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Using CO2 To Convert Seawater Into Drinking Water | Earth Wise

October 27, 2020 By EarthWise Leave a Comment

A chemist at the University of Copenhagen has invented a technology that uses carbon dioxide to convert seawater into drinking water within minutes. This desalination technology has the potential to replace electricity with CO2 and be used in survival gear and in large-scale industrial plants in places where people don’t have clean drinking water.

Over 800 million people worldwide lack access to clean drinking water and that number is growing rapidly. Seawater is a vital source of drinking water in many parts of the world, but desalination faces the major challenge of being highly energy intensive. Desalination plants use huge amounts of fossil fuel-generated electricity and therefore contribute to climate change.

The Copenhagen technology is reminiscent of a SodaStream machine. Carbon dioxide is added to water, initiating a chemical reaction. But instead of using it for bubbly carbonation, it is used to separate salt from water. It works by adding a chemical called CO2-responsive diamine to saltwater. The diamine compound binds with the added CO2 and acts as a sponge to absorb the salt, which can then be separated. The entire process takes one to ten minutes. Once the CO2 is removed, the salt is released again, allowing the diamine to be reused for several more rounds of desalination.

In the laboratory, the method removed 99.6% of the salt in seawater. The technology is still being developed to lower its price and optimize the recycling process. It is also being tested on a small scale in the form of water bottles fitted with special filters that can be used in lifeboats or in other outdoor settings. Ultimately, it could be used to greatly reduce the energy consumption of desalination plants.

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Chemist uses CO2 to convert seawater into drinking water

Photo, posted January 10, 2015, courtesy of Daniel Orth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Artificial Aquatic Polyps | Earth Wise

September 16, 2020 By EarthWise Leave a Comment

Corals are often mistaken for rocks because of their hardened surfaces. And, since they attach or “take root” to the sea floor, they are often mistaken for plants. But unlike rocks, corals are alive. And unlike plants, corals do not make their own food. Corals are actually animals.

Most of these structures that we call “coral” are made up of hundreds to thousands of tiny coral creatures called polyps. A coral polyp, which is often no thicker than a nickel, has a saclike body and mouth that is encircled by stinging tentacles. Polyps are responsible for a host of ecosystem services, including nourishing corals, and aiding coral survival by generating self-made currents through the motion of their soft bodies.

Inspired by these marine organisms, researchers from the University of Warwick in the UK and Eindhoven University of Technology in the Netherlands have collaborated to develop an artificial aquatic polyp capable of removing contaminants from water. The 1 square centimeter wireless robot polyp can attract, grasp, and release objects, moving under the influence of a magnetic field and whose “tentacles” are triggered by light.

The next step for the researchers is to see if the technology can be successfully scaled up from laboratory to pilot scale. In order for that to happen, the team has to design an array of artificial polyps capable of working harmoniously together.

Corals are an incredibly important part of ocean ecosystems. And while it remains to be seen how much value artificial polyps can achieve in future applications, it serves as another example of scientists emulating nature to create more sustainable designs.

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Aquatic robots can remove contaminant particles from water

An artificial aquatic polyp that wirelessly attracts, grasps, and releases objects

Photo, posted April 14, 2011, courtesy of Derek Keats via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Heat-Resistant Coral | Earth Wise

June 23, 2020 By EarthWise Leave a Comment

Coral reefs are in decline all over the world. Corals are under increasing pressure as water temperatures rise and the frequency and severity of coral bleaching events increase. Nowhere is this more evident than in Australia’s Great Barrier Reef system, where severe bleaching events have happened in three of the past five years. Long-term prospects for the survival of the world’s largest reef system are now considered to be poor.

A team of scientists at Australia’s national science agency – the Commonwealth Scientific and Industrial Research Organization – along with the Australian Institute of Marine Science and the University of Melbourne have successfully produced in a laboratory setting a coral that is more resistant to increased seawater temperatures.

The team made the coral more tolerant to temperature-induced bleaching by bolstering the heat tolerance of the microalgae symbionts that live inside the coral tissue. They isolated the microalgae from coral and cultured it in the laboratory using a technique called “directed evolution”. Over the course of four years, they exposed the microalgae to increasingly warmer temperatures. When the heat-adapted strain of algae was reintroduced into coral larvae, the newly established coral-algal symbiosis was more heat tolerant than the original one. The heat-tolerant microalgae are better at photosynthesis and improve the heat response of the coral animal.

The next step is to further test the algal strains in adult colonies across a range of coral species. This groundbreaking research provides a promising and novel tool to increase the heat tolerance of corals and might potentially lead to a way to save the Great Barrier Reef as the world continues to warm.

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Scientists successfully develop heat resistant coral to fight bleaching

Photo, posted September 22, 2010, courtesy of NOAA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Jet Fuel From Acetone | Earth Wise

February 25, 2020 By EarthWise Leave a Comment

Acetone is a common organic solvent. It is used to make plastic, fibers, drugs, and other chemicals. It is commonly used by consumers as nail polish remover. Acetone is a manufactured chemical, but it is also found naturally in the environment in plants, among other places. There are now companies that produce acetone entirely by fermentation of plant feedstocks, such as corn.

Researchers at Los Alamos National Laboratory have now developed a process by which acetone can be converted into a fuel additive that can improve the performance of petroleum-based jet fuel, providing both environmental and economic benefits.

The process takes biomass-derived acetone and converts it to isophorone, which they produce by a process called photochemical cycloaddition that creates more complex hydrocarbons. They then use ultraviolet light to convert the isophorone into cyclobutane, which is a type of hydrocarbon with high energy density that is suitable for aviation fuel applications.

Acetone itself is quite volatile and is unsuitable for fuel applications. It also cannot be added directly to any fuel supply since it can dissolve engine parts and o-rings. Cyclobutane, on the other hand, is a safer and more energy-dense fuel that can be a replacement for additives that require high-pressure hydrogen treatment in their synthesis. Currently, most hydrogen is produced by a process that generates carbon dioxide. The new conversion process does not result in carbon emissions.

According to the Los Alamos researchers, their process can result in a domestically generated product that will provide environmental benefits, create domestic jobs, improve U.S. energy security, and further U.S. global leadership in bioenergy technologies.

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Acetone plus light creates a green jet fuel additive

Photo, posted December 18, 2007, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The ‘Biggest Ever’ Arctic Expedition

October 3, 2019 By EarthWise Leave a Comment

The Arctic is warming faster than any other region on Earth. In fact, it’s warming at a rate of almost twice the global average. And, since what happens in the Arctic doesn’t stay in the Arctic, the world is already feeling the effects: rising sea levels, changes in climate and precipitation patterns, increasing severe weather events, and so on.

As a result, researchers from more than a dozen countries have launched the biggest and most complex expedition ever attempted in the Arctic. They plan to freeze Germany’s largest research vessel, the Polarstern, into Arctic sea ice, where it will remain trapped for twelve months. The ship will drift with the sea ice as the sea ice drifts. The vessel will serve as a research laboratory, hosting a rotating crew of 300 scientists. The ice, the ocean, the atmosphere, and even the wildlife will all be sampled. This year-long journey will give researchers their closest look at how the polar climate and its fragile ecosystems are changing.

Led by the Alfred Wegener Institute for Polar and Marine Research in Germany, the Multidisciplinary drifting Observatory for the Study of Arctic Climate project (or MOSAiC) is expected to cost about $150 million.

One major goal of MOSAiC is to improve strikingly uncertain climate projections for the Arctic. Climate models disagree on how much more the Arctic will warm as the concentration of greenhouse gases in the atmosphere rises and sea ice shrinks. Some project a 5ºC rise by 2100 relative to the 1986-2005 average. Others predict a 10ºC increase.

Understanding the complex processes occurring in the Arctic is essential for projecting the future impacts of climate change.

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Climate scientists prepare for largest ever Arctic expedition

Climate change: Polarstern leaves for ‘biggest ever’ Arctic expedition

Image courtesy of the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility.

Earth Wise is a production of WAMC Northeast Public Radio.

New Membranes For Carbon Capture

October 2, 2019 By EarthWise Leave a Comment

Drastically reducing the amount of carbon dioxide being emitted into the atmosphere is an essential goal in the effort to mitigate the effects of climate change. While the ultimate solution is to avoid combustion of fossil fuels by the use of clean alternative energy sources, that transition will take time – possibly more time than we have. As a result, there is a great deal of effort underway to develop techniques for capturing the carbon emitted by fossil fuel combustion and either recycling it or storing it.

There are multiple ways to capture carbon emissions, but the ultimate goal is to find a technique that is both inexpensive and scalable. One promising technique involves the use of high-performance membranes, which are filters that can specifically pick out CO2 from a mix of gases, such as those coming out of a factory smokestack.

Scientists at a Swiss laboratory have now developed a new class of high-performance membranes that exceeds the targeted performance for carbon capture by a significant margin. The membranes are based on single-layer graphene with a selective layer thinner than 20 nanometers – only about 40 atoms thick. The membranes are highly tunable in terms of chemistry, meaning that they can be designed to capture specific molecules.

The membranes are highly permeable – meaning that they don’t impede gas flow too much – but highly selective. The CO2/N2 separation factor is 22.5, which means that 22.5 times more nitrogen can get through the membrane than carbon dioxide.

The work is just at the laboratory stage at this point, but it is a very promising step towards developing a practical scheme for keeping carbon dioxide from escaping from power-plant and factory smokestacks.

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Next-gen membranes for carbon capture

Photo, posted December 28, 2010, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Collecting Clean Water From The Air

February 6, 2019 By EarthWise Leave a Comment

Clean water is an essential requirement for human life and there are many places where it is a scarce commodity. In the world’s deserts, getting water to people requires feats of engineering and irrigation that can be cumbersome and expensive.

Researchers at Ohio State University have produced a couple of new studies that explore options for gathering water from fog and condensation that are based on principles of biomimicry: copying strategies already in use by plants and animals.

The researchers looked at how cactus, beetles and desert grasses all collect water condensed from nighttime fog, gathering droplets from the air and filtering them to roots or reservoirs.

The cactus they studied collects water on its barbed tips before guiding droplets down conical spines to the base of the plant. They learned that conical shapes gather more water than do cylindrical shapes. This is because of a physics phenomenon called the Laplace pressure gradient.

The beetles they studied collect drops of water on waxy, water-repellent bumps on their backs. The water then slides towards the beetle’s mouth on the flat surface between the bumps. Based on this, the researchers experimented with structures that include multiple hydrophilic cones with spaces in between where water droplets can coalesce.

From grasses, they learned that grooved surfaces move water more quickly than ungrooved surfaces – in fact, about twice as much.

The work so far has been on a laboratory-level, but the researchers envision scaling up to structures in the desert that can gather water from fog or condensation and supplement public systems or wells either on a house-by-house basis or on a community-wide basis. Copying cacti, beetles and grasses could supply clean water to people in the desert.

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