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Better Ways To Make Bioplastics | Earth Wise

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The world produces over 300 million tons of plastics each year, mostly produced from petroleum.  The environmental consequences are substantial and there is a critical need to replace as much of that plastic production with biodegradable plastics as possible.  Thus, there is global research aimed at making bioplastics more economical and as environmentally friendly as possible.

Researchers at Texas A&M University have developed an improved approach for making bioplastics from corn stubble, grasses, and mesquite agricultural production.  Apart from the obvious environmental benefits of having biodegradable plastics, producing bioplastics from common agricultural waste would create new revenue streams for farmers as well as the people who transport harvested feedstock and byproduct crops to refinery operations.

The key to bioplastic production is the efficient extraction and use of lignin, the organic polymer that is the primary structural support material in most plants.  The new research takes five conventional pretreatment technologies for plant materials and modifies them to produce both biofuel and plastics together at a lower cost.  The new method is called “plug-in preconditioning processes of lignin” and it can be directly and economically added into current biorefineries.  The process is designed to integrate dissolving, conditioning, and fermenting lignin, extracting energy from it and making it easily adaptable to biorefinery designs.

The so-called bioeconomy currently supports some 286,000 jobs.  Innovation is the key to achieving more widespread use of biodegradable plastic.  With improved economics of so-called lignocellulosic biorefineries, there can be new avenues to use agricultural waste to produce biodegradable plastics.

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‘Plugging in’ to produce environmentally friendly bioplastics

Photo, posted November 5, 2015, courtesy of Kathryn Faith via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Is Peak Oil Here? | Earth Wise

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For many years there has been talk of “peak oil”, the point at which rising world oil consumption would peak and then start declining.  Some analysts have been predicting that this could happen by the 2030s.   But the coronavirus pandemic drove a 9% slump in oil demand in 2020 that some economists are saying might never be entirely reversed.

There are three major forces driving down the world’s appetite for oil:  decarbonization of economies to meet the goals of the Paris climate agreement, declining demand for oil as renewable energy sources and electric vehicles are increasingly adopted, and detoxification as cities act to curb particulates and emissions from burning petroleum.

The largest single factor is electric vehicles.  Automobiles currently consume almost half of the world’s oil.  As of the end of 2020, there were an estimated 10 million electric cars as well as more than 600,000 electric buses and trucks.  This is still less than 1% of all vehicles, but 5% of all new cars being bought are now electric and the number is growing rapidly.  Experts estimate that nearly a quarter of global car sales will be electric vehicles by 2025 and many car manufacturers are promising to sell only electric cars within the next 10 years.

The decline in oil demand is pretty much inevitable at this point.  The main question is how quickly it will happen.  Road transport makes up 48% of global oil demand, petrochemicals account for 14%, aviation 7%, and shipping 6%.  Ultimately all these things are likely to diminish over time. 

Only time will tell, but the long-awaited arrival of peak oil may already have happened.

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Amid Troubles for Fossil Fuels, Has the Era of ‘Peak Oil’ Arrived?

Photo, posted April 14, 2019, courtesy of Tony Webster via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Transparent Wood | Earth Wise

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In recent years, there have been efforts to change the nature of wood to give it new properties.  People have demonstrated so-called augmented wood with integrated electronics, energy storage capabilities, and other properties.  Several different groups of researchers have developed wood that is actually transparent.

In 2016, researchers at KTH Royal Institute of Technology in Stockholm demonstrated transparent wood made by selectively extracting lignin – the substance that makes up the cell walls of wood -and replacing it with a polymer.  The result is a new material that is weatherproof, fairly fire resistant, stronger than wood, lighter than wood, and transparent.

When the lignin is removed from wood, the empty pores left behind need to be filled with something that restores the wood’s strength.  The early versions of transparent wood used polymethyl methacrylate – essentially acrylic plastic – for this purpose.  But that material is made from petroleum, so it is not an environmentally desirable approach.

Recently, the KTH researchers have successfully tested an eco-friendly alternative:  limonene acrylate, which is a monomer made from renewable citrus, such as peel waste that can be recycled from the orange juice industry.

There are many potential applications for transparent wood as a structural material.  These include load-bearing windows, skylights, and semi-transparent facades that are strong and thermally insulating and yet permit light to enter. 

Transparent wood would be a very attractive material for many applications in that it comes from renewable sources and offers excellent mechanical properties including strength, toughness, low density, and low thermal conductivity.

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Citrus derivative makes transparent wood 100 percent renewable

Photo, posted October 12, 2018, courtesy of Mussi Katz via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Replacing Plastic Tableware | Earth Wise

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Plastics have been described as the “ubiquitous workhorse material of the modern economy.”  But their versatility, pliability, and durability comes at a heavy price to the environment.  Plastic pollution is quite literally everywhere.  Plastic debris and microplastic particles can be found in every corner of the globe, including the Arctic and Antarctic. 

The scourge of plastic pollution is driving scientists to create ecologically-friendly alternatives.  According to a paper recently published in the journal Matter, scientists have developed “green” tableware made from sugarcane and bamboo that doesn’t sacrifice on convenience or functionality.  This eco-friendly tableware could serve as a permanent replacement for plastic cups and other disposable plastic containers. 

Traditional plastic polymers, a product of petroleum, can take as long as 1,000 years to decompose in landfills.  The new material only takes 60 days to break down.

To create this material, scientists used bamboo and bagasse, also known as sugarcane pulp.  Bagasse is one of the largest food-industry waste products.  The researchers wound the fibers together to form a mechanically stable and biodegradable material.  They added an alkyl ketene dimer, an eco-friendly chemical, to increase the oil and water resistance of the material.  The green material is durable enough to hold liquids like hot coffee and hot greasy foods like pizza.   

There’s another advantage: the green material’s manufacturing process emits 97% less CO2 than the process to make commercial plastic containers.  The next step is to lower the manufacturing cost.  While the cost of cups made from the green material is $2,333 per ton, traditional cups made from plastic are still slightly cheaper at $2,177 per ton.

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This tableware made from sugarcane and bamboo breaks down in 60 days

Photo, posted May 19, 2013, courtesy of Henry Burrows via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plastic From Algae | Earth Wise

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Many researchers consider algae to be one of the best renewable resources for replacing fossil fuels and even as a food source.  The green microalgae Nannochloropsis salina is already a common source of omega-3 fatty acids that are sold as dietary supplements.  As a result, that algae strain is already grown on a large scale for the production of omega-3 products.

A group of researchers at UC San Diego has developed a way to make use of the waste stream from that production to create plastics and other useful products.  Currently, when the algae is processed to extract the omega-3 oil, leftover oils comprising more than 70% of the starting material are either thrown away or burned. 

The UCSD team has developed a process to purify and convert this waste stream into azelaic acid, which is a building block for flexible polyurethanes.   These materials have all kinds of commercial applications from flip-flops and running shoe soles to mattresses and yoga mats.

By analogy to the use of animals by native American tribes, the researchers wanted to “use the whole buffalo” in their solution for algae processing waste and therefore figured out how to convert heptanoic acid – another substance in the algae waste stream – into a food flavoring and fragrance.  The flavoring molecule is valued at over $500 per kilogram.

The work, published in the journal Green Chemistry, demonstrates that an algae-source waste stream has both the practical and economic potential to support production of polyurethanes.  The team is already working with shoe companies to commercialize the technology.  With mounting concern over petroleum-based plastic waste, renewable plastic made from algae is an attractive alternative.

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Researchers Turn Algae Leftovers into Renewable Products with Flare

Photo, posted November 8, 2006, courtesy of Adam Moore via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plants Paying For Biofuels | Earth Wise

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Biofuels are an important element in broader strategies to replace petroleum in transportation fuels like gasoline, diesel, and jet fuel.  The idea is that biofuels recycle carbon by getting it from growing plants rather than from fossil sources.  The biggest problem with biofuels is that they cost more than conventional petroleum fuels, so there is economic incentive to keep burning the fossil fuels.

One strategy to make biofuels cost competitive is to have the plants provide additional economic benefits beyond being a feedstock for fuel.  This in principle can be done by engineering plants to produce valuable chemical compounds, or bioproducts, as they grow.  Bioproducts include such things as flavoring agents and fragrances as well as biodegradable plastic.  These bioproducts can be extracted from the plants and then the remaining plant material can be converted to fuel. 

Researchers at Lawrence Berkeley National Laboratory recently published a study to determine what quantities of bioproducts plants need to produce to result in cost-effective biofuel production.

The study looked at a compound called limonene, which is used for flavoring and fragrance.  They calculated that if this compound was accumulated at 0.6% of the biomass dry weight, it would offer net economic benefits to biorefineries.  This corresponds to recovering 130 pounds of limonene from 10 tons of sorghum on an acre of land.

Such quantities are completely practical but, on the other hand, none of these substances are needed in huge quantities. Just six refineries could supply the world with limonene.  So, fuel crops would need to be engineered to produce a broad range of bioproducts to enable a viable cost-effective biofuel industry.

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Making Biofuels Cheaper by Putting Plants to Work

Photo, posted September 28, 2019, courtesy of Michele Dorsey Walfred via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

More Plastic Pollution On The Way | Earth Wise

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Public concern about plastic pollution has been rising.  More and more of us are choosing reusable grocery bags, metal straws, and reusable water bottles.  We shake our heads at images of immense plastic garbage patches in the ocean. We see reports of birds with 15% of their body weight in plastic.

While all of this is going on, companies like ExxonMobil, Shell, and Saudi Aramco are ramping up production of plastic – which is mostly made from oil, gas, and their byproducts.  They are doing this as a hedge against the growing possibility that the global response to climate change will reduce demand for their fuels.  Plastics are part of the category called petrochemicals, which currently account for 14% of oil use.  Petrochemicals are expected to drive half of oil demand growth over the next 30 years.

The World Economic Forum predicts plastic production will double in the next 20 years.  The fracking boom in the United States has turned this country into a big growth area for plastic production.  Natural gas prices are low which is hurting profits at fracking operations.  But fracking also unearths ethane, which is a feedstock for plastic production.  So plastic is becoming a kind of subsidy for fracking.

The American petroleum industry’s hub has historically been the Gulf Coast of Texas and Louisiana as well as a stretch along the lower Mississippi River.  There is a slew of new projects there.  The industry is also seeking to create a new plastics corridor in Ohio, Pennsylvania, and West Virginia, where fracking wells are rich in ethane.

Society in general may be increasingly concerned about the impact of things like carbon emissions and plastic pollution, but the fossil fuel industry continues to focus entirely on growth and profits.

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The Plastics Pipeline: A Surge of New Production Is on the Way

Photo, posted January 10, 2015 , courtesy of Daniel Orth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Problem Of Gas Flaring | Earth Wise

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Gas flaring is the burning off of flammable gas released by pressure relief values during over-pressuring of plant equipment at petroleum refineries, chemical plants, natural gas processing plants, and a variety of oil and gas production plants.  Flaring is also used during plant startups and shutdowns.

A new study by Rice University concludes that reducing gas flaring would benefit both the environment and the economy. Flaring and venting of gas in West Texas’s Permian Basin and certain other parts of the U.S. have reached levels that the intended result of burning gas to allow oil extraction now looks more like wasting one resource to produce another.

At current rates, enough gas is flared in the Permian Basin to yield nearly 5 million metric tons of exportable liquid natural gas if it was captured and liquified.  At these rates, the wasted gas could fill the largest sized LNG carrier every ten days.  If that liquified natural gas was exported to China and used in a power plant, it would displace 440,000 metric tons of coal burned to generate electricity.

Burning natural gas to heat homes, power industrial processes, or generate electricity all emit carbon dioxide, but at least these things also perform valuable functions. Flaring gas produces CO2 as well as other combustion products but doesn’t even do anything useful.  The venting of unburned gas, which also takes place with some frequency, is even worse since it is dumping methane directly into the atmosphere.

Across the U.S., some 14.1 billion cubic meters of natural gas was flared in 2018, equivalent to nearly 9 million metric tons per year of LNG.  In energy terms, that is equivalent to more than one-third of the total LNG volume U.S. firms actually exported that year.

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Reducing gas flaring will benefit economy and environment, says Baker Institute expert

Photo courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Falling U.S. Carbon Emissions

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Reducing carbon emissions is a goal embraced by nearly every country in the world, but actually accomplishing it isn’t easy. It is true that renewable energy sources are playing a growing role in energy systems, but counterbalancing that trend is growing energy demand, especially in developing countries.

Here in the US, energy-related CO2 emissions actually went up nearly 3% in 2018 compared with 2017.  But the US Energy Information Administration is now forecasting a 2% drop in emissions this year.

The main reason energy-related emissions are headed lower at this point is coal-fired power plant retirements.  More than 90% of the coal used in the US goes toward electric power and utilities are increasingly turning away from coal.

The rapid shift away from coal has mostly been due to the increasing use of natural gas.  Natural gas is not actually a clean and green fuel, but it is definitely less carbon-intensive than coal.  Overall, the total installed capacity of renewable sources – hydropower, wind, solar, geothermal, and biomass – has now actually surpassed the capacity of coal plants.  Given that renewables have in many places become the cheapest power option, there is little chance that coal has much of a future, despite efforts by the current administration.

The electric power sector is gradually moving away from all carbon-emitting sources – a trend that is being reinforced by legislation in many states.  The real CO2 emissions leader is petroleum, which accounts for nearly half of the total.  We have a long way to go to reduce emissions from the use of petroleum.  There are over 250 million cars and trucks on US roads and only a little over a million of them don’t burn fossil fuels.

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US energy-related CO2 emissions expected to fall this year, almost solely due to a drop in coal use

Photo, posted November 6, 2017, courtesy of Cindy Shebley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Jet Fuels

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The global aviation industry uses a whole lot of fuel:  more than 5 million barrels a day.  It is an incredibly energy-intensive industry and almost all of its energy comes from petroleum-based fuels.

While other large energy sectors such as electric power, ground transportation and commercial buildings have well-defined pathways to adopting renewable energy sources, the aviation industry does not have such a straightforward way to make a transition to sustainability.  Electrifying planes using batteries or fuel cells is very challenging for a number of reasons, notably the weight restrictions on aircraft.  So liquid biofuels as replacements for petroleum-based fuels remain the most promising approach.

A new study at the Lawrence Berkeley National Laboratory concludes that sustainable plant-based biofuels could provide a competitive alternative to conventional petroleum fuels if current development and scale-up initiatives are successful.

Multidisciplinary teams based at the Department of Energy’s Joint BioEnergy Institute are focused on optimizing each stage of the bio-jet fuel production process.  This includes bioengineering ideal source plants and developing methods for efficiently isolating the carbohydrates in non-food biomass that bacteria can digest and bioconvert into fuel molecules.

The critical issue is cost.  The theoretical cost of bio-jet fuel has come down dramatically in recent years but is still around $16 a gallon.  The cost of standard jet fuel is about $2.50 a gallon.  So, the real challenge is bridging that gap.

Reducing the cost of the fuel could come both from the material and process improvements that are underway as well as by finding ways to turn the leftover lignin residuals from the bioconversion process into valuable chemicals. 

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Bright Skies for Plant-Based Jet Fuels

Photo, posted March 28, 2009, courtesy of Yasuhiro Chatani via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Sustainable Plastics

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According to the United Nations, plastic accounts for up to 90% of all the pollutants in the ocean. Conventional plastics take hundreds of years to decay, so all the plastic that gets into the oceans piles up and endangers marine life and pollutes the environment. Unfortunately, there are few comparable, environmentally friendly alternatives.  

An often-proposed solution is bioplastics, which are not made from petroleum and degrade quickly.  The downside of bioplastics is that growing the plants or bacteria used to make the plastic requires fertile soil and fresh water, which are scarce commodities in many places.

One such place is Israel.  So, researchers there at Tel Aviv University have developed a process to make a bioplastic polymer that doesn’t require land or fresh water.  The new polymer is derived from microorganisms that feed on seaweed.  It is biodegradable, produces zero toxic waste and recycles into organic waste.

The polymer is called polyhydroxyalkanoate, or PHA for short.  The raw material is multicellular seaweed, cultivated in the ocean.  These algae are eaten by single-celled microorganisms, which also grow in salty seawater and produce a polymer that can be used to make bioplastic.  PHA is already produced in commercial quantities, but it is currently made from plants that require agricultural land and fresh water.  The new process would enable countries with limited fresh water, such as Israel, China and India, to switch from petroleum-based plastics to biodegradable plastics.

Plastics from fossil sources are one of the world’s biggest pollution problems.  The new study shows that it is possible to produce bioplastic completely based on marine resources in an environmentally-friendly process. 

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Sustainable ‘plastics’ are on the horizon

Photo, posted March 14, 2015, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaning Up Shipping Fuel

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Cargo ships are significant sources of global air pollution because of their fuel oil.  Most ships burn something called “bunker fuel” which is a pitch-black, molasses-thick fuel made from the dregs of the oil refining process.  It is loaded with sulfur, so when it is burned it produces noxious gases and fine particles that can harm human health and the environment.  Because bunker fuel is made from petroleum refining residues, waste byproducts sometimes end up in the mix, making the stuff even a worse source of pollution.

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The Changing Face Of Air Pollution

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Air pollution in cities is a global problem that has reached crisis proportions in places like China and India.   In our country, since the Clean Air Act was passed in 1970, there has been a great deal of effort exerted in controlling pollution from vehicles.  A combination of pollution-limiting changes to engines, fuels, and pollution control systems has significantly reduced the amount of air pollution associated with the transportation sector.

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Mass Production Of Biodegradable Plastic  

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Plastic pollution is a major problem for the world’s oceans and non-biodegradable plastics continue to fill the planet’s landfills and litter the landscape.   There are many approaches to making plant-derived, biodegradable plastics but most of these materials do not offer the resistance to heat and moisture that is characteristic of petroleum-based plastics.

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Americans And Beef

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There’s ample evidence over the past decade or so that Americans are gradually changing their diets, driven by health concerns among other factors.  But there’s one change that really stands out.  According to a study by the Natural Resources Defense Council, Americans have sliced their beef consumption by 19% between 2005 and 2014. 

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