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Concrete And Carbon | Earth Wise

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After water, concrete is the world’s second most consumed material.  It is the cornerstone of modern infrastructure.  Its production accounts for 8% of global carbon dioxide emissions.  The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement.  These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat.  However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide.  The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete.  The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly.  Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint.  In addition, the resulting concrete sets much more quickly.  It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pulling Carbon Dioxide Out Of Seawater | Earth Wise

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The world’s largest sink for carbon dioxide from the atmosphere is the ocean.  The world’s oceans soak up 30-40% of all the gas produced by human activities.  Dissolving carbon dioxide in water produces carbonic acid.   This is the reason that oceans are becoming increasingly acidic, which is causing serious damage to ocean ecosystems.

There are many efforts underway aimed at directly removing carbon dioxide from the air as a way to mitigate the effects of ongoing emissions.  But another possibility is to remove CO2 directly from ocean water.  Existing methods for doing it involve the use of expensive membranes and complex chemicals. The economics of such methods are quite unfavorable.

Recently, a team of researchers at MIT has identified what they claim is a truly efficient and inexpensive removal mechanism. It involves a reversible process based on membrane-free electrochemical cells.  Electrodes in the cells release protons that are introduced to seawater which drive the release of carbon dioxide dissolved in the water. The carbon dioxide can be collected and the processed water ends up being alkaline.

Running this process at a site that is already collecting seawater – such as at a desalination plant – would be an effective way to collect carbon dioxide as well as help mitigate ocean acidification.

Once the carbon dioxide is removed from the water, it still needs to be disposed of, just as is the case for other carbon removal processes.  It could be turned into useful chemicals or it could be stored in underground caverns.  But this approach is fairly unique in that the carbon dioxide has already been captured by the ocean.  The issue remains what to do with it.

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How to pull carbon dioxide out of seawater

Photo, posted January 19, 2016, courtesy of Judy Dean via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Plastic Into Protein | Earth Wise

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Our planet is choking on plastic.  According to the United Nations, 79% of the 6.3 billion tons of plastic produced every year accumulates in landfills.  Half of all plastic produced is actually designed to be used just once and thrown away.  But plastic is not only accumulating on land.  In fact, the world’s oceans are projected to contain more plastic by weight than fish by the year 2050.     

According to new research, solving the plastic waste issue could help address another prominent global issue: hunger.  A multidisciplinary team of engineers, chemists, and biologists led by researchers from Michigan Tech University has developed a process to break plastics down to be recycled into useful products, including edible protein powder.

The research team’s process converts plastic into compounds using heat and a reactor that deconstructs the material’s polymer chains. The oil-like substance is then fed to a community of oil-eating bacteria.  The bacteria grow rapidly on the oily diet, producing more bacterial cells composed of roughly 55% protein.  This majority-protein byproduct is then dried out and turned into an edible powder.   The end result doesn’t look like plastic at all.  In fact, it resembles a yeast byproduct that comes from brewing beer. 

This research is funded by an award from the US Department of Defense.  The DoD often deploys soldiers in areas where access to food is challenging.  Converting plastic to protein could be part of a solution to that problem. 

While eating something that began as plastic might take some getting used to, it could be part of the solution to both plastic pollution and global hunger.

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Turning Trash Into Treasure: The Plastic to Protein Powder Solution

Beat Plastic Pollution

Photo, posted February 2, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Better Way To Recycle Plastics | Earth Wise

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The global accumulation of plastic waste is an ever-growing problem.  At least five billion tons of the stuff has accumulated on land and sea and is even showing up in the bodies of animals and humans.  Recycling plastic instead of making even more of it seems like an essential thing to do but it has proven to be extremely challenging.

The main problem is that plastics come in many different varieties and the ways of breaking them down into a form that can be reused are very specific to each type of plastic.  Sorting plastic waste by plastic type is extremely impractical at large scale.  Certainly, most consumers can’t do it themselves.  As a result, most plastic gathered in recycling programs ends up in landfills.

New research at MIT has developed a chemical process using a catalyst based on cobalt that is very effective at breaking down a variety of plastics, including polyethylene and polypropylene, which are the two most widely produced plastics.   The MIT process breaks plastics down into propane.  Propane can be used as a fuel or as a feedstock for making many different products, including new plastics.

Plastics are hard to recycle because their long-chain molecules are very stable and difficult to break apart.  Most chemical methods for breaking their chemical bonds produce a random mix of different molecules which would somehow have to be sorted out in order to be useful for anything.

The new process uses a catalyst called a zeolite that contains cobalt nanoparticles.  The catalyst selectively breaks down various plastic polymer molecules and turns more than 80% of them into propane.

The researchers are still studying the economics and logistics of the method, but it looks quite promising.

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New process could enable more efficient plastics recycling

Photo, posted April 25, 2016, courtesy of NOAA Coral Reef Ecosystem Program via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Bitcoin Mining And The Environment | Earth Wise

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Bitcoin mining, the process by which the prominent cryptocurrency is created, is well-known to be energy intensive, but the environmental impact of it has not been extensively studied.  People have described Bitcoin as ‘digital gold.’  A new analysis by researchers at the University of New Mexico has found that Bitcoin mining shouldn’t be compared to gold mining.  It is more appropriately compared to the creation of much more energy-intensive products such as beef, natural gas, and crude oil.

Furthermore, the study found that rather than becoming more sustainable over time, Bitcoin mining is becoming dirtier and more damaging to the climate as long as it relies upon fossil-fuel generated electricity.  Estimates are that in 2020, Bitcoin mining used 75.4 terawatt hours of electricity, which is more electricity than the entire country of Austria, as well as 150 other nations around the world.

The study looked at the economic cost of the air pollution and carbon emissions associated with Bitcoin mining and found that in many instances, the negative economic impact of creating a single Bitcoin is more than what the resultant coin is worth.

Based on the market value of Bitcoins, the cost of climate damage for that value is a little less that that of electricity produced by natural gas and gasoline produced from crude oil, but actually more than that of beef production.

There are multiple cryptocurrencies.  Ether is one that voluntarily switched away from so-called proof-of-work mining.  Whether Bitcoin or others will act similarly absent potential regulation remains to be seen.  Until such time, Bitcoin mining remains an increasingly dirty and damaging business.

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Technology: UNM researchers find Bitcoin mining is environmentally unsustainable

Photo, posted May 11, 2017, courtesy of Komers Real via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Recycling Shingles | Earth Wise

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Every year in the US, about 13 million tons of asphalt material is removed from old roofs to be replaced with new shingles.  Only about 10% of that is recycled for use in paving and various roadway projects.  The other 12 million tons of asphalt ends up in landfills where it takes a very long time to break down.

GAF, the largest roofing manufacturer in North America, has developed a shingle recycling process for which it has received three patents.  The process involves grinding torn-off shingles into a refined material which can then be introduced into the shingle manufacturing process.  The material – referred to as RAS for recycled asphalt shingles – has the potential to significantly reduce the amount of virgin asphalt needed to make new shingles.

Tests by GAF reclaimed upwards of 90% of the waste shingle material and produced new shingles containing up to 15% recycled content.  Underwriters Laboratories certified the shingles containing RAS material with regard to their safety and effectiveness.  The GAF process opens to door to creating a circular, sustainable economy for asphalt used for roofing shingles.

Roofs play an important role in the transition to a green economy.  Apart from recycling asphalt shingles, there are increasing options for solar shingles, which take the place of both traditional asphalt shingles and ordinary solar panels by integrating them into a single roofing product.  There are also so-called green roofs, which replace conventional roofing materials with a contained green space atop a building. Such roofs provide stormwater management, cooling, and an interesting aesthetic.

All aspects of buildings play important roles in our environment – even their roofs.

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5 Ways Roofers Can Celebrate Earth Day, Everyday

Photo, posted April 15, 2012, courtesy of Robert Taylor via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Capturing Carbon Dioxide With Plastic | Earth Wise

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The world is awash in both waste plastic and in carbon dioxide emissions.   Researchers at Rice University have discovered a chemical technique for making waste plastic into an effective carbon dioxide absorbent for industry.

Chemists at Rice reported in the journal ACS Nano that heating plastic waste in the presence of potassium acetate produces particles with nanometer-scale pores that trap carbon dioxide molecules.   According to the researchers, these particles could be used to remove CO2 from the flue gas streams of power plants.

Significant sources of CO2 emissions like power plant exhaust stacks could be fitted with this waste-plastic-derived material to absorb large amounts of carbon dioxide that would otherwise enter the atmosphere. 

The Rice University process is an enhancement to the current process of pyrolyzing waste plastic – that is, breaking it down in the presence of heat.  By pyrolyzing plastic in the presence of potassium acetate, porous particles are formed that can hold up to 18% of their own weight in carbon dioxide.

According to the researchers, the cost of capturing carbon from a power plant would be $21 a ton, which is far less expensive than existing energy-intensive processes used to pull carbon dioxide from natural gas feeds.

The sorbent material can be reused.  Heating it to about 167 degrees Fahrenheit releases trapped carbon dioxide from the pores and regenerates about 90% of the material’s binding sites.

The Rice process may represent a much better way to capture carbon dioxide from power plant exhaust stacks.  It could be a way to make use of one environmental problem – waste plastic – to deal with another one.

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Treated plastic waste good at grabbing carbon dioxide

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Pollution Into Cash | Earth Wise     

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Power plants and other industrial facilities are a major source of carbon emissions.  There are a variety of techniques under development to prevent those emissions by capturing them rather than releasing them into the atmosphere.  All of them add costs to the functioning of the facility.  A good way to offset those costs is to convert the emissions into useful products, ideally making it profitable to capture emissions.

Engineers at the University of Cincinnati have developed an electrochemical system that converts carbon dioxide into ethylene, which is a chemical used in a wide range of manufacturing.  Ethylene has sometimes been called “the world’s most important chemical”.  It is used in many kinds of plastics, textiles, and the rubber found in tires and insulation. It is also used in heavy industry such as steel and cement plants as well as in the oil and gas industry.

The Cincinnati process is a two-stage cascade reaction that converts carbon dioxide to carbon monoxide and then into ethylene.  It is based on the underlying principle of the plug-flow reactor that is used for variety of production applications.  The study, published in the journal Nature Catalysis, demonstrates that the process has high ethylene selectivity – meaning that it effectively isolates the desired compound – as well as high productivity – meaning that it makes a lot of it.  The system will take more time to become truly economical, but the researchers are continuing to make progress on that front with improved catalysts.

The researchers believe that this technique can reduce carbon emissions and make a profit doing it.  Power plants and other facilities emit a lot of carbon dioxide.  With this process, it may be possible to capture it and produce a valuable chemical.

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Conversion process turns pollution into cash

Photo, posted February 27, 2018, courtesy of Cyprien Hauser via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Energy In Rochester | Earth Wise

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New York’s largest community choice clean energy program has been activated in the City of Rochester.   The program, offered by Rochester Community Power, offers 57,000 residences and small businesses access to clean energy from hydropower and wind sources.  It requires customers to opt out rather than enroll in order to provide clean energy to the greatest number of people.

Rochester Community Power is the city’s local community choice aggregation (CCA) program that leverages the collective buying power of participating residents to purchase renewable electricity and negotiate better terms for energy supply contracts.

The program will supply customers with more than 300 million kWh of renewable energy each year, which will avoid the emission of about 250,000 tons of carbon dioxide.  Rochester plans to add a community solar program next year which will provide additional clean energy opportunities, including offering guaranteed savings to thousands of participants in its Home Energy Assistance Program.

The project will be managed by Joule Assets, which is a provider of energy reduction market analysis, tools, and financing. Joule Assets, as program administrator for the Rochester program, managed the competitive bidding process that secured a fixed rate for electricity for the next two years, shielding participating residences and businesses from volatile market prices.

Community choice aggregation programs are local, not-for-profit public agencies that are an alternative to investor-owned utilities.  They give municipalities the ability to make decisions about the procurement, sourcing, and rates for energy for its residents.

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New York activates its largest opt-out 100% renewable energy program

Photo, posted June 25, 2011, courtesy of Paulo Valdivieso via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Tracking Endangered Species From Space | Earth Wise

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Scientists at the University of Bath and the University of Oxford in the UK have developed a technique for remotely surveying elephants and other wildlife using satellite images and deep learning.  The technique has the same accuracy as human counts done on the ground or from low-flying airplanes.

The new computer algorithm can analyze high-resolution satellite images and detect African elephants in both grasslands and forests.  Previous techniques for monitoring wildlife from space were limited to homogenous habitats, such as the case of tracking whales in the open ocean.

On-the-ground or airplane surveys to monitor animal numbers are expensive and time-consuming.  Satellites can collect nearly 2,000 square miles of imagery in a few minutes thereby eliminating the risk of double counting and reducing a process that previously took weeks to just a few days.  The use of satellites also eliminates the logistical problems of monitoring species populations that cross international borders.

Accurate monitoring is important for efforts to save endangered species.  There are only 40,000 – 50,000 African elephants left in the wild.  It is essential to know where the animals are and how many there are in various locations. The new method is able to count elephants in mixed ecosystems, such as savannah and forests, where tree cover would previously have made satellite tracking difficult.

With satellite imagery resolution increasing every few years, it should be possible to see ever-smaller things in greater detail.  The new algorithm works well for elephants; it may eventually become practical to track animals as small as an albatross from space.

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A New Way to Track Endangered Wildlife Populations from Space

Photo, posted March 15, 2008, courtesy of Michelle Gadd/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Finding Methane Leaks from Space | Earth Wise

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There is growing concern about the climate effects of methane leaking from oil and gas wells.  The 20-year global warming potential of methane is 84, meaning that over a 20-year period, it traps 84 times more heat per mass unit than carbon dioxide.  Global methane concentrations have increased by nearly a factor of 3 since the industrial revolution.

More than a century of oil and gas drilling has left behind millions of abandoned wells, many of which are leaching pollutants into the air and water.   In the U.S. alone, more than 3.2 million abandoned oil and gas wells emitted 280,000 tons of methane just in 2018.  And the data is incomplete.

Part of the problem is finding out which wells are leaking.  Ground-based sensors or airplanes and drones are effective ways to find leaks but considering how many wells there are to check, the costs are considerable, and the process is time consuming and complicated. 

New technology is coming along that uses satellites to detect methane leaks.  A Canadian company called GHGSat recently used satellites to detect what it has called the smallest methane leak ever seen from space and has begun selling data to emitters interested in pinpointing leaks.

Another company, New York-based Bluefield Technologies, plans a group of satellites for launch in 2023 that promises even finer resolution.  The Environmental Defense Fund, with support from Jeff Bezos’ Earth Fund, plans to launch MethaneSAT in the next couple of years, which is designed to find small sources of methane.

Research at Stanford University determined that just 5% of methane leaks produce around half the total leakage. 

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New Technology Claims to Pinpoint Even Small Methane Leaks From Space

Photo, posted June 8, 2011, courtesy of Jeremy Buckingham via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Palm Oil Replacement | Earth Wise

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In the 1990s, cardiovascular health issues associated with partially hydrogenated oils containing harmful trans fats became a focus of great concern.  As a result, food companies looked for substitutes and the alternative they identified was palm oil.  Its ability to remain solid at room temperature made it well suited for many food applications.  Unfortunately, that property stems from its high saturated fat content, which means it also increases the risk of coronary heart disease.

The widespread use of palm oil has also caused significant environmental problems.  Palm oil plantations have replaced millions of acres of tropical forests, destroying the habitat for numerous species and threatening biodiversity.

Other potential replacements for partially hydrogenated oils such as coconut oil tend to be more costly, limited in supply, and also high in saturated fats.

Food scientists at the University of Guelph in Ontario, Canada, recently demonstrated the use of enzymatic glycerolysis (EG) to turn liquid vegetable oils into solid fats.  Their process is able to produce solid fats with the textural and structural properties desired by consumers.

The process is fairly simple, relatively easy to scale up, and is amenable to smaller food production or even local production.  Using it would enable food producers to use all sorts of readily available vegetable oils that can be produced in parts of the world that are not necessarily tropical regions.

Palm oil use is not going to go away, but this work may point a way to help slow down the destruction of ecosystems and animal habitats as well lead to more sustainable and healthy food sources.

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U of G Food Scientists Find Palm Oil Alternative That’s Good for Human, Planet Health

Photo, posted February 21, 2010, courtesy of Craig Morey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Use Of Invasive Seaweed | Earth Wise

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In recent years, millions of tons of brown Sargassum seaweed have formed gigantic blooms stretching all the way across the Atlantic Ocean from West Africa to the Gulf of Mexico.  The seaweed has become a problem for shorelines in the Caribbean, the Gulf of Mexico, and the east coast of Florida.  The massive increase in seaweed populations is related to changes in ocean chemistry resulting from nutrients from fertilizer use entering the water as well as from changes to the climate affecting ocean currents and temperatures.  The seaweed is harming the tourism industry as well as fisheries and ocean ecosystems.

Cleaning up the seaweed that washes ashore is labor-intensive and therefore expensive.  A research team led by two British universities has developed a cheap and simple way to pre-process seaweed to facilitate making it into bulk chemicals and biofuels.  With the new process, cleaning up the seaweed can be both economically and environmentally viable.

Previous techniques for processing seaweed generally required removing it from the saltwater, washing it in fresh water, and drying it – all of which add significant costs.  The new technique makes use of catalysts to release sugars from untreated seaweed that feed a yeast to produce a palm oil substitute.  At the same time, the process creates heat and pressure, turning the residual materials into a bio-oil that can be processed further into fuels, and a high-quality, low-cost fertilizer.

Apart from getting economic value out of the seaweed that is collected, any plastic collected alongside the seaweed can be converted to useful materials as well. 

It appears that the seaweed scourge is here to stay, so finding an economically viable way to deal with it is a welcome development.

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Solve invasive seaweed problem by turning it into biofuels and fertilisers

Photo, posted August 10, 2015, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Safe And Simple Hydrogen Peroxide

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We don’t think about hydrogen peroxide very often.  Perhaps we have a bottle of it under our bathroom sink that we haven’t touched in a few years.   But it is an important product manufactured in the millions of tons each year and the basis of a $6 billion global business.

Hydrogen peroxide is widely used as an antiseptic, a detergent, in cosmetics, as a bleaching agent, in water purification, and in many other applications.  It is produced in industrial concentrations of up to 60% in solution with water in order to maximize the economics of transportation.  This makes transportation hazardous and costly because the concentrated form is unstable.  Most applications use a far more diluted form.

Researchers at Rice University have developed a new method for producing hydrogen peroxide that is much simpler and safer than the current technology, which actually dates back to the 1930s.  The Rice technique requires only air, water and electricity to produce the chemical.  The electrosynthesis process, which is detailed in the journal Science, uses an oxidized carbon nanoparticle-based catalyst.

The process could enable point-of-use production of pure hydrogen peroxide solutions, which would eliminate the need to transport the hazardous concentrated chemical.  The use of a solid electrolyte instead of the traditional liquid electrolyte eliminates the need for product separation or purification that is part of the current technology.

In the future, instead of storing containers of hydrogen peroxide, hospitals that use it as a disinfectant could turn on a spigot and get, for example a 3% solution on demand.  Instead of storing chemicals to disinfect swimming pool water, future homeowners could flick a switch and turn on their peroxide reactor to clean their pools.

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Water + air + electricity = hydrogen peroxide

Photo, posted April 19, 2009, courtesy of Robert Taylor via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Jet Fuels

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The global aviation industry uses a whole lot of fuel:  more than 5 million barrels a day.  It is an incredibly energy-intensive industry and almost all of its energy comes from petroleum-based fuels.

While other large energy sectors such as electric power, ground transportation and commercial buildings have well-defined pathways to adopting renewable energy sources, the aviation industry does not have such a straightforward way to make a transition to sustainability.  Electrifying planes using batteries or fuel cells is very challenging for a number of reasons, notably the weight restrictions on aircraft.  So liquid biofuels as replacements for petroleum-based fuels remain the most promising approach.

A new study at the Lawrence Berkeley National Laboratory concludes that sustainable plant-based biofuels could provide a competitive alternative to conventional petroleum fuels if current development and scale-up initiatives are successful.

Multidisciplinary teams based at the Department of Energy’s Joint BioEnergy Institute are focused on optimizing each stage of the bio-jet fuel production process.  This includes bioengineering ideal source plants and developing methods for efficiently isolating the carbohydrates in non-food biomass that bacteria can digest and bioconvert into fuel molecules.

The critical issue is cost.  The theoretical cost of bio-jet fuel has come down dramatically in recent years but is still around $16 a gallon.  The cost of standard jet fuel is about $2.50 a gallon.  So, the real challenge is bridging that gap.

Reducing the cost of the fuel could come both from the material and process improvements that are underway as well as by finding ways to turn the leftover lignin residuals from the bioconversion process into valuable chemicals. 

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Bright Skies for Plant-Based Jet Fuels

Photo, posted March 28, 2009, courtesy of Yasuhiro Chatani via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Deforestation-Free Palm Oil

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Few of us cook with palm oil or have ever even seen the stuff.  Nevertheless, 50% of all packaged grocery items – everything from ice cream and pizza to detergents and cosmetics – include it as an ingredient.  The global market for palm oil was $65 billion in 2015, and that number was projected to grow by more than 7% each year through 2021.

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The High Cost Of The Cloud

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More and more often we make use of “the cloud” – that mysterious place where we store, move, process and analyze data.  We keep our photos there.  We stream music and videos from there.  We do our work there.  Perhaps we have a mental image of all of this digital information floating above our heads in some ethereal way:  like in a cloud.

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