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green hydrogen

Soda can hydrogen

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Hydrogen is an ideal climate-friendly fuel because it doesn’t release carbon dioxide when it is used.  But most hydrogen is produced in ways that result in significant carbon emissions. Thus, the search for green hydrogen goes on. 

Last year, engineers at MIT developed a new process for making hydrogen that significantly reduces the carbon footprint of its production.  The recipe uses seawater and recycled soda cans. 

Pure aluminum reacts with water, breaking up the water molecules to produce aluminum oxide and pure hydrogen.  But when aluminum is exposed to oxygen, it forms a shield-like layer that prevents the reaction.

The MIT researchers found that the shield can be removed by treating aluminum with a small amount of gallium-indium alloy.  Mixing the pure aluminum with seawater not only produces hydrogen, but the salt in the seawater precipitates out the gallium-indium, making it available for reuse.

The research team carried out a “cradle-to-grave” life cycle assessment of the process, taking into account every step in using the hydrogen-production process at an industrial scale.  They found that using recycled aluminum – chopped-up soda cans – is environmentally and economically superior to using “primary” aluminum, mined from the earth. The cans would be shredded into pellet and treated with the gallium-indium alloy.  The pellets would be processed near a source of seawater where they would be combined to generate hydrogen on demand.

According to their analysis, the hydrogen produced would be at least competitive economically and environmentally with other potential methods of producing green hydrogen.

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Study shows making hydrogen with soda cans and seawater is scalable and sustainable

Photo, posted July 29, 2020, courtesy of Bruce Dupree via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Hydrogen-powered aviation

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The transportation sector is responsible for about a quarter of human-generated greenhouse gas emissions.  Most of the energy used by transport systems comes from fossil fuels.  The transition to electric vehicles – cars, trucks, and buses – is making a real difference.  However, the emissions from the aviation industry have continued to grow faster than those of other forms of transportation.  There have been increased efforts to develop hydrogen-powered aircraft, but the challenges are substantial.

Hydrogen can be used for aviation both as a directly combusted fuel, or to power electric fuel cells.  Its advantages are that its use produces no carbon dioxide, and, in fact, hydrogen produces more energy per pound than jet fuel.

A study by researchers at MIT looked at the prospects for hydrogen use in aircraft and what needs to be done to make it practical.  The biggest issue is that the extra bulk of a hydrogen fuel tank and fuel cells in a plane would have to be offset by weight reductions elsewhere, such as reducing payload (cargo or passengers).  This would mean there would need to be more flights, thereby reducing the gains made.  The researchers argued that improvements in fuel cell power and more weight efficient fuel systems could eliminate the need for additional flights.

The bigger challenge is the infrastructure for generating and distributing hydrogen.  There needs to be green hydrogen – hydrogen produced without carbon emissions – and the infrastructure for getting it to planes where it is needed has to also not produce substantial emissions.

The study suggests that the rollout of hydrogen-based aviation should start at locations that have favorable conditions for hydrogen production.

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Fueling greener aviation with hydrogen

Photo, posted December 20, 2016, courtesy of Dylan Agbagni via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A better way to produce green hydrogen

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Hydrogen has great potential as a fuel and an energy carrier for many applications.  Burning it or consuming it in fuel cells does not produce carbon emissions.  As a result, there has long been the vision for a future hydrogen economy.  Whether the hydrogen economy would ever come about given how various other technologies have evolved over time is questionable.  But regardless, hydrogen is valuable for many industrial and commercial applications including the manufacture of ammonia and the refining of metals.

Hydrogen is produced in industrial quantities from natural gas by a carbon-dioxide-producing process known as methane-steam reforming.  To take its place as a green energy source, hydrogen needs to be produced by splitting water into its constituent oxygen and hydrogen components by the process of electrolysis. 

The problem is economic.  Methane-steam reforming produces hydrogen at a cost of about $1.50 per kilogram.  Green hydrogen costs about $5 a kilogram.

Researchers at Oregon State University have developed a new photocatalyst that enables the high-speed, high-efficiency production of hydrogen.  The material, called RTTA, is a metal organic framework containing ruthenium oxide and titanium oxide.  Ruthenium oxide is expensive, but very little is needed.  For industrial applications, if the catalyst shows good stability and reproducibility, the cost of the small amount of this exotic material becomes less important.

The photocatalyst, when exposed to sunlight, quickly and efficiently splits water yielding hydrogen.  The Oregon State discovery has real potential.

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Oregon State University research uncovers better way to produce green hydrogen

Photo, posted July 7, 2023, courtesy of Bill Abbott via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Natural hydrogen

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Hydrogen is considered to be a potential substitute for conventional fossil fuels in applications where electricity cannot easily be used such as in blast furnaces, cement works, industrial heating, long-distance aviation, and shipping.  But most hydrogen is manufactured by separating it from methane, which is energy-intensive and produces carbon dioxide.  So-called green hydrogen is made by splitting water using electricity.  It is a carbon-free process if the electricity is from renewable sources, but it is pretty expensive.

A small community in Mali gets its electricity by burning natural hydrogen, which bubbles up from underground into a village well.  It has long been known that processes in the Earth’s crust can make hydrogen gas from water under certain circumstances.  But conventional wisdom has been that this occurrence is rare and that the hydrogen produced is either inaccessible or seeps away.

An increasing number of geoscientists now are convinced that there is actually an enormous quantity of hydrogen beneath the planet’s surface and that we just haven’t been looking for it in the right places, or at all, for that matter.  Some say that there could be trillions of tons of hydrogen, and more is being generated all the time.

Prospectors have recently been drilling for hydrogen in France, Australia, Morocco, Brazil, and in the United States, in Nebraska, Arizona, and Kansas.  Will extracting natural hydrogen be practical at the scale required and will it be economical?  The jury is still out on all of this, but if it turns out as proponents claim, natural hydrogen could be a very big deal.

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Natural Hydrogen: A Potential Clean Energy Source Beneath Our Feet

Photo, posted November 4, 2012, courtesy of Heather Paul via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Sustainable hydrogen from methane

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Hydrogen could serve as a viable alternative to fossil fuels that can be used directly as a fuel or can be used to generate electricity to power cars and other devices. However, large-scale production of hydrogen currently relies on fossil fuels and creates carbon emissions in the process.

So-called green hydrogen involves using electricity to split water into its component elements to produce it.  If the electricity is generated without emissions, then the hydrogen is truly green.

Another way to get hydrogen is by breaking down hydrocarbons like methane, which itself is a very powerful greenhouse gas.  This so-called blue hydrogen could be environmentally friendly if an appropriate method for producing it can be developed.

Existing techniques for converting methane into hydrogen involve the use of metal catalysts – often nickel – that are energy-intensive to mine and manufacture, and can negatively affect the environment.  Research at the University of Surrey in the UK has shown promising results for the use of nitrogen-doped nanocarbons as metal-free catalysts for the direct conversion of methane into hydrogen.  One of the biggest problems with using metal catalysts for hydrogen production is that they get poisoned by carbon.  The carbon that comes out of the methane ends up stopping the catalyst from continuing to do its chemical job.  It turns out that the doped nanocarbon approach to hydrogen catalysis appears to be resistant to this problem.

The development of sustainable hydrogen production methods, including efficient and sustainable electrolysis of water as well as catalysis of hydrocarbons like methane, is crucial to realizing the potential of hydrogen fuel as a clean energy source.

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‘Game-changing’ findings for sustainable hydrogen production

Photo, posted April 30, 2021, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Solar thermochemical hydrogen

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For decades, there has been talk of the hydrogen economy in which hydrogen would take the place of fossil fuels in a wide range of domestic and industrial applications.  Over time, hydrogen’s potential advantages in some applications have diminished but it is still seen as perhaps the most promising way to decarbonize long-distance truck, ship, and plane transportation as well as many heavy-duty industrial processes.

Hydrogen is the most common element in the universe, but here on Earth, it is tightly bound up in chemical compounds, notably water and hydrocarbons.  Extracting hydrogen from these compounds takes lots of energy.  To date, most hydrogen is produced from fossil fuel sources, resulting in carbon dioxide emissions.  So-called green hydrogen is made by splitting up water into its component elements.

Getting hydrogen from water generally uses electrolysis, which requires lots of electrical power.  That is why it isn’t the standard way to produce hydrogen; it costs too much to pay for all that power.

MIT scientists have been developing a process to make solar thermochemical hydrogen, or STCH.  STCH uses the sun’s heat to split apart water and no other energy source.  An existing source of solar heat drives a thermochemical reaction in which a heated metal surface grabs oxygen from steam and leaves hydrogen behind.  MIT did not invent the concept; their efforts are to make it practical.

Previous STCH designs were only capable of using 7% of incoming solar heat to make hydrogen.  The MIT process may be able to harness up to 40% of the sun’s heat and therefore generate far more hydrogen. 

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MIT design would harness 40 percent of the sun’s heat to produce clean hydrogen fuel

Photo, posted August 23, 2017, courtesy of Evan Lovely via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Geologic Hydrogen | Earth Wise

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There is great interest in the potential use of hydrogen as a fuel or an energy storage medium.  Unlike hydrocarbon-based fuels, pure hydrogen combustion produces nothing but water as an emission.  But most hydrogen used at present is made by reforming natural gas, which is a process that results in carbon dioxide emissions.  Thus, the search goes on for cost-effective and energy-efficient ways to make “green hydrogen” that doesn’t result in greenhouse gas emissions.

Researchers at Colorado University Boulder are investigating the potential effectiveness of coaxing hydrogen from subterranean rocks – a commodity known as geologic hydrogen.

When water mixes with iron-rich minerals deep in the earth’s crust, ensuing chemical reactions can generate pockets of hydrogen gas. 

The questions are whether it is possible to bring these deposits up to the surface without harming the environment or human communities in the process and whether they can be extracted in large enough quantities to meet growing global energy demands.

The Colorado researchers will conduct experiments both in the lab and hundreds of meters below the earth’s surface to see if it is possible to induce the subterranean rock to make more hydrogen than it normally does.  If the hydrogen-producing reactions can be accelerated, then geologic hydrogen could become a clean and abundant energy source.

Geologists have known about hidden underground deposits of hydrogen for a long time, but recent research has found that there may be a lot more of it than once thought.  According to a 2022 report by the US Geological Survey, there may be enough hydrogen below ground to supply humanity’s need for fuel for hundreds of years.

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Can rocks produce abundant clean energy? New project to explore

Photo, posted December 26, 2013, courtesy of Juozas Šalna via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Hydrogen And The Methane Problem | Earth Wise

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Theoretically, hydrogen could be the fuel of the future.  It is the most common element in the universe and its combustion produces no harmful emissions.  Most industrial hydrogen comes from a process called steam reforming that extracts it from natural gas – basically methane.  Carbon dioxide is a byproduct of the process.   But it is also possible to get hydrogen by breaking down water resulting only in oxygen as a byproduct.   There is a great deal of ongoing development of so-called green hydrogen.

New research from Princeton University and the National Oceanic and Atmospheric Administration has uncovered a potential problem associated with the use of hydrogen as a clean fuel. 

There is a molecule in the atmosphere called the hydroxyl radical.  It is known as “the detergent of the troposphere”.  It plays a critical role in eliminating greenhouse gases such as methane and ozone from the atmosphere.  It turns out that the hydroxyl radical also reacts with any hydrogen gas in the atmosphere and there is only so much hydroxyl to go around.  If large amounts of hydrogen were to enter the atmosphere, much of the hydroxyl radical would be used up reacting with it and there would be much less available to break down methane.  As a result, there would end up being more methane in the atmosphere, and methane is a powerful greenhouse gas.

The bottom line is that there would need to be proactive efforts to limit the amount of hydrogen getting into the atmosphere whether from producing it, transporting it, or anyplace else in the value chain.  Otherwise, the hydrogen economy would cancel out many of the climate benefits of eliminating fossil fuels.

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Switching to hydrogen fuel could prolong the methane problem

Photo, posted June 12, 2021, courtesy of Clean Air Task Force via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fuel From Wind And Water | Earth Wise

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Hydrogen is the most common element in the universe and it can be used as a fuel to run cars, trains, and even airplanes.  Using it produces no harmful emissions.  However, to date, the way it is economically produced is not clean and green.  It is made from natural gas and leaves behind lots of carbon dioxide.

Around the world there are many projects working on so-called green hydrogen.  Producing hydrogen by splitting water into its component elements is called electrolysis and produces only oxygen as a waste product.  The problem with electrolysis is that it takes prodigious amounts of energy and therefore is very expensive.

A new project taking place in north Texas hopes to create the country’s first large-scale producer of green hydrogen.  The project is building a 900-megawatt wind farm along with a 500-megawatt solar farm.  The 1.4 gigawatts of total production capacity is more energy than the city of Austin consumes.  That energy will be used to produce 200,000 kilograms of hydrogen a day.

This project is among the largest proposed green hydrogen projects in the U.S.   There are green hydrogen proposals in Europe, Australia, Africa, and the Middle East that range from 10 GW to 67 GW. 

The Texas project, being developed in partnership by Air Products and AES, has been enabled by government support from the Inflation Reduction Act.    

There are a few thousand hydrogen-powered cars, boats, and trains but without substantial, cost-effective hydrogen infrastructure, the market is very limited.   Subsidizing the development of the necessary infrastructure is essential if there is any real chance to create the long-imagined hydrogen economy.

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Texas Project Will Use Wind to Make Fuel Out of Water

Photo, posted June 5, 2005, courtesy of City Transport Info via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Green Steel | Earth Wise

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The Inflation Reduction Act provides $369 billion in investments to ramp up renewable energy generation and manufacturing of solar panels, wind turbines, energy storage, and electric vehicles. 

Every megawatt of solar power deployed requires 35 to 45 tons of steel.  Every megawatt of wind power uses 120 to 180 tons of steel.   Estimates are that it will take 1.7 billion tons of steel just to build all the wind turbines needed to reach net zero emissions by 2050.

This is a big problem because steel production accounts for roughly 10% of global carbon emissions and is one of the most carbon-intensive industries in the world.

Making steel is a complex and age-old process that hasn’t changed much over time.  Green steel is steel made with little or no carbon emissions.  There are a few ways to do it.  One is called the direct reduced iron method that uses green hydrogen instead of fossil fuel gas to produce iron and then a renewable-powered electric arc furnace to make the steel. 

Molten Oxide Electrolysis is an alternative green steel approach that doesn’t depend on having a green hydrogen infrastructure.  It uses electrolysis, powered by renewable energy, to separate the bonds of iron ore and produce liquid metal while releasing only oxygen in the process.

Green steel solutions rely on the availability of renewable energy, but the ultimate success of renewable energy will depend on the success of green steel.  The U.S. steel industry will leverage about $6 billion under the Inflation Reduction Act to make progress on it.

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Building tomorrow’s clean energy systems on green steel

Photo, posted October 30, 2008, courtesy of Paul Bica via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Decarbonizing The Most Polluting Heavy Industries | Earth Wise

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The production of steel, cement, and ammonia accounts for about 20% of the carbon dioxide humans pour into the atmosphere.  Modern cities are largely constructed from concrete and steel and most of our food is grown using fertilizer made from ammonia. 

The most widely discussed solutions to decarbonizing these industries are green hydrogen and carbon capture and storage or CCS.

Steel manufacture is responsible for 11% of society’s emissions.  Most production starts by burning coal in a blast furnace. Using CCS could reduce emissions from burning the coal.  But the blast furnace could be eliminated entirely by the use of electrolysis to produce the pure iron needed to make steel.  This would be extremely energy-intensive but using a low-carbon source like green hydrogen could greatly reduce the emissions from making steel.

Ammonia is made by producing hydrogen from natural gas and then combining it with atmospheric nitrogen.  Both the hydrogen production and ammonia synthesis are energy intensive.  Using green hydrogen would eliminate emissions from the hydrogen production itself and new research on catalysts aims at lower-temperature, less-energy intensive ammonia synthesis.

Decarbonizing cement manufacturing is perhaps the toughest challenge.  Cement is made in a high-temperature kiln, typically heated by burning fossil fuels.  The process converts calcium carbonate and clay into a hard solid called clinker.  The main byproduct of that is even more carbon dioxide.  Burning green hydrogen and capturing carbon emission are about the best hope for reducing cement manufacturing emissions.

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Can the World’s Most Polluting Heavy Industries Decarbonize?

Photo, posted June 30, 2009, courtesy of Portland Bolt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Shipping And Aviation | Earth Wise

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The global marine shipping and aviation industries are each responsible for about 3% of greenhouse gas emissions.  These are relatively small numbers, but as other industries decarbonize, the contributions from shipping and aviation will loom larger and larger.

In October, both of these industries made commitments to reach net zero emissions by 2050.  How can they do it?  We don’t really have the details of the technologies to be used, and neither do these industries.  But there are ideas being considered.

For both ships and planes, the solution for short-distance trips can be electrification.  Electric planes are in the works for short distances.  Battery-powered container ships are also under development.  But the electrification of longer international and intercontinental routes for both industries is very difficult.  The size and weight of batteries needed for long hauls are major challenges to overcome.

The low-carbon solution slowly being deployed in aviation is sustainable aviation fuel made from renewable sources. Longer term, green hydrogen fuel for planes may be a solution.  For shipping, hydrogen may play an even larger role.  As in the other potential uses for hydrogen, the essential requirement is to be able to produce hydrogen in a way that does not emit greenhouse gases.

There are multiple ways to move towards the decarbonization of both aviation and shipping.  Which will turn out to be the most practical and successful is not yet known.  What is essential is for both industries to follow through on their commitments to research, develop, and deploy zero-carbon solutions.  They appear to have embraced the vision for the future.  Now comes the hard work of achieving that vision.

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Shipping & Aviation Plan To Go Net Zero. How?

Photo, posted August 8, 2014, courtesy of Tomas Del Coro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

New York And Green Hydrogen | Earth Wise

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In July, outgoing New York Governor Andrew Cuomo announced plans for the state to explore the potential role of green hydrogen as part of New York’s decarbonization strategy.

Green hydrogen is hydrogen produced using renewable energy, such as wind, solar, and hydro power.  While hydrogen itself is a carbon-free fuel, most of the hydrogen produced today is made with a process called natural gas reforming which has byproducts of carbon monoxide and carbon dioxide.  As a result, the environmental benefits of using hydrogen are largely lost.  Hydrogen is the most plentiful element in the universe but extracting it for use as a fuel is not easy.

Green hydrogen is obtained by splitting water molecules into their constituent hydrogen and oxygen parts.  In principle, oxygen is the only byproduct of the process.  The main drawback of electrolysis, as this process is called, is that it is energy intensive as well as being expensive.  But if that energy comes from renewable sources, then it is a clean process.

New York’s announcement is that the state will collaborate with the National Renewable Energy Laboratory and join two hydrogen-focused organizations to inform state decision-making, as well as make $12.5 million in funding available for long duration energy storage techniques and demonstration projects that may include green hydrogen.

Green hydrogen has the potential to decarbonize many of the more challenging sectors of the economy.  Hydrogen is a storable, transportable fuel that can replace fossil fuels in many applications.  Many experts believe that the so-called hydrogen economy could be the future of the world’s energy systems.  For that to happen, green hydrogen will need to be plentiful, sustainable, and inexpensive.

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New York announces initiatives to explore green hydrogen for decarbonization

Photo, posted October 26, 2019, courtesy of Pierre Blache via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Floating Renewable Energy | Earth Wise

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A team of researchers at Texas A&M University believes that the next generation of offshore energy could come in the form of a synergistic combination of multiple renewable energy generators installed on a floating offshore platform.

Their concept for the ocean renewable energy station comprises wind, wave, ocean current, and solar energy elements that could generate electricity for anything from a coastal or island community to a research lab or military unit.  The station would be tethered to the sea bottom and could be used in locations where the water depth increases quickly, such as along the U.S. Pacific Coast or Hawaii.

Offshore wind is already commercially competitive, while wave-energy converters so far have been less cost-effective and only useful for specialized, smaller-scale applications.  The proposed ocean renewable energy station would make use of multiple different methods of electricity generation and incorporate innovative smart materials in the wave energy converters that respond to changes in wave height and frequency and allow for more consistent power production.

Denmark is already building a huge multi-source, multi-purpose ocean energy island.  This world’s first energy island will be 30 acres in area and serve as a hub for 200 giant offshore wind turbines generating 3 GW of electric power.  It is the largest construction project in Danish history, and will cost an estimate $34 billion.  As well as supplying other European countries with electricity, the goal is to use the new offshore island to produce green hydrogen from seawater, which can also be exported.  Large battery banks on the island will store surplus electricity for use in times of high demand.

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Research Underway On Floating Renewable Energy Station

Photo, posted September 27, 2014, courtesy of Eric Gross via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Scaling Up Green Hydrogen | Earth Wise

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The global hydrogen market generates about $150 billion dollars a year.  The bulk of the market consists of hydrogen used to produce ammonia, refine oil, and produce methanol.  Advocates for hydrogen foresee a $600 billion a year market based on power and industry uses, mobility and transport uses, chemical feedstocks, and construction.  But the problem with expanding the use of hydrogen is that the vast majority of hydrogen in use today is produced from fossil fuels such as natural gas and coal and producing it creates carbon dioxide emissions.

The great hope of the industry is “green hydrogen”- hydrogen produced either without using fossil fuels at all or by capturing and storing the emissions generated. The most likely approach is electrolysis – using electricity to produce hydrogen from water.

Billions of dollars are being invested by both governments and by large oil companies in a race to scale up electrolysis and make it economically attractive.  According to the Hydrogen Council industry lobby group, at least $300 billion is expected to be invested globally over the next decade aimed at developing the green hydrogen that could one day meet almost a fifth of global energy demand.

Many argue that producing green hydrogen with electrolysis is an extremely inefficient way to utilize renewable energy.  Critics of hydrogen-powered vehicles particularly make this argument.   But industrial applications of hydrogen that currently use large amounts of fossil fuels – such as steel manufacturing – may be places where green hydrogen would make a real dent in global emissions.

The race to clean up hydrogen is definitely on.

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The Race to Scale Up Green Hydrogen to Help Solve Some of the World’s Dirtiest Energy Problems

Photo, posted December 16, 2020, courtesy of Sharon Hahn Darlin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Green Hydrogen | Earth Wise

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Saudi Arabia is a country built around oil, but it is now placing a big bet on green hydrogen as the next big thing in its energy future.  The country is constructing a $500 billion futuristic city called Neom in the desert along the Red Sea.  The brand-new city will be home to a million people, and it will be powered by green hydrogen.

The U.S. company Air Products & Chemicals has been building a green hydrogen plant there for the last four years.  The giant plant will be powered by 4 gigawatts of wind and solar projects.

Green hydrogen is hydrogen produced without carbon emissions.  Most hydrogen produced commercially is made from natural gas, which results in CO2 emissions.  Green hydrogen is made by using electricity to split water into its component elements using renewable energy to power the process.

Saudi Arabia is an ideal place for a giant green hydrogen plant.  The Middle East has the world’s cheapest wind and solar power.  The sun reliably shines there almost every day and the wind blows almost every night.

While some proponents argue that hydrogen should fuel the entire energy system, other experts see it as a more targeted solution.  The view is that wind and solar power can provide the electricity we need to power homes and electric cars.  However, green hydrogen could be ideal to power energy-intensive industries like concrete and steel manufacturing, as well as parts of the transportation sector that are more difficult to electrify.

While green hydrogen is barely on the radar in the US, around the world a green hydrogen rush is underway, developing it as an energy source that could help end the reign of fossil fuels.

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Green Hydrogen: Could It Be Key to a Carbon-Free Economy?

Photo, posted November 6, 2020, courtesy of RSM Chrystie via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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