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An Iron-Air Battery Plant | Earth Wise

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Lithium-ion batteries are the standard energy source for electric vehicles, and they are also the dominant technology for storing energy in the electric grid.  However, they are not the only game in town.  There are other battery technologies that have various potential advantages over lithium-ion and some of them are getting the chance to show what they can do.

One is the iron-air battery.  Unlike lithium-ion batteries that require expensive and strategically challenging materials like lithium, cobalt, nickel, and graphite, iron-air batteries make use of one of the most common elements in the earth’s crust.

Iron-air batteries operate on a principle known as “reversible rusting”.  When discharging, the battery takes in oxygen from the air and converts iron into rust.  While charging, electrical current converts rust back into iron and the battery releases oxygen.  Batteries consist of a slab of iron, a water-based electrolyte, and a membrane that feeds a controlled stream of air into the battery. 

A Massachusetts-based company called Form Energy is building a $760 million iron-air battery storage facility in the city of Weirton in West Virginia.  Investment financing along with a $290 million government incentive package is paying for the facility. 

The facility is designed to address the need for long-duration energy storage and will be capable of storing electricity for 100 hours at competitive prices.  The battery modules will be about the size of a side-by-side washer/dryer and will contain a stack of 50 3-foot-tall cells.  Such batteries are too big and heavy for use in cars but will be cheaper and higher-capacity than equivalent lithium-ion battery systems.

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Form Energy selects West Virginia for its first iron-air battery plant

Photo credit: Form Energy

Earth Wise is a production of WAMC Northeast Public Radio

Lithium Mining And Andes Ecosystems | Earth Wise

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A remote region in the high Andes straddling the borders between Argentina, Bolivia, and Chile has become known as the Lithium Triangle.   The area has become the focus of a global rush for lithium to make batteries for electric cars.  The global demand for lithium is expected to quadruple by 2030 to 2.6 million tons a year.

According to the U.S. Geological Survey, more than half of the world’s lithium reserves are dissolved in ancient underground water within the Lithium Triangle.  The cheapest way to extract the lithium is to pump the underground water to the surface and evaporate it in the sun to concentrate the lithium carbonate contained in it.

Every ton of lithium carbonate extracted using this cheap, low-tech method dissipates into the air about half a million gallons of water that is vital to the arid high Andes.  The process lowers water tables and has the potential to dry up lakes, wetlands, springs, and rivers.  Hydrologists and conservationists say the lithium rush in Argentina is likely to turn the region’s delicate ecosystems to deserts.

The global drive for green vehicles to fight climate change has the potential to be an ecological disaster in this remote region of South America and for the indigenous people who live there.

The environmental impacts are not an inevitable price for the transition to electric vehicles.  First of all, there are alternatives to lithium.  Both zinc and nickel are potential substitutes in rechargeable batteries.  But, there are also ways of obtaining lithium that are less destructive than evaporating the metal from saline ecosystems.  It is up to battery manufacturers, automakers, and financiers to start demanding lithium from sources that are less environmentally destructive.

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Why the Rush to Mine Lithium Could Dry Up the High Andes

Photo, posted September 25, 2015, courtesy of Nuno Luciano via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

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Existuje také spousta přípravků ve formě vitaminových a minerálních komplexů, které nasycují tělo všemi užitečnými zdroji pro správné fungování celého těla a sexuálního systému. Nejoblíbenější jsou dnes syntetické stimulanty, protože poskytují silný apothekeein.com a stabilní účinek, doplňky stravy a homeopatické léky se častěji používají pro prevenci problémů tohoto druhu.

The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications.  Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt. 

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly.  However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages.  The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers.   Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes.  This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

 Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese.  It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Race For American Lithium Mining | Earth Wise

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The auto industry is making a massive transition from gas-powered cars to electric cars.  The exploding electric vehicle market has set off what some call a global battery arms race.  Battery manufacturers are urgently trying to source the raw materials needed to make batteries, which presently include cobalt, nickel, graphite, and lithium.  There is encouraging progress in reducing and even eliminating cobalt and nickel from electric car batteries, but so far lithium seems to be essential.

The International Energy Agency has named lithium as the mineral for which there is the fastest growing demand in the world.  Estimates are that if the world is to meet the global climate targets set by the Paris Agreement, at least 40 times more lithium will be needed in 2040 compared with today.

According to the US Geological Survey, the US has about 9 million tons of lithium, which puts it in the top 5 most lithium-rich countries in the world.  Despite this, our country mines and processes only 1% of global lithium output.  Most of the rest comes from China, Chile, and Australia.  Being dependent upon these foreign sources is a serious concern for national security.

There is only one operational lithium mine in the US at present.  Multiple companies are pressing to get more mining projects in operation, including sites in North Carolina and Nevada.  But there are serious environmental problems associated with lithium mining and there is considerable local opposition to establishing the mines.

The US wants to be a leader in the global race to build the batteries that will power the green transition but it is a complicated situation that combines both undeniably important benefits as well as very real dangers.

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Powering electric cars: the race to mine lithium in America’s backyard

Photo, posted January 18, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Metal From Plants | Earth Wise

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Large amounts of metal in soil are generally bad for plants.  But there are about 700 species of plants that thrive in metal-rich soils.  These plants don’t just tolerate minerals from soil in their bodies but actually seem to hoard them to ridiculous levels.

In areas where soils are naturally rich in nickel, typically in the tropics and Mediterranean basin, plants have either died off or have adapted to become nickel loving.  Slicing open a tree with this adaptation produces a neon blue-green sap that is actually one-quarter nickel, which is far more concentrated than the ore that typically feeds commercial nickel smelters.

A group of researchers from the University of Melbourne and other institutions is investigating whether this phenomenon is not just interesting but might also be of real commercial value.  They established a plot of land in a rural village in Borneo and have been harvesting growth from nickel-hyper accumulating plants.  Every six to twelve months, a farmer shaves off one foot of growth from these plants and either burns or squeezes the metal out.  After a short purification, they end up with about 500 pounds of nickel citrate, potentially worth thousands of dollars on international markets.

Phytomining – extracting minerals from hyper-accumulating plants – cannot fully replace traditional mining techniques.  But the technology could enable areas with toxic soils to be made productive and might allow mining companies to use plants to clean up their former mines and waste while actually collecting some revenue.

There are other plants that suck up cobalt, zinc, and similarly crucial metals.  With growing demand for metals, perhaps it is time to harvest them on the farm.

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Down on the Farm That Harvests Metal From Plants

Photo courtesy of the University of Queensland.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

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There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy.  Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen.  But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it.  The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants.  This membrane is an essential part of pairing the two photosystems.  It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes.  Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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