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Hydrogen And The Methane Problem | Earth Wise

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Theoretically, hydrogen could be the fuel of the future.  It is the most common element in the universe and its combustion produces no harmful emissions.  Most industrial hydrogen comes from a process called steam reforming that extracts it from natural gas – basically methane.  Carbon dioxide is a byproduct of the process.   But it is also possible to get hydrogen by breaking down water resulting only in oxygen as a byproduct.   There is a great deal of ongoing development of so-called green hydrogen.

New research from Princeton University and the National Oceanic and Atmospheric Administration has uncovered a potential problem associated with the use of hydrogen as a clean fuel. 

There is a molecule in the atmosphere called the hydroxyl radical.  It is known as “the detergent of the troposphere”.  It plays a critical role in eliminating greenhouse gases such as methane and ozone from the atmosphere.  It turns out that the hydroxyl radical also reacts with any hydrogen gas in the atmosphere and there is only so much hydroxyl to go around.  If large amounts of hydrogen were to enter the atmosphere, much of the hydroxyl radical would be used up reacting with it and there would be much less available to break down methane.  As a result, there would end up being more methane in the atmosphere, and methane is a powerful greenhouse gas.

The bottom line is that there would need to be proactive efforts to limit the amount of hydrogen getting into the atmosphere whether from producing it, transporting it, or anyplace else in the value chain.  Otherwise, the hydrogen economy would cancel out many of the climate benefits of eliminating fossil fuels.

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Switching to hydrogen fuel could prolong the methane problem

Photo, posted June 12, 2021, courtesy of Clean Air Task Force via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

An Iron-Air Battery Plant | Earth Wise

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Lithium-ion batteries are the standard energy source for electric vehicles, and they are also the dominant technology for storing energy in the electric grid.  However, they are not the only game in town.  There are other battery technologies that have various potential advantages over lithium-ion and some of them are getting the chance to show what they can do.

One is the iron-air battery.  Unlike lithium-ion batteries that require expensive and strategically challenging materials like lithium, cobalt, nickel, and graphite, iron-air batteries make use of one of the most common elements in the earth’s crust.

Iron-air batteries operate on a principle known as “reversible rusting”.  When discharging, the battery takes in oxygen from the air and converts iron into rust.  While charging, electrical current converts rust back into iron and the battery releases oxygen.  Batteries consist of a slab of iron, a water-based electrolyte, and a membrane that feeds a controlled stream of air into the battery. 

A Massachusetts-based company called Form Energy is building a $760 million iron-air battery storage facility in the city of Weirton in West Virginia.  Investment financing along with a $290 million government incentive package is paying for the facility. 

The facility is designed to address the need for long-duration energy storage and will be capable of storing electricity for 100 hours at competitive prices.  The battery modules will be about the size of a side-by-side washer/dryer and will contain a stack of 50 3-foot-tall cells.  Such batteries are too big and heavy for use in cars but will be cheaper and higher-capacity than equivalent lithium-ion battery systems.

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Form Energy selects West Virginia for its first iron-air battery plant

Photo credit: Form Energy

Earth Wise is a production of WAMC Northeast Public Radio

Oxygen Loss In Lakes | Earth Wise

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Researchers from Cornell University and Rensselaer Polytechnic Institute have found that the continual warming in the world over the past 25 years has been reducing the amount of oxygen in many lakes.

Data from more than 400 lakes – mostly in the United States – shows that lakes with dissolved oxygen losses strongly outnumber those with gains.  Overall, the researchers found that the amount of low oxygen water is increasing by 0.9% to 1.7% per decade on average  and the volume of lake water lacking oxygen has increased by more than 50% from 25 years ago.

In the summer, lake surfaces may be about 70 degrees while the lake bottom may be about 40 degrees.  The colder water is denser than the warmer water which causes resistance to the layers mixing.  It is akin to having oil and vinegar in a cruet.  This is known as stratification.   The result is that oxygen from the atmosphere is prevented from replenishing dissolved oxygen in deep waters.  This is a normal seasonal phenomenon.

However, with winter ending sooner than it used to, seasonal stratification is starting earlier and ending later. As warming continues, it is likely that there will be an increasing number of oxygen-depleted lakes in the future.

Oxygen deprivation in water can lead to hypoxia (low oxygen) and even anoxia (no oxygen), which have negative consequences for fish and other species.  Reducing oxygen in lake water can lead to buildup of methane.   Nutrients from agricultural runoff, released from unsettled lake sediment, increase the likelihood of harmful algal blooms.

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Warming climate prompts harmful oxygen loss in lakes

Photo, posted June 23, 2010, courtesy of Alexander Acker via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Snail Darter Is Safe | Earth Wise

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The snail darter is a three-inch-long snail-eating fish that was once only found in the Little Tennessee River.  When that river was going to be dammed by the Tellico Dam under construction in the 1970s, the snail darter was listed on the endangered species list and the little fish subsequently became the subject of a legal battle that made it all the way up to the U.S. Supreme Court.   With the dam project 95% complete in 1978, the Supreme Court blocked further construction, citing the Endangered Species Act.  A year later, Congress exempted the project from the requirements of the Act, thereby clearing the way for the completion of the dam.

In order to save the snail darter, biologists transplanted the fish into several other nearby rivers and waterways.  In addition, the Tennessee Valley Authority modified the operation of the Tellico Dam to release more oxygen-rich water downstream.  Beyond those measures, the river cleanup under the Clean Water Act further aided the fish’s recovery.

In 1984, the snail darter was removed from the endangered species list and was listed as threatened or vulnerable.  Recently, the U.S. Department of the Interior officially removed the snail darter from the federal list of threatened and endangered wildlife. 

The snail darter is the fifth fish species to be delisted because its population has recovered.  It is the first in the eastern United States.  With better management of water releases at dams, many other imperiled aquatic species could be recovered.

Overall, more than 50 plants and animals have recovered under federal protection, including American alligators, humpback whales, peregrine falcons, and bald eagles.

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Once at Center of Controversial Case, the Snail Darter Fish Is No Longer Threatened

Photo, posted July 22, 2015, courtesy of The U.S. Fish and Wildlife Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Green Steel | Earth Wise

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The Inflation Reduction Act provides $369 billion in investments to ramp up renewable energy generation and manufacturing of solar panels, wind turbines, energy storage, and electric vehicles. 

Every megawatt of solar power deployed requires 35 to 45 tons of steel.  Every megawatt of wind power uses 120 to 180 tons of steel.   Estimates are that it will take 1.7 billion tons of steel just to build all the wind turbines needed to reach net zero emissions by 2050.

This is a big problem because steel production accounts for roughly 10% of global carbon emissions and is one of the most carbon-intensive industries in the world.

Making steel is a complex and age-old process that hasn’t changed much over time.  Green steel is steel made with little or no carbon emissions.  There are a few ways to do it.  One is called the direct reduced iron method that uses green hydrogen instead of fossil fuel gas to produce iron and then a renewable-powered electric arc furnace to make the steel. 

Molten Oxide Electrolysis is an alternative green steel approach that doesn’t depend on having a green hydrogen infrastructure.  It uses electrolysis, powered by renewable energy, to separate the bonds of iron ore and produce liquid metal while releasing only oxygen in the process.

Green steel solutions rely on the availability of renewable energy, but the ultimate success of renewable energy will depend on the success of green steel.  The U.S. steel industry will leverage about $6 billion under the Inflation Reduction Act to make progress on it.

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Building tomorrow’s clean energy systems on green steel

Photo, posted October 30, 2008, courtesy of Paul Bica via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Beavers Are Flooding The Warming Arctic | Earth Wise

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The accelerating warming in the Arctic has transformed the region into a warmer, wetter, and more diverse environment.  Warming temperatures have encouraged the increasing growth of vegetation, particularly shrubs that provide beavers with bark to eat and branches to build with.  Warming temperatures also mean that lakes and streams freeze solid for shorter periods of time or not at all, allowing beavers to pursue their construction projects for longer periods during the year.

Prior to the mid-1970s, residents of the Alaskan Arctic encountered few beaver ponds.  In 2018, researchers using satellite imagery mapped 12,000 beaver ponds in Alaskan tundra.

Beavers are causing major changes in the streams and floodplains that many small Alaskan villages depend upon for food, water, and navigation.  As the rodents transform lowland tundra ecosystems, they are eliminating food sources, deteriorating water quality, and making it difficult to navigate waterways.

The migration of beavers across the Arctic landscape is largely a result of climate change.  But it is also becoming one of the factors amplifying climate change.  Scientists are trying to figure out the degree of permafrost thawing that beaver dam-and-den building is causing and how fast these defrosted organic soils will degrade and release trapped carbon and methane.

Beaver dams alter the hydrology of streams by slowing the flow, storing and spreading water to create wetlands, raising the water table, and lowering the oxygen content of the water. 

Climate-driven changes in species distributions affect human well-being as entire ecosystems continue to change.  Shifts in animal habitat stimulated by climate change could have profound consequences across the globe.

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Beavers Are Flooding the Warming Alaskan Arctic, Threatening Fish, Water and Indigenous Traditions

Photo, posted June 12, 2018, courtesy of Peter Pearsall/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Climate Change And The World’s Fisheries | Earth Wise

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According to a new study, approximately 70% of the world’s oceans could be suffocating from a lack of oxygen by 2080 as a consequence of climate change.  This has the potential to impact marine ecosystems all around the world.  

The study, which was recently published in the journal Geophysical Research Letters, is the first to use climate models to predict how and when deoxygenation will occur throughout the world’s oceans outside of its natural variability. 

According to the findings, significant and potentially irreversible deoxygenation of the ocean’s middle depths began occurring last year.  The models predict that deoxygenation will begin affecting all zones of the ocean by 2080.

According to the study’s models, mid-ocean depths are already losing oxygen at unnatural rates. Globally, the ocean’s middle depth – known as the mesopelagic zone – is home to many of the world’s commercially fished species.  This makes these new findings a potential harbinger of economic hardship, seafood shortages, and environmental disruption. 

Just like land animals, aquatic animals need oxygen to breathe.  As climate change warms the oceans, the water holds less oxygen and is more buoyant than cooler water.  This leads to less mixing of oxygenated water near the surface with deeper waters, which naturally contain less oxygen.  Warmer water also raises oxygen demand among living organisms, resulting in less availability for marine life. 

The researchers also found that oceans closer to both the North Pole and the South Pole are particularly vulnerable to deoxygenation.  While they are not yet sure why, accelerated climate warming could be the culprit. 

These findings should add new urgency to climate change mitigation efforts. 

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Climate change has likely begun to suffocate the world’s fisheries

Photo, posted January 28, 2019, courtesy of Joseph Gage via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

New York And Green Hydrogen | Earth Wise

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In July, outgoing New York Governor Andrew Cuomo announced plans for the state to explore the potential role of green hydrogen as part of New York’s decarbonization strategy.

Green hydrogen is hydrogen produced using renewable energy, such as wind, solar, and hydro power.  While hydrogen itself is a carbon-free fuel, most of the hydrogen produced today is made with a process called natural gas reforming which has byproducts of carbon monoxide and carbon dioxide.  As a result, the environmental benefits of using hydrogen are largely lost.  Hydrogen is the most plentiful element in the universe but extracting it for use as a fuel is not easy.

Green hydrogen is obtained by splitting water molecules into their constituent hydrogen and oxygen parts.  In principle, oxygen is the only byproduct of the process.  The main drawback of electrolysis, as this process is called, is that it is energy intensive as well as being expensive.  But if that energy comes from renewable sources, then it is a clean process.

New York’s announcement is that the state will collaborate with the National Renewable Energy Laboratory and join two hydrogen-focused organizations to inform state decision-making, as well as make $12.5 million in funding available for long duration energy storage techniques and demonstration projects that may include green hydrogen.

Green hydrogen has the potential to decarbonize many of the more challenging sectors of the economy.  Hydrogen is a storable, transportable fuel that can replace fossil fuels in many applications.  Many experts believe that the so-called hydrogen economy could be the future of the world’s energy systems.  For that to happen, green hydrogen will need to be plentiful, sustainable, and inexpensive.

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New York announces initiatives to explore green hydrogen for decarbonization

Photo, posted October 26, 2019, courtesy of Pierre Blache via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Gulf Of Mexico Dead Zone | Earth Wise

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Every summer, a so-called dead zone forms in the Gulf of Mexico.  It is primarily caused by excess nutrient pollution from human activities in urban and agricultural areas throughout the Mississippi River watershed. 

When these excess nutrients reach the Gulf, they stimulate excess growth of algae, which eventually die and decompose, depleting oxygen as they sink to the bottom.  These low oxygen levels near the Gulf bottom cannot support most marine life.  Animals that are sufficiently mobile – such as fish, shrimp, and crabs – generally swim out of the area.  Those that can’t move away are stressed or killed by the low oxygen.

A team of scientists funded by the National Oceanic and Atmospheric Administration issues an annual forecast for the dead zone based upon a suite of models that incorporate river flow and nutrient data. 

The 2021 forecasted area is somewhat smaller than, but close to, the five-year measured average for the dead zone, which is 5,400 square miles, roughly the size of the state of Connecticut.   Each year, these forecasts are reported as comparisons to long-term averages, but the problem is that the long-term average is unacceptable.

The Interagency Mississippi River and Gulf of Mexico Hypoxia Task Force has set a goal of reducing the size of the dead zone to a five-year average of 1,900 square miles – about a third of the current average.

Large reductions in nutrient loads have been called for in federal and state action plans for nearly 20 years, but clearly these reductions have not yet been sufficient. The Interagency Task Force continues to provide information for managing nutrient loads in the Mississippi River Basin. 

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Average-sized ‘dead zone’ forecast for Gulf of Mexico

Photo, posted October 6, 2020, courtesy of Christine Warner via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wind Farms Slowing Each Other Down | Earth Wise

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Offshore wind is booming in Europe.  The expansion of wind energy in the German Bight and Baltic Sea has been especially dramatic.  At this point, there are about 8 gigawatts of wind turbines in German waters, the equivalent of about 8 nuclear power plants.  But space in this region is limited so that wind farms are sometimes built very close to one another.

A team of researchers from the Helmholtz Center Hereon, a major German research institute, has found that wind speeds downstream from large windfarms are significantly slowed down.  In a study published in the journal Nature Scientific Reports, they found that this braking effect can result in astonishingly large-scale lowering of wind speeds.

On average, the regions of lowered wind can extend 20-30 miles and, under certain weather conditions, can even extend up to 60 miles.  As a result, the output of a neighboring wind farm located within this distance can be reduced by 20 to 25 percent.

These wake effects are weather dependent.  During stable weather conditions, which are typically the case in the spring in German waters, the effects can be especially large.  During stormy times, such as in November and December, the atmosphere is so mixed that the wind farm wake effects are relatively small.

Based on their modeling, it is clear that if wind farms are planned to be located close together, these wake effects need to be taken into account.  The researchers next want to investigate the effects that reduced wind speeds have on life in the sea.  Ocean winds affect salt and oxygen content, temperatures, and nutrients in the water.  It is important to find out how reduced winds might affect marine ecosystems.

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Are wind farms slowing each other down?

Photo, posted November 23, 2011, courtesy of David J Laporte via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Overwintering Fires | Earth Wise

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Fires that go on for long periods of time, surviving the snow and rain of winter to reemerge in the spring, are becoming more common in high northern latitudes as the climate warms.  Such fires are called holdover fires, hibernating fires, overwintering fires, or even zombie fires.  Whatever people choose to call them, this type of wildfire is occurring more often.

These smoldering fires start out as flaming fires but then enter an energy-saver mode.  They start above ground but then smolder in the soil or under tree roots through the winter.  They barely survive based on the oxygen and fuel resources that they have but can transition back into flaming fires once conditions are more favorable.

Dutch researchers used ground-based data with fire detection data from NASA’s Moderate Resolution Imaging Spectroradiometer instruments on the Terra and Aqua satellites to study fires in the boreal forests of Alaska and Canada’s Northwest Territories.  They found a way to identify overwintering fires based on their unique characteristics.  

Their data indicates that overwintering fires tend to be linked to high summer temperatures and large fire seasons.  Between 2002 and 2018, overwintering fires generally accounted for a small amount of the total burned area in the region but in individual years with hot and severe fire seasons, the number can escalate.  In 2008 in Alaska, for example, overwintering fires accounted for nearly 40% of the burned area.

Early detection of these overwintering fires could help with fire management and reduce the amount of carbon – which is stored in large amounts in the region’s organic soils – that gets released to the atmosphere during fires.

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Overwintering Fires on the Rise

Photo, posted September 14, 2017, courtesy of Andrew R. Mitchell/USDA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen-Powered Jetliners | Earth Wise

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Airbus, the giant European aerospace company, hopes to have hydrogen-powered commercial airliners in the sky by 2035.  Such planes would have no carbon dioxide emissions.

Greenhouse gas emissions from commercial aviation have been a rapidly increasing contribution to the global total.  Of course, the Covid-19 pandemic has drastically reduced air travel, so emissions are currently lower than they have been in a very long time.  But at some point, they will resume at previous levels and continue to increase.

Planes themselves produce over 2% of global CO2 emissions, and between the climate effects of contrails and the emissions associated with the rest of the air travel industry, commercial aviation drives about 5% of global warming.

Airbus is studying design concepts in which planes run off of hydrogen and oxygen fuel and have no carbon exhaust.   Making such planes practical and environmentally advantageous requires solving an array of complex technical challenges. 

One of the biggest challenges is that the hydrogen on the market today is considered to be “brown” rather than green, meaning that it is not a sustainably produced energy source.  Almost all hydrogen produced today comes from natural gas reforming, which results in carbon emissions.  A viable hydrogen-powered aviation technology assumes that producing hydrogen by splitting water molecules into oxygen and hydrogen using renewable energy becomes the standard source for it.

There have been test flights of small planes and drones powered by hydrogen, but Airbus expects that intensive research and development for the next five years will be required to evolve its current preliminary designs to a stage where they could be developed for future use in its product line.  It won’t happen overnight, but according to Airbus, hydrogen planes are coming.

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Airbus Hopes to Be Flying Hydrogen-Powered Jetliners With Zero Carbon Emissions by 2035

Photo, posted April 15, 2019, courtesy of Olivier Cabaret via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen-Powered Transport In Britain | Earth Wise

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The first hydrogen-powered train in the UK had its first mainline runs at the end of September.  The train, known as HydroFLEX, was developed under a project headed by the University of Birmingham under the UK government’s Department for Transport. 

Hydrogen-powered trains do not emit harmful gases but rather use hydrogen and oxygen to produce electricity, water, and heat.  The technology in the HydroFLEX train will be available by 2023 to retrofit existing diesel-powered trains and thereby de-carbonize the rail network and make train travel greener and more efficient.

The UK has ambitious plans for the use of hydrogen technology.  The Department of Transport plans to publish a master plan in January that will outline how green hydrogen could power buses, trucks, rail, maritime, and aviation transport across the UK.

The HydroFLEX trial is taking place in Tees Valley in northeastern England and the plan is for that area to become a Hydrogen Transport Hub that will include the world’s largest versatile hydrogen refueling facility.   The plans for Tees Valley involve academia, industry, and government participants.  The next stages of the HydroFLEX project are well underway with the University of Birmingham developing a hydrogen and battery-powered module that can be fitted underneath a train to allow for more space for passengers in train cars.

The UK government’s Hydrogen for Transport Program is also funding a green hydrogen refueling station and 19 hydrogen-powered garbage trucks in Glasgow, Scotland.

The UK plans to switch to a net zero economy and their current program increasingly embraces hydrogen technology to provide more sustainable, greener forms of transportation.

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UK embraces hydrogen-fueled future as transport hub and train announced

Photo, posted May 15, 2019, courtesy of Jeremy Segrott via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Fuel From Lignin | Earth Wise

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Lignin is an organic polymer that provides the rigid structure of plants and is what gives wood and bark their characteristic properties.  Lignin typically comprises between 20 and 35% of the mass of wood.  The two major substances extracted from trees, grasses, and other biomass materials are cellulose and lignin.  Cellulose is used to make paper, bioethanol, and other products, but lignin is largely unused because it is difficult to break down into useful substances such as feedstocks for fuels.  As a result, lignin is largely wasted.  Worldwide, some 50 million tons of lignin are produced from paper and bioethanol manufacturing each year and almost all of that is simply burned to generate heat.

Lignin can be broken down using pyrolysis techniques at high temperatures to create bio-oils, but those oils lack sufficient hydrogen and contain too much oxygen to be useful as fuels.  There is a process called hydrodeoxygenation that adds hydrogen and removes oxygen, but it requires high temperatures and very high pressures as well as producing char and tar that reduces the efficiency of the process.

Researchers at Georgia Tech recently published work describing a new process for turning lignin into useful products.  They developed a dual catalyst system of super-acid and platinum particles that adds hydrogen and removes oxygen from lignin bio-oil and makes it useful as a fuel and source of chemical feedstocks. 

The new process could help meet the growing demand for bio-based oils as well as helping the forest product, paper, and bioethanol industries by providing an additional revenue stream from what previously was a waste product.

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New Process Boosts Lignin Bio-oil as a Next-Generation Fuel

Photo, posted August 16, 2017, courtesy of evcabartakova via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Shrinking Ice In The Bering Sea | Earth Wise

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The Bering Sea forms the divide between the two largest landmasses on Earth:  Eurasia and the Americas.  Recent analysis of vegetation from a Bering Sea island has determined that the extent of sea ice in the region is the lowest it has been for over 5,000 years.

St. Matthew Island, a small island in the middle of the Bering Sea, has essentially been recording what is happening in the ocean and atmosphere around it, in the form of the composition of peat layers on the island.  By analyzing the chemical composition of peat core samples, scientists can estimate how sea ice in the region has changed over the course of time.

Changes in the relative amounts of two oxygen isotopes in the sediment and plant debris trapped in the peat on the island reflect the nature of precipitation during the period when the peat layers formed.  That ratio is correlated with the amount of sea ice in the region.  Satellite data acquired over the past 40 years confirms this correlation.

Analysis of the data shows that the current ice levels are unprecedented in the last 5,500 years.  These long-term findings affirm that reductions in Bering Sea ice are due to more than recent higher temperatures associated with global warming.  Atmospheric and ocean currents, which have also been altered by climate change, play a large role in the presence of sea ice.

Summertime sea ice in the Arctic was expected to reach its second-lowest extent in September in 40 years of observation.  Sea ice typically builds up again each winter, but the changes in ice extents actually lag behind changes in greenhouse gas level by decades.  Future ice loss is already built into the system.

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Bering Sea ice extent is at most reduced state in last 5,500 years

Photo, posted December 2, 2012, courtesy of Bering Land Bridge National Preserve via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Generating Hydrogen From Poor-Quality Water | Earth Wise

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Hydrogen could be the basis of a complete energy system.  It could be stored and transported and could be used to power vehicles and to generate electricity in power plants.  Proponents of the so-called hydrogen economy contend that hydrogen is the best solution to the global energy challenge.  But among the challenges faced by a hydrogen economy is the development of an efficient and green method to produce hydrogen.

The primary carbon-free method of producing hydrogen is to break down water into its constituent elements – hydrogen and oxygen.  This can be done in a number of ways, notably by using electricity in a process called electrolysis.  A method that seems particularly attractive is to use sunlight as the energy source that breaks down the water molecule.

While there is an abundance of water on our planet, only some of it is suitable for people to drink and consume in other ways.    Much of the accessible water on earth is salty or polluted.  So, a technique to obtain hydrogen from water ideally should work with water that is otherwise of little use to people.

Researchers in Russia and the Czech Republic have recently developed a new material that efficiently generates hydrogen molecules by exposing water – even saltwater or polluted water – to sunlight. 

The new material is a three-layer structure composed of a thin film of gold, an ultra-thin layer of platinum, and a metal-organic framework or MOF of chromium compounds and organic molecules.  The MOF layer acts as a filter that gets rid of impurities.

Experiments have demonstrated that 100 square centimeters of the material can generate half a liter of hydrogen in an hour.  The researchers continue to improve the material and increase its efficiency over a broad range of the solar spectrum.

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New Material Can Generate Hydrogen from Salt and Polluted Water

Photo courtesy of Tomsk Polytechnic University.

Earth Wise is a production of WAMC Northeast Public Radio.

The Dead Zone In The Gulf Of Mexico | Earth Wise

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The Gulf of Mexico has an area of low to no oxygen in the water that can kill fish and other marine life.  It is an annual event that is primarily caused by excess nutrient pollution from human activities in urban and agricultural areas throughout the Mississippi River watershed.   When these excess nutrients reach the Gulf, they stimulate the overgrowth of algae, which eventually die and decompose, depleting the oxygen in the water as the algae sink to the bottom.

These low oxygen levels near the bottom of the Gulf cannot support most marine life.  Some species – among them many fish, shrimp, and crabs – swim out of the area, but animals that can’t swim or move away are stressed or killed by the low oxygen.  The dead zone in the Gulf occurs every summer.

A recent forecast for this summer’s dead zone predicts that the area of low or no oxygen will be approximate 6,700 square miles, which is roughly the size of Connecticut and Delaware combined.  This is about 1,100 square miles smaller than last year’s dead zone and much less than the record of 8,776 square miles set in 2017.  But it is still larger than the long-term average size of 5,387 square miles.

Making comparisons to the long-term average ignores the fact that the long-term average itself is unacceptable.  The dead zone not only hurts marine life, but it also harms commercial and recreational fisheries and the communities they support.  The actions that have been taken so far to reduce pollution in the Mississippi watershed are clearly not sufficient to drastically reduce the dead zone in the Gulf.

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Large ‘dead zone’ expected for Gulf of Mexico

Photo, posted October 17, 2017, courtesy of NOAA’s National Ocean Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Microplastic Hotspots In The Ocean | Earth Wise

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Many of us are aware of the infamous ocean “garbage patches” of floating plastic.  The Great Pacific Garbage Patch is roughly the size of Texas.  But over 10 million tons of plastic waste enter the oceans each year and the floating patches only account for 1% of that total.  The remaining 99% of the plastic ends up in the deep ocean, generally in the form of microplastics – tiny fragments of large plastic debris that have broken down as well as manufactured polyethylene beads used in various products.

According to a new study published in the journal Science, there are actually microplastic hotspots on the ocean floor, formed by deep-sea currents that act as conveyer belts moving the tiny plastic fragments around.  One of these hotspots – in the Tyrrhenian Sea off the west coast of Italy – contained 1.9 million microplastic pieces in just one square meter of seafloor.  This is the highest reported value for any place in the world.

Because of their small size, microplastics can be ingested by organisms across all levels of the marine food chain and eventually find their way into human diets. 

The spatial distribution and ultimate fate of ocean microplastics are strongly controlled by near-bed thermohaline currents.  These are deep-ocean currents driven by differences in water density, which is controlled by temperature and salinity.  Thermohaline currents are known to supply oxygen and nutrients to the flora and fauna found at the ocean bottom.  As a result, deep sea biodiversity hotspots are likely to be in same places where there are microplastic hotspots.

The discovery of these deep- sea hotspots is just another reason why we need behavior and policy interventions to limit the flow of plastics into natural environments.

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Seafloor microplastic hotspots controlled by deep-sea circulation

Photo, posted September 6, 2012, courtesy of Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Road Salt Pollution

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Mirror Lake is a popular recreational lake located in the Village of Lake Placid.  It is the most developed lake within the Adirondack Park, which is a publicly protected area that is actually larger than Yellowstone, Yosemite, Glacier, and Grand Canyon National Parks combined.

New research has revealed that road salt runoff into Mirror Lake is preventing natural water turnover which poses a risk to the balance of its ecology.  The study, which was published in Lake and Reservoir Management, found that road salt runoff is preventing spring mixing of the water column.    This creates more anoxic water conditions, meaning there is less oxygen in the water, and limits the ability of the habitat to support the native lake trout. 

Mirror Lake is the first lake in the Adirondack Park to show an interruption in lake turnover due to road salt.  Many lakes in northern climes experience so-called “dimictic turnover”, which is a natural process where wind and less stratified water conditions of spring and fall allow mixing of the water column that redistribute oxygen and nutrients throughout the lake.  High levels of surface-water chloride introduced into the lake from road salt runoff inhibit the mixing of the water column.

The lack of mixing and oxygenation is bad news for fish species such as lake trout, which require cold, oxygenated water to survive.  It may also put the lake at a greater risk of algal blooms.

Mirror Lake is small, surrounded by concentrated development, and receives the direct discharge of stormwater.  So, it is particularly vulnerable to road salt contamination.  Other lakes elsewhere in New York may experience similar conditions.  The researchers are confident that natural turnover conditions could be restored to the lake if road salt application in the watershed is reduced.

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Road salt pollutes lake in one of the largest US protected areas, new study shows

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Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From The Ocean

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Hydrogen is frequently touted as an excellent source of clean energy that could be used as a fuel in vehicles, or as a storage medium for energy generated by wind and solar power.  The challenge is that hydrogen is rather difficult and expensive to attain, and the most economical methods are not clean and green.

Most industrial hydrogen is produced by reforming natural gas, which has the drawback that carbon dioxide is generated in the process.  The environmentally friendly way to produce hydrogen is via electrolysis, in which a chemical reaction is triggered by a catalyst enabling electricity to split water into its constituent elements of oxygen and hydrogen.

The best performing catalyst for electrolysis is platinum, but its high price is a big drawback for the economics of making hydrogen.  Researchers at the Pacific Northwest National Laboratory have found a pairing of minerals that may solve the problem.  Testing a molybdenum-phosphide catalyst with wastewater in a small reactor called a microbial electrolysis cell revealed that the new catalyst actually worked better than platinum.

Even better, the molybdenum-phosphide catalyst worked well with seawater.  If hydrogen can be produced using seawater, there would be a pretty much unlimited resource for making it.  By eliminating the use of platinum catalysts, it may be possible to reduce the cost of hydrogen made by electrolysis to a competitive level.

Hydrogen as a vehicle fuel currently costs about twice as much as gasoline on an energy-equivalent basis.  Given that running cars from batteries is considerably cheaper than using gas, the cost of hydrogen needs to come down considerably for it to be a viable vehicle fuel.

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Ditching Platinum for the Ocean Could Make Hydrogen Cheap

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Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)