fuels

Liquid Fuel From Sunshine | Earth Wise

July 6, 2023 By EarthWise Leave a Comment

A key goal of artificial photosynthesis research is to be able to produce a useful liquid fuel using only carbon dioxide, water, and sunlight in a single step. Such a so-called solar fuel would produce net zero carbon emissions and would be completely renewable.

Bioethanol has long been touted as a green alternative to fossil fuels, since it is made from plants rather than petroleum. But producing it takes up agricultural land that could be used to grow food instead and there are emissions associated with many aspects of the process by which plant mass becomes fuel.

Researchers from the University of Cambridge in the UK have developed a so-called artificial leaf that produces ethanol or propanol – usable liquid fuels – in a single step. They developed a copper and palladium-based catalyst that allows the artificial leaf to directly produce multicarbon complex chemicals. Earlier versions of artificial leaves could make simple chemicals, such as syngas, which would then require additional processing to turn into high-density fuels.

The new device produces liquid fuel from carbon dioxide and water simply by shining sunlight on it.

At present, the artificial leaf is a proof-of-concept device that exhibits only modest efficiency. The researchers are working to optimize the device’s light absorbers so that they can better make use of sunlight and to optimize the catalyst so that it can convert more of the sunlight into fuel. In addition, the device needs to be scaled up so that it can produce large volumes of fuel.

All that being said, it is an important step towards people being able to do what plants have been doing for millions of years.

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Driving on sunshine: clean, usable liquid fuels made from solar power

Photo, posted March 23, 2015, courtesy of Astro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic From Sunlight | Earth Wise

March 13, 2023 By EarthWise Leave a Comment

Photosynthesis is the process that plants use to turn water, carbon dioxide, and energy from sunlight into plant biomass. It provides humans and much of animal life with food. Photosynthesis is also nature’s way of reducing the amount of carbon dioxide in the atmosphere. The CO2 is not directly stored in plants but rather is combined into organic compounds.

Researchers across the globe are trying to find effective ways to mimic photosynthesis. One version of artificial photosynthesis seeks to take carbon dioxide and combine it into organic compounds that can be used as raw materials for various kinds of manufacturing.

A research team in Japan has found a way to synthesize fumaric acid from carbon dioxide using sunlight to power the process. Fumaric acid is a chemical typically synthesized from petroleum and is used as a raw material for making biodegradable plastics such as polybutylene succinate.

Much of artificial photosynthesis research is aimed at using solar energy to convert carbon dioxide directly into a fuel rather than a raw material. Such solar fuels can be produced by a variety of means including thermochemical (using the sun’s heat to drive chemical reactions), photochemical (using the sun’s light to drive chemical reactions), and electrochemical (using solar-generated electricity to drive chemical reactions.) These approaches generally involve the use of specialized catalysts to drive the desired chemical reactions.

One way or another, what techniques for artificial photosynthesis have in common is trying to imitate what plant life on Earth has been doing for millions of years.

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Artificial photosynthesis uses sunlight to make biodegradable plastic

Photo, posted June 14, 2017, courtesy of Alex Holyake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Renewables Will Overtake Coal | Earth Wise

January 17, 2023 By EarthWise Leave a Comment

According to a recent report by the International Energy Agency, worldwide growth in renewable power capacity is set to double in the next five years. In fact, by 2027, the world will add as much renewable power as it did over the previous 20 years.

Of particular significance is that renewables are going to overtake coal as the largest source of electricity generation by early 2025.

The global energy crisis triggered by the war in Ukraine has had multiple effects on the evolution of the energy system. While the war has driven a resurgence in fossil fuel consumption in Europe in order to replace gas from Russia, that resurgence is expected to be short-lived. Instead, the current energy crisis may turn out to be an historic turning point toward a cleaner and more secure energy system.

Soaring fossil-fuel prices triggered by the war have caused many countries to respond by embracing wind turbines, solar panels, nuclear power plants, hydrogen fuels, electric vehicles, and electric heat pumps. In the US, Congress approved more than $370 billion in spending for clean energy technologies as part of the Inflation Reduction Act. China, India, South Korea, and Japan have all increased their national targets for renewable power. However, heating and cooling buildings with renewable power remains a sector needing larger improvement, according to the energy agency.

Overall, the expansion of renewable power over the next five years is now projected to happen much faster than what was projected just one year ago. The new IEA report revised last year’s forecast for renewables growth by 30% as a result of the introduction of new policies by many of the world’s largest greenhouse gas emitters.

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Renewables Will Overtake Coal by Early 2025, Energy Agency Says

Photo, posted March 8, 2021, courtesy of Stanze via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Liquid Fuels From Carbon Dioxide | Earth Wise

January 5, 2022 By EarthWise Leave a Comment

Most of the world’s energy demands are still being met by burning fossil fuels, thereby releasing carbon dioxide into the atmosphere. The energy system is in the midst of a transition to renewable sources such as solar and wind power, but it will be quite some time before fossil fuels are only a minor part of energy production. To reduce global warming, it will be necessary to prevent the carbon dioxide from fossil fuels from entering the atmosphere by capturing it and either locking it away or making use of it.

Recent research at several Chinese universities has developed a novel electrocatalyst that efficiently converts CO₂ to liquid fuels containing multiple carbon atoms. The main products of the high-efficiency reaction are ethanol, acetone, and n-butanol. Previous electrocatalystic methods have mostly produced simpler hydrocarbons – namely, ones with only a single carbon atom. The fuels the new catalyst produces are much more useful.

The catalyst is made from thin ribbons of a copper/titanium alloy that are etched with hydrofluoric acid to remove the titanium from the surface. The process results in a material with a porous copper surface on an amorphous CuTi alloy. The substance exhibits remarkably high activity, selectivity, and stability for catalyzing the reactions leading to the production of the hydrocarbon fuels.

Converting carbon dioxide into liquid fuels would be advantageous because they have high energy density and are safe to store and transport. Apart from preventing carbon dioxide from entering the atmosphere, the process could also be a way to make use of excess energy produced by solar and wind generation by essentially storing that energy in the form of liquid fuels.

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Liquid Fuels from Carbon Dioxide

Photo courtesy of Angewandte Chemie via Wiley-VCH.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Cement Manufacturing | Earth Wise

December 7, 2021 By EarthWise Leave a Comment

Cement is the basic ingredient of concrete, which is the most widely used construction material in the world. About 8% of global carbon dioxide emissions are associated with cement production.

More than half of these emissions come from making clinker, which is a major component of cement produced by heating ground limestone and clay to a temperature of over 2500 degrees Fahrenheit. Some of the emissions come from burning fossil fuels to heat the materials, but much of them come from the chemical reaction that creates the clinker.

The Portland Cement Association, which represents 92% of US cement manufacturing capacity, has recently released its “Roadmap to Carbon Neutrality”, which lays out a plan to reach carbon net zero across the cement and concrete value chain by 2050.

The plan includes the greater use of alternative fuels to reduce emissions from energy use. It also involves the adoption of newer versions of cement such as Portland limestone cement, which reduces CO2 levels. The industry has already reduced emissions by some shifting to Portland limestone cement, but it still only represents a small fraction of cement production.

The most significant strategy would be the adoption of carbon capture, utilization, and storage (or CCUS) technologies. The idea is to capture the CO2 generated in the production of clinker and inject it into the fresh concrete. It would actually be permanently sequestered in the concrete and would not be released even if a structure is demolished in the future.

It will take a combination of technologies and initiatives for the cement industry to reduce its emissions. Fortunately, the industry appears to be committed to that goal.

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US cement manufacturers release their road map to carbon neutrality by 2050

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Dangerous Fire Season | Earth Wise

June 9, 2021 By EarthWise Leave a Comment

The western United States is entering the fire season under much worse drought conditions than last year. Last year, 15,800 square miles burned in the U.S., mostly in the West.

The western U.S. is in the midst of a 20-year mega-drought. Rainfall in the Rocky Mountains and farther west was the second lowest on record this April. The soil in the western half of the country is the driest it has been since 1895.

The situation is particularly bad in California and the Southwest. In March, less than a third of California was experiencing extreme or exceptional drought. Now, 73% of the state is. A year ago, a record-breaking fire season burned 4% of the state and, at that time, only 3% of California was in a state of extreme drought.

A year ago, no parts of Arizona, Nevada, or Utah were in extreme or exceptional drought. Now, more than 90% of Utah, 86% of Arizona, and 75% of Nevada face severe drought conditions. At this time last year, only 4% of New Mexico faced extreme drought but 77% does now.

These extreme drought conditions, which are believed to be linked to climate change, are causing increased tree mortality among many species, ranging from junipers in the Southwest even to drought-tolerant blue oaks in the San Francisco Bay Area.

Conditions are extremely ripe for a lot of forest fire this year. Last year was a terrible year for wildfires in the West and we are heading into a fire season with much drier fuels than there were last year. The risks of great damage from wildfires are higher than ever.

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US West Enters Fire Season Facing Extremely Dry Conditions

Photo, posted September 18, 2020, courtesy of USFS/National Interagency Fire Center via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaner Water Using Corn | Earth Wise

May 12, 2021 By EarthWise Leave a Comment

Corn is the largest agricultural crop in the U.S., and it is also one of the most wasteful. About half of the harvest ends up as stover – corn stalks, leaves, husks, and cobs – once the kernels are used for food.

Corn stover has relatively few commercial or industrial uses. It can be used to produce biofuel, but that is not very energy efficient. It is sometimes used as a low-quality livestock feed as well. Mostly, it is just burned if it is used at all.

Researchers at the University of California Riverside have developed an energy-efficient way to make good use of stover by transforming it into activated carbon for use in water treatment.

Activated carbon – often called activated charcoal – is an organic material that is specially treated to contain millions of microscopic pores that make it highly absorbent. It has many industrial uses, the most common of which is for filtering pollutants out of drinking water. Most household water filters such as Brita filters as well as the ones built into refrigerators make use of activated carbon.

The Riverside researchers explored methods for producing activated carbon from charred corn stover and found that processing the material with hot compressed water – a process known as hydrothermal carbonization – produced highly absorbent activated carbon with superior properties compared to material produced by slow pyrolysis, where corn stover is charred at increasing temperatures over a long period of time.

According to the researchers, it is important to create approaches that convert waste into high-value materials, fuels, and chemicals in order to create new value streams and eliminate the environmental harm that comes from a so-called “take-make-dispose” economic model.

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Cleaner Water Through Corn

Photo, posted September 15, 2010, courtesy of the United Soybean Board / the Soybean Checkoff via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Fuel From Lignin | Earth Wise

November 26, 2020 By EarthWise Leave a Comment

Lignin is an organic polymer that provides the rigid structure of plants and is what gives wood and bark their characteristic properties. Lignin typically comprises between 20 and 35% of the mass of wood. The two major substances extracted from trees, grasses, and other biomass materials are cellulose and lignin. Cellulose is used to make paper, bioethanol, and other products, but lignin is largely unused because it is difficult to break down into useful substances such as feedstocks for fuels. As a result, lignin is largely wasted. Worldwide, some 50 million tons of lignin are produced from paper and bioethanol manufacturing each year and almost all of that is simply burned to generate heat.

Lignin can be broken down using pyrolysis techniques at high temperatures to create bio-oils, but those oils lack sufficient hydrogen and contain too much oxygen to be useful as fuels. There is a process called hydrodeoxygenation that adds hydrogen and removes oxygen, but it requires high temperatures and very high pressures as well as producing char and tar that reduces the efficiency of the process.

Researchers at Georgia Tech recently published work describing a new process for turning lignin into useful products. They developed a dual catalyst system of super-acid and platinum particles that adds hydrogen and removes oxygen from lignin bio-oil and makes it useful as a fuel and source of chemical feedstocks.

The new process could help meet the growing demand for bio-based oils as well as helping the forest product, paper, and bioethanol industries by providing an additional revenue stream from what previously was a waste product.

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New Process Boosts Lignin Bio-oil as a Next-Generation Fuel

Photo, posted August 16, 2017, courtesy of evcabartakova via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Use Of Invasive Seaweed | Earth Wise

June 26, 2020 By EarthWise Leave a Comment

In recent years, millions of tons of brown Sargassum seaweed have formed gigantic blooms stretching all the way across the Atlantic Ocean from West Africa to the Gulf of Mexico. The seaweed has become a problem for shorelines in the Caribbean, the Gulf of Mexico, and the east coast of Florida. The massive increase in seaweed populations is related to changes in ocean chemistry resulting from nutrients from fertilizer use entering the water as well as from changes to the climate affecting ocean currents and temperatures. The seaweed is harming the tourism industry as well as fisheries and ocean ecosystems.

Cleaning up the seaweed that washes ashore is labor-intensive and therefore expensive. A research team led by two British universities has developed a cheap and simple way to pre-process seaweed to facilitate making it into bulk chemicals and biofuels. With the new process, cleaning up the seaweed can be both economically and environmentally viable.

Previous techniques for processing seaweed generally required removing it from the saltwater, washing it in fresh water, and drying it – all of which add significant costs. The new technique makes use of catalysts to release sugars from untreated seaweed that feed a yeast to produce a palm oil substitute. At the same time, the process creates heat and pressure, turning the residual materials into a bio-oil that can be processed further into fuels, and a high-quality, low-cost fertilizer.

Apart from getting economic value out of the seaweed that is collected, any plastic collected alongside the seaweed can be converted to useful materials as well.

It appears that the seaweed scourge is here to stay, so finding an economically viable way to deal with it is a welcome development.

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Solve invasive seaweed problem by turning it into biofuels and fertilisers

Photo, posted August 10, 2015, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Coronavirus And European Energy | Earth Wise

April 23, 2020 By EarthWise Leave a Comment

As people all over the world shelter in place and much ordinary commerce and other activities have ground to a halt, there have been big changes in energy usage. With production halted, offices shut down, schools closed, and public transport operated on reduced timetables, the demand for energy has decreased dramatically.

In Europe, as a result of all this, during the first quarter of this year, renewables’ share of total energy production was greater than 60%. Wind farms provided more than 40% of the renewables’ share of total electricity generation. During February, Denmark, Germany and Ireland saw nearly 50% of their electricity demand met with wind power. Hydroelectric power was the second largest source of renewable energy during the first quarter, with Norway providing the largest share of this. In contrast, generation from nuclear plants was at its lowest first quarter figure for the past five years.

The large shift to renewable generation was in great part due to the overall reduction in demand. This impacts nuclear and fossil-fuel generation much more than renewables because those plants can be throttled back or shut down entirely so as not to needlessly consume costly fuels. Generation that runs on sunlight, wind, or flowing water does not require fuel expenses, so it makes sense to prefer them when demand is reduced.

The reduction in demand has in turn had a major effect on fuel costs as oil reached low prices that haven’t been seen in years.

The decline in demand and fuel prices and the enhanced role of renewables are expected to continue in the current quarter as the timetable for renewed economic activity remains unknown.

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Renewables achieve clean energy record as COVID-19 hits demand

Photo, posted June 25, 2010, courtesy of Martin Abegglen via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Capture As Big Business

December 26, 2019 By EarthWise Leave a Comment

Removing greenhouse gasses from the atmosphere is an essential part of the overall effort to achieve zero net carbon emissions and stabilize the climate. Since we have not been able to reduce emissions fast enough to do the job, it is important to find ways to pull carbon dioxide out of the atmosphere.

There are many ways to do it, but they tend to be rather expensive and, so far, the need to mitigate climate change does not seem to provide sufficient incentive. A new study by researchers at UCLA, the University of Oxford, and five other institutions, analyzed the possibility of creating a large global industry based on capturing carbon dioxide and turning it into commercial products.

The study investigated the potential future scale and cost of 10 different ways to use carbon dioxide, including in fuels and chemicals, plastics, building materials, soil management, and forestry. The study looked at processes using carbon dioxide captured from waste products that are produced by burning fossil fuels as well as by simply capturing it directly from the atmosphere. The study also looked at processes that use carbon dioxide captured biologically by photosynthesis.

The conclusions of the study were that on average each of the ten utilization pathways could use about half a billion tons of carbon dioxide that would otherwise escape into the atmosphere. Thus, theoretically, these various pathways could take more than five billion tons of CO2 out of the atmosphere. Currently, fossil fuel combustion emits about 40 billion tons of carbon dioxide.

The authors of the study stress that there is no silver bullet in the fight against climate change. It will require multiple approaches – including CO2 removal for industrial use – to make real progress

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Carbon dioxide capture and use could become big business

Photo, posted September 18, 2015, courtesy of Tony Webster via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Gas From An Artificial Leaf

November 27, 2019 By EarthWise Leave a Comment

Photosynthesis is the process used by plants, algae and certain bacteria to harness energy from sunlight and turn it into chemical energy. It is often described as the green engine of life on earth.

For quite some time, there have been extensive research efforts around the world in the area of artificial photosynthesis. The goal is to somehow mimic the behavior of plants in order to generate clean-burning fuels using nothing more than sunlight and the carbon dioxide in the air.

Researchers at the University of Cambridge have recently demonstrated a so-called artificial leaf that can directly produce syngas using sunlight. Syngas is a fuel gas mixture consisting primarily of hydrogen and carbon monoxide. Most people haven’t heard of syngas, but many products are created using it. Being able to produce it sustainably would be a critical step to a far greener chemical and fuel industry.

The artificial leaf contains two light absorbers, similar to the molecules in plants that harvest sunlight, which are combined with a catalyst made from the naturally abundant element cobalt. When the device is immersed in water, one light absorber uses the catalyst to produce oxygen. The other carries out the chemical reaction that reduces carbon dioxide and water into carbon monoxide and hydrogen. The result is the syngas mixture.

It turns out that even a rainy or overcast day provides enough light to drive the process.

Previous artificial leaf devices have mostly just produced hydrogen. The Cambridge device produces syngas thanks to the novel combination of materials and catalysts it uses.

The researchers are now focused on finding ways to use the technology to produce a sustainable gasoline substitute.

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‘Artificial leaf’ successfully produces clean gas

Photo, posted August 15, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Jet Fuels

May 9, 2019 By EarthWise Leave a Comment

The global aviation industry uses a whole lot of fuel: more than 5 million barrels a day. It is an incredibly energy-intensive industry and almost all of its energy comes from petroleum-based fuels.

While other large energy sectors such as electric power, ground transportation and commercial buildings have well-defined pathways to adopting renewable energy sources, the aviation industry does not have such a straightforward way to make a transition to sustainability. Electrifying planes using batteries or fuel cells is very challenging for a number of reasons, notably the weight restrictions on aircraft. So liquid biofuels as replacements for petroleum-based fuels remain the most promising approach.

A new study at the Lawrence Berkeley National Laboratory concludes that sustainable plant-based biofuels could provide a competitive alternative to conventional petroleum fuels if current development and scale-up initiatives are successful.

Multidisciplinary teams based at the Department of Energy’s Joint BioEnergy Institute are focused on optimizing each stage of the bio-jet fuel production process. This includes bioengineering ideal source plants and developing methods for efficiently isolating the carbohydrates in non-food biomass that bacteria can digest and bioconvert into fuel molecules.

The critical issue is cost. The theoretical cost of bio-jet fuel has come down dramatically in recent years but is still around $16 a gallon. The cost of standard jet fuel is about $2.50 a gallon. So, the real challenge is bridging that gap.

Reducing the cost of the fuel could come both from the material and process improvements that are underway as well as by finding ways to turn the leftover lignin residuals from the bioconversion process into valuable chemicals.

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Bright Skies for Plant-Based Jet Fuels

Photo, posted March 28, 2009, courtesy of Yasuhiro Chatani via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Liquid Fuel From The Sun

February 21, 2019 By EarthWise Leave a Comment

Most forms of energy we use ultimately come from the sun in one way or another. Even fossil fuels are the end product of millions of years of plant life that captured solar energy. The advantage fossil fuels have over direct solar power is that they are, in fact, fuels and therefore can be stored for use when needed.

Scientists in Sweden have now developed a specialized fluid that absorbs some of the sun’s energy, holds it for months or even years, and then releases it when needed. This solar thermal fuel is like a rechargeable battery for heat rather than electricity.

The special fluid is pumped through transparent tubes where ultraviolet light from the sun excites its molecules into an energized state. A compound called norbornadiene is converted into quadricyclane. The quadricyclane is a quite stable substance until it is passed over a cobalt-based catalyst, which causes it to turn back into norbornadiene and release copious amounts of heat.

Such a solar thermal fuel could be stored in uninsulated tanks in homes or factories or piped or trucked to where it was needed. It could then be used for water heaters, dishwashers, or clothes driers. The room temperature fluid quickly warms to about 183 degrees when passed over the catalyst, plenty warm enough for heating a home or office. Both the fuel and the catalyst are damaged very little by the reactions, so the process can be recycled many times.

There is much development work needed to optimize shelf life, energy density, good recyclability and other properties before this technology can be commercialized but there are at least 15 groups around the world now studying this intriguing way to get liquid fuel from the sun.

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