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A new way to recycle plastic

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Researchers at Northwestern University have developed a new method for recycling plastic that is safer, cleaner, cheaper, and more sustainable than those currently in use.  The U.S. is the world’s largest plastic polluter per capita, and we only recycle 5% of our plastics.  There is a pressing need for better technologies for processing different types of plastic waste.

The Northwestern method is designed to break down polyethylene terephthalate or PET, which is the most common type of polyester plastic.  PET plastic is used in food packaging and beverage bottles and represents 12% of total plastics used globally.  It does not break down easily and is therefore a major contributor to plastic pollution.  It mostly either ends up in landfills or, over time, degrades into tiny microplastics or nanoplastics that end up almost everywhere. 

The non-toxic, environmentally friendly, solvent-free Northwestern process first uses an inexpensive molybdenum catalyst to break apart the bonds in PET.  Then the broken plastic is exposed to ambient air.  Just from the trace amounts of moisture in air, the broken-down PET is converted into monomers, which are the building blocks of plastic.  The monomers could then be recycled back into PET products or used to make other valuable materials.

The process is fast and effective and takes just a few hours.  The catalyst is durable and recyclable, meaning it can be used over and over again.  It only works on polyesters, which means it can be used for recycling mixed plastics without sorting them since it will select only the PET from its inputs.

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Plastic recycling gets a breath of fresh air

Photo, posted August 10, 2013, courtesy of Lisa Risager via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Storing Sunshine To Make Electricity On Demand | Earth Wise

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Researchers at Chalmers University in Sweden have developed an entirely new way of capturing and storing energy from sunlight.  The system is called the Molecular Thermal Energy Storage System or MOST.  It is based on a specially designed molecule that changes shape when it is exposed to sunshine.

The molecule is composed of carbon, hydrogen, and nitrogen.  When sunlight hits it, it changes into an energy-rich isomer – a molecule made up of the same atoms but arranged together in a different way.  That isomer is stable and can be stored for many years.  When a specially designed catalyst is applied, the stored energy is released in the form of heat and the molecule returns to its original form and can be reused. 

The Chalmers researchers sent some of the energy-laden isomer to researchers in China who used it to operate a micron-thin thermoelectric generator, which used the heat released by the isomer material to generate electricity.  The generator is an ultra-thin chip that could be integrated into electronics such as headphones, smart watches, and telephones.  It is currently only at the proof-of-concept stage, but the results are quite promising.  The integration with the MOST technology provides a way that solar energy can generate electricity regardless of weather, time of day, season, or geographical location.  The results of the study were recently published in the journal Cell Reports Physical Science.

In effect, for this demonstration, Swedish sunshine was sent to the other side of the world and converted into electricity in China. The ultimate goal of this research is to create self-charging electronics that uses stored solar energy on demand.

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Converting solar energy to electricity on demand

Photo, posted March 11, 2013, courtesy of Steve Slater via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Destroying Forever Chemicals | Earth Wise

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PFAS, short for poly and perfluoroalkyl substances, have been used in commercial products since the 1940s.  There are more than 4,000 different chemicals in the class.   Some of the most commonly used PFAS chemicals, like PFOS and PFOA, have long half-lives, which has earned them the moniker “forever chemicals.” 

These dangerous chemicals have not been manufactured in the U.S. since the early 2000s, but they can still be found in various imported goods.  PFAS chemicals have been linked to cancer, birth defects, thyroid disease, and liver damage.  These forever chemicals linger in the environment and scientists have found them in the blood of virtually all Americans.

Researchers at Rice University have recently discovered an efficient catalyst for destroying PFAS forever chemicals.  Unexpectedly, the catalyst was actually in the control group in a study they were performing.

The study, published in the journal Environmental Science and Technology Letters, found that boron nitride, acting as a light-activated catalyst, destroyed PFOA at a faster clip than any previously reported photocatalyst.

The catalyst, boron nitride powder, is a commercially available synthetic mineral that is widely used in makeup, skincare products, thermal pastes for cooling computer chips, and various other industrial products.  The discovery began with dozens of failed experiments on a variety of more promising PFAS catalysts.  But along the way, they found that the boron nitride control material repeatedly yielded positive results.

The research has already attracted the attention of industrial partners seeking to develop off-grid water treatment systems that both protect human lives and support sustainable economic development.

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Boron nitride destroys PFAS ‘forever’ chemicals PFOA, GenX

Photo, posted April 9, 2009, courtesy of Rex Roof via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Possible Storage Breakthrough: Solar Energy | Earth Wise

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Solar energy is a nearly unlimited resource, but it is only available to us when the sun is shining.  For solar power to provide for the majority of our energy needs, there needs to be a way to capture the energy from the sun, store it, and release it when we need it.  There are many approaches to storing solar energy, but so far none have provided an ideal solution.

Scientists at the Chalmers Institute of Technology in Sweden have developed a way to harness solar energy and keep it in reserve so it can be released on demand in the form of heat—even decades after it was captured. Their solution combines several innovations, including an energy-trapping molecule, a storage system, and an energy-storing laminate for windows and textiles.

The energy-trapping molecule is made up of carbon, hydrogen, and nitrogen.  When hit by sunlight, the molecule captures the sun’s energy and holds on to it until it is released as heat by a catalyst.  The specialized storage unit is claimed to be able to store energy for decades.  The transparent coating that the team developed also collects solar energy and releases heat.  Using it would reduce the amount of electricity required for heating buildings.

So far, the team has concentrated on producing heat from stored solar energy.  It is unclear whether the technology can be adapted to produce electricity, which would be even more valuable.  In any event, the team does not yet have precise cost estimates for its technology, but there are no rare or expensive elements required, so the economics seem promising.  There is much more work to be done, but this could be a very important technology for the world’s energy systems.

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An Energy Breakthrough Could Store Solar Power for Decades

Photo courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Gas From An Artificial Leaf

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Photosynthesis is the process used by plants, algae and certain bacteria to harness energy from sunlight and turn it into chemical energy.  It is often described as the green engine of life on earth.

For quite some time, there have been extensive research efforts around the world in the area of artificial photosynthesis.  The goal is to somehow mimic the behavior of plants in order to generate clean-burning fuels using nothing more than sunlight and the carbon dioxide in the air.

Researchers at the University of Cambridge have recently demonstrated a so-called artificial leaf that can directly produce syngas using sunlight.   Syngas is a fuel gas mixture consisting primarily of hydrogen and carbon monoxide.  Most people haven’t heard of syngas, but many products are created using it.  Being able to produce it sustainably would be a critical step to a far greener chemical and fuel industry.

The artificial leaf contains two light absorbers, similar to the molecules in plants that harvest sunlight, which are combined with a catalyst made from the naturally abundant element cobalt.  When the device is immersed in water, one light absorber uses the catalyst to produce oxygen.  The other carries out the chemical reaction that reduces carbon dioxide and water into carbon monoxide and hydrogen.  The result is the syngas mixture.

It turns out that even a rainy or overcast day provides enough light to drive the process.

Previous artificial leaf devices have mostly just produced hydrogen.  The Cambridge device produces syngas thanks to the novel combination of materials and catalysts it uses.

The researchers are now focused on finding ways to use the technology to produce a sustainable gasoline substitute.

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‘Artificial leaf’ successfully produces clean gas

Photo, posted August 15, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

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There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy.  Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen.  But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it.  The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants.  This membrane is an essential part of pairing the two photosystems.  It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes.  Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Liquid Fuel From The Sun

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Most forms of energy we use ultimately come from the sun in one way or another.  Even fossil fuels are the end product of millions of years of plant life that captured solar energy.  The advantage fossil fuels have over direct solar power is that they are, in fact, fuels and therefore can be stored for use when needed.

Scientists in Sweden have now developed a specialized fluid that absorbs some of the sun’s energy, holds it for months or even years, and then releases it when needed.  This solar thermal fuel is like a rechargeable battery for heat rather than electricity.

The special fluid is pumped through transparent tubes where ultraviolet light from the sun excites its molecules into an energized state.  A compound called norbornadiene is converted into quadricyclane. The quadricyclane is a quite stable substance until it is passed over a cobalt-based catalyst, which causes it to turn back into norbornadiene and release copious amounts of heat.

Such a solar thermal fuel could be stored in uninsulated tanks in homes or factories or piped or trucked to where it was needed.  It could then be used for water heaters, dishwashers, or clothes driers.  The room temperature fluid quickly warms to about 183 degrees when passed over the catalyst, plenty warm enough for heating a home or office.  Both the fuel and the catalyst are damaged very little by the reactions, so the process can be recycled many times.

There is much development work needed to optimize shelf life, energy density, good recyclability and other properties before this technology can be commercialized but there are at least 15 groups around the world now studying this intriguing way to get liquid fuel from the sun.

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Scientists transform sunlight into a liquid fuel that can be stored for 18 years

Photo, posted August 17, 2009, courtesy of Hiromichi Torihara via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Way to Make Hydrogen

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Many people consider hydrogen to be the fuel of the future, both for powering vehicles and for storing energy generated by renewable sources.   Hydrogen itself is a clean and green fuel.  Generating energy from it using fuel cells results in only water as a byproduct.

The biggest problem with hydrogen is that the most economical way to produce it and therefore the way most hydrogen is produced today, is by reforming natural gas, which is a process that generates carbon emissions.

The desirable way to make hydrogen is to produce it by breaking apart water into its hydrogen and oxygen components, a process known as electrolysis.   There are many ways to do it, but none of them to date measures up in terms of efficiency, cost, and longevity.

Researchers at the University of Toronto have recently developed a new catalyst that uses abundant, low-cost elements to split water molecules into hydrogen and oxygen.  The catalyst is made from copper, nickel, and chromium, all of which are more abundant and less costly than platinum, which is the usual electrolysis catalyst.

The new catalyst performs well under pH-neutral conditions, which means it could even work on seawater without incurring the expense of desalination.  The Toronto researchers also believe their catalyst could be used as part of a process to make hydrocarbon fuels from hydrogen and CO22.  Their group is among the five finalists in the Carbon XPrize competition, which has a grand prize of $7.5 million for finding a way to convert waste CO2 into fuel.

Finding a low-cost, energy-efficient, and reliable way to make hydrogen out of water will be a big deal if it can be done on an industrial scale.

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U of T researchers discover low-cost way to produce hydrogen from water

Photo, posted July 23, 2015, courtesy of Magnus Johansson via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Catalyst For Splitting Water

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Hydrogen is widely considered to be a desirable source of clean energy.  It can be used in fuel cells to power electric motors in cars or can be burned directly in internal combustion engines.   If it is compressed or converted to liquid, it can be efficiently stored and transported.  Most of all, when it is used as an energy source, the only emission it produces is water.

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Clean Air And Energy

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Researchers in Belgium have engineered a device that uses sunlight to purify polluted air and, in the process, produces hydrogen gas that can be stored and used for power.  Two teams of researchers separately investigating processes for air purification and hydrogen production combined their efforts to create the new device.

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