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Fossil-free fertilizer

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Ammonia is a major industrial commodity.  About 70% of it is used to make fertilizer, with the rest for a wide range of industrial applications.  Ammonia is the starting point for all mineral nitrogen fertilizers. 

Typically, ammonia is a byproduct of isolating hydrogen from natural gas, which releases large amounts of carbon dioxide.  On a global scale, the climate impact of ammonia production is comparable to that of air travel.  The world needs more ammonia but really cannot afford the emissions that come with its production.

There are also political implications of ammonia production.  Because it relies so heavily on natural gas, ammonia supply is vulnerable to disruptions from events like the Russian invasion of Ukraine.  Sanctions imposed after the invasion have hindered fertilizer exports, driving up costs, especially in places like Africa.

A small fertilizer plant near Nairobi, Kenya will be the first farm in the world to produce its own nitrogen fertilizer on site that is free of fossil fuels.  The plant is being built by an American startup company Talus Renewables and will use solar power to strip hydrogen from water.  The hydrogen will then bond with nitrogen from the air to form liquid ammonia.  The plant will produce one ton of ammonia each day.

The typical bag of fertilizer in sub-Saharan Africa travels 6,000 miles to get there, which of course only adds to the environmental burden of using it as well as its cost.  By building a small green ammonia plant like the one coming online in Kenya, it is possible to locally produce a critical raw material in a carbon-free manner.

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Farm in Kenya First to Produce Fossil-Free Fertilizer On Site

Photo courtesy of Talus Renewables via LinkedIn.

Earth Wise is a production of WAMC Northeast Public Radio

Salt Marshes And Climate Change | Earth Wise

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Salt marshes are coastal wetlands that are flooded and drained by salt water brought in and out by the tides. These low-lying wetlands are also sometimes called tidal marshes because they occur in the zone between low and high tides. These wetlands are some of the most biologically productive ecosystems on Earth.

Cape Cod’s beautiful salt marshes are as important as they are iconic.  They act as carbon sinks, protect coastal development from storm surge, play an outsized role in nitrogen cycling, and provide critical habitats for many fish, shellfish, and coastal birds.

According to scientists from the Marine Biological Laboratory in Woods Hole, Massachusetts, more than 90% of salt marshes around the world are likely to be underwater by the end of the century. 

Since 1971, scientists from the Marine Biological Laboratory have mapped vegetative cover in Great Sippewissett Marsh in Falmouth, Massachusetts, to examine whether increased nitrogen in the environment would impact species of marsh grass.  Because of the length of the study, the researchers were also able to investigate the impacts of climate change on the ecosystem, especially those driven by accelerating sea level rise. 

The research team found that increased nitrogen favored higher levels of vegetation and accretion of the marsh surface.  However, the researchers found that salt marshes will not be able to outpace the submergence from global sea level rise – no matter how much nitrogen is applied.

Sea level rise is the biggest threat to salt marshes around the world.  Mitigating some of these projected losses is critical in order for salt marshes to continue to provide their important ecosystem services for people and the planet.  

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Most of the World’s Salt Marshes Could Succumb to Sea Level Rise by Turn of Century

Photo, posted September 27, 2011, courtesy of Chris M Morris via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Seaweed On The Way | Earth Wise

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A type of seaweed called sargassum has long formed large blooms in the Atlantic Ocean.  It gets its name from the Sargasso Sea in the western Atlantic.  Since 2011, scientists have been tracking massive accumulations of the stuff each year that starts out off the coast of Africa and works its way across the Atlantic to end up in the Gulf of Mexico. 

The amount of sargassum present each year can shift depending on factors like changes in nutrients, rainfall, and wind conditions.  But since the 1980s, nitrogen content in the Atlantic has gone up by 45%.  This is likely due to human activities such as agriculture and fossil fuel production dumping materials into the rivers that feed into the ocean.

According to recent observations, the mass of seaweed now heading for Florida and other coastlines throughout the Gulf of Mexico may be the largest on record.  The giant blob of sargassum spans more than 5,000 miles in extent.  It is moving west and will pass through the Caribbean and up into the Gulf during the summer.  The seaweed is expected to become prevalent on beaches in Florida around July.

The seaweed provides food and protection for fishes, mammals, marine birds, crabs, sea turtles, and more.  But unfortunately, when sargassum hits the beaches, it piles up in mounds that can be difficult to walk through and eventually emits a gas that smells like rotten eggs.

Tourist destinations in the Caribbean region have their work cut out for them to remove seaweed that can pile up several feet deep.  For example, in Barbados, locals were using 1,600 dump trucks a day to clean their beaches.  Caribbean and Florida resorts spend millions of dollars each year to remove sargassum seaweed.

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A 5,000-mile-wide blob of seaweed is headed for Florida, threatening tourism across the Caribbean

Photo, posted February 24, 2020, courtesy of Bernard Dupont via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Electricity From Bacteria | Earth Wise

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Microbiologists at Radboud University in the Netherlands have demonstrated in the laboratory that methane-consuming bacteria can generate electrical power.  Their study was recently published in the journal Frontiers in Microbiology.

The bacteria studied is called Candidatus Methanoperedens and in the natural environment it consumes methane in water sources that are contaminated with nitrogen including places like water-filled ditches and some lakes. The bacteria in the study make use of the nitrates in the water to break down and digest the methane. Methanogens, which are bacteria that reduce carbon dioxide to form methane, are the source of the methane in these places. 

The researchers exploited these complex interactions of bacteria to create a source of electrical power that is essentially a kind of battery with two terminals.  One of the terminals is a chemical terminal and one is a biological terminal.  They grew the bacteria on one of the electrodes where the bacteria donate electrons that result from its conversion of methane.  (Other microbiologists at the same institution had previously demonstrated electrical generation from a similar battery containing anammox bacteria that use ammonium rather than methane in their metabolic processing).

In the study, the Radboud scientists managed to convert 31% of the methane in the water into electricity but they are aiming at higher efficiencies. 

This approach represents a potential alternative to conventional biogas electricity generation.  In those installations, methane is produced by microorganisms digesting plant materials and the methane is subsequently burned to drive a turbine to generate power.  Those systems in fact have an efficiency of less than 50%.  The researchers want to determine whether microorganisms can do a better job of generating electricity from biological sources than combustion and turbines can do.

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Bacteria generate electricity from methane

Photo, posted December 3, 2008, courtesy of Martin Sutherland via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Storing Sunshine To Make Electricity On Demand | Earth Wise

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Researchers at Chalmers University in Sweden have developed an entirely new way of capturing and storing energy from sunlight.  The system is called the Molecular Thermal Energy Storage System or MOST.  It is based on a specially designed molecule that changes shape when it is exposed to sunshine.

The molecule is composed of carbon, hydrogen, and nitrogen.  When sunlight hits it, it changes into an energy-rich isomer – a molecule made up of the same atoms but arranged together in a different way.  That isomer is stable and can be stored for many years.  When a specially designed catalyst is applied, the stored energy is released in the form of heat and the molecule returns to its original form and can be reused. 

The Chalmers researchers sent some of the energy-laden isomer to researchers in China who used it to operate a micron-thin thermoelectric generator, which used the heat released by the isomer material to generate electricity.  The generator is an ultra-thin chip that could be integrated into electronics such as headphones, smart watches, and telephones.  It is currently only at the proof-of-concept stage, but the results are quite promising.  The integration with the MOST technology provides a way that solar energy can generate electricity regardless of weather, time of day, season, or geographical location.  The results of the study were recently published in the journal Cell Reports Physical Science.

In effect, for this demonstration, Swedish sunshine was sent to the other side of the world and converted into electricity in China. The ultimate goal of this research is to create self-charging electronics that uses stored solar energy on demand.

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Converting solar energy to electricity on demand

Photo, posted March 11, 2013, courtesy of Steve Slater via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Florida’s Starving Manatees | Earth Wise

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Manatees, also called “sea cows”, have been the victims of farm runoff.  They have starved to death by the hundreds along Florida’s east coast because algae blooms fed by nitrogen-rich fertilizer runoff are proliferating on the ocean surface and blocking sunlight from reaching seagrass below.  Seagrass is the primary source of food for manatees in the winter.  As seagrass dies off, so do the manatees.

Over 1,000 manatees have been found dead so far this year.  It is estimated that fewer than 8,000 remain in Florida waters.  Efforts are underway to restore coastal seagrass in the region as well as clams and oysters, which filter pollutants from water.  Unless the water is cleared up, it will be difficult to regrow the seagrass.  But the current situation is that manatees are so short on food that they are eating seagrass roots, killing the plants and thwarting efforts to help seagrass recovery.

Given this dire situation, the federal governmental has approved a program of feeding manatees.  The starving animals will be fed by hand in Florida, which is a rare wildlife intervention.  Conservation agencies tend to favor leaving wild animals to their own foraging and hunting so that they don’t become dependent on human handouts.

During the trial phase of the program, wildlife experts are likely to feed the animals romaine lettuce and cabbage, which is what manatees in captivity eat.  The hope is to give the animals enough additional food for them to get through the winter.  The trial feeding will begin on private property.  It remains illegal for the public to feed manatees.

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Florida to feed starving manatees in rare conservation move

Photo, posted February 21, 2008, courtesy of Keith Ramos/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Decarbonizing The Most Polluting Heavy Industries | Earth Wise

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The production of steel, cement, and ammonia accounts for about 20% of the carbon dioxide humans pour into the atmosphere.  Modern cities are largely constructed from concrete and steel and most of our food is grown using fertilizer made from ammonia. 

The most widely discussed solutions to decarbonizing these industries are green hydrogen and carbon capture and storage or CCS.

Steel manufacture is responsible for 11% of society’s emissions.  Most production starts by burning coal in a blast furnace. Using CCS could reduce emissions from burning the coal.  But the blast furnace could be eliminated entirely by the use of electrolysis to produce the pure iron needed to make steel.  This would be extremely energy-intensive but using a low-carbon source like green hydrogen could greatly reduce the emissions from making steel.

Ammonia is made by producing hydrogen from natural gas and then combining it with atmospheric nitrogen.  Both the hydrogen production and ammonia synthesis are energy intensive.  Using green hydrogen would eliminate emissions from the hydrogen production itself and new research on catalysts aims at lower-temperature, less-energy intensive ammonia synthesis.

Decarbonizing cement manufacturing is perhaps the toughest challenge.  Cement is made in a high-temperature kiln, typically heated by burning fossil fuels.  The process converts calcium carbonate and clay into a hard solid called clinker.  The main byproduct of that is even more carbon dioxide.  Burning green hydrogen and capturing carbon emission are about the best hope for reducing cement manufacturing emissions.

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Can the World’s Most Polluting Heavy Industries Decarbonize?

Photo, posted June 30, 2009, courtesy of Portland Bolt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wastewater And Ammonia | Earth Wise

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Ammonia is the second most produced chemical in the world.  More than half of it is used in agriculture to produce various kinds of fertilizer, to produce cotton defoliants that make cotton easier to pick, and to make antifungal agents for fruits.  Globally, ammonia represents more than a $50 billion a year market.

Current methods to make ammonia require enormous amounts of heat – generated by burning fossil fuels – to break apart nitrogen molecules so that they can bind to hydrogen to form the compound. Ammonia production accounts for about 2% of worldwide fossil energy use and generates over 400 million tons of CO2 annually.

Engineers at the University of Illinois Chicago have created a solar-powered electrochemical reaction that uses wastewater to make ammonia and does it with a solar-to-fuel efficiency that is 10 times better than previous comparable technologies.

The process uses nitrate – which is one of the most common groundwater contaminates – to supply nitrogen and uses sunlight to power the reaction.  The system produces nearly 100% ammonia with almost no hydrogen side reactions.  No fossil fuels are needed, and no carbon dioxide or other greenhouse gases are produced.  The new method makes use of a cobalt catalyst that selectively converts nitrate molecules into ammonia.

Not only is the reaction itself carbon-neutral, which is good for the environment, but if it is scaled up for industrial use, it will consume wastewater, thereby actually being good for the environment.  The new process is the subject of a patent filing and the researchers are already collaborating with municipal corporations, wastewater treatment centers, and others in industry to further develop the system.

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Combining sunlight and wastewater nitrate to make the world’s No. 2 chemical

Photo, posted August 29, 2018, courtesy of Montgomery County Planning Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Pesticide From Beer | Earth Wise

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Researchers from the Neiker Basque Institute for Agricultural Research and Development in Spain have demonstrated that a combination of rapeseed cake and beer bagasse can be used to reduce populations of soil parasites and increase crop yields. 

Beer bagasse is spent brewers’ grain – the stuff that is left over after the beer is made.  Beer brewing generates substantial amounts of by-products, including large amounts of spent grain.  It already has some practical uses, including as a feedstock for biofuel, as a food additive, and it even has some medical uses.  But the new research has shown that the bagasse can be the basis for a biodisinfestation treatment to be used in agriculture.  The aim is to disinfect soils, protect soil microorganisms, and increase crop yields.

The actual material studied was a mixture of beer bagasse, rapeseed cake, and a generous amount of fresh cow manure.  The high nitrogen content of the mixture promotes the activity of beneficial microorganisms in the soil, which helps to break down organic matter and kill off nematodes and other parasites that damage crops.

Nematodes are common parasites that can penetrate plant roots to lay their eggs, which damages the root and prevents the plants from absorbing nutrients effectively.  Application of the bagasse-based mixture over 12 months increased crop yields by 15% and boosted healthy soil microbes.

The study demonstrated that agricultural byproducts can be an effective treatment for root-knot nematodes and other soil parasites, increase crop yields, and help promote sustainable food systems to reduce waste from the agricultural industry.  The researchers hope to identify other potential organic treatments for tackling soil parasite problems.

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Beer byproduct mixed with manure proves an excellent organic pesticide

Photo, posted July 1, 2011, courtesy of Quinn Dombrowski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The World’s Largest Harmful Algal Bloom | Earth Wise

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Brown sargassum seaweed floats in surface water in a bloom that stretches all the way from West Africa to the Gulf of Mexico.  Sargassum provides habitat for turtles, crabs, fish, and birds.

The stuff carpets beaches along the tropical Atlantic, the Caribbean Sea, the Gulf of Mexico, and the east coast of Florida disrupting tourism.  Florida’s Miami-Dade County alone spends $45 million a year cleaning up sargassum.  Annual Caribbean clean-up is in excess of $120 million.

A study by Florida Atlantic University has discovered dramatic changes in the chemistry and composition of sargassum which has transformed the so-called Great Atlantic Sargassum Belt into a toxic dead zone.

The findings of the study suggest that increased nitrogen availability from both natural and human-generated sources, including sewage, is supporting blooms of sargassum and turning a critical marine nursery habitat into harmful algal blooms with catastrophic impacts on coastal ecosystems, economies, and human health.

The study found that today’s sargassum tissues compared with those of the 1980s have 35% more nitrogen content and 42% less phosphorus.  Much of the nitrogen increase is a result of agricultural and industrial runoff from the Congo, Amazon, and Mississippi Rivers. 

The fact that the bloom itself has expanded so tremendously was already suspected to be the result of significant changes in the ocean’s chemistry.  Given the negative effect that the Great Atlantic Sargassum Belt is having on the coastal communities, additional research is essential to guide mitigation and adaptation efforts.

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Sargassum now world’s largest harmful algal bloom due to nitrogen

Photo, posted June 5, 2016, courtesy of J Brew via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Food Waste Back Into Food | Earth Wise

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Scientists at the University of California Riverside have discovered that fermented food waste can boost bacteria that increase crop growth, make plants more resistant to pathogens, and reduce the carbon emissions resulting from farming.

Food waste is a serious problem from multiple perspectives.  As much as 50% of food is thrown away in the United States and most of that simply ends up in landfills, taking up more than 20% of America’s landfill volume.  Food waste is a huge economic loss as well as a significant waste of freshwater resources used to produce food.

The researchers studied byproducts from two kinds of food waste readily available in Southern California:  beer mash – a byproduct of beer production – and mixed food waste discarded by grocery stores.

Both types of waste were fermented and then added to the irrigation system watering citrus plants in a greenhouse.  Within 24 hours, the average population of beneficial bacteria was two to three orders of magnitude greater than in plants that did not receive the treatments. This led to improvements in the carbon to nitrogen ratio in crops.  When there are enough so-called good bacteria in plants, they produce antimicrobial compounds and metabolites that help plants grow better and faster.

The results of the study suggest that the use of food waste products in agriculture is beneficial and could complement the use of synthetic chemical additives by farmers, perhaps eliminating it entirely.  Crops would in turn become less expensive.

Making use of food waste in agriculture is a step towards a more circular economy in which we use something and then find a new purpose for it.

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Turning food waste back into food

Photo, posted October 28, 2012, courtesy of Daniel Lobo via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Renewable Energy And Green Ammonia | Earth Wise

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Several different clean technology trends may come together on farms across the country where wind turbines could power devices that produce green ammonia for fertilizer and zero emission fuel.

Distributed wind is a kind of renewable energy that doesn’t get much attention.  It refers to turbines that are used to generate electricity for on-site use, as for a factory or a farm.  It typically involves smaller turbines than the behemoths that are used in giant wind farms.

Installing a wind turbine or two on a farm could be quite valuable if the electricity generated could be used to make green ammonia.  Such an application would eliminate the problem of “stranded wind”, which is when a location has lots of wind but lacks access to the electricity transmission infrastructure.

If farmers could utilize wind energy to produce ammonia, they could make their own fertilizer as well as fuel and get relief from price spikes and uncertainties in the commodities market.  Of course, they would also make use of the electricity they generate on site.

Most ammonia is produced using a proven technology called the Haber-Bosch process.   Ammonia contains only nitrogen and hydrogen, both of which can be extracted from the air.  The trick is how to do it efficiently using renewable electricity.   The Department of Energy has a program called the REFUEL Initiative, which aims at deploying renewable energy to produce ammonia.  The University of Minnesota, among other places, has multiple programs dedicated to green ammonia technology. 

There is encouraging progress being made that may ultimately result in a common sight of wind turbines on farms producing fertilizer, fuel, and electricity.

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The Renewable Energy Cows Come Home, Now With Green Ammonia

Photo, posted July 15, 2009, courtesy of Daniel_Bauer via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Carbon Capture Technique | Earth Wise

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Carbon dioxide emissions by electricity generating plants, fossil-fuel burning vehicles, and industry produce about 2/3 of the greenhouse gases driving climate change.  Without decreasing these emissions, the earth will continue to get warmer, sea levels will continue to rise, and the world will face more droughts, floods, wildfires, famine and conflict.

Electrification of vehicles and reliance upon renewable energy sources will ultimately drastically reduce the use of fossil fuels and the resultant emissions, but that transition may take too long to reverse the direction of climate change.  In the meantime, there is a great need to find effective and efficient ways to capture emissions from fossil fuel plants. 

Recent research at the University of California, Berkeley, Lawrence Berkeley National Laboratory, and ExxonMobil has developed a new technique for carbon capture.  The technique makes use of metal-organic framework (or MOF) technology.  An MOF, modified with nitrogen-containing amine molecules, captures CO2 and then low-temperature steam is used to flush out the CO2 either to be used or sequestered underground.

Experiments demonstrated the technique to have a six-times greater capacity for removing CO2 from the flue gas of a refinery than current amine-based technology.  It selectively removed 90% of the emitted CO2. 

There is a relatively limited market for captured CO2, so power plants using the capture technology would likely pump the CO2 into the ground, or otherwise sequester it.  The cost of doing this sort of emission scrubbing would have to be facilitated by government policies, such as carbon trading or a carbon tax, which would provide the necessary economic incentive for doing carbon capture and sequestration.

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New technique to capture CO2 could reduce power plant greenhouse gases

Photo courtesy of UC Berkeley.

Earth Wise is a production of WAMC Northeast Public Radio.

A Hidden Source Of Arctic Carbon | Earth Wise

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Researchers from the University of Texas at Austin, the U.S. Fish and Wildlife Service, and Florida State University have published a paper presenting evidence of significant and previously undetected concentrations and fluxes of dissolved organic matter entering Arctic coastal waters.  The source of the organic matter is groundwater flow atop the frozen permafrost.  The groundwater moves from land to sea unseen, but the new research reveals that it carries significant concentrations of carbon and other nutrients to Arctic coastal food webs.

Globally, groundwater is important for delivering carbon and other nutrients to oceans, but in the Arctic, where much water is trapped in the permafrost, its role was thought to be minimal.  But the new research reveals that groundwater may be contributing an amount of dissolved organic matter to the Alaskan Beaufort Sea that is comparable to what comes from neighboring rivers during the summer.

The researchers found that shallow groundwater flows beneath the surface and picks up new, young organic carbon and nitrogen, but it also mixes with layers of deeper soils and thawing permafrost, picking up and transporting century-to-millennia old organic carbon and nitrogen.  This material is unique because it is directly transported to the ocean without seeing or being photodegraded by sunlight and may be valuable as a food source to bacteria and higher organisms that live in Arctic coastal waters.

The study concluded that the supply of leachable organic carbon from groundwater amounts to as much as 70% of the dissolved organic matter that enters the Beaufort Sea from rivers during the summer.  The role that groundwater inputs play in Arctic coastal ecosystems will be an area of active research for years to come.

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Hidden Source of Carbon Found at the Arctic Coast

Photo, posted June 14, 2015, courtesy of Eugen Marculesco via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Working Forest Buffers | Earth Wise

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More than 100,000 miles of U.S. rivers and streams are polluted by nitrogen and phosphorus, mostly from agricultural runoff.  In the past, forests grew naturally alongside these waterways and helped stabilize stream banks and decrease flooding while trapping and filtering pollutants.  But most of these forests have been cut down to make way for towns, cities, livestock, and crops.

Farmers are reluctant to retire valuable farmland with non-productive buffer planting.  But in Pennsylvania, there is an innovative program that encourages farmers to plant cash crops in waterway buffer zones that can help stabilize stream banks and clean up the waterways.  These plantings are called working buffers.

Strips of streamside land are replanted with native floodplain trees and shrubs.  These are known as riparian forest buffers.  Pennsylvania has instituted a grant program under which farmers and landowners plant these buffers and turn a profit.

Many of these buffers have three zones.  A conventional forest buffer that can be just 15 feet wide is composed of native woodland and stabilizes the bank with tree roots and enhances wildlife habitat.  A second zone, some 20 feet wide, is planted with trees and shrubs that can tolerate periodic flooding.  Apart from slowing floodwater and taking up nutrients, this zone can provide profits by planting trees like black walnut, hazelnut, persimmon, and elderberry.  Only hand harvesting is allowed.  A third zone, adjacent to conventional crop, can contain blueberries, raspberries, and decorative woody florals.

How many farmers can be enticed to create these riparian buffers remains to be seen, but they do represent a way to help farmers to reduce pollution and turn a profit along the way.

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A Movement Grows to Help Farmers Reduce Pollution and Turn a Profit

Photo, posted March 19, 2010, courtesy of the USDA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Powerful Case For Protecting Whales

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Efforts to mitigate climate change typically face two major challenges.  One is to find effective ways to reduce the amount of atmospheric carbon dioxide.  The other is how to raise enough money to implement climate mitigation strategies. 

Many proposed solutions to climate change, like carbon capture and storage, are complex, expensive, and in some cases, untested.  What if there was a low-tech solution that was effective and economical?

Well, it turns out there is one, and it comes from a surprisingly simple, “no-tech” strategy to capture CO2: increase global whale populations. 

According to a recent analysis by economists with the International Monetary Fund, whales help fight climate change by sequestering CO2 in the ocean. 

Whales sequester carbon in a few ways.  They hoard it in their fat and protein-rich bodies, stockpiling tons of carbon apiece.  When whales die, they turn into literal carbon sinks on the ocean floor.  While alive, whales dive to feed on tiny marine organisms like krill and plankton before surfacing to breathe and excrete. Those latter activities release an enormous plume of nutrients, including nitrogen, iron, and phosphorous, into the water.  These so-called “poo-namis” stimulate the growth of phytoplankton, microscopic marine algae that pull CO2 out of the air and return oxygen to the air via photosynthesis.  Phytoplankton are responsible for every other breath we take, contributing at least 50% of all oxygen to the atmosphere and capturing approximately 40% of all CO2 produced. 

With other economic benefits like ecotourism factored in, economists estimate that each whale is worth $2 million over its lifetime, making the entire global population possibly a one trillion dollar asset to humanity.

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How much is a whale worth?

Photo, posted June 12, 2013, courtesy of Gregory Smith via Flickr.

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New Membranes For Carbon Capture

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Drastically reducing the amount of carbon dioxide being emitted into the atmosphere is an essential goal in the effort to mitigate the effects of climate change.  While the ultimate solution is to avoid combustion of fossil fuels by the use of clean alternative energy sources, that transition will take time – possibly more time than we have.  As a result, there is a great deal of effort underway to develop techniques for capturing the carbon emitted by fossil fuel combustion and either recycling it or storing it.

There are multiple ways to capture carbon emissions, but the ultimate goal is to find a technique that is both inexpensive and scalable.  One promising technique involves the use of high-performance membranes, which are filters that can specifically pick out CO2 from a mix of gases, such as those coming out of a factory smokestack.

Scientists at a Swiss laboratory have now developed a new class of high-performance membranes that exceeds the targeted performance for carbon capture by a significant margin.  The membranes are based on single-layer graphene with a selective layer thinner than 20 nanometers – only about 40 atoms thick. The membranes are highly tunable in terms of chemistry, meaning that they can be designed to capture specific molecules.

The membranes are highly permeable – meaning that they don’t impede gas flow too much – but highly selective.  The CO2/N2 separation factor is 22.5, which means that 22.5 times more nitrogen can get through the membrane than carbon dioxide.

The work is just at the laboratory stage at this point, but it is a very promising step towards developing a practical scheme for keeping carbon dioxide from escaping from power-plant and factory smokestacks.

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Next-gen membranes for carbon capture

Photo, posted December 28, 2010, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Mexico’s Wonder Plant

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In 1979, an American naturalist named Thomas Hallberg visiting a small town in Oaxaca, Mexico was amazed to find a type of local maize – or corn – that grew nearly 20 feet high in poor-quality soil even though the local farmers did not use any fertilizer.

The unique corn plant had aerial roots that grew a mucous-like gel just before harvest season.  It seemed totally implausible, but the plant seemed to be fixing its own nitrogen:  extracting it from the air and somehow making it useful to the plant.

In 1992, Hallberg returned with a group of Mexican scientists and collected samples to study in his lab.  His research showed that the maize indeed received nitrogen from the air through its aerial roots.  It took over 20 years to figure out what was going on in the plants.  It turns out that bacteria that thrive in the low-oxygen environment of the maize’s mucus pulls nitrogen from the air and feeds it to the plant.

Scientists will probably spend years figuring out if a commercial application of this indigenous maize is viable.  It isn’t guaranteed that the self-fertilizing trait of the plant can be bred into a commercial crop.  But if it can, the payoff would be huge.  Farmers spend more than $3 billion a year on corn fertilizer in the US alone.

A vexing problem is who should reap the financial benefits of the maize.  The isolated village where the plant is grown has already signed an agreement to share in any such benefits.   But there are other Oaxacan villages that also grow the plant. 

Mexico’s wonder plant is likely to be caught up in the growing issue of biopiracy, which is the exploitation of indigenous knowledge and biological resources without permission.

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Indigenous Maize: Who Owns the Rights to Mexico’s ‘Wonder’ Plant?

Photo credit: ALLEN VAN DEYNZE/UC DAVIS

Earth Wise is a production of WAMC Northeast Public Radio.

High-Tide Flooding And Pollution

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Global sea levels are steadily rising.  They are up 8 inches in the past century and now increasing at an average of 1.3 inches per decade.  As a result, the incidence of high-tide “sunny day” flooding is on the rise, especially along the U.S. East Coast.

Norfolk Virginia experienced fewer than 2 days of high-tide flooding a year in the 1960s; it had 14 in 2017.  Up and down the East Coast, flood days have increased by factors of 5 and more.

This has led to a form of pollution that hasn’t gathered much attention in the past:  when these floodwaters recede, they can carry debris, toxic pollutants and excess nutrients into rivers, bays, and oceans.

In the aftermath of high-tide flooding in Norfolk, Chesapeake Bay was littered with tipped-over garbage cans, tossed-away hamburgers, oil, dirty diapers, pet waste and all manner of other things.  Water that comes up on the landscape takes everything back into the river or ocean with it.

Analysis of tidal flooding along the Lafayette River in Norfolk indicated that just one morning of tidal flooding poured nearly the entire EPA annual allocation of nitrogen runoff for the river – nearly 2,000 pounds – into Chesapeake Bay.  The effects of excess nitrogen in the water are well-known and responsible for the toxic algal blooms that endanger aquatic life as well as human health.

According to the National Oceanic and Atmospheric Administration, high-tide flooding frequency along the southeastern coast of the U.S. rose 160% since 2000.  With the expected continuing rises in sea level, NOAA projects that as many as 85 days of high-tide flooding will occur along the coast by the year 2050.  It’s a big problem.

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As High-Tide Flooding Worsens, More Pollution Is Washing to the Sea

Photo, posted September 20, 2018, courtesy of SC National Guard via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Disease On Coral Reefs

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The warming oceans have led to bleaching events in coral reefs around the world, but bleaching is not the only problem corals face.  Disease outbreaks are also becoming more frequent, severe, and widespread.

Many factors are contributing to the problem, including pollution and nitrogen runoff from fertilizers and coastal sewer and septic systems.  However, the key culprit is likely the steadily increasing ocean temperatures, which are the cause of coral bleaching.  Elevated water temperatures can cause coral polyps to expel the algae that sustains them and gives them color. 

According to scientists, bleaching makes corals more susceptible to illness.  In the Caribbean, a coral disease hotspot, about 80% of coral cover has disappeared, largely from outbreaks of “white band disease”, so called because of a white band of dead tissue that forms in affected corals.  Two crucial reef-building species, elkhorn and staghorn coral, are now nearing extinction in the regions.  The reef extending along the Florida coastline is the third largest reef ecosystem in the world and nearly 35% of it has been lost to disease.

Estimates are that disease outbreaks have wiped out at least 6% of the corals on the Great Barrier Reef in Australia.  In that region, diseases are more prevalent in areas where corals were damaged by fishing and other human activity because wounded coral provides an entry point for pathogens and bacteria.

In the face of climate change and mounting disease outbreaks, scientists are scrambling for solutions to stave off catastrophe.  Assisting the migration of hardier coral species and breeding so-called “super corals” are among the strategies being pursued.  It is unknown whether these and other forms of intervention can be used on a wide enough scale to really make a difference.

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As Disease Ravages Coral Reefs, Scientists Scramble for Solutions

Photo, posted November 29, 2012, courtesy of Robert Linsdell via Flickr.

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