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The bloated carbon footprint of LNG

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According to the U.S. Department of Energy, the United States is the world’s largest producer of natural gas.  In fact, natural gas supplies approximately one third of the United States’ primary energy consumption, most of which is used to heat buildings and to generate electricity.  While most natural gas is delivered in its gaseous form in this country, the demand for natural gas in international markets has given rise to the use of natural gas in a liquified form. 

Liquified natural gas (LNG) is natural gas that has been cooled to a liquid state, at about -260° Fahrenheit, for easier storage and transportation.  The volume of natural gas in its liquid state is about 600 times smaller than its volume in its gaseous state, which makes it possible to transport it to places pipelines do not reach.

Liquified natural gas is considered a clean fossil fuel because burning it produces less emissions than coal and oil.  However, according to a new study by researchers from Cornell University, LNG imported from the U.S. actually has a larger climate impact than any other fossil fuel—including coal – once processing and shipping are taken into account. 

The study, which was recently published in the journal Energy Science & Engineering, found that LNG leaves a greenhouse gas footprint that is 33% worse than coal when emissions are analyzed over a 20-year time frame. 

According to the research team, there is no need for LNG as an interim energy source because the transition requires massive infrastructure expenditures.  Instead, those financial resources should be used to “build a fossil-fuel-free future as rapidly as possible.”

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Liquefied natural gas carbon footprint is worse than coal

Photo, posted November 17, 2017, courtesy of Colin Baird via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Dark chocolate is not so dangerous

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Last year, Consumer Reports published a story stating that a third of chocolate products contain potentially dangerous amounts of heavy metals, in particular lead and cadmium. Since it contains much more cacao, dark chocolate was singled out as the most worrisome product.  Needless to say, chocolate lovers found this report quite alarming.

A new study by Tulane University published in Food Research International employed a larger sample size, expanded the scope of testing to 16 metals, and included a risk assessment of toxic metals as well as accounted for the nutritional contribution of essential minerals.

The conclusions of the study were that dark chocolate poses no adverse risk for adults and contains nutritionally beneficial levels of essential minerals.  Some risks remain for very young children, but only from a very small number of chocolate products and only when large quantities are consumed.

The study sampled 155 dark and milk chocolates from various global brands sold in the United States.  It modeled the risk of eating one ounce of the chocolate per day or two large whole bars a week.

Only one brand exceeded the international limit for cadmium; four had cadmium levels that could pose a risk for a child weighing less than 33 pounds.  Only two bars contained lead levels above California interim standard, but neither posed adverse risks for anyone.

Lead in chocolate comes from post-harvest processing; cadmium comes from the soil.  South American chocolates generally have higher levels of metals than chocolates from Asia and West Africa.  Most dark chocolate in the U.S. is sourced from West Africa.

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A dark side to dark chocolate? New study finds very minimal risk for kids from metals in chocolates

Photo, posted February 19, 2012, courtesy of Bodo via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Huge American Lithium Discovery | Earth Wise

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Human history has often been described in terms of a succession of metal ages:  the copper age, the bronze age, and the iron age.  In many ways, we have now entered the lithium age.  The light metal goes into the batteries that power smartphones, electric vehicles, and massive storage banks for the power grid.  Lithium has become a critical strategic resource.

As it stands now, the U.S. gets most of its lithium from imports from Australia and South America.  Major lithium sources are not commonplace; in 2022 there were only 45 lithium mines in the world.  Many of the known deposits are not in North America but in Chile, Bolivia, Argentina, China, and Australia.  The current largest known lithium deposits lie beneath the salt flats of Bolivia.

Lithium Americas Corporation, a company dedicated to advancing lithium projects to the stage of production, funded research over the past decade that has identified vast deposits of lithium-rich clay in a dormant volcanic crater along the Nevada-Oregon border.  The McDermitt Caldera is estimated to hold between 20 and 40 million tons of lithium, which would make it the largest deposit in the world.

There are many questions still to answer.  It is not clear how easy it will be to extract lithium from the clay, in particular how expensive or carbon-intensive it will be.  There are also political complexities since the area where the lithium deposit was found is considered to be unceded ancestral land for both the Paiute and Shoshone tribes.

Apart from a dearth of domestic sources of lithium, the US also lags well behind China in lithium processing capabilities.  The country has catching up to do in the new lithium age.

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America Just Hit the Lithium Jackpot

Photo, posted April 19, 2020, courtesy of Ken Lund via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Falling Lithium Prices | Earth Wise

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Lithium, the key element in the batteries that power electric cars, as well as smartphones, tablets, and laptop computers, is sometimes called white gold.  Over time, the price of the metal has gone up and up.  But recently, and surprisingly, the price of lithium has actually gone down, helping to make electric vehicles more affordable.

Over the first couple of months of this year, the price of lithium has dropped by nearly 20%.  The price of cobalt, another important component of vehicle batteries, has fallen by more than half.  Even copper, another battery material, has seen its price drop by 18%.

Many analysts predicted that prices of these commodities would stay high or even climb higher.  The reason for the decline, as well as whether it is likely to persist, is the subject of much debate.

Some experts believe that the price drops are a result of demand not being as high as expected, perhaps related to slowing sales growth of EVs in Europe and China after certain subsidies expired.  Other industry experts said that the drop was a result of new mines and processing plants providing additional supply sooner than was thought possible.

Despite the price drops, mining and processing lithium remains an extraordinarily profitable business.  It costs from $5,000 to $8,000 to produce a ton of lithium that sells for ten times that amount.  With such fat profit margins, there is no shortage of banks and investors eager to finance lithium mining and processing projects.  Such profit margins are probably not sustainable and that will likely result in more reasonable prices over time.

There is plenty of lithium in the world.  The huge demand for it is a recent phenomenon and the world is still working out how to meet that demand.

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Falling Lithium Prices Are Making Electric Cars More Affordable

Photo, posted January 9, 2023, courtesy of Phillip Pessar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Atmospheric Carbon Into Useful Materials | Earth Wise

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Plants have the ability to capture carbon dioxide from the atmosphere and incorporate it into leaves, fruits, wood, and other plant materials.  This beneficial process is mostly temporary, as much of this carbon dioxide from plant matter ends up back in the atmosphere through decomposition, or even burning.

Researchers at the Salk Institute have proposed a more permanent fate for captured carbon by turning plant matter into a valuable industrial material called silicon carbide.

In a recent study published in the journal RSC Advances, Salk scientists transformed tobacco and corn husks into silicon carbide and evaluated and quantified the benefits of the process.

The researchers used a previously reported method to transform plant matter into silicon carbide in three stages and carefully tracked the carbon utilization at each stage.

Stage one is growing the plants.  They used tobacco from seed, chosen for its short growing season.  Then the harvested plants are frozen, ground into a powder, and treated with chemicals including a silicon-containing compound.  Finally, the powder is subjected to a high-temperature process resulting in the production of silicon carbide.

Their analysis showed that much of the carbon sequestered by growing the plants could be preserved through the full process and the amount of energy required for the production of the silicon carbide (mostly from the high-temperature process) is comparable to current manufacturing processes for the material.

Permanently sequestering carbon from agricultural waste products by incorporating it into a valuable industrial material would be a valuable addition to strategies for reducing greenhouse gases in the atmosphere.

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Transforming Atmospheric Carbon Into Industrially Useful Materials

Photo, posted August 3, 2013, courtesy of AJ Garrison via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Wood Into Plastic | Earth Wise

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Plastic pollution is particularly pernicious because plastics can take hundreds of years to degrade in the environment.  For this reason, researchers across the globe search for ways to shift from petrochemical plastics to ones that are biodegradable.

Producing biodegradable plastics is challenging both from the standpoint of the methods needed and from the results obtained.  Producing them often requires toxic chemicals and can be very expensive.  The materials that emerge often do not have the durability and strength of conventional plastics and can be unstable when exposed to moisture.

Researchers at the Yale School of the Environment have developed a process of decomposing the porous matrix of natural wood into a slurry that can be formed into a biodegradable plastic.  The material shows high mechanical strength, stability when holding liquids, and is resistant to the effects of ultraviolet light.  Along with all these favorable properties, the material can be recycled or safely biodegraded in the natural environment.

The slurry mixture is created by taking wood powder – a processing residue usually discarded in lumber mills – and deconstructing it with a biodegradable and recyclable solvent.  The resulting mixture has a high solid content and high viscosity and can be casted and rolled without breaking.

The researchers conducted a comprehensive life cycle assessment to test the environmental impacts of the bioplastic compared with conventional plastics.  Sheets of it were buried in soil and observed to fracture after two weeks and completely degrade after three months.  The material can also be broken back down into the slurry by mechanical stirring.

The remaining topic to investigate is the potential impact on forests if the manufacturing of this bioplastic is scaled up.

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Turning wood into plastic

Photo, posted October 12, 2016, courtesy of the US Forest Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Natural Gas Processing

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Qatar, a small country in the Middle East with a population of about 2.5 million has the highest per capita income of any country in the world.  This is largely a result of being one of the world’s top producers of natural gas.  The upshot of that is that the tiny country has the dubious honor of being the world’s leading emitter of CO2 per capita.

Texas A&M University has a campus in Qatar and researchers there in collaboration with colleagues at the main campus in College Station, Texas have developed a new reactor technology that can help Qatar process its wealth of natural gas while reducing the country’s carbon footprint.

The technology processes natural gas and captured CO2 to produce both syngas – which is a valuable precursor for many products – and high-quality carbon nanotubes, all without releasing CO2 into the atmosphere.

Natural gas reforming is a process by which syngas – a feedstock for liquid hydrocarbons and ultraclean fuels- is produced.  The process requires lots of heat and emits CO2.  The new technology adds a novel CARGEN (or CARbon GENerator) reactor that advances the natural gas reforming process and includes a catalyst that captures the CO2 emissions and produces nanotubes.  The reactor can be driven by either electric or solar power, eliminating the need to burn fuel that ordinarily results in more carbon emissions.

The result is that Qatar’s CO2 emissions would be converted into two products that are important to its economy.  In particular, carbon nanotubes are very expensive and extremely versatile, and can be used to manufacture products such as computers and other high-quality materials.

The next step for the researchers is to partner with industry collaborators to further scale up the technology.

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Qatar Researchers Develop Natural Gas Processing Technology That Could Reduce Qatar’s Carbon Footprint

Photo, posted September 30, 2012, courtesy of Jimmy Baikovicius via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

China And Plastic Waste

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In January 2018, China enacted its “National Sword” policy which banned the import of most plastics and other materials headed for that country’s recycling processors.  Those processors had handled nearly half of the world’s recyclable waste for the past quarter century.  China took this step because the deluge of soiled and contaminated materials was overwhelming its processing facilities and creating yet another environmental problem for the country, this time not even of its own making.

Prior to China’s ban, 95% of the plastics collected for recycling in the European Union and 70% in the U.S. were sold and shipped to Chinese processors.  A combination of favorable rates for shipping in cargo vessels that carried Chinese goods abroad and low Chinese labor rates made it a very profitable enterprise.

Before China’s ban, only 9% of globally discarded plastics were being recycled and 12% were burned.  The rest ended up in landfills or simply dumped into the environment.  Over the coming decade, as many as 11 million tons of plastic will have to find a new place to be processed or otherwise disposed of.  There is already evidence that plastic waste is accumulating in countries that are dependent on exporting.  In many places, including a number of American cities, there are curtailed collections and new restrictions on what kinds of plastics are accepted.

Some experts are hopeful that China’s ban might actually have an upside if it leads to better solutions for managing the world’s waste.  North America and Europe need to expand processing capabilities and manufacturers need to make their products more easily recyclable.  Mostly, the Chinese ban should be a wake-up call to the world on the need to greatly reduce single-use plastics.

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Piling Up: How China’s Ban on Importing Waste Has Stalled Global Recycling

Photo, posted August 8, 2017, courtesy of Sino-German Urbanisation Partnership via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Another Way To Make Solar Cells

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Millions of rooftops now contain solar panels and the majority of the solar cells that make up those panels today are made from silicon.  Silicon solar cells require expensive, multi-step processing conducted at very high temperatures in special clean room facilities.  Despite these complications, the price of solar panels has continued to drop dramatically over the years.

But even as the price of solar cells gets lower and lower, there are still widespread efforts to find even better ways to make them.   One of those ways is with perovskite solar cells.  Perovskites are materials with a characteristic crystal structure and are quite common in nature.  Perovskites can be formed with a wide range of elements and can exhibit a variety of properties.

They were first used to make solar cells about 10 years ago and those first cells were unimpressive in most respects.  However, there has been steady progress since that time.  The potential advantages of perovskite solar cells are that they can be made from low-cost materials and can be manufactured using liquid chemistry, a far cheaper process than what is used to make silicon cells.

Researchers at MIT and several other institutions have recently published the results of research on how to tailor the composition of perovskite solar cells to optimize their properties.   What used to be a trial-and-error process can now become much more engineered and should lead to perovskite solar cells with performance that could exceed that of silicon cells.

Silicon solar panels are a huge, worldwide industry and displacing them in favor of an alternative technology is a tall order.  But if perovskite cells can be optimized for large-scale manufacturability, efficiency and durability, they could definitely give silicon a run for its money.

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Unleashing perovskites’ potential for solar cells

Photo courtesy of Ken Richardson/MIT.

Earth Wise is a production of WAMC Northeast Public Radio.

A Carbon Loophole

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Many power plants in Europe and elsewhere are replacing coal with wood.  For example, the Drax Power Station in Britain was its largest coal-burning plant and is now using wood pellets shipped from the southern U.S. in its boilers.    According to the carbon accounting rules at the EU and elsewhere, the process is considered to be “carbon neutral.”   But is it?

The idea is that new trees are being planted in the forests where the trees are cut to be burned in power plants.  So, there is carbon neutrality.  In principle.

European countries have embarked on a massive effort to switch to generating power from renewable energy.  While there has indeed been major growth in wind and solar power in the 28 countries of the European Union, much of the new “green” power has come from burning wood in converted coal power stations.

A group of 200 scientists wrote to the EU last September insisting that bioenergy from forest biomass is not carbon neutral and that there must be tighter rules to protect forests and their carbon.  Wood burning has become a loophole in controlling carbon emissions.

There are problems with the claims of carbon neutrality.  There is no way to know whether enough new trees are actually being planted to replace those being burned.  And then there is the time lag for tree replacement.  Trees don’t grow overnight.  There are also the carbon emissions associated with harvesting, processing and transporting wood.

There are most certainly ways in which burning biomass can be carbon neutral and can represent real progress over the use of fossil fuels.  But caution must be taken to avoid exploiting loopholes in current climate rules that might actually result in increased carbon emissions.

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Carbon Loophole: Why Is Wood Burning Counted as Green Energy?

Photo, posted April 26, 2014, courtesy of Flickr.

 

‘A Carbon Loophole’ from Earth Wise is a production of WAMC Northeast Public Radio.

Cryptocurrency And Climate Change

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Bitcoin is a form of digital currency.  Bitcoins aren’t printed, like dollars or euros.  They are produced by people and businesses using computer software to perform the necessary complex calculations.  A bitcoin is essentially a line of computer code that’s signed digitally when it goes from one owner to another.  Bitcoin is the most prominent example of a growing category of money known as cryptocurrency. 

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A New Low-Cost Battery

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Batteries have never been more important.  Not only do we all depend on cell phones, tablets and laptop computers that run on batteries, but two enormous industries are in major transitions that rely upon battery technology: personal transportation and the utility industry.   The electricity grid is increasingly turning to solar and wind power for generation and both will require effective energy storage if they are to truly become the predominant sources of electricity.

[Read more…] about A New Low-Cost Battery

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