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Cheaper Carbon Capture | Earth Wise

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As the years roll by without sufficient progress in reducing carbon dioxide emissions, the need for technologies that can capture CO2 from its sources or remove it from the air becomes stronger and stronger.  People have developed various ways to capture carbon dioxide, but to date, they generally suffer from some combination of being too costly or not being able to scale up to the necessary magnitude.

Scientists at the Pacific Northwest National Laboratory in Richland, Washington recently announced the creation of a new system that they claim is the least costly to date that captures carbon dioxide and turns it into a widely-used chemical: methanol.

Technologies that simply capture carbon dioxide that then needs to be stored in some secure location are difficult to implement from a cost perspective.  The PNNL researchers believe that turning CO2 into methanol can provide the financial incentive for widespread implementation.   Methanol can be used as a fuel, a solvent, or an important ingredient in plastics, paint, construction materials, and car parts.

The system is designed to be installed in fossil fuel-fired power plants as well as cement and steel plants.  Using a capture solvent developed by PNNL, the system grabs carbon dioxide molecules before they are emitted and converts them into methanol. Creating methanol from CO2 is nothing new, but capturing the carbon dioxide and converting into methanol in one continuously flowing system is new.

More work is needed to optimize and scale the process and it may be several years before it is ready for commercial deployment.

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Scientists Unveil Least Costly Carbon Capture System to Date

Photo, posted November 25, 2022, courtesy of Massachusetts Department of Environmental Conservation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Better Way To Capture Carbon | Earth Wise

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The goal of carbon capture and storage technology is to remove carbon dioxide from the atmosphere and safely store it for the indefinite future.  There are existing industrial facilities that capture carbon dioxide from concentrated sources – like the emissions from power plants.  The technology currently captures and stores only about a tenth of a percent of global carbon emissions.

Most existing CCS technologies use chemical binders to trap carbon dioxide quickly and efficiently, but they are extraordinarily energy intensive as well as expensive.

Researchers at the University of Colorado Boulder have developed a new tool that could lead to more efficient and cheaper ways to capture carbon dioxide directly out of the air.  The tool predicts how strong the bond will be between carbon dioxide and a candidate molecule for trapping it – that is, a binder.  This new electrochemical diagnostic tool can be used to identify suitable molecular candidates for capturing carbon dioxide from everyday air.

Current carbon capture technologies are very expensive at the scale required to be able to turn the captured CO2 into useful substances, such as carbonates – which are an ingredient in cement – or formaldehyde or methanol, which can be used as fuels.  Making useful materials out of the captured CO2 is an important way to offset the cost of capturing it that merely storing it away does not permit.

The new electrochemical analytical tool developed by the Colorado researchers offers the potential for identifying binders that will be more efficient and less expensive, thereby making direct air carbon capture a realistic part of the efforts to address climate change.

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New method could lead to cheaper, more efficient ways to capture carbon

Photo, posted October 25, 2015, courtesy of Frans Berkelaar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Scaling Up Green Hydrogen | Earth Wise

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The global hydrogen market generates about $150 billion dollars a year.  The bulk of the market consists of hydrogen used to produce ammonia, refine oil, and produce methanol.  Advocates for hydrogen foresee a $600 billion a year market based on power and industry uses, mobility and transport uses, chemical feedstocks, and construction.  But the problem with expanding the use of hydrogen is that the vast majority of hydrogen in use today is produced from fossil fuels such as natural gas and coal and producing it creates carbon dioxide emissions.

The great hope of the industry is “green hydrogen”- hydrogen produced either without using fossil fuels at all or by capturing and storing the emissions generated. The most likely approach is electrolysis – using electricity to produce hydrogen from water.

Billions of dollars are being invested by both governments and by large oil companies in a race to scale up electrolysis and make it economically attractive.  According to the Hydrogen Council industry lobby group, at least $300 billion is expected to be invested globally over the next decade aimed at developing the green hydrogen that could one day meet almost a fifth of global energy demand.

Many argue that producing green hydrogen with electrolysis is an extremely inefficient way to utilize renewable energy.  Critics of hydrogen-powered vehicles particularly make this argument.   But industrial applications of hydrogen that currently use large amounts of fossil fuels – such as steel manufacturing – may be places where green hydrogen would make a real dent in global emissions.

The race to clean up hydrogen is definitely on.

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The Race to Scale Up Green Hydrogen to Help Solve Some of the World’s Dirtiest Energy Problems

Photo, posted December 16, 2020, courtesy of Sharon Hahn Darlin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Membrane For Converting Carbon Dioxide | Earth Wise

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Methanol is a valuable chemical used as fuel in the production of countless products. Carbon dioxide is a greenhouse gas that is produced by countless industrial processes.  Carbon dioxide can be converted into methanol, which is one way all that CO2 can be put to good use instead of causing harm. 

In research recently published in Science, chemical engineers from Rensselaer Polytechnic Institute have developed a process that converts CO2 to methanol in a more efficient way by using a highly effective separation membrane they produced.  

The chemical reaction responsible for the transformation of CO2 into methanol also produces water, which severely restricts the continued reaction. The Rensselaer team has found a way to filter out the water as the reaction is happening, without losing other essential gas molecules. 

They produced a membrane made up of sodium ions and zeolite crystals that was able to carefully and quickly permeate water through small pores — known as water-conduction nanochannels — without losing gas molecules. The sodium ions effectively only allow water to go through. When water was effectively removed from the process, the team found that the chemical reaction was able to happen very quickly. By removing the water, the equilibrium shifts, which means more CO2 will be converted and more methanol will be produced.  

The team is now working to develop a scalable process and a startup company that would allow this membrane to be used commercially to produce high purity methanol.  This membrane could also be used to improve a number of other reactions. 

In industry there are many reactions limited by water and this RPI membrane could be an important enhancement for many of them. 

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Water-Conducting Membrane Allows Carbon Dioxide To Transform into Fuel More Efficiently

Photo courtesy of RPI.

Earth Wise is a production of WAMC Northeast Public Radio.

Floating Solar Fuel Farms

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Limiting global warming will require a massive reduction in CO2 emissions from fossil fuel burning.  Renewable energy sources are playing a growing role in the power grid and electric cars are becoming increasingly popular.  Despite all this, carbon-based liquid fuels will continue to dominate our energy use for the foreseeable future.

Researchers in Norway and Switzerland have described a potential scheme that would help remove CO2 from the atmosphere and produce a valuable liquid fuel.

The idea is to create floating islands containing large numbers of solar panels that convert carbon dioxide in seawater into methanol, which can fuel airplanes and trucks.

A combination of largely existing technologies would be the basis of these floating islands, which would be similar to present-day floating fish farms.  The researchers envision clusters each composed of 70 circular solar panels that in total cover an area of roughly half a square mile.  The solar panels would produce electricity, which would split water molecules and isolate hydrogen.  The hydrogen would then react with carbon dioxide pulled from seawater to produce usable methanol.

The technology already exists to build the floating methanol islands on a large scale in areas of the ocean free from large waves and extreme weather.  Suitable locations are off the coasts of South America, North Australia, the Arabian Gulf, and Southeast Asia.

A single floating solar farm could produce more than 15,000 tons of methanol a year – enough to fuel a Boeing 737 airliner for more than 300 round-trip flights across the country.  Floating energy islands would not be a magic bullet for limiting the effects of climate change, but they could well be an important part of an overall strategy.

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Giant Floating Solar Farms Could Make Fuel and Help Solve the Climate Crisis, Says Study

Photo courtesy of PNAS.

Earth Wise is a production of WAMC Northeast Public Radio.

The Methanol Economy

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The methanol economy is an idea that was promoted by the late Nobel-prize-winning chemist George Olah since the 1990s.  The idea is to replace fossil fuels with methanol for energy storage, ground transportation fuel, and raw material for hydrocarbon-based products.   Methanol is the simplest alcohol and can be produced from a wide variety of sources ranging from fossil fuels to agricultural products to just carbon dioxide.  Methanol can be used directly as a fuel or it can be reformed into hydrogen, which can then itself be used as a fuel.

[Read more…] about The Methanol Economy

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