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Carbon-Negative Concrete | Earth Wise

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Concrete is a mainstay of modern civilization.  The world produces more than 4 billion tons of it each year and the process requires high temperatures, mostly obtained by burning fossil fuels.  The chemical reactions that produce concrete also produce large amounts of carbon dioxide.  In all, cement production is responsible for about 8% of total global carbon emissions by human activities.

This situation is the impetus for a wide range of research activities aimed at reducing the environmental impact of concrete production.  Researchers at Washington State University have recently developed a way of making carbon-negative concrete: a recipe for concrete that absorbs large amounts of carbon dioxide.

There have been attempts in the past to add biochar to concrete.  Biochar is a type of charcoal made from organic waste that sucks up carbon dioxide from the air.  In earlier attempts, even adding 3% of biochar would dramatically reduce the strength of the concrete.

The WSU researchers found that treating biochar with concrete washout wastewater makes it possible to add much more biochar to concrete without reducing its strength.  Mixing it with biochar adds calcium, which induces the formation of the mineral calcite, which in turn strengthens the concrete.

The researchers were able to add up to 30% biochar to their cement mixture.  Within a month, the resultant concrete was comparable in strength to ordinary concrete.  But at the same time, the biochar was able to absorb up to 23% of its weight in carbon dioxide from the air.  The new concrete is potentially the most environmentally friendly concrete ever developed.

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Researchers develop carbon-negative concrete

Photo, posted January 31, 2012, courtesy of Michael J. Nevins / U.S. Army Corps of Engineers via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Concrete And Carbon | Earth Wise

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After water, concrete is the world’s second most consumed material.  It is the cornerstone of modern infrastructure.  Its production accounts for 8% of global carbon dioxide emissions.  The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement.  These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat.  However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide.  The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete.  The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly.  Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint.  In addition, the resulting concrete sets much more quickly.  It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Coastal Land Reclamation | Earth Wise

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People are artificially expanding the coastlines of cities by extending industrial ports and creating luxury residential waterfronts.  Major cities have added 900 square miles to their coastlines just since 2000. 

A recent study published in the journal Earth’s Future made use of satellite imagery to analyze land changes in 135 cities with populations of at least 1 million.  But population growth is not the only driver of coastal land reclamation.  It is popular in places that are eager to enhance their reputation and promote revenue growth.

At present, coastal land reclamation is most common in the Global South, where many economies are growing. In the past, the Global North dominated the use of coastal land construction.

The largest additions to land area occurred in China, Indonesia, and the United Arab Emirates.  Port extension is the most common reason for development.  Shanghai alone has added 135 square miles of land.

New land is typically created by piling sediments in the ocean, building cement sea walls and structures to contain sediments or cement, or sometimes filling in wetlands and other shallow areas of water near the coast.  The ecological impacts of reclamation are immense and, unfortunately, are not always considered.  Projects affect both the local ecosystems as well as those of the places where fill materials are obtained.

Industrialization and the need for urban space have driven much coastal reclamation.  Some projects, such as the palm-tree-shaped artificial islands of Dubai, are essentially for prestige.  Some cities, including Shanghai, are building new land in consideration of future sea level rise.

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New Land Creation on Waterfronts Increasing, Study Finds

Photo, posted October 15, 2010, courtesy of Werner Bayer via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cheaper Carbon Capture | Earth Wise

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As the years roll by without sufficient progress in reducing carbon dioxide emissions, the need for technologies that can capture CO2 from its sources or remove it from the air becomes stronger and stronger.  People have developed various ways to capture carbon dioxide, but to date, they generally suffer from some combination of being too costly or not being able to scale up to the necessary magnitude.

Scientists at the Pacific Northwest National Laboratory in Richland, Washington recently announced the creation of a new system that they claim is the least costly to date that captures carbon dioxide and turns it into a widely-used chemical: methanol.

Technologies that simply capture carbon dioxide that then needs to be stored in some secure location are difficult to implement from a cost perspective.  The PNNL researchers believe that turning CO2 into methanol can provide the financial incentive for widespread implementation.   Methanol can be used as a fuel, a solvent, or an important ingredient in plastics, paint, construction materials, and car parts.

The system is designed to be installed in fossil fuel-fired power plants as well as cement and steel plants.  Using a capture solvent developed by PNNL, the system grabs carbon dioxide molecules before they are emitted and converts them into methanol. Creating methanol from CO2 is nothing new, but capturing the carbon dioxide and converting into methanol in one continuously flowing system is new.

More work is needed to optimize and scale the process and it may be several years before it is ready for commercial deployment.

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Scientists Unveil Least Costly Carbon Capture System to Date

Photo, posted November 25, 2022, courtesy of Massachusetts Department of Environmental Conservation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon Capture: Solution Or Band-Aid? | Earth Wise

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The idea of capturing the CO2 emissions from industry and locking them up is nothing new.  It’s been going on for decades in some places.  Norway’s state-owned oil company Equinor has been holing away a million tons of CO2 a year for a long time.  But overall, CCS – carbon capture and storage – has had very limited use.  As of last year, there were only about 30 large-scale projects in operation around the world, capturing only 0.1% of global emissions.

There is now growing interest in CCS and many new projects are underway.  A combination of rising carbon prices in Europe, tax breaks for CCS in the US, national net-zero targets, and the increasing need to ramp down global emissions are all driving rising CCS activities. 

While recent reports from the Intergovernmental Panel on Climate change still claim that it is possible to remain below 2 degrees Celsius of warming without using carbon capture, there is growing belief that it may be necessary given the present pace of the transition away from fossil fuels.

Two industries that together produce about 14% of global CO2 emissions are cement and steel.  These are both industries for which it is difficult to eliminate emissions regardless of the energy sources used. CCS may be the best approach to reducing their emissions.

But there is considerable pushback against CCS.  The concern is that CCS is primarily a way to delay decarbonization.  It encourages various industries to continue to use fossil fuels instead of shifting away from them.  Nonetheless, CCS no doubt has its place as part of the solution to climate change.

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Solution or Band-Aid? Carbon Capture Projects Are Moving Ahead

Photo, posted June 5, 2022, courtesy of Mark Dixon via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Carbon Dioxide Levels Higher Again | Earth Wise

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The National Oceanic and Atmospheric Administration reported that carbon dioxide levels measured in May at the Mauna Loa Observatory reached a value of 421 parts per million.  This is 50% greater than pre-industrial levels and is in a range not seen on earth for millions of years.

Before the Industrial Revolution, CO2 levels fairly steadily measured around 280 parts per million, pretty much for all 6,000 years of human civilization.  Since the Industrial Revolution began in the 18th century, humans have generated an estimated 1.5 trillion tons of CO2 pollution, much of which will continue to warm the atmosphere for thousands of years.

The present levels of carbon dioxide are comparable to those of an era known as the Pliocene Climatic Optimum, which took place over 4 million years ago. 

The bulk of the human-generated carbon dioxide comes from burning fossil fuels for transportation and electrical generation, from cement and steel manufacturing, and from the depletion of natural carbon sinks caused by deforestation, agriculture, and other human impacts on the natural environment.

Humans are altering the climate in ways that are dramatically affecting the economy, infrastructure, and ecosystems across the planet.  By trapping heat that would otherwise escape into space, greenhouse gases are causing the atmosphere to warm steadily, leading to increasingly erratic weather episodes ranging from extreme heat, droughts, and wildfires, to heavier precipitation, flooding, and tropical storm activity.

The relentless increase of carbon dioxide measured at Mauna Loa is a sober reminder that we need to take serious steps to try to mitigate the effects of climate change.

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Carbon dioxide now more than 50% higher than pre-industrial levels

Photo, posted December 20, 2016, courtesy of Kevin Casey Fleming via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Cement Manufacturing | Earth Wise

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Cement is the basic ingredient of concrete, which is the most widely used construction material in the world.  About 8% of global carbon dioxide emissions are associated with cement production.

More than half of these emissions come from making clinker, which is a major component of cement produced by heating ground limestone and clay to a temperature of over 2500 degrees Fahrenheit.  Some of the emissions come from burning fossil fuels to heat the materials, but much of them come from the chemical reaction that creates the clinker.

The Portland Cement Association, which represents 92% of US cement manufacturing capacity, has recently released its “Roadmap to Carbon Neutrality”, which lays out a plan to reach carbon net zero across the cement and concrete value chain by 2050.

The plan includes the greater use of alternative fuels to reduce emissions from energy use.  It also involves the adoption of newer versions of cement such as Portland limestone cement, which reduces CO2 levels.  The industry has already reduced emissions by some shifting to Portland limestone cement, but it still only represents a small fraction of cement production.

The most significant strategy would be the adoption of carbon capture, utilization, and storage (or CCUS) technologies.  The idea is to capture the CO2 generated in the production of clinker and inject it into the fresh concrete.  It would actually be permanently sequestered in the concrete and would not be released even if a structure is demolished in the future.

It will take a combination of technologies and initiatives for the cement industry to reduce its emissions.  Fortunately, the industry appears to be committed to that goal.

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US cement manufacturers release their road map to carbon neutrality by 2050

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Decarbonizing The Most Polluting Heavy Industries | Earth Wise

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The production of steel, cement, and ammonia accounts for about 20% of the carbon dioxide humans pour into the atmosphere.  Modern cities are largely constructed from concrete and steel and most of our food is grown using fertilizer made from ammonia. 

The most widely discussed solutions to decarbonizing these industries are green hydrogen and carbon capture and storage or CCS.

Steel manufacture is responsible for 11% of society’s emissions.  Most production starts by burning coal in a blast furnace. Using CCS could reduce emissions from burning the coal.  But the blast furnace could be eliminated entirely by the use of electrolysis to produce the pure iron needed to make steel.  This would be extremely energy-intensive but using a low-carbon source like green hydrogen could greatly reduce the emissions from making steel.

Ammonia is made by producing hydrogen from natural gas and then combining it with atmospheric nitrogen.  Both the hydrogen production and ammonia synthesis are energy intensive.  Using green hydrogen would eliminate emissions from the hydrogen production itself and new research on catalysts aims at lower-temperature, less-energy intensive ammonia synthesis.

Decarbonizing cement manufacturing is perhaps the toughest challenge.  Cement is made in a high-temperature kiln, typically heated by burning fossil fuels.  The process converts calcium carbonate and clay into a hard solid called clinker.  The main byproduct of that is even more carbon dioxide.  Burning green hydrogen and capturing carbon emission are about the best hope for reducing cement manufacturing emissions.

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Can the World’s Most Polluting Heavy Industries Decarbonize?

Photo, posted June 30, 2009, courtesy of Portland Bolt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

An Incentive For Carbon Capture | Earth Wise

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Convincing industries to reduce their carbon dioxide emissions has not been easy.  Many approaches have been debated, including carbon taxes, carbon tax-and-trade schemes, and passing a giant Green New Deal.  Most economists agree that putting a price on carbon is likely to be the most effective approach.

But there is already in place an adjustment to the US tax code that is more of a carrot than a stick.  It is a tax credit that is designed to make capturing CO2 a financial winner for a number of high-emitting industries.  The credit, called 45Q, was enacted in February 2018.

The 45Q credit earns industrial manufacturers $50 per metric ton of CO2 stored permanently or $35 per ton if the CO2 is put to use.  An earlier credit for capturing carbon dioxide was limited to only $20 per metric ton and was capped at 75 million tons.  Some large fossil fuel companies did make use of the earlier credit.

The new version does not have a cap, but to qualify, companies need to start constructing carbon-capture facilities within 7 years and have 12 years to claim their money.

Companies with emission-intensive operations are busy figuring out how to take advantage of the credit.  These include cement makers, steel and power plants, corn ethanol producers, and ammonia plants.

Because the credit mandates that companies start constructing their carbon-capture facilities within seven years, most companies will tend to rely on mature technologies.  But the tax credit should also drive demand for next-generation carbon-capture technologies, of which there are many under development.  Saving lots of money on taxes is likely to lure US companies to capture carbon dioxide.

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45Q, the tax credit that’s luring US companies to capture CO2

Photo, posted October 2, 2014, courtesy of Sask Power via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Conspicuous Consumption

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Human civilization consumes vast amounts of material.   The Circle Economy think tank actually puts some numbers on it.  According to their latest report, the amount of material consumed by humanity has passed 100 billion tons every year.  So, on average, every person on Earth uses more than 13 tons of materials per year.

That number has quadrupled since 1970, which is far faster than the population, which has only doubled during that time.  In the past two years alone, consumption has jumped by more than 8%.  While this has been going on, the proportion being recycled has been falling.

Of the 100 billion tons of materials, half of the total is sand, clay, gravel, and cement used for building, along with other minerals used for fertilizer.  Coal, oil and gas make up 15% and metal ores 10%. The final quarter are plants and trees used for food and fuel.  About 40% of all materials are turned into housing.  A third of the annual materials consumed remain in use, such as in buildings or vehicles.  But 15% is emitted into the atmosphere as greenhouse gases and a third is treated as waste.

The global emergencies of climate change and disappearing wildlife have been driven by the unsustainable extraction of fossil fuels, metals, building materials, and trees.  The authors of the report warn that if we continue to treat the world’s resources as limitless, we are heading for a global disaster.

The Circle Economy think tank promotes the idea of a circular economy in which renewable energy supports systems where waste and pollution are reduced to zero.  Some nations are taking steps towards circular economies, while others are not.  This is a problem we can’t allow to be unaddressed.

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World Consumes 100 Billion Tons of Materials Every Year, Report Finds

Photo, posted March 13, 2015, courtesy of Joyce Cory via Flickr.

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Extreme Heat From Solar Power | Earth Wise

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Renewable sources are playing a growing role in meeting our energy needs, but one place where they have continued to fall short is in industrial processes that require extreme heat.  These include the cement, steel, and glass industries, among others.  These industries account for a significant amount of CO2 emissions because the most effective way to reach the necessary temperatures continues to be combustion of fossil fuels.  The cement industry alone accounts for 7% of global emissions and the need for cement continues to grow.

A previously stealthy startup company backed by Bill Gates and fellow billionaire Soon-Shiong has made a breakthrough in the area of using solar energy to achieve high temperatures.  The company, called Heliogen, has created a solar oven that is capable of generating heat above 1800 degrees Fahrenheit, which is enough for high-temperature industrial processes.

The Heliogen technology uses concentrated solar power to generate heat.  Concentrated solar power uses arrays of mirrors to reflect sunlight and focus it to a single point.  That technology is not new;  there are systems that use it to produce electricity and, to some extent, heat for industry.  But it could not achieve high enough temperatures for producing cement or steel.

The new system uses computer vision software, automatic edge detection and other sophisticated technologies to focus the sun’s rays far more finely than ever before and thereby generate far higher temperatures at the focal point.

Heliogen is now focused on demonstrating how the technology can be used in a large-scale application, such as cement-making.  The selling points to industry are that not only will there be no emissions generated, but that the fuel needed to obtain their extreme heat will be free.

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Secretive energy startup backed by Bill Gates achieves solar breakthrough

Photo courtesy of Heliogen.

Earth Wise is a production of WAMC Northeast Public Radio.

Emissions-Free Cement

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The production of cement – which is the world’s leading construction material – is a major source of greenhouse gas emissions, accounting for about 8% of global man-made emissions. 

Cement production produces carbon dioxide in two ways:  from a key chemical process and from burning fuel to produce the cement.  The process of making “clinker” – the key constituent of cement – emits the largest amount of CO2.  Raw materials, mainly limestone and clay – are fed into huge kilns and heated to over 2,500 degrees Fahrenheit, requiring lots of fossil fuel.  This calcination process splits the material into calcium oxide and CO2.  The so-called clinker is then mixed with gypsum and limestone to produce cement.

A team of researchers at MIT has come up with a new way of manufacturing cement that greatly reduces the carbon emissions.  The new process makes use of an electrolyzer, where a battery is hooked up to two electrodes in water producing oxygen at one electrode and hydrogen at the other.  The oxygen-evolving electrode produces acid and the hydrogen-evolving electrode produces a base.  In the new process, pulverized limestone is dissolved in the acid at one electrode and calcium hydroxide precipitates out as a solid at the other.

High-purity carbon dioxide is released at the acid electrode, but it can be easily captured for further use such as the production of liquid fuels or even in carbonated beverages and dry ice.  The new approach could eliminate the use of fossil fuels in the heating process, substituting electricity generated from renewable sources. 

The process looks to be scalable and represents a possible approach to greatly reducing one of the perhaps lesser known but nevertheless very significant sources of greenhouse gas emissions.

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New approach suggests path to emissions-free cement

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Forecasting A Bad Year For Carbon

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Carbon dioxide levels in the atmosphere are higher than they have been for hundreds of thousands of years, and they continue to grow.  The United Kingdom’s national meteorological service – known as the Met Office – issues annual predictions of global CO2 levels based in part on readings taken at the Mauna Loa observatory in Hawaii.  Their forecast for this year is that there will be one of the largest rises in atmospheric carbon-dioxide concentration in the 62 years of measurements at Mauna Loa.

Since 1958, there has been a 30% increase in the concentration of carbon dioxide in the atmosphere.  This has been caused by emissions from fossil fuels, deforestation and cement production.  The increase would actually have been even larger if it were not for natural carbon sinks in the form of various ecosystems that soak up some of the excess CO2.

Weather patterns linked to year-by-year swings in Pacific Ocean temperatures are known to affect the uptake of carbon dioxide by land ecosystems.  In years with a warmer tropical Pacific – such as El Niño years – many regions become warmer and drier, which limits the ability of plants to grow and to absorb CO2 .  The opposite happens when the Pacific is cool, as was the case last year.

The Met Office predicts that the contribution of natural carbon sinks will be relatively weak, so the impact of human-caused emissions will be larger than last year.  The predicted rise in atmospheric CO2 is 2.75 parts-per-million, which is among the highest rises on record.  The forecast for the average carbon dioxide concentration is 411 ppm, with peak monthly averages reaching almost 415 ppm.  With global emissions not really declining, the numbers just get higher and higher.

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Faster CO₂ rise expected in 2019

Photo, posted March 18, 2006, courtesy of Darin Marshall via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Greener Concrete

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The battle to reduce carbon emissions is heavily focused on electricity generation, transportation, buildings, and agriculture, which collectively account for more than 75% of the total.  However, there are other sources of carbon emissions that cannot be ignored.  Among industrial activities, the production of cement is responsible for 7% of industrial energy use and is the second largest industrial emitter of carbon dioxide.  Making cement accounts for about 7% of global emissions.

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Lots Of Credit For Carbon Capture

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These days, the federal government has mostly turned its back on efforts to mitigate climate change or, for that matter, to even recognize its existence.  However,the budget bill passed in February contained a major increase in the tax credit known as 45Q, which provides incentives to businesses to develop and utilize carbon capture, utilization and storage technologies.

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