waterways

Turning Trash Into Treasure

December 12, 2019 By EarthWise Leave a Comment

Every year, 380 million tons of plastic are created worldwide, and that number continues to grow. Furthermore, more than 75% of these materials are discarded after one use. Much of it ends up in oceans and waterways, harming wildlife and spreading toxins.

Recycling most plastics is difficult because while they can be melted and reprocessed, the resultant material is not as structurally strong as the original material. Thus, plastics are often down-cycled such as turning plastic bottles into molded park benches.

Researchers at Northwestern University, Argonne National Laboratory, and Ames Laboratory have developed a new method for upcycling abundant, seemingly low-value plastics into high-quality liquid products, such as motor oils, lubricants, detergents, and even cosmetics. The catalytic method could remove plastic pollution from the environment and contribute to a circular economy.

Plastics don’t degrade when disposed of because they have very strong carbon-carbon bonds. Instead they just break into smaller bits, known as microplastics. The researchers viewed these strong bonds as an opportunity rather than a problem.

The new technique actually recoups the high energy that holds these bonds together by catalytically converting polyethylene molecules into value-added commercial products. The catalyst consists of platinum nanoparticles deposited onto perovskite nanocubes. Under moderate pressure and temperature, the catalyst cleaves the carbon-carbon bonds in plastic to produce high-quality liquid hydrocarbons.

The researchers believe these findings could lead to a future in which we can continue to benefit from plastic materials but do so in a way that is sustainable and less harmful to the environment.

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Turning plastic trash into treasure

Photo, posted August 15, 2012, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Pesticides In The Great Barrier Reef

November 7, 2019 By EarthWise Leave a Comment

Australia’s Great Barrier Reef is one of the greatest natural wonders in the world and it has been under siege by warming waters and ocean acidification. Widespread coral bleaching has damaged or destroyed large portions of the 1,400-mile long coral reef system. But the effects of climate change are not the only threat to the reef. Pesticides found in waterways that flow into the Great Barrier Reef are another serious problem.

According to a new study by the University of Queensland, the combined toxicity of 22 of the most common pesticides that flow into the Reef are not meeting pollution reduction targets.

Different pesticides affect different organisms. Herbicides affect organisms that photosynthesize such as seagrass, corals, mangroves, and algae. Insecticides affect insect larvae in freshwater, and crustaceans such as crabs, prawns, and lobsters. Previous assessments have only examined individual pesticides and only for limited times. The new study has utilized a methodology that estimates the combined toxicity of multiple pesticides found in the waterways that discharge into the Reef and does it for the entire wet season.

The research revealed that the pesticide reduction target set in the Australian Government’s Reef 2050 Water Quality Improvement Plan is not being met. Only one natural resource management region – the Cape York region – was found to be meeting its target.

By having estimates of the risk posed by pesticides in the various regions and individual waterways, governments, farmers, and conservationists can see which areas pose the greatest risk and where to maximize efforts. Stakeholders have to come together to reduce pesticide concentrations through better management practices and by using less toxic pesticides.

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High pesticide concentrations continue to enter Great Barrier Reef

Photo, posted July 29, 2010, courtesy of Kyle Taylor via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Forever Chemicals

October 25, 2019 By EarthWise Leave a Comment

One of the toughest classes of pollutants are per- and polyfluoralkyl substances, or PFAS, as they are known. PFAS are often called “forever chemicals” because they are extremely long-lasting and difficult to clean up. They are found in household products including non-stick pans, dental floss, water-repellent fabrics, and many others. They can be found extensively in U.S. waterways and soil.

PFAS move through the food chain, accumulating in humans at levels that scientists say can cause adverse health effects. While these have not been definitively proven, there is evidence that higher cholesterol levels, cancer, thyroid disruption, and low infant birth rates are all associated with PFAS ingestion.

PFAS are difficult to get rid of because their carbon-fluorine covalent bonds are some of the strongest in organic chemistry. Researchers at Princeton University have been studying a process known as Feammox in which ammonium breaks down in acidic, iron-rich soils in New Jersey wetlands and similar locations. They found that this reaction takes place when a bacterium called Acidimicrobium A6 is present.

Using gene-sequencing techniques, they found that the microbe has characteristics that could help break down carbon-fluorine bonds, and therefore break down PFAS. In tests using microbe-loaded soil samples, they found that the bacterium removed 60% of PFAS pollutants within 60 days.

The research has been published in the journal Environmental Science and Technology and the team is now testing the bacterium’s effectiveness over different time-spans in lab conditions before testing it in the field.

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New Jersey Soil Microbe Shown to Break Down ‘Forever Chemicals’

Photo, posted November 9, 2017, courtesy of the Department of Environmental Quality via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

China And Rare Earth Mining

September 4, 2019 By EarthWise Leave a Comment

Rare earth elements are a crucial part of much of modern technology. Everything from computers to X-ray machines and aircraft engines needs one or more rare earth elements for magnets, lenses, and other functions. The world’s tech giants such as Apple, Huawei, and Tesla depend on suppliers of rare earths.

Rare earth elements are not actually rare, but they are very expensive to extract in ways that are not extremely harmful to the environment. China has been a major source of these elements since its rare earth mining industry took off in the 1990s. The removal of rare earths from the earth’s crust, using a mix of water and chemicals, has caused extensive water and soil pollution.

Today, concrete leaching ponds and plastic-lined wastewater pools dot the hills of Southeast China. Large wastewater ponds sit uncovered and open to the elements in many places. Landslides or barrier failures can spill contaminated contents into waterways or groundwater.

Local and federal officials in China have started to shut down illegal and small-scale rare earth mining operations and have embarked on a cleanup of polluted sites. The rare earth mining cleanup operation is part of wider efforts across China to address severe problems of water, air and soil pollution.

China’s Ministry of Industry and Information Technology estimated that the cleanup bill for southern Jiangxi Province could amount to more than $5 billion. Many environmental experts and local officials say that the cost of the cleanup should not be shouldered by the Chinese government alone, but also by the rare earth industry and the global companies and consumers that benefit from rare earth technology. As rare earth mining efforts start up elsewhere around the world, it is important not to repeat the mistakes made in China.

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China Wrestles with the Toxic Aftermath of Rare Earth Mining

Photo, posted April 21, 2019, courtesy of John Beans via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Threat From Nurdles

March 4, 2019 By EarthWise Leave a Comment

Just when we thought we knew all about the environmental threats caused by plastics, environmentalists have identified yet another problem. It is called a nurdle.

Nurdles are tiny pellets of plastic resin no bigger than a pencil eraser that manufacturers transform into packaging, plastic straws, water bottles and all the other things that are wreaking havoc on the environment.

It turns out that nurdles themselves are a problem because billions of them are lost from production and supply chains during handling, shipping and production every year, spilling or washing into waterways. There is limited information on the extent of this kind of plastic pollution and global researchers are still struggling to make an accurate assessment. A study last year estimated that 3 million to 36 million pellets escape every year from just one small industrial area in Sweden.

Eunomia, a British environmental consultancy, contends that nurdles are the second-largest source of microplastic pollution and estimated that the U.K. could be unwittingly losing billions of pellets into the environment every year.

New research is revealing the ubiquity of plastic pellets, from the bellies of fish caught in the South Pacific, to the digestive tracks of short-tailed albatross in the north and on the beaches of the Mediterranean.

A shareholder advocacy group called As You Sow has filed resolutions with Chevron, DowDupont, Exxon Mobil, and Phillips 66 asking them to disclose how many nurdles escape their production process each year and how they plan to address the issue. Several of the companies have responded with statements saying they are working to develop solutions that keep plastic out of our environment.

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