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A Better Way To Recycle Plastic | Earth Wise

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The current state of plastic recycling is not very effective.  Plastic recycling is only able to replace 15-20% of the fossil-fuel-derived raw material needed to produce society’s demand for plastic.

Researchers at Chalmers University in Sweden have now demonstrated how the carbon content in mixed waste could be used to replace all of the fossil raw materials in the production of new plastic.  In principle, their technology could completely eliminate the climate impact of plastic materials.

According to the researchers, there are enough carbon atoms in waste to meet the needs of all global plastic production.

The Chalmers process is based on thermochemical technology and involves heating waste to 1100-1500 degrees Fahrenheit.  The waste is thereby vaporized and when hydrogen is added, becomes a carbon-based substance that can replace the fossil-fuel building blocks of plastic.  The method does not require sorting the waste materials.  Different types of waste, such as old plastic products and even paper cups, with or without food residues, can be fed into the recycling reactors.  The researchers are now developing the techniques required to utilize their recycling technology in the same factories in which plastic products are currently being made from fossil oil or gas.

The principle of the process is inspired by the natural carbon cycle in which plants break down into carbon dioxide when they wither and die, and then photosynthesis uses carbon dioxide and solar energy to grow new plants.

Producing new plastics would no longer require petroleum or other fossil fuels as raw materials.  If the energy needed to drive the recycling reactors is taken from renewable sources, plastics could become the basis of a sustainable and circular economy.

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Pioneering recycling turns mixed waste into premium plastics with no climate impact

Photo, posted August 10, 2013, courtesy of Lisa Risager via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Lithium-Sulfur Batteries | Earth Wise

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The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications.  Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt. 

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly.  However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages.  The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers.   Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes.  This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

 Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese.  It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Emissions-Free Cement

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The production of cement – which is the world’s leading construction material – is a major source of greenhouse gas emissions, accounting for about 8% of global man-made emissions. 

Cement production produces carbon dioxide in two ways:  from a key chemical process and from burning fuel to produce the cement.  The process of making “clinker” – the key constituent of cement – emits the largest amount of CO2.  Raw materials, mainly limestone and clay – are fed into huge kilns and heated to over 2,500 degrees Fahrenheit, requiring lots of fossil fuel.  This calcination process splits the material into calcium oxide and CO2.  The so-called clinker is then mixed with gypsum and limestone to produce cement.

A team of researchers at MIT has come up with a new way of manufacturing cement that greatly reduces the carbon emissions.  The new process makes use of an electrolyzer, where a battery is hooked up to two electrodes in water producing oxygen at one electrode and hydrogen at the other.  The oxygen-evolving electrode produces acid and the hydrogen-evolving electrode produces a base.  In the new process, pulverized limestone is dissolved in the acid at one electrode and calcium hydroxide precipitates out as a solid at the other.

High-purity carbon dioxide is released at the acid electrode, but it can be easily captured for further use such as the production of liquid fuels or even in carbonated beverages and dry ice.  The new approach could eliminate the use of fossil fuels in the heating process, substituting electricity generated from renewable sources. 

The process looks to be scalable and represents a possible approach to greatly reducing one of the perhaps lesser known but nevertheless very significant sources of greenhouse gas emissions.

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New approach suggests path to emissions-free cement

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New Low-Cost Battery

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Batteries have never been more important.  Not only do we all depend on cell phones, tablets and laptop computers that run on batteries, but two enormous industries are in major transitions that rely upon battery technology: personal transportation and the utility industry.   The electricity grid is increasingly turning to solar and wind power for generation and both will require effective energy storage if they are to truly become the predominant sources of electricity.

[Read more…] about A New Low-Cost Battery

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