sulfur

Getting Rid Of Hydrogen Sulfide | Earth Wise

December 20, 2022 By EarthWise Leave a Comment

Hydrogen sulfide gas produces the characteristic smell of rotten eggs, sewers, stockyards, and landfills. The petroleum industry produces thousands of tons of the stuff each year as a byproduct of the processes that remove sulfur from petroleum, natural gas, coal, and other products. The industry faces substantial fines for emitting hydrogen sulfide, but remediation is expensive.

Researchers at Rice University have developed a method for turning hydrogen sulfide into hydrogen gas and sulfur in a single step. Called plasmonic photocatalysis, it not only gets rid of an undesirable substance, it does so by producing valuable byproducts.

The established way of getting rid of hydrogen sulfide is called the Claus process. It requires multiple steps, including some that require combustion chambers heated to 1,500 degrees Fahrenheit. The end product is sulfur and water.

The Rice University process gets all of its energy from light. A surface of grains of silicon dioxide is dotted with tiny gold nanoparticles. These particles interact strongly with a specific wavelength of visible light and cause plasmonic reactions that create short-lived, high-energy electrons that drive the catalysis of hydrogen sulfide. Given that the process requires only visible light and no external heating, it should be relatively straightforward to scale up using solar energy or very efficient LED lamps.

The new hydrogen sulfide remediation technology has been licensed by a Houston-based startup company with more than 60 employees whose founders include some of the Rice researchers. The process may end up being efficient enough and cheap enough for cleaning up non-industrial sources of hydrogen sulfide such as sewers and animal waste.

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New catalyst can turn smelly hydrogen sulfide into a cash cow

Photo, posted July 8, 2021, courtesy of Doug Letterman via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

July 19, 2022 By EarthWise Leave a Comment

Existuje také spousta přípravků ve formě vitaminových a minerálních komplexů, které nasycují tělo všemi užitečnými zdroji pro správné fungování celého těla a sexuálního systému. Nejoblíbenější jsou dnes syntetické stimulanty, protože poskytují silný apothekeein.com a stabilní účinek, doplňky stravy a homeopatické léky se častěji používají pro prevenci problémů tohoto druhu.

The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications. Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt.

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly. However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages. The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers. Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes. This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese. It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Smog And Solar Power

January 22, 2019 By EarthWise Leave a Comment

China has been struggling with some of the worst air pollution in the world. Beijing frequently sits under a brown blanket made of exhaust gases from industry, cars and coal fires, which dump harmful particulate matter, soot, sulfur dioxide and nitrogen oxides into the air.

The human health consequences are severe. According to the World Health Organization,air pollution contributes to about 1.6 million premature deaths in China each year. World-wide, air pollution is implicated in over 7 million deaths annually.

Faced with this air pollution crisis, China has undertaken a wide variety of measures to improve its air and curb carbon dioxide emissions alongthe way. Among other things, China has invested heavily in the deployment of solar power and has plans for ever greater expansion of solar power in the future.

A study by researchers at ETH in Zurich looked at the impact of China’s air pollution on the production of solar energy. The smog in China’s cities reduces the amount of solar radiation that reaches the ground and therefore significantly reduces the power output of solar energy systems. According to the study, solar radiation would increase by an average of 11% nationwide as a result of strict air pollution control measures. In some places, cleaning up the air would result in 26% more energy production.

China’s electric power industry is the world’s largest electricity producer, having passed the United States in 2011. Two-thirds of the electricity in China still comes from coal, which, apart from the serious climate and health consequences associated with its use, continues to make it more difficult to switch to clean solar power. Much work remains to be done.

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Fighting smog supports solar power

Photo, posted February 7, 2014, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaner Air For China

December 5, 2018 By EarthWise Leave a Comment

For more than 15 years, the Chinese government has been grappling with some of the deadliest air pollution in the world. Extreme pollution events are a regular wintertime occurrence and health experts estimate that more than a million people die each year in China from particulate air pollution.

Cleaning Up Shipping Fuel

August 21, 2018 By EarthWise Leave a Comment

Cargo ships are significant sources of global air pollution because of their fuel oil. Most ships burn something called “bunker fuel” which is a pitch-black, molasses-thick fuel made from the dregs of the oil refining process. It is loaded with sulfur, so when it is burned it produces noxious gases and fine particles that can harm human health and the environment. Because bunker fuel is made from petroleum refining residues, waste byproducts sometimes end up in the mix, making the stuff even a worse source of pollution.

Geoengineering And Developing Countries

June 21, 2018 By EarthWise Leave a Comment

There are some mind-boggling schemes being discussed to mitigate the global warming caused by greenhouse gases. These include placing giant mirrors in orbit to reflect sunlight before it reaches Earth and launching millions of tons of sulfur into the stratosphere to simulate the effects of a major volcanic eruption.

Why Do Animals Eat Ocean Plastic?

November 21, 2016 By WAMC WEB

It’s no secret that there is a lot of plastic debris in our oceans. In fact, scientists estimate that there is more than 165 million tons of plastic trash swirling about in our oceans today, with an additional 8.8 million tons flowing in every year. And as the oceans swell with plastic litter, hundreds of marine species are ingesting the stuff – often with dire consequences.

Less Sulfur In The Soil

June 9, 2016 By WAMC WEB

Acid rain is rain containing high levels of nitric and sulfuric acids. The main culprit for it is the burning of fossil fuels, particularly coal-burning power plants. The most serious effect of acid rain is the creation of toxicity in lakes, wetlands and other aquatic environments, doing great harm to a wide range of aquatic animals.