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A Better Way To Recycle Plastics | Earth Wise

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The global accumulation of plastic waste is an ever-growing problem.  At least five billion tons of the stuff has accumulated on land and sea and is even showing up in the bodies of animals and humans.  Recycling plastic instead of making even more of it seems like an essential thing to do but it has proven to be extremely challenging.

The main problem is that plastics come in many different varieties and the ways of breaking them down into a form that can be reused are very specific to each type of plastic.  Sorting plastic waste by plastic type is extremely impractical at large scale.  Certainly, most consumers can’t do it themselves.  As a result, most plastic gathered in recycling programs ends up in landfills.

New research at MIT has developed a chemical process using a catalyst based on cobalt that is very effective at breaking down a variety of plastics, including polyethylene and polypropylene, which are the two most widely produced plastics.   The MIT process breaks plastics down into propane.  Propane can be used as a fuel or as a feedstock for making many different products, including new plastics.

Plastics are hard to recycle because their long-chain molecules are very stable and difficult to break apart.  Most chemical methods for breaking their chemical bonds produce a random mix of different molecules which would somehow have to be sorted out in order to be useful for anything.

The new process uses a catalyst called a zeolite that contains cobalt nanoparticles.  The catalyst selectively breaks down various plastic polymer molecules and turns more than 80% of them into propane.

The researchers are still studying the economics and logistics of the method, but it looks quite promising.

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New process could enable more efficient plastics recycling

Photo, posted April 25, 2016, courtesy of NOAA Coral Reef Ecosystem Program via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

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The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications.  Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt. 

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly.  However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages.  The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers.   Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes.  This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

 Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese.  It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Race For American Lithium Mining | Earth Wise

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The auto industry is making a massive transition from gas-powered cars to electric cars.  The exploding electric vehicle market has set off what some call a global battery arms race.  Battery manufacturers are urgently trying to source the raw materials needed to make batteries, which presently include cobalt, nickel, graphite, and lithium.  There is encouraging progress in reducing and even eliminating cobalt and nickel from electric car batteries, but so far lithium seems to be essential.

The International Energy Agency has named lithium as the mineral for which there is the fastest growing demand in the world.  Estimates are that if the world is to meet the global climate targets set by the Paris Agreement, at least 40 times more lithium will be needed in 2040 compared with today.

According to the US Geological Survey, the US has about 9 million tons of lithium, which puts it in the top 5 most lithium-rich countries in the world.  Despite this, our country mines and processes only 1% of global lithium output.  Most of the rest comes from China, Chile, and Australia.  Being dependent upon these foreign sources is a serious concern for national security.

There is only one operational lithium mine in the US at present.  Multiple companies are pressing to get more mining projects in operation, including sites in North Carolina and Nevada.  But there are serious environmental problems associated with lithium mining and there is considerable local opposition to establishing the mines.

The US wants to be a leader in the global race to build the batteries that will power the green transition but it is a complicated situation that combines both undeniably important benefits as well as very real dangers.

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Powering electric cars: the race to mine lithium in America’s backyard

Photo, posted January 18, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Iron Flow Batteries | Earth Wise

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Lithium-ion batteries power computers, cell phones, and increasingly, automobiles.  They started out being rather expensive but have become dramatically cheaper over the last decade, with prices dropping about 90%.  Batteries are needed to store clean power from wind and solar generation and lithium-ion batteries are increasingly being used for that purpose as well.

Utility-scale energy storage requires substantial battery installations and battery cost is still very much an inhibiting factor in the widespread adoption of the technology.  Lithium-ion battery costs continue to drop but because they require expensive materials like lithium and cobalt, there are limits to how low their prices are likely to get.

As a result, researchers have continued to seek ways to produce batteries made out of cheaper materials.  Among the more promising technologies are flow batteries, which are rechargeable batteries in which electrolyte flows through electrochemical cells from tanks. 

Flow batteries are much larger than lithium-ion batteries and include physical pumps to move electrolytes.  They typically are sold inside shipping containers.  Clearly, such batteries are not suitable for use in vehicles, much less in consumer electronics.  Nevertheless, they represent a practical option for grid storage.

A company called ESS has developed an iron flow battery suitable for utility energy storage.  Clean energy firm CSB Energy plans to install iron flow batteries at several solar projects across the U.S. that will store enough energy to provide power 50,000 homes for a day.  According to ESS, the iron-based batteries should sell for about half the price of lithium-ion batteries by 2025 and be able to store energy for longer periods.

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New Iron-Based Batteries Offer an Alternative to Lithium

Photo, posted March 21, 2021, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wastewater And Ammonia | Earth Wise

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Ammonia is the second most produced chemical in the world.  More than half of it is used in agriculture to produce various kinds of fertilizer, to produce cotton defoliants that make cotton easier to pick, and to make antifungal agents for fruits.  Globally, ammonia represents more than a $50 billion a year market.

Current methods to make ammonia require enormous amounts of heat – generated by burning fossil fuels – to break apart nitrogen molecules so that they can bind to hydrogen to form the compound. Ammonia production accounts for about 2% of worldwide fossil energy use and generates over 400 million tons of CO2 annually.

Engineers at the University of Illinois Chicago have created a solar-powered electrochemical reaction that uses wastewater to make ammonia and does it with a solar-to-fuel efficiency that is 10 times better than previous comparable technologies.

The process uses nitrate – which is one of the most common groundwater contaminates – to supply nitrogen and uses sunlight to power the reaction.  The system produces nearly 100% ammonia with almost no hydrogen side reactions.  No fossil fuels are needed, and no carbon dioxide or other greenhouse gases are produced.  The new method makes use of a cobalt catalyst that selectively converts nitrate molecules into ammonia.

Not only is the reaction itself carbon-neutral, which is good for the environment, but if it is scaled up for industrial use, it will consume wastewater, thereby actually being good for the environment.  The new process is the subject of a patent filing and the researchers are already collaborating with municipal corporations, wastewater treatment centers, and others in industry to further develop the system.

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Combining sunlight and wastewater nitrate to make the world’s No. 2 chemical

Photo, posted August 29, 2018, courtesy of Montgomery County Planning Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Metal From Plants | Earth Wise

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Large amounts of metal in soil are generally bad for plants.  But there are about 700 species of plants that thrive in metal-rich soils.  These plants don’t just tolerate minerals from soil in their bodies but actually seem to hoard them to ridiculous levels.

In areas where soils are naturally rich in nickel, typically in the tropics and Mediterranean basin, plants have either died off or have adapted to become nickel loving.  Slicing open a tree with this adaptation produces a neon blue-green sap that is actually one-quarter nickel, which is far more concentrated than the ore that typically feeds commercial nickel smelters.

A group of researchers from the University of Melbourne and other institutions is investigating whether this phenomenon is not just interesting but might also be of real commercial value.  They established a plot of land in a rural village in Borneo and have been harvesting growth from nickel-hyper accumulating plants.  Every six to twelve months, a farmer shaves off one foot of growth from these plants and either burns or squeezes the metal out.  After a short purification, they end up with about 500 pounds of nickel citrate, potentially worth thousands of dollars on international markets.

Phytomining – extracting minerals from hyper-accumulating plants – cannot fully replace traditional mining techniques.  But the technology could enable areas with toxic soils to be made productive and might allow mining companies to use plants to clean up their former mines and waste while actually collecting some revenue.

There are other plants that suck up cobalt, zinc, and similarly crucial metals.  With growing demand for metals, perhaps it is time to harvest them on the farm.

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Down on the Farm That Harvests Metal From Plants

Photo courtesy of the University of Queensland.

Earth Wise is a production of WAMC Northeast Public Radio.

Minerals And Metals For A Low-Carbon Future | Earth Wise

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For the past century, economies and geopolitics have largely been driven by our insatiable appetite for oil and fossil fuels in general.  As we gradually make the transition to a low-carbon energy future, the focus on oil will shift to sustainable supplies of essential minerals and elements.

The use of solar panels, batteries, electric vehicle motors, wind turbines, and fuel cells is growing rapidly around the world.  These technologies make use of cobalt, copper, lithium, cadmium, and various rare earth elements.  The need for any one of these things may diminish if alternatives are found, but there will continue to be a growing reliance on multiple substances whose physical and chemical properties are essential to the function of modern devices and technologies.

In some cases, global supplies of particular minerals and elements are dominated by a particular country, are facing social and environmental conflicts, or face other market issues.  Shortages of any of them could create economic problems and derail progress much as the oil-related energy crises of the past have.

The world faces challenges in managing the demand for low-carbon technology minerals as well as limiting the environmental and public health damage that might be associated with their extraction and processing.  Expanded use of recycling and reuse of rare minerals will be essential.

As the relatively easy sources of these materials become exhausted, other resources will become more attractive.  These include various valuable ecosystems, oceanic deposits, and even space-based reserves.

Ushering in the low-carbon future is not a simple matter and will require responsible actions by the world’s governments and industries. In undoing the damage from the oil age, we must avoid new damage from the low-carbon age.

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Sustainable supply of minerals and metals key to a low-carbon energy future

Photo, posted March 13, 2015, courtesy of Joyce Cory via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Gas From An Artificial Leaf

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Photosynthesis is the process used by plants, algae and certain bacteria to harness energy from sunlight and turn it into chemical energy.  It is often described as the green engine of life on earth.

For quite some time, there have been extensive research efforts around the world in the area of artificial photosynthesis.  The goal is to somehow mimic the behavior of plants in order to generate clean-burning fuels using nothing more than sunlight and the carbon dioxide in the air.

Researchers at the University of Cambridge have recently demonstrated a so-called artificial leaf that can directly produce syngas using sunlight.   Syngas is a fuel gas mixture consisting primarily of hydrogen and carbon monoxide.  Most people haven’t heard of syngas, but many products are created using it.  Being able to produce it sustainably would be a critical step to a far greener chemical and fuel industry.

The artificial leaf contains two light absorbers, similar to the molecules in plants that harvest sunlight, which are combined with a catalyst made from the naturally abundant element cobalt.  When the device is immersed in water, one light absorber uses the catalyst to produce oxygen.  The other carries out the chemical reaction that reduces carbon dioxide and water into carbon monoxide and hydrogen.  The result is the syngas mixture.

It turns out that even a rainy or overcast day provides enough light to drive the process.

Previous artificial leaf devices have mostly just produced hydrogen.  The Cambridge device produces syngas thanks to the novel combination of materials and catalysts it uses.

The researchers are now focused on finding ways to use the technology to produce a sustainable gasoline substitute.

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‘Artificial leaf’ successfully produces clean gas

Photo, posted August 15, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

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There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy.  Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen.  But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it.  The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants.  This membrane is an essential part of pairing the two photosystems.  It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes.  Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Liquid Fuel From The Sun

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Most forms of energy we use ultimately come from the sun in one way or another.  Even fossil fuels are the end product of millions of years of plant life that captured solar energy.  The advantage fossil fuels have over direct solar power is that they are, in fact, fuels and therefore can be stored for use when needed.

Scientists in Sweden have now developed a specialized fluid that absorbs some of the sun’s energy, holds it for months or even years, and then releases it when needed.  This solar thermal fuel is like a rechargeable battery for heat rather than electricity.

The special fluid is pumped through transparent tubes where ultraviolet light from the sun excites its molecules into an energized state.  A compound called norbornadiene is converted into quadricyclane. The quadricyclane is a quite stable substance until it is passed over a cobalt-based catalyst, which causes it to turn back into norbornadiene and release copious amounts of heat.

Such a solar thermal fuel could be stored in uninsulated tanks in homes or factories or piped or trucked to where it was needed.  It could then be used for water heaters, dishwashers, or clothes driers.  The room temperature fluid quickly warms to about 183 degrees when passed over the catalyst, plenty warm enough for heating a home or office.  Both the fuel and the catalyst are damaged very little by the reactions, so the process can be recycled many times.

There is much development work needed to optimize shelf life, energy density, good recyclability and other properties before this technology can be commercialized but there are at least 15 groups around the world now studying this intriguing way to get liquid fuel from the sun.

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Scientists transform sunlight into a liquid fuel that can be stored for 18 years

Photo, posted August 17, 2009, courtesy of Hiromichi Torihara via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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