exhaust

Reducing emissions from ocean shipping

August 13, 2025 By EarthWise Leave a Comment

Ocean shipping is a significant contributor to global carbon emissions, accounting for about 3% of the total. It is a key part of international trade, moving goods like electronics, automobiles, and oil. It relies on fossil fuels, and, without significant changes, shipping’s emissions could more than double by 2050. Ocean shipping is one of the world’s most difficult to decarbonize industrial sectors.

Scientists at the University of Southern California and Caltech, collaborating with a startup company called Calcarea, have developed a shipboard system that could remove up to half of the carbon dioxide emitted by shipping vessels. The system is fairly simple and scalable.

The process mimics a natural chemical reaction that takes place in the ocean. As a cargo ship moves through seawater, the CO2 from the ship’s exhaust is absorbed into water that is pumped onboard. This makes the water more acidic. The treated water is then passed through a bed of limestone, where it reacts with the rock to form bicarbonate, which is a stable compound that already exists naturally in seawater. The treated seawater, now stripped of the carbon dioxide, is dumped back into the ocean.

Sophisticated ocean modeling examined what would happen when the bicarbonate-rich water is released back into the sea over a hypothetical 10-year period. The model showed a negligible impact on ocean pH and chemistry.

The researchers estimate that widespread adoption of the technique could reduce shipping-related carbon dioxide emissions by 50%. The startup company Calcarea is working to bring the technology to market and is in early discussions with commercial shippers.

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USC technology may reduce shipping emissions by half

Photo, posted November 14, 2017, courtesy of Bernard Spragg via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Capturing hot carbon dioxide

December 13, 2024 By EarthWise Leave a Comment

Decarbonizing industries like steel and cement is a difficult challenge. Both involve emitting large amounts of carbon dioxide both from burning fossil fuels and from intrinsic chemical reactions taking place. A potential solution is to capture the carbon dioxide emissions and either use them or store them away. But this sort of carbon capture is not easy and can be quite expensive.

The most common method for capturing carbon dioxide emissions from industrial plants uses chemicals called liquid amines which absorb the gas. But the chemical reaction by which this occurs only works well at temperatures between 100 and 140 degrees Fahrenheit. Cement manufacturing and steelmaking plants produce exhaust that exceeds 400 degrees and other industrial processes produce exhaust as hot as 930 degrees.

Costly infrastructure is necessary to cool down these exhaust streams so that amine-based carbon capture technology can work.

Chemists at the University of California, Berkeley, have developed a porous material – a type of metal-organic framework – that can act like a sponge to capture CO2 at temperatures close to those of many industrial exhaust streams. The molecular metal hydride structures have demonstrated rapid, reversible, high-capacity capture of carbon dioxide that can be accomplished at high temperatures.

Removing carbon dioxide from industrial and power plant emissions is a key strategy for reducing greenhouse gases that are warming the Earth and altering the global climate. The captured CO2 can be used to produce value-added chemicals or can be stored underground or chemically-reacted into stable substances.

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Breakthrough in capturing ‘hot’ CO2 from industrial exhaust

Photo, posted March 3, 2010, courtesy of Eli Duke via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Progress towards electric school buses

November 8, 2024 By EarthWise Leave a Comment

The U.S. has nearly half a million school buses providing daily transportation for about 20 million students. Most of these buses are powered by diesel engines which not only dump greenhouse gases into the atmosphere but also fill kids’ lungs with harmful fumes.

Thanks to various federal and state incentive programs, this situation is starting to change. School districts all over the country are beginning to swap out old diesel buses for emissions-free electric-powered school buses.

Electric school buses are finding their way into school districts of all sizes and demographics. The first district in the country to go fully electric was in Martinsville, Texas, which last year converted its 4-bus fleet. The first large urban district to go all-electric was the 74-bus fleet in Oakland, California this summer.

The EPA’s $5 billion Clean School Bus program and many state initiatives are providing incentives for the transition. Five years ago, there were less than 1,000 electric school buses in the U.S. Now there are about 5,000 and more than 7,000 additional buses are in the pipeline.

Apart from the climate implications, there is urgency to replacing diesel school buses from a health perspective. Diesel exhaust is classified as a carcinogen by the World Health Organization, and it contains fine particles and nitrogen oxides, both of which are well-documented asthma triggers.

Electric buses are more expensive than diesel buses, but they are much cheaper to operate. School districts need to put in place charging infrastructure. The transition is not so easy to accomplish, but it is an important step, and more and more school districts are taking it.

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Slowly but Surely, U.S. School Buses Are Starting to Electrify

Photo, posted May 5, 2021, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Wildlife Reclaims Yosemite National Park | Earth Wise

May 12, 2020 By EarthWise Leave a Comment

Our stories often discuss how human activities change the natural environment. With most of us confined to our homes, the lack of human activities is having profound effects on the environment. We are talking about some of these this week.

Yosemite National park is normally awash in humanity – there were over 300,000 visitors in April of 2019 and typically 4 million people visit each year. But as of March 20, the park was closed to tourists to prevent the spread of the coronavirus. Only a skeleton crew of employees remains in the park.

Without all the people, wildlife is coming out of hiding. It did so in previous park closures during government shutdowns, but those closures were pretty short. This one is expected to be the longest on record.

The bear population within the park has quadrupled and many larger animals – such as bobcats and coyotes – are congregating outside of cabins and other buildings and prowling empty roads and walkways instead of hanging back at the edges of human settlements.

In addition, the air at Yosemite is cleaner due to the lack of exhaust and diesel, and Yosemite Valley is nearly silent, apart from natural sounds from the river and the wind. According to some observers, the park’s current condition is probably similar to what visitors in the 19^th century witnessed.

The few park employees sheltering in place are taking advantage of the virtually unimpeded natural amenities of the park. Many are hiking to its lakes and waterfalls, enjoying trails that are empty apart from animals. As some of the people staying in the park have noted, one could not ask for a better place to be isolated.

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Coyotes, bobcats and bears: Wildlife is reclaiming Yosemite National Park

Photo, posted October 30, 2019, courtesy of Ania Mendrek via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Converting A Toxin Into An Industrial Chemical | Earth Wise

January 16, 2020 By EarthWise Leave a Comment

Nitrogen dioxide is a prominent air pollutant produced by internal combustion engines burning fossil fuels as well as by a variety of industrial processes. It is a toxic material associated with a number of respiratory illnesses.

Researchers at the University of Manchester in the UK along with an international team of scientists have developed a new advanced material that can convert nitrogen dioxide from an exhaust gas stream into useful industrial chemical using only water and air.

The material is a metal-organic framework (or MOF) that provides a selective, fully reversible, and repeatable capability to capture nitrogen dioxide. MOFs are tiny three-dimensional structures that are porous and can trap gases inside as though there were tiny cages. MOFs have enormous amounts of surface area for their size. One gram of material can have a surface area as large as a football field.

The material, named MOF-520, can capture nitrogen dioxide at ambient temperatures and pressures and even at low concentration and during flow in the presence of moisture, sulfur dioxide, and carbon dioxide. Such conditions are typical of the exhaust of internal combustion engines. In fact, the process works best at the typical temperature of automobile exhausts.

Once the nitrogen oxide is absorbed, treating the material with water in air converts it into nitric acid and restores the MOF for additional use. Nitric acid is the basis of a multi-billion dollar industry with uses including agricultural fertilizers, rocket propellant, and nylon. Thus, there is great potential for recouping the costs of using the MOF technology and even profiting from it.

It would be great to convert a toxic pollutant into valuable industrial chemicals.

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Clean air research converts toxic air pollutant into industrial chemical

Photo courtesy of the University of Manchester.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Way To Remove CO2 From The Air

December 13, 2019 By EarthWise Leave a Comment

Researchers at MIT have developed a new way of removing carbon dioxide from a stream of air that could be a powerful tool in the battle against climate change. The new system can pull carbon dioxide out of almost any concentration level of the gas, even including the roughly 400 parts per million level currently found in the atmosphere.

The technique is described in a new paper in the journal Energy and Environmental Science and is based on passing air through a stack of electrochemical plates. The device is essentially a large battery that absorbs carbon dioxide from the air passing over its electrodes as it is being charged up, and then releases the gas as it is being discharged.

To use it, the device would simply alternate between charging and discharging. Fresh air or some other feed gas would be blown through the system during the charging cycle and then pure, concentrated carbon dioxide would be blown out during discharging.

The specialized battery uses electrodes coated with a compound called polyanthraquinone, which is composited with carbon nanotubes. These unique electrodes have a binary affinity to carbon dioxide, which means that they either strongly want to capture carbon dioxide or not at all, depending upon whether the device is charging or discharging.

Carbon dioxide is important in many industries such as soft drinks and greenhouse agriculture. With this device, the stuff could literally be pulled out of the air. And, of course, in power plants where exhaust gas is dumped into the air, these novel electrochemical cells could be used to prevent the emission of CO2 into the atmosphere. At the right price, this could be a game changer.

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MIT engineers develop a new way to remove carbon dioxide from air

Photo, posted August 9, 2007, courtesy of William Clifford via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Contrails And Climate Change

September 6, 2019 By EarthWise Leave a Comment

The white wispy trails of condensation produced by the exhaust from aircraft engines have been the subject of a popular conspiracy theory for quite a while. The story goes that the long-lasting condensation trails are actually “chemtrails” composed of chemical or biological agents left in the sky by aircraft and are intentionally sprayed for a variety of nefarious purposes undisclosed to the general public. This story, of course, is nonsense.

But while contrails are not deliberate efforts to modify weather, control population, manipulate psychology, or any of the other bizarre things attributed to them, it turns out that they are having unfortunate effects on the climate.

It turns out that contrails are creating an often-invisible thermal blanket of cloud across the planet that has a significant effect on atmospheric temperatures. Contrails are essentially human-made clouds that form above 25,000 feet where the air is moist and colder than -40 degrees Celsius. At times, contrails stick around in the sky, either as tight, white lines like chalk marks, or by spreading to create thin layers of ice clouds. At any one time, contrail-created clouds cover more than half a percent of global skies.

Research has shown that when contrails are around, nighttime temperatures can go up appreciably. After 9/11, when all U.S. flights were grounded for three days, the difference between daytime and nighttime temperatures actually increased by about 3 degrees Fahrenheit because nights were cooler.

The effects of aviation on climate, both from the CO2 emissions from aircraft engines and from these contrail effects are becoming an increasingly important issue. To complicate matters further, as aircraft engines become more efficient, they will create more, whiter, and longer-lasting contrails.

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How Airplane Contrails Are Helping Make the Planet Warmer

Photo, posted May 15, 2012, courtesy of Mike Lewinski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Indoor Pollution

July 26, 2019 By EarthWise 1 Comment

We mostly think of air pollution as an outdoor problem. The primary culprits are vehicle and factory exhaust as well as occasional wildfire smoke. What we don’t think about is the air quality inside our own homes.

Researchers at Washington State University have found that indoor pollution levels can be surprisingly high and that they vary throughout the day and increase as temperatures rise.

Indoor air pollution comes from a variety of sources, including building materials, furniture, household chemical products, and from activities like cooking. One of the most serious pollutants is formaldehyde, which often is emitted from gypsum wallboard. About half of the gypsum used in homes as drywall is made from waste products from the coal industry. When the material is heated, formaldehyde and possibly even mercury can be emitted.

Pollutant levels rise in homes as temperatures increase. Thus, the highest levels of pollution occur in the afternoon and the lowest are in the early morning. Before this research, manufacturers and builders assumed that pollution levels were pretty much constant over time.

Building laws require that homes are structurally sound, and that people are comfortable, but there is little regulation of air quality in people’s homes. One of the best ways to clear out harmful chemicals is with ventilation to the outdoors. But with increased concern about reducing energy use, builders are making homes more airtight, which may inadvertently be worsening the problem.

We need to balance making more energy efficient homes with protecting our health by being aware of the dangers that lurk in the air in our homes. Running the air conditioning or opening windows are good things to do.

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Researchers uncover indoor pollution hazards

Photo, posted October 14, 2010, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Smog And Solar Power

January 22, 2019 By EarthWise Leave a Comment

China has been struggling with some of the worst air pollution in the world. Beijing frequently sits under a brown blanket made of exhaust gases from industry, cars and coal fires, which dump harmful particulate matter, soot, sulfur dioxide and nitrogen oxides into the air.

The human health consequences are severe. According to the World Health Organization,air pollution contributes to about 1.6 million premature deaths in China each year. World-wide, air pollution is implicated in over 7 million deaths annually.

Faced with this air pollution crisis, China has undertaken a wide variety of measures to improve its air and curb carbon dioxide emissions alongthe way. Among other things, China has invested heavily in the deployment of solar power and has plans for ever greater expansion of solar power in the future.

A study by researchers at ETH in Zurich looked at the impact of China’s air pollution on the production of solar energy. The smog in China’s cities reduces the amount of solar radiation that reaches the ground and therefore significantly reduces the power output of solar energy systems. According to the study, solar radiation would increase by an average of 11% nationwide as a result of strict air pollution control measures. In some places, cleaning up the air would result in 26% more energy production.

China’s electric power industry is the world’s largest electricity producer, having passed the United States in 2011. Two-thirds of the electricity in China still comes from coal, which, apart from the serious climate and health consequences associated with its use, continues to make it more difficult to switch to clean solar power. Much work remains to be done.

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