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Rare Earths And The Energy Transition | Earth Wise

May 19, 2023 By EarthWise Leave a Comment

Limiting the rise in global temperature to no more than 1.5 degrees Celsius requires decarbonization. This means slashing fossil fuel use, switching to renewable energy sources, and electrifying as many sectors of the economy as possible. Doing these things requires huge numbers of wind turbines, solar panels, electric vehicles, and storage batteries. All of them use rare earth elements and other critical metals.

The 17 rare earth elements are actually common, but they are called rare because they are seldom found in sufficient quantities to be extracted easily or economically.

China once supplied 97% of the world’s rare earth elements as a result of government support, cheap labor, lax environmental regulations, and low prices. Once the world started to realize the dangers of being so dependent on China, many countries began developing their own rare earth element production. (However, today China still produces 60-70% of the world’s rare earth elements).

It is difficult to mine rare earth elements without causing environmental damage. The prevalent extraction techniques involve toxic chemicals that can leach into the environment and, because rare earths are often found near radioactive elements, mining often brings dangerous radioactive waste into the environment.

Researchers are working on ways to make rare earth mining more sustainable. Some of these include biomining – which uses microbes to extract rare earths from ores, electrical methods to free rare earths from ores, and so-called agromining, which is growing plants that hyperaccumulate rare earths from the soil into their tissues.

Making rare earth mining more sustainable and less harmful to the environment is an essential part of the world’s future.

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The Energy Transition Will Need More Rare Earth Elements. Can We Secure Them Sustainably?

Photo, posted November 18, 2008, courtesy of the Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Better Zinc Batteries | Earth Wise

May 17, 2023 By EarthWise Leave a Comment

The rapid growth of wind and solar power continues to drive a global quest for new battery technologies that can be used to store the energy generated by these sources when the sun isn’t shining, and the wind isn’t blowing.

For the most part, current battery energy storage systems use lithium-ion batteries – the same sort of batteries found in cellphones and electric vehicles. There are many other battery chemistries, but they mostly have shortcomings in performance, economy, or longevity.

Batteries store electricity in the form of chemical energy and chemical reactions convert that energy into electrical energy. Every battery has two electrodes: the anode, from which electrons flow into external circuits, and the cathode, which receives electrons from the external circuit. The electrolyte is the chemical medium through which the electrons flow.

One technology that has great potential is zinc-based batteries. Zinc itself is a metal that is safe and abundant. Batteries based on it are energy dense. However, zinc batteries have faced the challenge of having a short cycle life. The batteries end up plating zinc on their anodes and battery performance degrades.

A team of researchers at Oregon State University and three other universities have recently developed a new electrolyte for zinc batteries that raises the efficiency of the zinc metal anode to nearly 100% – actually slightly better than lithium-ion batteries.

Zinc batteries have a number of potential advantages over lithium-ion. The new hybrid electrolyte developed by the researchers is non-flammable, cost-effective, and has low environmental impact. Lithium-ion batteries rely on the supplies of relatively rare metals that are often difficult and environmentally harmful to obtain.

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Researchers develop electrolyte enabling high efficiency of safe, sustainable zinc batteries

Photo, posted May 13, 2017, courtesy of Jeanne Menjoulet via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fuel From Coffee Grounds | Earth Wise

December 8, 2022 By EarthWise Leave a Comment

The world drinks a lot of coffee. Americans alone consume 400 million cups a day. Each cup of coffee results in about half an ounce of coffee grounds. Adding that up, this country produces over 6,000 tons of coffee grounds each day. While coffee grounds are not particularly harmful, that is an awful lot of waste that mostly ends up in landfills or is incinerated.

Researchers at Aston University in the UK have developed a method of producing high-quality biodiesel fuel from coffee grounds. Their study was published in the journal Renewable and Sustainable Energy Reviews.

The technique consists of growing a particular species of microalgae (Chlorella vulgaris) directly on spent coffee grounds. The coffee grounds provide both the nutrients for the microalgae and a structure upon which it can grow. Exposing the algae to light for 20 hours a day and dark for just four hours a day produced the best quality biodiesel.

Microalgae is well-known as a feedstock for biodiesel production. Previously, it has been grown on materials like polyurethane foam or nylon which don’t provide any nutrients. Using the coffee grounds as the substrate for growth means that no external nutrients are needed.

The resultant enhanced biodiesel produces minimal emissions and good engine performance and meets both US and European specifications. This feedstock for producing biodiesel is ideal since it doesn’t require any competition with food crops and instead makes use of a widely available waste product. The hope is that it may reduce the cutting down of palm trees to extract oil for biofuel. In southeast Asia, this has been a major source of deforestation and increased greenhouse gas emissions.

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Aston University researchers ‘feed’ leftover coffee grounds to microalgae to produce low emission biodiesel

Photo, posted October 13, 2007, courtesy of David Joyce via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cleaning Up Forever Chemicals | Earth Wise

August 29, 2022 By EarthWise Leave a Comment

PFAS, per- and polyfluoroalkyl substances, are chemical pollutants that threaten human health and ecosystem sustainability. They are used in a wide range of applications including food wrappers and packaging, dental floss, firefighting foam, nonstick cookware, textiles, and electronics. Over decades, these manufactured chemicals have leached into our soil, air, and water. Chemical bonds in PFAS molecules are some of the strongest known, so the substances do not degrade easily in the environment.

Studies have shown that at certain levels, PFAS chemicals can be harmful to humans and wildlife and have been associated with a wide variety of health problems.

Currently, the primary way to dispose of PFAS chemicals is to burn them, which is an expensive multistep process. Even trace levels are toxic, so when they occur in water in low amounts, they need to be concentrated in order to be destroyed.

Researchers at Texas A&M University have developed a novel bioremediation technology for cleaning up PFAS. It uses a plant-derived material to absorb the PFAS which is then eliminated by microbial fungi that literally eat the forever chemicals.

The sustainable plant material serves as a framework to adsorb the PFAS. That material containing the adsorbed PFAS serves as food for the fungus. Once the fungus has eaten it, the PFAS is gone.

The EPA has established a nationwide program to monitor the occurrence and levels of PFAS in public water systems and is considering adding PFAS threshold levels to drinking water standards. If this happens, the technology developed at Texas A&M may become an essential part of municipal water systems.

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Texas A&M AgriLife develops new bioremediation material to clean up ‘forever chemicals’

Photo, posted August 10, 2013, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Lake Tuz Is Disappearing | Earth Wise

January 10, 2022 By EarthWise Leave a Comment

Lake Tuz is Turkey’s second-largest lake and one of the world’s largest hypersaline lakes. Its high salt content makes it an ideal breeding ground for some migratory bird species, including flamingos, which are often present there in huge numbers in the spring and summer.

Now, Lake Tuz rarely spans an area much larger than a puddle. In some summers, it completely dries up. It did so this past summer, which resulted in the deaths of thousands of flamingos.

According to experts, Lake Tuz is a victim of climate change-induced drought, which has hit the region hard, and decades of harmful agricultural policies that exhausted the underground water supply.

Water in this region has become increasingly scarce. The Mediterranean Basin has already seen more frequent and intense droughts, and is considered a climate change hotspot.

According to new research, which was recently published in the journal Regional Environmental Change, Lake Tuz generally contained enough water in August for the lake to be considered permanent up until 2000. But between 2001 and 2016, something shifted. Water spanned less than 20% of the lake in every August except for one, and droughts became more frequent and intense. And in some years, the lake completely dried up.

What caused this change? According to the research team, Lake Tuz’s decline coincided with the excessive use of groundwater and surface water resources responsible for feeding the lake. Some streams were rerouted for agricultural purposes, while others were dammed. And when surface water sources dwindled, people turned to groundwater that historically fed the springs in Lake Tuz.

Lake Tuz may be on the brink of extinction.

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Impact of climate variability on the surface of Lake Tuz (Turkey), 1985–2016

Disappearing Lake Tuz

Photo, posted August 16, 2021, courtesy of Godot via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing COVID-19 Spread With UV Light | Earth Wise

November 24, 2021 By EarthWise 1 Comment

New research published by the University of Colorado Boulder analyzes the effects of different wavelengths of ultraviolet light on the SARS-CoV-2 virus. The research found that a specific wavelength of UV light is not only extremely effective at killing the virus that causes COVID-19, but also that this wavelength is safer for use in public spaces.

UV light is naturally emitted by the sun and most forms of it are harmful to living things – including microorganisms and viruses. The most harmful UV radiation from the sun is filtered out by the atmosphere’s ozone layer. Human-engineered UV light sources screen out harmful UV rays with a phosphorus coating on the inside of the tube lamps. Hospitals and some other public spaces already use UV light technology to disinfect surfaces when people are not present.

The new research found that a specific wavelength of far-ultraviolet-C, at 222 nanometers, was particularly effective at killing SARS-CoV-2, but that wavelength is blocked by the very top layers of human skin and eyes. In other words, that light has essentially no detrimental health effects for people while it is very capable of killing off viruses.

The researchers argue that this safe wavelength of Far UV-C light could serve as a key mitigation measure against the COVID-19 pandemic. They imagine systems that could cycle on and off in indoor spaces to routinely clean the air and surfaces or perhaps create an ongoing, invisible barrier between teachers and students, customers and service workers, and other places where social distancing is not practical. Installing these specialized UV lights would be much cheaper than upgrading entire HVAC systems in buildings.

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Specific UV light wavelength could offer low-cost, safe way to curb COVID-19 spread

Photo, posted January 18, 2008, courtesy of Phil Whitehouse via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Tracking Ocean Plastics | Earth Wise

July 30, 2021 By EarthWise Leave a Comment

Plastic pollution in the oceans is a major problem. An estimated 8 million tons of plastic trash enters the ocean every year. Most of it is broken up by sun and waves into microplastics, which are tiny bits that ride currents for hundreds or thousands of miles. All of this debris is harmful to marine ecosystems, and it is both challenging to track and very difficult to clean up.

University of Michigan researchers have developed a new technique for spotting and tracking ocean microplastics across the globe. The approach relies on the Cyclone Global Navigation Satellite System, or CYGNSS, which is a constellation of eight microsatellites launched in 2016 to monitor weather near large storm systems. It turns out that the radar systems on CYGNSS that measure surface roughness to calculate the wind speed near the eyes of hurricanes can also be used to detect the presence of microplastics.

With the satellite measurements, the researchers have found that global microplastic concentrations tend to vary by season, peaking during the summer months. For example, June and July are the peak months for the Great Pacific Garbage Patch. The data also showed spikes in microplastic concentration at the mouth of China’s Yangtze River, long suspected to be a chief source of plastic pollution. The researchers produced visualizations that show microplastic concentrations around the world.

The information provided by the new technique could help organizations that clean up microplastics to deploy ships and other resources more efficiently. Data of single-point release of plastics, such as from rivers, may also be useful to UNESCO, which has sponsored a task force to find new ways to track the release of microplastics into the world’s waters.

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Ocean microplastics: First global view shows seasonal changes and sources

Photo, posted April 3, 2018, courtesy of Rey Perezoso via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The World’s Largest Harmful Algal Bloom | Earth Wise

July 1, 2021 By EarthWise Leave a Comment

Brown sargassum seaweed floats in surface water in a bloom that stretches all the way from West Africa to the Gulf of Mexico. Sargassum provides habitat for turtles, crabs, fish, and birds.

The stuff carpets beaches along the tropical Atlantic, the Caribbean Sea, the Gulf of Mexico, and the east coast of Florida disrupting tourism. Florida’s Miami-Dade County alone spends $45 million a year cleaning up sargassum. Annual Caribbean clean-up is in excess of $120 million.

A study by Florida Atlantic University has discovered dramatic changes in the chemistry and composition of sargassum which has transformed the so-called Great Atlantic Sargassum Belt into a toxic dead zone.

The findings of the study suggest that increased nitrogen availability from both natural and human-generated sources, including sewage, is supporting blooms of sargassum and turning a critical marine nursery habitat into harmful algal blooms with catastrophic impacts on coastal ecosystems, economies, and human health.

The study found that today’s sargassum tissues compared with those of the 1980s have 35% more nitrogen content and 42% less phosphorus. Much of the nitrogen increase is a result of agricultural and industrial runoff from the Congo, Amazon, and Mississippi Rivers.

The fact that the bloom itself has expanded so tremendously was already suspected to be the result of significant changes in the ocean’s chemistry. Given the negative effect that the Great Atlantic Sargassum Belt is having on the coastal communities, additional research is essential to guide mitigation and adaptation efforts.

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Sargassum now world’s largest harmful algal bloom due to nitrogen

Photo, posted June 5, 2016, courtesy of J Brew via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Mealworms And Plastic | Earth Wise

January 21, 2020 By EarthWise Leave a Comment

Mealworms are widely cultivated beetle larvae that people feed to pets and to wild birds. But it turns out, they may have an even more valuable purpose: they can eat plastic and even plastic containing dangerous chemical additives.

Four years ago, researchers at Stanford discovered that mealworms can actually subsist on a diet of various types of plastic. They found that microorganisms in the worms’ guts actually biodegrade the plastic. It might be possible to cultivate the worms using unrecyclable plastic, rather than feeding them grains and fruits. However, there is the issue of whether it would be safe to feed the plastic-eating worms to other animals, given the possibility that harmful chemicals in plastic additives might accumulate in the worms over time.

Recently, the Stanford researchers studied what happens when the worms ingested Styrofoam or polystyrene. The plastic commonly used for packaging and insulation typically contains a flame retardant called hexabromocyclododecane, or HBCD. Studies have shown that HBCD can have significant health and environmental impacts, ranging from endocrine disruption to neurotoxicity.

According to the study, mealworms in the experiment excreted about half of the polystyrene they consumed as tiny, partially degraded fragments and the other half as carbon dioxide. With it, they excreted the HBCD. Mealworms fed a steady diet of HBCD-laden polystyrene were as healthy as those eating a normal diet. And shrimp fed a steady diet of the HBCD-ingesting mealworms also had no ill effects.

It is true that the HBCD excreted by the worms still poses a hazard and must be dealt with in some manner, but mealworms may have a role to play in dealing with unrecyclable plastics like Styrofoam.

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Stanford researchers show that mealworms can safely consume toxic additive-containing plastic

Photo, posted May 11, 2015, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Trash Into Treasure

December 12, 2019 By EarthWise Leave a Comment

Every year, 380 million tons of plastic are created worldwide, and that number continues to grow. Furthermore, more than 75% of these materials are discarded after one use. Much of it ends up in oceans and waterways, harming wildlife and spreading toxins.

Recycling most plastics is difficult because while they can be melted and reprocessed, the resultant material is not as structurally strong as the original material. Thus, plastics are often down-cycled such as turning plastic bottles into molded park benches.

Researchers at Northwestern University, Argonne National Laboratory, and Ames Laboratory have developed a new method for upcycling abundant, seemingly low-value plastics into high-quality liquid products, such as motor oils, lubricants, detergents, and even cosmetics. The catalytic method could remove plastic pollution from the environment and contribute to a circular economy.

Plastics don’t degrade when disposed of because they have very strong carbon-carbon bonds. Instead they just break into smaller bits, known as microplastics. The researchers viewed these strong bonds as an opportunity rather than a problem.

The new technique actually recoups the high energy that holds these bonds together by catalytically converting polyethylene molecules into value-added commercial products. The catalyst consists of platinum nanoparticles deposited onto perovskite nanocubes. Under moderate pressure and temperature, the catalyst cleaves the carbon-carbon bonds in plastic to produce high-quality liquid hydrocarbons.

The researchers believe these findings could lead to a future in which we can continue to benefit from plastic materials but do so in a way that is sustainable and less harmful to the environment.

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Turning plastic trash into treasure

Photo, posted August 15, 2012, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

China And Rare Earth Mining

September 4, 2019 By EarthWise Leave a Comment

Rare earth elements are a crucial part of much of modern technology. Everything from computers to X-ray machines and aircraft engines needs one or more rare earth elements for magnets, lenses, and other functions. The world’s tech giants such as Apple, Huawei, and Tesla depend on suppliers of rare earths.

Rare earth elements are not actually rare, but they are very expensive to extract in ways that are not extremely harmful to the environment. China has been a major source of these elements since its rare earth mining industry took off in the 1990s. The removal of rare earths from the earth’s crust, using a mix of water and chemicals, has caused extensive water and soil pollution.

Today, concrete leaching ponds and plastic-lined wastewater pools dot the hills of Southeast China. Large wastewater ponds sit uncovered and open to the elements in many places. Landslides or barrier failures can spill contaminated contents into waterways or groundwater.

Local and federal officials in China have started to shut down illegal and small-scale rare earth mining operations and have embarked on a cleanup of polluted sites. The rare earth mining cleanup operation is part of wider efforts across China to address severe problems of water, air and soil pollution.

China’s Ministry of Industry and Information Technology estimated that the cleanup bill for southern Jiangxi Province could amount to more than $5 billion. Many environmental experts and local officials say that the cost of the cleanup should not be shouldered by the Chinese government alone, but also by the rare earth industry and the global companies and consumers that benefit from rare earth technology. As rare earth mining efforts start up elsewhere around the world, it is important not to repeat the mistakes made in China.

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China Wrestles with the Toxic Aftermath of Rare Earth Mining

Photo, posted April 21, 2019, courtesy of John Beans via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Coal To Fight Climate Change

April 19, 2019 By EarthWise Leave a Comment

Coal is the most harmful fossil fuel for the environment and, furthermore, for human health. Its use has stubbornly persisted because it is so plentiful and, therefore, cheap. As a result, a big part of efforts to fight climate change is finding a way to remove the carbon dioxide dumped into the atmosphere by the combustion of coal.

Researchers at the Royal Melbourne Institute of Technology in Australia have developed a remarkable technology that in effect reverses the process that has led to soaring CO2 levels in the atmosphere. They have found a way to pull carbon dioxide from the atmosphere and turn it into coal, after which it can be stored cheaply and safely underground.

Most previous carbon capture and storage technologies have focused on compressing carbon dioxide gas into a liquid form and then pumping it into rock formations. Such techniques are rather expensive, require lots of energy, and pose risks that the liquid CO2 could escape from its underground storage sites. More recently, research on solid metal catalysts has led to the possibility of turning CO2 into solid carbon, but most of these reactions require very high temperatures and use a lot of energy.

The new technique developed at RMIT uses a new class of catalysts based on metal alloys. With a small jolt of electricity applied at room temperature, CO2 can be converted into solid carbon – basically, coal.

If this technique can be industrialized economically, it would be like turning back the clock by taking carbon dioxide that entered the atmosphere by the combustion of coal and turning it back into coal and putting it back underground. It seems like excellent environmental justice.

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