catalysts

Plastic From Sunlight | Earth Wise

March 13, 2023 By EarthWise Leave a Comment

Photosynthesis is the process that plants use to turn water, carbon dioxide, and energy from sunlight into plant biomass. It provides humans and much of animal life with food. Photosynthesis is also nature’s way of reducing the amount of carbon dioxide in the atmosphere. The CO2 is not directly stored in plants but rather is combined into organic compounds.

Researchers across the globe are trying to find effective ways to mimic photosynthesis. One version of artificial photosynthesis seeks to take carbon dioxide and combine it into organic compounds that can be used as raw materials for various kinds of manufacturing.

A research team in Japan has found a way to synthesize fumaric acid from carbon dioxide using sunlight to power the process. Fumaric acid is a chemical typically synthesized from petroleum and is used as a raw material for making biodegradable plastics such as polybutylene succinate.

Much of artificial photosynthesis research is aimed at using solar energy to convert carbon dioxide directly into a fuel rather than a raw material. Such solar fuels can be produced by a variety of means including thermochemical (using the sun’s heat to drive chemical reactions), photochemical (using the sun’s light to drive chemical reactions), and electrochemical (using solar-generated electricity to drive chemical reactions.) These approaches generally involve the use of specialized catalysts to drive the desired chemical reactions.

One way or another, what techniques for artificial photosynthesis have in common is trying to imitate what plant life on Earth has been doing for millions of years.

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Artificial photosynthesis uses sunlight to make biodegradable plastic

Photo, posted June 14, 2017, courtesy of Alex Holyake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Pollution Into Cash | Earth Wise

April 22, 2022 By EarthWise Leave a Comment

Power plants and other industrial facilities are a major source of carbon emissions. There are a variety of techniques under development to prevent those emissions by capturing them rather than releasing them into the atmosphere. All of them add costs to the functioning of the facility. A good way to offset those costs is to convert the emissions into useful products, ideally making it profitable to capture emissions.

Engineers at the University of Cincinnati have developed an electrochemical system that converts carbon dioxide into ethylene, which is a chemical used in a wide range of manufacturing. Ethylene has sometimes been called “the world’s most important chemical”. It is used in many kinds of plastics, textiles, and the rubber found in tires and insulation. It is also used in heavy industry such as steel and cement plants as well as in the oil and gas industry.

The Cincinnati process is a two-stage cascade reaction that converts carbon dioxide to carbon monoxide and then into ethylene. It is based on the underlying principle of the plug-flow reactor that is used for variety of production applications. The study, published in the journal Nature Catalysis, demonstrates that the process has high ethylene selectivity – meaning that it effectively isolates the desired compound – as well as high productivity – meaning that it makes a lot of it. The system will take more time to become truly economical, but the researchers are continuing to make progress on that front with improved catalysts.

The researchers believe that this technique can reduce carbon emissions and make a profit doing it. Power plants and other facilities emit a lot of carbon dioxide. With this process, it may be possible to capture it and produce a valuable chemical.

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Conversion process turns pollution into cash

Photo, posted February 27, 2018, courtesy of Cyprien Hauser via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Decarbonizing The Most Polluting Heavy Industries | Earth Wise

November 23, 2021 By EarthWise Leave a Comment

The production of steel, cement, and ammonia accounts for about 20% of the carbon dioxide humans pour into the atmosphere. Modern cities are largely constructed from concrete and steel and most of our food is grown using fertilizer made from ammonia.

The most widely discussed solutions to decarbonizing these industries are green hydrogen and carbon capture and storage or CCS.

Steel manufacture is responsible for 11% of society’s emissions. Most production starts by burning coal in a blast furnace. Using CCS could reduce emissions from burning the coal. But the blast furnace could be eliminated entirely by the use of electrolysis to produce the pure iron needed to make steel. This would be extremely energy-intensive but using a low-carbon source like green hydrogen could greatly reduce the emissions from making steel.

Ammonia is made by producing hydrogen from natural gas and then combining it with atmospheric nitrogen. Both the hydrogen production and ammonia synthesis are energy intensive. Using green hydrogen would eliminate emissions from the hydrogen production itself and new research on catalysts aims at lower-temperature, less-energy intensive ammonia synthesis.

Decarbonizing cement manufacturing is perhaps the toughest challenge. Cement is made in a high-temperature kiln, typically heated by burning fossil fuels. The process converts calcium carbonate and clay into a hard solid called clinker. The main byproduct of that is even more carbon dioxide. Burning green hydrogen and capturing carbon emission are about the best hope for reducing cement manufacturing emissions.

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Can the World’s Most Polluting Heavy Industries Decarbonize?

Photo, posted June 30, 2009, courtesy of Portland Bolt via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Coal To Fight Climate Change

April 19, 2019 By EarthWise Leave a Comment

Coal is the most harmful fossil fuel for the environment and, furthermore, for human health. Its use has stubbornly persisted because it is so plentiful and, therefore, cheap. As a result, a big part of efforts to fight climate change is finding a way to remove the carbon dioxide dumped into the atmosphere by the combustion of coal.

Researchers at the Royal Melbourne Institute of Technology in Australia have developed a remarkable technology that in effect reverses the process that has led to soaring CO2 levels in the atmosphere. They have found a way to pull carbon dioxide from the atmosphere and turn it into coal, after which it can be stored cheaply and safely underground.

Most previous carbon capture and storage technologies have focused on compressing carbon dioxide gas into a liquid form and then pumping it into rock formations. Such techniques are rather expensive, require lots of energy, and pose risks that the liquid CO2 could escape from its underground storage sites. More recently, research on solid metal catalysts has led to the possibility of turning CO2 into solid carbon, but most of these reactions require very high temperatures and use a lot of energy.

The new technique developed at RMIT uses a new class of catalysts based on metal alloys. With a small jolt of electricity applied at room temperature, CO2 can be converted into solid carbon – basically, coal.

If this technique can be industrialized economically, it would be like turning back the clock by taking carbon dioxide that entered the atmosphere by the combustion of coal and turning it back into coal and putting it back underground. It seems like excellent environmental justice.

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