syngas

Liquid Fuel From Sunshine | Earth Wise

July 6, 2023 By EarthWise Leave a Comment

A key goal of artificial photosynthesis research is to be able to produce a useful liquid fuel using only carbon dioxide, water, and sunlight in a single step. Such a so-called solar fuel would produce net zero carbon emissions and would be completely renewable.

Bioethanol has long been touted as a green alternative to fossil fuels, since it is made from plants rather than petroleum. But producing it takes up agricultural land that could be used to grow food instead and there are emissions associated with many aspects of the process by which plant mass becomes fuel.

Researchers from the University of Cambridge in the UK have developed a so-called artificial leaf that produces ethanol or propanol – usable liquid fuels – in a single step. They developed a copper and palladium-based catalyst that allows the artificial leaf to directly produce multicarbon complex chemicals. Earlier versions of artificial leaves could make simple chemicals, such as syngas, which would then require additional processing to turn into high-density fuels.

The new device produces liquid fuel from carbon dioxide and water simply by shining sunlight on it.

At present, the artificial leaf is a proof-of-concept device that exhibits only modest efficiency. The researchers are working to optimize the device’s light absorbers so that they can better make use of sunlight and to optimize the catalyst so that it can convert more of the sunlight into fuel. In addition, the device needs to be scaled up so that it can produce large volumes of fuel.

All that being said, it is an important step towards people being able to do what plants have been doing for millions of years.

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Driving on sunshine: clean, usable liquid fuels made from solar power

Photo, posted March 23, 2015, courtesy of Astro via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Reducing Emissions From Natural Gas Processing

December 4, 2019 By EarthWise Leave a Comment

Qatar, a small country in the Middle East with a population of about 2.5 million has the highest per capita income of any country in the world. This is largely a result of being one of the world’s top producers of natural gas. The upshot of that is that the tiny country has the dubious honor of being the world’s leading emitter of CO2 per capita.

Texas A&M University has a campus in Qatar and researchers there in collaboration with colleagues at the main campus in College Station, Texas have developed a new reactor technology that can help Qatar process its wealth of natural gas while reducing the country’s carbon footprint.

The technology processes natural gas and captured CO2 to produce both syngas – which is a valuable precursor for many products – and high-quality carbon nanotubes, all without releasing CO2 into the atmosphere.

Natural gas reforming is a process by which syngas – a feedstock for liquid hydrocarbons and ultraclean fuels- is produced. The process requires lots of heat and emits CO2. The new technology adds a novel CARGEN (or CARbon GENerator) reactor that advances the natural gas reforming process and includes a catalyst that captures the CO2 emissions and produces nanotubes. The reactor can be driven by either electric or solar power, eliminating the need to burn fuel that ordinarily results in more carbon emissions.

The result is that Qatar’s CO2 emissions would be converted into two products that are important to its economy. In particular, carbon nanotubes are very expensive and extremely versatile, and can be used to manufacture products such as computers and other high-quality materials.

The next step for the researchers is to partner with industry collaborators to further scale up the technology.

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Qatar Researchers Develop Natural Gas Processing Technology That Could Reduce Qatar’s Carbon Footprint

Photo, posted September 30, 2012, courtesy of Jimmy Baikovicius via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Gas From An Artificial Leaf

November 27, 2019 By EarthWise Leave a Comment

Photosynthesis is the process used by plants, algae and certain bacteria to harness energy from sunlight and turn it into chemical energy. It is often described as the green engine of life on earth.

For quite some time, there have been extensive research efforts around the world in the area of artificial photosynthesis. The goal is to somehow mimic the behavior of plants in order to generate clean-burning fuels using nothing more than sunlight and the carbon dioxide in the air.

Researchers at the University of Cambridge have recently demonstrated a so-called artificial leaf that can directly produce syngas using sunlight. Syngas is a fuel gas mixture consisting primarily of hydrogen and carbon monoxide. Most people haven’t heard of syngas, but many products are created using it. Being able to produce it sustainably would be a critical step to a far greener chemical and fuel industry.

The artificial leaf contains two light absorbers, similar to the molecules in plants that harvest sunlight, which are combined with a catalyst made from the naturally abundant element cobalt. When the device is immersed in water, one light absorber uses the catalyst to produce oxygen. The other carries out the chemical reaction that reduces carbon dioxide and water into carbon monoxide and hydrogen. The result is the syngas mixture.

It turns out that even a rainy or overcast day provides enough light to drive the process.

Previous artificial leaf devices have mostly just produced hydrogen. The Cambridge device produces syngas thanks to the novel combination of materials and catalysts it uses.

The researchers are now focused on finding ways to use the technology to produce a sustainable gasoline substitute.

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‘Artificial leaf’ successfully produces clean gas

Photo, posted August 15, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Coal For Real

February 20, 2017 By EarthWise

We have heard the term “clean coal” for years, mostly from politicians and in coal company advertising. The concept sounds good: burn coal but don’t produce carbon dioxide emissions. While there have been various small-scale tests of technologies to accomplish this, it has not actually been a viable option for the power industry.

[Read more…] about Clean Coal For Real