Earth Wise

A look at our changing environment.

You are here: Home / Archives for materials

materials

Recycling Solar Panels | Earth Wise

By Leave a Comment

It is inevitable that the things we make and use eventually outlive their useful lives and become waste that we have to deal with.  Solar panels, despite their impressively long lifetime, can’t escape this general principle.   As pioneering solar panels near the end of their 30-year electronic lives, they could well become the world’s next big wave of e-waste.

According to the International Renewable Energy Agency, nearly 90 million tons of solar panels will have reached their end of life by the year 2050, resulting in about 7 million tons of new solar e-waste per year.

Solar photovoltaic deployment has grown at unprecedented rates in recent years.  The total global installed capacity is about 600 GW today; projections are that there will be 1,600 GW by 2030 and 4,500 GW by 2050.

Solar panels contain valuable materials, including silver and high-purity silicon.  But current recycling procedures are not cost-effective.   Only about 10% of panels are currently recycled in the U.S.   The rest go to landfills or are shipped overseas to become another country’s problem.

Before solar waste becomes a major problem, the industry needs to better address the issue.  Strategies include improving the design of panels to align with recycling capabilities as well as developing new recycling methods that can more efficiently extract and purify the valuable materials in the panels.  Industry researchers are also looking into ways to repair and resell panels that are still in good condition and to repurpose old panels for less demanding functions like e-bike charging stations and housing complexes.

Like most things, solar panels do fail over time and with a rapidly growing number of them in the world, we need to figure out how to avoid them adding to the world’s problems.

**********

Web Links

Solar Panels Are Starting to Die. Will We be Able to Recycle the E-Waste?

Photo, posted January 6, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Recycling Tough Plastics | Earth Wise

By Leave a Comment

Thermoset plastics are ones that contain polymers that cross-link together during the curing process to form an irreversible chemical bond.  This improves the material’s mechanical properties, provides chemical resistance, heat resistance, and structural integrity.  Thermosets include epoxies, polyurethanes, and rubber used for tires.  The big problem with thermosets is that they cannot be easily recycled or broken down after use.

Seventy-five percent of all plastics are thermoplastics, which can be recycled by heating them until they become liquid and can then be remolded.   Thermoset plastics, on the other hand, have such strong chemical bonds that they simply will not melt.  They will typically burn before they can be remolded.

Chemists at MIT have recently developed a way to modify thermoset plastics with a chemical linker that makes them much easier to break down, but still retain the mechanical properties that make them so useful.

In a study published in Nature, the researchers produced a degradable version of a thermoset plastic called pDCPD.  They then broke the plastic down into a powder and were able to use the powder to create more pDCPD.  The paper also proposed a theoretical model that suggests that their approach could be used for a wide range of other plastics and polymers, including rubber.

By adding a chemical called a silyl ether monomer to the liquid precursors that from pDCPD plastic, they found that the resultant material retained its mechanical strength but can be broken down into a soluble powder upon exposure to fluoride ions.

Using this approach with other thermoset materials, the researchers believe it will be possible to create recyclable versions of many of the toughest plastic materials.

**********

Web Links

Chemists make tough plastics recyclable

Photo, posted September 1, 2019, courtesy of Luke McKernan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A High-Tech Fire Alarm | Earth Wise

By Leave a Comment

In recent years, wildfires have been a global problem, notably in California, Brazil, and Australia.  It has become increasingly important to be able to respond to new fires as soon and as quickly as possible.  Such response can make the task of extinguishing them easier, thereby reducing the amount of damage and the loss of property and life.

Traditional methods for detecting forest fires include satellite monitoring, ground patrols, and watch towers, all of which have high labor and financial costs but suffer from low efficiency.  Remote sensing technologies are becoming increasingly common but rely on batteries for power, requiring servicing in remote locations to replace depleted batteries.  Solar cells represent an alternative to batteries, but it is challenging to use them in forests because of shading and foliage coverage.

A team of researchers at Michigan State University has developed a remote forest fire detection and alarm system powered by nothing more than the movement of tree limbs in the wind.  The device is known as an MC-TENG, which is an acronym for multilayered cylindrical triboelectric nanogenerator.  The triboelectric effect is a phenomenon where certain materials become electrically charged when they separate from a second material with which they were previously in contact.  In the new device, two cylindrical sleeves fit within one another – one anchored and the other free to slide.  The device is tied to a tree branch and when the branch sporadically moves in the wind, electricity is generated and stored in a carbon-nanotube-based micro supercapacitor.  This powers a sensing system that can continuously monitor environmental conditions without requiring any maintenance.

A combination of carbon monoxide and temperature sensors provides a high-tech fire alarm that can operate continuously in the most remote forest.

**********

Web Links

Self-Powered Alarm Fights Forest Fires, Monitors Environment

Photo, posted August 3, 2012, courtesy of Lukas Schlagenhauf via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Concrete Production And Diminishing Coal Burning | Earth Wise

By Leave a Comment

Coal burning is still one of the primary means of generating electricity in the United States, but its use is diminishing and doing so fairly rapidly.  The coal burning process produces residual, incombustible materials.  One of them is fly ash, which is composed of fine, glassy, rounded particles rich in silicon, aluminum, calcium, and iron oxides.  Fly ash is captured from coal plant flue gas by precipitators and bag filters. It turns out that two-thirds of this fly ash is not dumped into landfills or impoundments, but rather is put to use.

Because of its chemical and physical characteristics, fly ash can substitute for a portion of portland cement in concrete.  Using this byproduct material in making cement actually reduces its cost. Beyond cost, the addition of fly ash as a so-called supplementary cementitious material or SCM improves concrete’s long-term strength and reduces porosity and permeability.  It reduces the risk of thermal cracking and provides good long-term mechanical properties.

The amount of fly ash used in concrete products increased by 5% between 2011 and 2017 while the amount produced dropped by 36%.  Concrete production continues to increase steadily while fly ash production is steadily dropping.

Therefore, the concrete industry is looking for alternative sources of SCM.  The most obvious is the approximately 1/3 of fly ash that hasn’t been used to make concrete.  Much of that is landfilled or ponded onsite at power plants.  So, opportunities exist for excavating or dredging and recovering these materials.

As coal burning goes away, concrete manufacturing needs to make some changes.

**********

Web Links

What Does the Changing Face of Electricity Production Mean for Concrete?

Photo, posted February 16, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Safer Disposal Of Printed Circuit Boards | Earth Wise

By Leave a Comment

Printed circuit boards are key elements of modern electronic devices that support and connect all of their electronic components.  On average, they are composed of 30% metallic and 70% nonmetallic substances.

Once the circuit boards have served their purpose, they are often burned or buried in landfills, and can pollute the air, soil, and water.  The biggest problem is that they have brominated flame retardants added to them in order to keep them from catching fire.  Compounds in brominated flame retardants have been linked to endocrine disorders and fetal tissue damage.

Many circuit boards are recycled to recover valuable materials – generally the metals they contain.  But recycling has its own problems.  Metallic components can be recovered from crushed circuit boards by magnetic and high-voltage electrostatic separations.  When the metals are removed, what remains are resins, reinforcing materials, brominated flame retardants, and other additives, which are of little value and present various dangers.

Researchers at Sun Yat-sen University in China have developed a ball-milling method to break down these potentially harmful compounds, enabling safe disposal.  A ball mill is a rotating machine that uses small agate balls to grind up materials. The researchers also added iron powder, which helps remove bromine from organic compounds by breaking the carbon-bromine bonds in the flame retardants.  The result was particles with half of their bromine content removed as well as decomposition of phenolic resin compounds.

The ever-increasing proliferation of device technology had led to a new set of pollution and waste challenges facing society.  Research on ways to reduce the impact of high-tech garbage is an important need for society.

**********

Web Links

Toward safer disposal of printed circuit boards

Photo, posted February 18, 2018, courtesy of Diego Torres Silvestre via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Conspicuous Consumption

By 2 Comments

Human civilization consumes vast amounts of material.   The Circle Economy think tank actually puts some numbers on it.  According to their latest report, the amount of material consumed by humanity has passed 100 billion tons every year.  So, on average, every person on Earth uses more than 13 tons of materials per year.

That number has quadrupled since 1970, which is far faster than the population, which has only doubled during that time.  In the past two years alone, consumption has jumped by more than 8%.  While this has been going on, the proportion being recycled has been falling.

Of the 100 billion tons of materials, half of the total is sand, clay, gravel, and cement used for building, along with other minerals used for fertilizer.  Coal, oil and gas make up 15% and metal ores 10%. The final quarter are plants and trees used for food and fuel.  About 40% of all materials are turned into housing.  A third of the annual materials consumed remain in use, such as in buildings or vehicles.  But 15% is emitted into the atmosphere as greenhouse gases and a third is treated as waste.

The global emergencies of climate change and disappearing wildlife have been driven by the unsustainable extraction of fossil fuels, metals, building materials, and trees.  The authors of the report warn that if we continue to treat the world’s resources as limitless, we are heading for a global disaster.

The Circle Economy think tank promotes the idea of a circular economy in which renewable energy supports systems where waste and pollution are reduced to zero.  Some nations are taking steps towards circular economies, while others are not.  This is a problem we can’t allow to be unaddressed.

**********

Web Links

World Consumes 100 Billion Tons of Materials Every Year, Report Finds

Photo, posted March 13, 2015, courtesy of Joyce Cory via Flickr.

XXXXXXXXXXX

Turning Trash Into Treasure

By Leave a Comment

Every year, 380 million tons of plastic are created worldwide, and that number continues to grow.  Furthermore, more than 75% of these materials are discarded after one use.  Much of it ends up in oceans and waterways, harming wildlife and spreading toxins.

Recycling most plastics is difficult because while they can be melted and reprocessed, the resultant material is not as structurally strong as the original material.  Thus, plastics are often down-cycled such as turning plastic bottles into molded park benches.

Researchers at Northwestern University, Argonne National Laboratory, and Ames Laboratory have developed a new method for upcycling abundant, seemingly low-value plastics into high-quality liquid products, such as motor oils, lubricants, detergents, and even cosmetics.  The catalytic method  could remove plastic pollution from the environment and contribute to a circular economy.

Plastics don’t degrade when disposed of because they have very strong carbon-carbon bonds.  Instead they just break into smaller bits, known as microplastics.  The researchers viewed these strong bonds as an opportunity rather than a problem.

The new technique actually recoups the high energy that holds these bonds together by catalytically converting polyethylene molecules into value-added commercial products.  The catalyst consists of platinum nanoparticles deposited onto perovskite nanocubes.  Under moderate pressure and temperature, the catalyst cleaves the carbon-carbon bonds in plastic to produce high-quality liquid hydrocarbons. 

The researchers believe these findings could lead to a future in which we can continue to benefit from plastic materials but do so in a way that is sustainable and less harmful to the environment.

**********

Web Links

Turning plastic trash into treasure

Photo, posted August 15, 2012, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Degraded Permafrost In The Arctic

By Leave a Comment

Permafrost is defined as rock or soil that has been at or below the freezing point of water for two or more years.  Most of it is located in high latitudes in and around the Arctic and Antarctic regions.   Permafrost covers nearly a quarter of the exposed land in the Northern Hemisphere.

Permafrost can contain many different materials including bedrock, sediment, organic matter, water and ice.  Because of the presence of organic matter, permafrost is potentially the source of significant methane emissions if it thaws and the trapped biomass begins to rot.

A recent study looked at the results of 30 years of aerial surveys and extensive ground mapping of an area of Canada’s high Arctic polar desert known as the Eureka Sound Lowlands.  This area has an extremely cold climate and the permafrost there is over 1/3 of a mile thick.  It has long been assumed that this landscape was stable.

Research led by McGill University in Montreal has found that this is not the case.  The increases in summer air temperatures seen in recent years are initiating widespread changes in the landscape.

A particular landform known as a retrogressive thaw slump that forms when ice within permafrost melts and the land slips down is widely occurring in the area.  The absence of vegetation and layers of organic soil in these polar deserts make permafrost in the area particularly vulnerable to increases in summer air temperatures.

The research indicates that despite the cold polar desert conditions that characterize much of the high Arctic, the interaction between ice-rich permafrost systems and climate factors is complex and the links between global warming and permafrost degradation are not well understood.

**********

Web Links

Widespread permafrost degradation seen in high Arctic terrain

Photo, posted August 11, 2018, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Shipping And Invasive Species

By Leave a Comment

The increasing numbers of invasive species around the world are a major driver of biodiversity change and cause billions of dollars in economic damages annually.  Climate change is a major factor in the spread of invasive species, but a new study by McGill University suggests that global shipping growth will far outweigh climate change in the spread of non-indigenous pests to new environments in the coming decades.

One of the most significant ways in which the disparate regions of the world are interconnected is via transportation networks.   The global shipping network is the primary means by which materials and goods are moved worldwide, accounting for over 80% of world trade.  And for this reason, the global shipping network is responsible for much of the introduction of non-indigenous species across the planet.

Living organisms are often transported through ballast water, which is taken up to stabilize cargo vessels.  Other species are transported by biofouling, whereby they attach to the hulls of ships.  Taken together, these two pathways account for anywhere between 60 and 90% of marine bioinvasions.   (Terrestrial invaders are generally moved as a byproduct of shipping, for example by infesting wood packaging material).

The McGill study looked at trends in global shipping and how socioeconomic factors are driving change.  For example, China’s share of global container throughput has gone from 1.4% in 1990 to 20.1% in 2013.  So, the distribution and patterns of shipping have been changing dramatically and with it the spread of non-indigenous species.

Awareness of this issue is increasing.  For example, there have been policy initiatives such as the International Ballast Water Management Convention that is an effort to control bio-invasions through measures such as ballast exchange.  We need to take measures to limit the unintentional spread of species.

**********

Web Links

Global forecasts of shipping traffic and biological invasions to 2050

Photo, posted December 3, 2009, courtesy of Roger W via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Rare Earths From Mining Waste

By Leave a Comment

The 17 rare earth elements have become important parts of much of modern technology.  Despite their name, most of these elements are relatively plentiful in the earth’s crust, but because of their geochemical properties they are typically dispersed and not often found concentrated in minerals.  As a result, economically exploitable ore deposits are uncommon.  There are no significant sources in the U.S.

Rare earths play important roles in high-performance magnets, electric motors in vehicles, wind turbines, microphones and speakers, and in portable electronics like cell phones.  As these applications become ever larger, the need for additional sources of rare earths increases.

Researchers at Idaho National Laboratory and Rutgers University have studied a method for extracting rare-earth elements from mining waste that could greatly increase the world’s supply of these valuable materials.

It turns out that large amounts of rare earths exist in phosphogypsum, a waste product from producing phosphoric acid from phosphate rock.  The U.S. alone mined 28 million tons of phosphate rock in 2017.  (Phosphoric acid is used in the production of fertilizers and other products).

The researchers estimate that more than a billion tons of phosphogypsum waste sits in piles at storage sites across the U.S. alone.   World-wide, about 100,000 tons of rare earth elements per year end up in phosphogypsum waste.  This compares to the total current world-wide production of rare earth oxides of 126,000 tons.

The researchers studied methods for extracting the elements from the waste. A method utilizing a common environmental bacterium showed great promise.

There are concerns about residual radioactivity and other environmental issues in dealing with the waste material, but the world’s supply of rare earth elements might become much greater based on this research.

**********

Web Links

Critical Materials: Researchers Eye Huge Supply of Rare-Earth Elements from Mining Waste

Photo, posted June 19, 2015, courtesy of David Stanley via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Another Way To Make Solar Cells

By Leave a Comment

Millions of rooftops now contain solar panels and the majority of the solar cells that make up those panels today are made from silicon.  Silicon solar cells require expensive, multi-step processing conducted at very high temperatures in special clean room facilities.  Despite these complications, the price of solar panels has continued to drop dramatically over the years.

But even as the price of solar cells gets lower and lower, there are still widespread efforts to find even better ways to make them.   One of those ways is with perovskite solar cells.  Perovskites are materials with a characteristic crystal structure and are quite common in nature.  Perovskites can be formed with a wide range of elements and can exhibit a variety of properties.

They were first used to make solar cells about 10 years ago and those first cells were unimpressive in most respects.  However, there has been steady progress since that time.  The potential advantages of perovskite solar cells are that they can be made from low-cost materials and can be manufactured using liquid chemistry, a far cheaper process than what is used to make silicon cells.

Researchers at MIT and several other institutions have recently published the results of research on how to tailor the composition of perovskite solar cells to optimize their properties.   What used to be a trial-and-error process can now become much more engineered and should lead to perovskite solar cells with performance that could exceed that of silicon cells.

Silicon solar panels are a huge, worldwide industry and displacing them in favor of an alternative technology is a tall order.  But if perovskite cells can be optimized for large-scale manufacturability, efficiency and durability, they could definitely give silicon a run for its money.

**********

Web Links

Unleashing perovskites’ potential for solar cells

Photo courtesy of Ken Richardson/MIT.

Earth Wise is a production of WAMC Northeast Public Radio.

Car Parts From Agricultural Waste

By Leave a Comment

A new bio-composite material made from date palm fiber biomass could be used to produce sustainable, lightweight and low-cost parts for the automobile and marine industries.

A team of researchers from the UK has developed a date palm fiber polycaprolactone composite that is completely biodegradable, renewable,sustainable and recyclable, in contrast to synthetic composite materials reinforced by glass and carbon fibers. The team tested the mechanical properties of the material and found that it achieved better low-velocity impact resistance than traditional man-made composites.

The idea would be to use the material in non-structural auto parts such as car bumpers and door linings.   The result would be to reduce the weight of vehicles, contributing to less fuel consumption and lower emissions.  The new material can be produced using less energy than glass and carbon fibers and is biodegradable and therefore easier to recycle.

Date palm fibers are one of the most available natural fibers in many parts of the world.  The trees produce a large quantity of agricultural waste, which is mostly burned or land-filled,causing serious environmental problems.

Convincing industry to use a new class of materials such as natural-fiber reinforced composites is challenging.  First it is necessary to obtain consistent,reliable properties from the material. Then the industries need to work closely with the developers to test the materials and convince themselves of the viability of using them.  The team, led by researchers at the University of Portsmouth, has been working with industry to test the viability of parts made from a variety of other sustainable materials as well including flax, hemp, and jute.  Someday, our cars may have bumpers made from agricultural waste.

**********

Web Links

Agricultural waste drives us closer to greener transport

Photo, posted October 27, 2017, courtesy of David Stanley via Flickr. 

Earth Wise is a production of WAMC Northeast Public Radio.

More Power From The Sun’s Heat

By Leave a Comment

When we think of solar power, we usually are talking about the panels that generate electricity using the photovoltaic effect.  These panels are on millions of rooftops around the world and in utility-scale solar farms.   There are also solar water heating systems that use the sun’s heat to provide hot water for homes and businesses.

[Read more…] about More Power From The Sun’s Heat

Designing Plastic To Fall Apart

By Leave a Comment

In the 1940s and 1950s, synthetic polymers became very popular.  These man-made materials were designed to be cheap and durable and soon began replacing metals and glass in everything from automobiles and airplanes to bottles and dishes.

[Read more…] about Designing Plastic To Fall Apart

Turning Heat Into Electricity

By Leave a Comment

Many of our technologies produce waste heat.  Internal combustion engines are a prime example, but all our industrial processes, motors, electronics and other machinery turn some (and, in many cases, most) of the energy it takes to run them into heat that just goes into the environment.

[Read more…] about Turning Heat Into Electricity

An Electric, Autonomous Container Ship

By Leave a Comment

Electric cars are big news these days and so are self-driving cars.   But now there is about to be an electric, self-navigating cargo ship.  The soon-to-be-finished ship is called the Yara Birkeland, and is being built under a partnership between two Norwegian companies.

[Read more…] about An Electric, Autonomous Container Ship

Help Save The Bees

By

Globally, 40% of invertebrate pollinator species, such as bees and butterflies, are facing extinction.  And since approximately three-quarters of the world’s food crops depend on pollination, the decline of these pollinators could pose a threat to food security around the globe. 

[Read more…] about Help Save The Bees

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)