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Better blue LEDs

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LEDs have become the standard source of energy-efficient lighting.  They make use of semiconductors to turn electricity into light.  Depending upon the materials used to make them, LEDs produce different colors.  In the early 1990s, the first blue LEDs were discovered, ultimately earning the Nobel Prize in physics, and enabling LEDs to produce white light, which is essential for general lighting applications.

Blue LEDs have shortcomings.  Some have issues with stability, scalability, cost, efficiency, complexity in manufacturing, or have environmental concerns because of the use of toxic components. 

Researchers at Rutgers University in collaboration with scientists at several other institutions have found a way to make blue LEDs more efficient and sustainable.  These LEDs use a new type of hybrid material that is a combination of copper iodide with organic molecules.  The impressive performance of these LEDs was achieved through an innovative technique called dual interfacial hydrogen-bond passivation.  This new manufacturing technique boosts the performance of LEDs by a factor of four.

The material has several advantages.  It has a very high photoluminescence quantum yield, which means that it converts nearly all the photoenergy it receives into blue light.  The LEDs last longer than many others and they work well in larger-scale applications, maintaining high efficiency.  The materials are eco-friendly and cost-effective.

According to the researchers, this new approach could be a versatile strategy for generating high-performance LEDs that can pave the way for better, brighter, and longer-lasting LEDs.

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Scientists Develop Deep-Blue LEDs Expected to Greatly Enhance General Lighting

Photo, posted February 1, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

The warmer, greener Arctic and greenhouse gas

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About 15% of the Northern Hemisphere is covered by permafrost.  Permafrost is soil and sediment that has remained frozen for long periods of time, in some cases as much as 700,000 years.  It contains large amounts of dead biomass that has accumulated over millennia and hasn’t fully decomposed.  Therefore, permafrost is an immense carbon sink.

The Arctic is warming four times faster than the rest of the planet and, as a result, thawing permafrost is becoming a carbon source.  As warming continues, ice is melting, and vegetation is spreading.    A new study, published in Nature Climate Change, looked at the state of the Arctic and boreal north from the period 1990 until 2020.  The study found that although half of the Arctic region has been growing greener, only 12% of those green areas are actually taking up more carbon.  For one thing, the growth of forests means that there is more fuel for wildfires which are increasingly common.

A study of lakes in West Greenland found that thousands of crystal blue lakes have turned brown during record heat spells.  Runoff from melting permafrost made the lakes opaque killing off plankton that absorb carbon dioxide.  Meanwhile, plankton that release carbon dioxide multiplied.  So, these lakes went from being carbon sinks to being carbon sources.

As the northern latitudes warm, ice and permafrost are melting, vegetation is spreading, and the region is becoming a source of heat-trapping gas after having been a place where carbon has been locked away for thousands of years.  According to the Nature Climate Change study, roughly 40% of the Arctic is now a source of carbon dioxide.

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Warmer, Greener Arctic Becoming a Source of Heat-Trapping Gas

Photo, posted October 14, 2024, courtesy of Christoph Strässler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Colorful Solar Panels | Earth Wise

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More and more buildings and public spaces are incorporating solar panels and not only just on rooftops.  Some buildings are incorporating power-generating structures all over their facades.

Using solar panels in this way puts some design constraints on buildings because solar panels are typically a deep black color.  This is because solar panels need to absorb light and making them any other color decreases their ability to do so and generate power.  But the problem is that people don’t necessarily want a black building.

One alternative to traditional solar panel design is to use structural sources of color that include microscopic shapes that only reflect specific light frequencies, like the scales on butterfly wings.  But this approach generally leads to iridescence – which might not be what is wanted – and is often quite expensive to implement.

A team of researchers at a university in Shanghai has now demonstrated a way to give solar panels color that is easy and inexpensive to apply and that does not reduce their ability to produce energy efficiently.

The technique involves spraying a thin layer of a material called a photonic glass onto the surface of solar cells.  The photonic glass is made of a thin, disorderly layer of dielectric microscopic zinc sulfide spheres.  Even though most light can pass through the photonic glass, certain colors are reflected back, depending on the sizes of the spheres.  By varying that size, the researchers created solar panels that were blue, green, or purple with only a very small drop in solar panel efficiency.

The solar panels made this way maintained their color and performance under durability testing.  With this new technology, there may soon be colorful solar panels on our buildings.

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Colorful solar panels could make the technology more attractive

Photo, posted December 15, 2021, courtesy of Pete via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Global Light Pollution

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Light pollution is excessive or obtrusive artificial light. It’s a consequence of industrial civilization.  Too much artificial light can cause a host of problems, including disrupting ecosystems, causing adverse health effects, and wasting energy. 

According to a new study led by researchers from the University of Exeter in the U.K., global light pollution has increased by at least 49% over 25 years.  But this figure only includes light visible via satellites.  Scientists estimate that the true increase may be significantly higher – up to 270% more globally. 

That’s because there is a hidden impact of LED technology that isn’t accounted for in the satellite data. LEDs emit more blue light than previous lighting technologies, but satellite sensors fail to pick up this blue light.   This leads to a large underestimate of global light pollution.

The researchers examined light pollution from 1992 to 2017.  They found persistently increasing light pollution in Asia, South America, Oceania and Africa.  In Europe, detected light increased until around 2010, after which it leveled off.  In North America, artificial light appears to be on the decline.  However, the researchers point out that the satellites inability to detect blue light of LEDs means that light pollution has likely actually increased in most locations.

Light pollution has widespread impacts on both animals and plants.  For example, light pollution can confuse the migratory patterns of animals and change predator-prey relationships.   It’s also been shown to cause trees to bud earlier in spring.      

While there’s no off switch for the planet, there are ways that we could reduce the amount of light drastically with little impact on our lives. 

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Rapid increase in global light pollution

Photo, posted November 2, 2008, courtesy of Timothy Tsui via Flickr.

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Rivers Changing Color | Earth Wise

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A recent study, published in Geophysical Research Letters, found that one-third of large American rivers have had significant changes of color over the past 30 years.  Rivers can appear to be shades of blue, green, and yellow and we tend to expect healthy rivers to have colors in shades of blue.  According to the new study, only 6% of American rivers are dominantly blue.

The study looked at 235,000 Landsat images taken from 1984 to 2018.  The results are that 56% of rivers studied were dominantly yellow, 38% dominantly green, and 6% blue.  Over the 34 years studied, 33% of the rivers had significant changes in color. About 21% became greener and 12% more yellow. 

The chief causes of color changes in rivers are farm fertilizer runoff, dams, efforts to fight soil erosion, and climate change.  Climate change increases water temperature and rain-related runoff.

Color changes are not necessarily a sign of poor river health, but dramatic changes could point to issues that need attention.  A river can change color based on the amount of sediment, algae, or dissolved organic carbon in the water.   If a river becomes greener, it can often mean large algae blooms are present that cause oxygen loss and can produce toxins.  On the other hand, rivers that are getting less yellow demonstrate the success of regulations to prevent soil erosion.

The study of river colors can pinpoint which rivers are undergoing rapid environmental change.  What the study does not provide is information on water quality.  Water quality measurements will be important to determine the health of many of the rapidly changing rivers.

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One Third of U.S. Rivers Changed Their Color, Three Decades of Satellite Images Show

Photo, posted July 6, 2016, courtesy of Jeffrey Beall via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Return Of The Blue Whales | Earth Wise

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An international research team has revealed that critically endangered Antarctic blue whales have returned to the sub-Antarctic island of South Georgia, 50 years after whaling just about wiped them out.  Other recent research has found that humpback whales are also returning to the region.

Blue whales were commonplace off South Georgia before 20th century industrial whaling taking place between 1904 and 1971 killed over 42,000 of them there.  Most of that number were killed before the mid-1930s.  As a result, blue whales essentially vanished from the region.  Whale survey ships sighted only a single blue whale between 1998 and 2018.

But things have changed in recent years.  A survey this past February resulted in 58 blue whale sightings and numerous acoustic detections.  Although commercial whaling was banned in the area in the 1960s, it has taken a long time for the whales to make a comeback.

Researchers are not sure why blue whales have taken so long to return to the area.  It may be that so many were killed over the years that the remaining population had little or no cultural memory of South Georgia Island as a foraging ground, and that it is only now being rediscovered.

In total, 41 individual blue whales have been photo-identified from South Georgia over the past 10 years, although none of those matched the 517 whales in the current Antarctic blue whale photographic catalogue.  Dedicated whale surveys are difficult in a region known for its harsh weather and inaccessibility but are crucial to the future management of South Georgia’s seas.  In any case, researchers see the recent sightings as a very positive step forward for conservation of the Antarctic blue whale. 

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Blue whales return to South Georgia after near extinction

Photo, posted September 7, 2007, courtesy of the NOAA Office of National Marine Sanctuaries via Flickr. Photo credit: NOAA.

Earth Wise is a production of WAMC Northeast Public Radio.

Safer Ways To Be Blue | Earth Wise

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Creating blue fabric has always been desirable for people.  It has never been easy, but the original way to do it – by using indigo from plants – has been around for 6,000 years.  Natural indigo is a rare commodity, often referred to as blue gold.  In the 19th century, synthetic indigo was developed and ultimately replaced the natural substance.

Synthetic indigo dye is not an environmentally friendly substance.  In order to get it to adhere to fabrics, substances called mordants are required.  These are commonly made from metals like chromium and aluminum, are generally toxic, and kill off plants exposed to factory wastewater, destroy ecosystems, and poison drinking water.   The dye itself is slow to decompose and is bad for the environment. 

Recently, an organic chemist in Brazil named Erick Bastos has figured out a new way to produce blue dye using, of all things, a pigment from beets.  By extracting the pigment and tweaking its molecular pattern, he has managed to transform the red color of the pigment to a brilliant blue.

Beet roots contain pigments called betalains and just a tiny amount of beetroot juice can render a lot of dye.  By mixing these pigments with a couple of ingredients, a chemical reaction occurred, and the color transformed from red, to yellow, then green, and finally blue.

Testing so far on human liver cells, retinal cells, and developing zebrafish has revealed no toxicity.  The results suggest that the new dye – dubbed BeetBlue – is safe.  Further testing is needed to know if it is truly safe and whether it will last in the wash.  Meanwhile, Professor Bastos is not patenting the dye and hopes it will provide a better way to be blue.

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How Do You Make a Less Toxic Blue Dye? Start With Red Beets

Photo, posted November 7, 2005, courtesy of Lain Buchanan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Green Way To Turn Blue

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Indigo dye is what is used to color denim cloth and blue jeans.  Historically, the dye came from a tropical plant most often found on the Indian subcontinent.  Eventually, it became economically favorable to synthesize the dye instead and almost all of the 50,000 tons of the dye used annually is synthetic.

The processes used to make synthetic indigo are efficient and inexpensive, but they often require toxic chemicals and create a lot of dangerous waste.  Researchers at the Department of Energy’s Joint BioEnergy Institute have now developed an eco-friendly production platform for a blue pigment called indigoidine.  It has a similarly vividly saturated blue hue as synthetic indigo.

The researchers were investigating the ability of various fungal strains to express large enzymes known as NRPSs.  They chose an NRPS that converts two amino acid molecules into indigoidine – a blue pigment – in order to make it easy to tell if the strain engineering had worked.  Having the culture turn blue was an effective indicator.

Their primary interest was not the pigment but when they saw just how blue the culture was for one particular fungus, they realized that the fungal strain did not just produce indigoidine; it produced large amounts of it.

Thus they have found a way to efficiently produce a blue pigment that uses inexpensive, sustainable carbon sources instead of harsh chemicals.  There is already a great deal of interest from the textile industry, where many companies are eager for more sustainably sourced pigments because customers are increasingly aware of the impacts of conventional dyes.

Thanks to a talented fungus called Rhodosporidium toruloides, there may now be a green way to turn blue.

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Blue Pigment from Engineered Fungi Could Help Turn the Textile Industry Green

Photo, posted March 7, 2006, courtesy of Willi Heidelbach via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)