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Facemask pollution

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During the height of the Covid-19 pandemic, the global usage of disposable facemasks reached a staggering 129 billion per month. Most of these masks are manufactured from petroleum-based non-renewable plastics like polypropylene and the disposal of these masks results in serious pollution problems.  These include the loss of ecological integrity from buried waste in landfills, air pollution from increased waste incineration, and microplastic pollution. 

Recent research by engineers at Washington University in St. Louis investigated the multipronged pollution problem brought about by discarded facemasks.  The study in particular looked at the chemical changes that occur when facemasks are exposed to sunlight, water, and trace metal ions.

Masks littering the environment degrade into nanoplastics and produce reactive oxygen species.  These chemical agents interact with trace metal ions in the environment within hours.  The result is oxides of metals like manganese and iron, which can drive various biogeochemical reactions.

Abandoning and forgetting about plastics like facemasks is an unsustainable practice.  Plastics not only cause physical damage, but also introduce unpredictable and potentially dangerous chemical changes into environmental systems.

Plastic waste is a global problem that has continued to grow and become an increasingly serious threat over decades.  Understanding the nature of the effects of billions of facemasks in the environment is essential to efforts to address the challenges created by them.

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Sun exposure changes chemical fate of littered face masks

Photo, posted August 21, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A new way to recycle plastic

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Researchers at Northwestern University have developed a new method for recycling plastic that is safer, cleaner, cheaper, and more sustainable than those currently in use.  The U.S. is the world’s largest plastic polluter per capita, and we only recycle 5% of our plastics.  There is a pressing need for better technologies for processing different types of plastic waste.

The Northwestern method is designed to break down polyethylene terephthalate or PET, which is the most common type of polyester plastic.  PET plastic is used in food packaging and beverage bottles and represents 12% of total plastics used globally.  It does not break down easily and is therefore a major contributor to plastic pollution.  It mostly either ends up in landfills or, over time, degrades into tiny microplastics or nanoplastics that end up almost everywhere. 

The non-toxic, environmentally friendly, solvent-free Northwestern process first uses an inexpensive molybdenum catalyst to break apart the bonds in PET.  Then the broken plastic is exposed to ambient air.  Just from the trace amounts of moisture in air, the broken-down PET is converted into monomers, which are the building blocks of plastic.  The monomers could then be recycled back into PET products or used to make other valuable materials.

The process is fast and effective and takes just a few hours.  The catalyst is durable and recyclable, meaning it can be used over and over again.  It only works on polyesters, which means it can be used for recycling mixed plastics without sorting them since it will select only the PET from its inputs.

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Plastic recycling gets a breath of fresh air

Photo, posted August 10, 2013, courtesy of Lisa Risager via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Politics and plastic

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The world currently produces nearly half a billion tons of plastic each year.  This is more than twice the amount it produced 20 years ago.  Half of all plastics ever manufactured have been made in the past 20 years.  Plastic waste is everywhere.  About eight million tons of plastic waste escapes into the ocean each year.

Environmental groups have urged nations to adopt a legally binding treaty to address the ever-growing problem of plastic pollution. The United Nations climate conference in South Korea last month took up the issue of reaching agreement on such a treaty.  At what was supposed to be the final round of talks on the topic, delegates could not bridge wide differences on what such a treaty should contain.

The main bone of contention was whether the treaty should include limits on plastic production itself.  Saudi Arabia, Russia, Kuwait, and other oil-producing countries opposed any curbs on plastic production.   They also opposed the phase-out of harmful chemicals used in the production of plastic.

The Saudi delegation claimed that if the issue of plastic pollution is addressed, there should be no problem with producing plastics.  They said the problem is pollution itself, not plastics.  They proposed a focus on improving recycling and waste management.

Of course, preventing plastic pollution from occurring is an extremely challenging thing to do.  Delegates from countries pushing for a wide-ranging treaty – led by Rwanda – were unwilling to accept a toothless theory lacking real constraints on the plastics industry.

As the conference ended, delegates said that they would reconvene in future months to try again to produce a treaty.  No date or place has been announced.

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Nations Fail to Reach an Agreement on Plastic Pollution

Photo, posted February 4, 2023, courtesy of Ingrid Taylar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Greenhouses and the environment

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The use of greenhouses around the world has been growing dramatically.  A new satellite mapping exercise estimated the total land area covered with permanent greenhouses at 3.2 million acres, which is an area the size of Connecticut.  More than half of this is in China, where the growth of greenhouses has been driven by the rapid urbanization of the country and by a more prosperous population increasingly consuming produce like tomatoes, cucumbers, peppers, and eggplants.

The intensive agricultural methods employed within greenhouses can be harmful to local environments because of overtaxing water supplies and by polluting rivers and soils with nutrients, pesticides, and plastic waste.  But the effects of vast areas of plastic coverings on local temperatures can be even more dramatic, and often beneficial.

There are so many plastic and glass roofs in many areas that they are reflecting sufficient amounts of solar radiation to cool local temperatures.  Greenhouse roofs increase the albedo – the reflectivity – of the land surface typically by a tenth.

All these greenhouses are just the tip of the albedo iceberg.  Many farms now temporarily cover crops with reflective plastic sheets.  If these coverings are included in the satellite survey, the total reflective area would be about ten times greater – roughly the size of New York State.

A study in Almeria, on the Mediterranean coast of Spain, which grows about 3 million tons of fruit and vegetables annually, determined the cooling effects of greenhouses.  Weather stations amid the greenhouses showed an average cooling of 1.3 degrees Fahrenheit compared with the surrounding area.

Greenhouses are an accidental and benign form of climate engineering. The cooling provided by greenhouses is similar to the effect of white roofs in urban areas. 

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Could the Global Boom in Greenhouses Help Cool the Planet?

Photo, posted September 6, 2017, courtesy of Lance Cheung / USDA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Eliminating plastic shipping pillows

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Anyone who gets packages from Amazon is familiar with the plastic air pillows used to keep products safe in transit.  Amazon uses almost 15 billion of them a year in North America.

Environmentalists have been urging Amazon and other vendors to cut down on the use of plastic packaging. The air-filled plastic pillows are made from plastic film, which is the most common form of plastic litter found in the sea and in seabeds along the shore.  Plastic film can be deadly to wildlife such as sea turtles and sea birds.  Plastic film generally can’t be composted or recycled either.

Recently, Amazon announced that it will replace its plastic pillows with recycled paper filler in all its North American markets – the United States, Canada, and Mexico – which together account for more than 70% of the retailer’s global sales.  It is already making the switch in a big way and is working towards fully removing the plastic materials by the end of the year.

Replacing plastic packaging with paper is a definite improvement.  Paper is recyclable and biodegradable.  It isn’t perfect:  if it ends up in landfills, it can contribute to methane pollution as it biodegrades.  But, on the other hand, paper packaging is more likely to be recycled.

Stemming the tide of plastic waste is an ongoing effort by environmental and consumer groups.  There is pending legislation in New York that aims to reduce the use of plastic packaging by 50% over 12 years by requiring manufacturers to either replace it or pay fees.  The bill cleared the State Senate but has not come up to a vote in the Assembly.  Similar legislation has already been passed in California, Oregon, Maine, and Colorado.

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Amazon Says It Will Stop Using Puffy Plastic Shipping Pillows

Photo, posted November 20, 2018, courtesy of Todd Van Hoosear via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic food packaging

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Reducing the use of plastic is an important environmental goal.  Plastic is made from fossil fuels and plastic pollutes the land and the oceans.  It is estimated that 40% of plastic waste comes from packaging.  Plastic packaging is extremely common in the supermarket and there is a growing desire to reduce its use.  But it isn’t that easy.

Plastic packaging works well to slow the decay of vegetables and fruit.  Its use results in less produce being tossed into the garbage, where it creates almost 60% of landfill methane emissions.  In fact, food is the most common material in landfills.  The average American family of four spends $1,500 a year on food that ends up uneaten and nearly half of all household food waste is fruits and vegetables.

Products like bagged salads, berries in plastic clamshells, and plastic sealed potatoes and cucumbers are popular with shoppers because they stay fresh longer.  They are popular with grocers because the items don’t have to be weighed.  But all these things result in plastic waste.  It is a tradeoff that is difficult to make between food quality and safety vs. the environmental harm caused by plastic.

There are a variety of alternatives to plastic packaging of food that are being explored.  They range from biodegradable, organic coatings that can take the place of plastic films, to cardboard and paper produce packaging. 

But practically, there is yet no affordable and biodegradable plastic alternative that keeps fruits and vegetables safe and fresh.  Solving the food packaging problem is not easy.

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So Much Produce Comes in Plastic. Is There a Better Way?

Photo, posted July 1, 2007, courtesy of Brian via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Better Plastic Recycling | Earth Wise

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Many of us are careful to put our plastic trash into the appropriate recycling bins hoping that we are helping to stem the global tide of plastic waste.  But many plastics are not recyclable at all and recycling those that are is not even always a good thing.  Breaking down plastics can generate polluting microplastics that are themselves a major environmental problem.  And perhaps the biggest problem for recycling efforts is that they are not cost effective and generally incur huge losses.

Chemical engineers at the University of Wisconsin-Madison recently published a study in the journal Nature outlining a new technique for turning low-value waste plastic into high-value industrial chemicals. 

The technique makes use of two existing chemical processing techniques.  The first is pyrolysis, which is high-temperature heating in an oxygen-free environment.  Heating waste plastic in this way produces pyrolysis oil, a liquid mix of various compounds that includes large amounts of olefins.  Olefins are simple hydrocarbons that are a central building block of many chemicals and polymers.  Olefins are most often produced by energy-intensive processes like steam cracking of petroleum. 

The UW-Madison process takes the olefins and subjects them to a process called homogenous hydroformylation catalysis, which converts them into aldehydes, which can then be further reduced into important industrial chemicals. 

The payoff is that the process can take waste plastics, which are only worth about $100 a ton, and turn them into high-value chemicals worth $1,200-$6,000 a ton.  If the process can be optimized and otherwise made ready for industrial-scale use, it would be a real game-changer in the battle against plastic waste.

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New recycling process could find markets for ‘junk’ plastic waste

Photo, posted September 16, 2015, courtesy of Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Upcycling Plastic Waste | Earth Wise

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People have generated 8 billion tons of plastic waste over time and less than 10% of it has been recycled.  Millions of tons of it escapes into the oceans.  Plastic piles up virtually everywhere on earth.

There are many approaches to dealing with the plastic waste problem and no one of them is a magic bullet.  Engineers at Stanford University have investigated the prospects for upcycling plastic waste for use in infrastructure like buildings and roads.

They used a mix of computer modeling, scientific research, experimental and field data to analyze the potential for using plastic waste in infrastructure.

Among their findings is that recycled glass fiber reinforced polymer composite – which is a tensile plastic commonly used in car, boat, and plane parts – is a promising material for reuse in buildings. 

Roads in which waste plastic is melted down and mixed with conventional paving materials are becoming more common around the world.  India has installed over 60,000 miles of these roads.  Studies show that roads containing waste plastic have the potential to perform better than conventional roads.  They can last longer, are more durable, can tolerate wide temperature swings, and are more resistant to water damage, cracking, and potholes.  Such roads rely less upon virgin fossil resources, which is obviously advantageous.

Upcycling plastic waste in infrastructure is attracting increasing interest because it creates value from something that is strictly a liability and may end up having regulatory advantages as societies move toward more environmentally friendly and sustainable policies.

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Can we use plastic waste to build roads, buildings, and more?

Photo, posted October 7, 2022, courtesy of the Grand Canyon National Park via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic Eating Fungus | Earth Wise

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More than five billion tons of plastic have accumulated on land and sea including the most remote regions of the planet as well as in the bodies of animals and humans.  There is a compelling need to recycle as much plastic as possible but doing so is a major challenge. Plastic comes in many varieties and breaking it down for reuse requires different methods for each.

Polypropylene is one of the biggest challenges for recycling.  It is a very common plastic used for all sorts of products including food containers, coat hangers, plastic wrap, toys, and much more. It accounts for roughly 28% of the world’s plastic waste, but only 1% of it is recycled.

Polypropylene is seldom recycled because it generally has a short life as a packaging material, and it often becomes contaminated by other materials and plastics.  Thus, it generally ends up in landfills.

Researchers at the University of Sydney in Australia have discovered that two common strains of fungi were able to successfully biodegrade polypropylene.  The fungi species – with unavoidable Latin names of Aspergillus terreus and Engyodontium album – are typically found in soil and plants.

The researchers found that the fungi were able to break down polypropylene after it had been pre-treated with either UV light or heat, by 21% over 30 days, and by 25-27% over 90 days.  This seems rather slow but compared with the nearly endless life of polypropylene in landfills, it is a major improvement.

The hope is that methods like this could ultimately reduce the amount of plastic polluting the environment by encouraging plastic to biodegrade naturally under the appropriate conditions.

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Fungi makes meal of hard to recycle plastic

Photo, posted March 5, 2010, courtesy of Kevin Krejci via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

How Much Plastic Is Really In The Ocean? | Earth Wise

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The world has produced more than 6 billion tons of plastic to date and much of that has become waste that has not been recycled, incinerated, or otherwise properly contained.  A great deal of it has ended up in the oceans of the world.

Researchers at Kyushu University in Japan have done an analysis to assess just how much plastic has ended up in the ocean.  According to the study, nearly 28 million tons of plastic waste has entered the ocean and nearly two-thirds of that cannot be monitored.

Gli scienziati hanno dimostrato che i ricordi sono sparsi nelle connessioni neurali del corpo. Il sistema limbico svolge un ruolo importante nel funzionamento della memoria. Si trova sul Dosi di vareniclina lato interno delle regioni temporali, dove si trova l’ipotalamo. Quest’ultimo raggruppa il processo di pensiero.

Furthermore, the Kyushu analysis suggests that those 28 million tons are just the tip of the plastic waste iceberg.  Their findings are that there may be another 600 million tons of mismanaged plastic waste trapped on land – nearly 10% of all the plastic ever produced.

The study created models that simulate the processes by which plastics find their way into the ocean, get transported, and fragment into pieces.  According to their models, large plastics and smaller pieces of microplastics floating on the ocean surface each account for only about 3% of all ocean plastics.  Microplastics on beaches account for another 3%, and 23% of ocean plastic waste is larger plastic litter on the world’s shores.

These things account for only about a third of ocean plastic.  The rest of it is in locations that are impossible to monitor such as heavy plastics that settle on the seafloor because they are denser than seawater.  Half of plastic products made today are made from these heavy plastics.

Plastic pollution is not just a big problem; evidently it is a bigger problem than we thought.

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Visible ocean plastics just the tip of the iceberg

Photo, posted February 28, 2010, courtesy of Kevin Krejci via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Better Way To Recycle Plastics | Earth Wise

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The global accumulation of plastic waste is an ever-growing problem.  At least five billion tons of the stuff has accumulated on land and sea and is even showing up in the bodies of animals and humans.  Recycling plastic instead of making even more of it seems like an essential thing to do but it has proven to be extremely challenging.

The main problem is that plastics come in many different varieties and the ways of breaking them down into a form that can be reused are very specific to each type of plastic.  Sorting plastic waste by plastic type is extremely impractical at large scale.  Certainly, most consumers can’t do it themselves.  As a result, most plastic gathered in recycling programs ends up in landfills.

New research at MIT has developed a chemical process using a catalyst based on cobalt that is very effective at breaking down a variety of plastics, including polyethylene and polypropylene, which are the two most widely produced plastics.   The MIT process breaks plastics down into propane.  Propane can be used as a fuel or as a feedstock for making many different products, including new plastics.

Plastics are hard to recycle because their long-chain molecules are very stable and difficult to break apart.  Most chemical methods for breaking their chemical bonds produce a random mix of different molecules which would somehow have to be sorted out in order to be useful for anything.

The new process uses a catalyst called a zeolite that contains cobalt nanoparticles.  The catalyst selectively breaks down various plastic polymer molecules and turns more than 80% of them into propane.

The researchers are still studying the economics and logistics of the method, but it looks quite promising.

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New process could enable more efficient plastics recycling

Photo, posted April 25, 2016, courtesy of NOAA Coral Reef Ecosystem Program via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Bidding ‘Adieu’ To Single-Use Plastics | Earth Wise

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Since the 1950s, more than nine billion tons of plastic have been produced, and 50% of that has been during the past 15 years.  While there are some use cases for plastic that are important, it generally serves as the poster child of our throwaway culture.

Plastic pollution can be found everywhere on earth, from the top of the tallest mountains to the bottom of the deepest oceans.  It’s in our food, water, and air. 

By 2040, researchers predict that there will be nearly 90 million tons of plastic pollution entering the environment each year.  By some estimates, single-use plastics account for half of all our plastic waste.    

Many cities, states, and even countries are limiting or even banning single-use plastics.  Canada recently announced a ban on single-use plastics.  The ban includes things like plastic shopping bags, cups, cutlery, straws, stirrers, and take-out food containers.

The ban will phase in over the next several years, beginning with a ban on the manufacture and import of single-use plastics by the end of this year.  Sales of these items will be prohibited in 2023, and the export of plastics will cease by the end of 2025.  

Canada’s southern neighbor, the United States, leads the world in plastic waste generation.  While some states have approved single-use plastic reforms, most of the effort at the federal level has focused on improving recycling rates.  However, a recent report from several environmental organizations found that plastic recycling rates in the U.S. have actually declined in the last several years, from an already-dismal 8.7% to less than 6%.    

Suggesting the plastic waste problem can be solved with improved recycling rates is greenwashing the issue. 

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Canada is banning single-use plastics, including grocery bags and straws

Photo, posted October 31, 2011, courtesy of Mara via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plastic Recycling Isn’t Working | Earth Wise

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A recent report from several environmental organizations shows that plastic recycling rates in the U.S. have actually declined in the last several years from about 8.7% of discarded plastic to less than 6%.   Meanwhile, since 1980, per capita plastic waste generation has increased 263%, totaling 218 pounds of plastic waste per person as of 2018.

Diminishing recycling rates don’t necessarily indicate a lack of interest by the public.  Plastic recycling is a complicated process.  There are multiple types of plastic that can’t be intermingled and there are no simple and sustainable ways to recycle many forms of plastic.   On top of that, the declining recycling rate also reflects the fact that we no longer can export our plastic waste to countries like China and Turkey, which have banned U.S. waste imports.

Recycling in general is a successful practice.  Paper recycling rates are around 66% as of 2020.  Cardboard recycling was at 88.8% in 2020, and metal recycling rates range from 27% to 76%, depending on the type of metal.  Glass recycling rates are a little over 30%.  Only plastic recycling has never reached 10%, even before shipping our waste overseas and declaring it to be recycled was going on.

According to environmental organizations focused on the global plastic problem, there is no circular economy of plastics.  Perhaps if truly biodegradable plastics became practical, economical, and widely utilized, the situation would be different.  As things stand, the only solution is to reduce the production, use, and disposal of plastics.

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Plastics Recycling ‘Does Not Work,’ Environmentalists Stress as U.S. Recycling Rates Drop to 5%

Photo, posted May 13, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Capturing Carbon Dioxide With Plastic | Earth Wise

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The world is awash in both waste plastic and in carbon dioxide emissions.   Researchers at Rice University have discovered a chemical technique for making waste plastic into an effective carbon dioxide absorbent for industry.

Chemists at Rice reported in the journal ACS Nano that heating plastic waste in the presence of potassium acetate produces particles with nanometer-scale pores that trap carbon dioxide molecules.   According to the researchers, these particles could be used to remove CO2 from the flue gas streams of power plants.

Significant sources of CO2 emissions like power plant exhaust stacks could be fitted with this waste-plastic-derived material to absorb large amounts of carbon dioxide that would otherwise enter the atmosphere. 

The Rice University process is an enhancement to the current process of pyrolyzing waste plastic – that is, breaking it down in the presence of heat.  By pyrolyzing plastic in the presence of potassium acetate, porous particles are formed that can hold up to 18% of their own weight in carbon dioxide.

According to the researchers, the cost of capturing carbon from a power plant would be $21 a ton, which is far less expensive than existing energy-intensive processes used to pull carbon dioxide from natural gas feeds.

The sorbent material can be reused.  Heating it to about 167 degrees Fahrenheit releases trapped carbon dioxide from the pores and regenerates about 90% of the material’s binding sites.

The Rice process may represent a much better way to capture carbon dioxide from power plant exhaust stacks.  It could be a way to make use of one environmental problem – waste plastic – to deal with another one.

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Treated plastic waste good at grabbing carbon dioxide

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Getting Rid Of Single-Use Plastics | Earth Wise

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Single-use plastics are used only once before they are recycled – or more likely – simply thrown away.  These are things like plastic bags, straws, coffee stirrers, soda and water bottles, and most food packaging.  They are primarily made from fossil fuel-based chemicals.

Since the 1950s, over 9 billion tons of plastics have been produced, and half of that has been in the past 15 years.  There are uses for plastic that are not only reasonable, but are even important, such as for surgical gloves.  But for the most part, single-use plastic is the poster child of our throwaway culture that is bad for the environment, for wildlife, and even for human health.

Many cities, states, and even countries are moving toward greatly limiting or outright banning single-use plastics.  A recent global survey indicates that the great majority of people around the world are with the program.

According to a 28-country survey from marketing firm Ipsos and the activist group Plastic Free July, three out of four people around the world agree with a ban on single-use plastics.  The poll of more than 20,000 people showed that in Latin America, China, and India, more than 80% agree that a ban should happen as soon as possible.  Unfortunately, Canada, the United States, and Japan were the least supportive countries.  In particular, only 40% of Japanese respondents favored a ban.

Ninety percent of respondents globally support an international treaty to combat plastic pollution and eighty percent said they personally want to buy products with as little plastic packaging as possible.  Unfortunately, people in wealthy countries, which produce the most plastic waste, are less likely to support a ban.  Those countries typically export their waste to the developing world.

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Three in Four People Worldwide Support a Ban on Single-Use Plastics

Photo, posted April 13, 2006, courtesy of Leonard J Matthews via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Regulating Plastic Pollution | Earth Wise

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Much of the world is united in the desire to do something about the problem of plastic waste.  But putting in place regulations that transcend national borders is complicated.

One hundred fifteen countries have established bans on plastic bags, but globally, there are seven different definitions of what is considered a plastic bag.  Things like bag thickness can determine whether something even counts as a plastic bag.  These differences create loopholes that enable illegal bags to be used.  For a global company like Nestle, which sells food products in 187 countries, it means complying with 187 different sets of national regulations on plastic packaging.

At least 100 nations have expressed support for a global plastic treaty.  Preliminary talks are dealing with issues like setting a specific date to eliminate plastic from spilling into the ocean, creating a harmonized set of definitions and standards, coordination of national targets and plans, and creating a fund to build waste management facilities where they are most needed in less developed countries.

New plastic waste is created at a rate of over 300 million tons a year.   To date, 75% of all plastic ever produced has become waste, and plastic production is expected to triple by 2050.

With public concern about plastic waste growing and increasing support by countries around the world, there is growing optimism that a global treaty to address plastic waste could be approved on a pace that could make a difference.  Negotiations for international treaties can drag on for a decade or more.  There is not that kind of time to spare in this case, so perhaps urgency will drive more efficient action.

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Global treaty to regulate plastic pollution gains momentum

Photo, posted February 3, 2015, courtesy of Thad Zajdowicz via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Takeout Food And Ocean Litter | Earth Wise

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The Covid-19 pandemic saw most of us making use of take-out or delivery services as our only access to restaurant food.  It was a valuable link to normal life.  But unfortunately, the packaging of takeout food is a major contributor to the global plastic waste problem that isn’t going to disappear just because people are returning to eating in restaurants.

A new analysis of more than 12 million items by UK researchers published in the journal Nature Sustainability has found that the majority of ocean litter collected around the world is in the form of takeout food items:  bags, wrappers, containers, straws and cutlery, aluminum cans, and plastic and glass bottles.  Eighty percent of all the items surveyed were made of plastic.

Wrappers and packaging tended to concentrate along coasts, gathering on the shore and the sea floor.  Takeout trash was rarer in the open ocean.  In those areas, fishing debris accounted for half of the litter.

The authors of the study argue that efforts to curb plastic waste should prioritize takeout food and beverage containers.  They recommend that avoidable takeout items, like single-use plastic bags, should be replaced with non-plastic and biodegradable materials.  The authors also recommended making plastic producers responsible for the collection and disposal of plastic products.

As of July 1, the European Union has banned the 10 most common plastic and Stryofoam products found on European beaches.  The EU is also establishing an active European market for recycled plastics based on the principles of extended producer responsibility.

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Takeout Food and Drink Containers Account for Bulk of Ocean Litter

Photo, posted September 14, 2009, courtesy of Susan White/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Infinitely Recyclable Plastic | Earth Wise

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The glut of plastics is one of the world’s most challenging environmental problems.  The average American generates over 200 pounds of plastic waste each year and most of that ends up in landfills.  Researchers around the globe continue to work on potential solutions to the plastic waste problem.

Two years ago, scientists at Lawrence Berkeley National Laboratory announced the invention of a new plastic that could be an answer to the plastic waste problem.  The material is called polydiketoenamine or PDK and it differs from traditional plastics in a very important way:  it can be recycled indefinitely with no loss in quality because it can easily be broken down into its constituent component monomers and be used to make brand new plastic.

Only a small percentage of plastics are currently recycled.  When many plastics are melted down together, the polymers are mixed with a slew of incompatible additives, resulting in a new material with much lower quality than newly produced plastic.  As a result, less than 10% of plastic is recycled more than once.

Recently, the Berkeley Lab researchers released a study that shows what could be accomplished if manufacturers began using PDKs on a large scale.  They determined that PDK-based plastic could quickly become commercially competitive with conventional plastics and, furthermore, would get less expensive and more sustainable as time goes on.

PDK is starting to draw interest from companies needing to source plastic.  The best initial application for PDKs are markets where manufacturers have the most access to products at the end of their lifespans such as in the automobile industry and consumer electronics.  Making plastics part of a circular economy is a challenging task.

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The Future Looks Bright for Infinitely Recyclable Plastic

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Polystyrene | Earth Wise

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The proliferation of global plastic waste continues to be a growing problem for the world.  Hundreds of millions of tons of plastics are produced each year and most of it is used once and then discarded.  The properties that make plastics so attractive – durability and chemical stability – make it difficult to do anything with discarded plastics other than deposit them in landfills – where they don’t easily degrade over time – or burn them, which dumps carbon dioxide and various hazardous gases into the atmosphere.

Polystyrene is one of the most widely used plastics.  It is found in foam packaging materials, disposable food containers, plastic cutlery, storage containers, and many other places. 

Recycling plastics like polystyrene is generally not economically feasible.  Sorting plastics by type is time and labor intensive and the chemical processes required to break down plastics into usable precursor materials require significant energy input and the use of toxic solvents.

Recently, a team of scientists at Ames Laboratory in Iowa has developed a process based on ball-milling that deconstructs commercial polystyrene in a single step, at room temperature, in ambient atmosphere, and in the absence of harmful solvents.

Ball-milling is a technique that places materials in a milling vial with metal ball bearings which is then agitated to initiate a chemical reaction.  This approach is known as mechanochemistry.

The method represents an important breakthrough that enables dismantling of a polymer that includes its chemical breakdown without requiring solvents or the high temperatures generally needed to thermally decompose it.  This discovery opens up new avenues for low-temperature recovery of monomers from polymer-based systems that include composites and laminates.  It could be a very useful weapon in the battle against plastic waste.

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Polystyrene waste is everywhere, and it’s not biodegradable. Scientists just found a way to break it down.

Photo, posted December 11, 2010, courtesy of Warrenski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Living On Trash | Earth Wise

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Litter is persistent and widespread in rivers worldwide.  The world’s major rivers and estuaries are hotspots for plastic waste.  Trash and microparticles wash down tributaries and build up before rivers enter oceans.

New research published in the journal Freshwater Biology has found that as this waste accumulates, aquatic river species like insects and snails are increasingly choosing to settle on plastic rather than on natural features like rocks and fallen branches.

Researchers from the University of Nottingham in the UK collected plastic waste from three rivers in eastern Britain along with rocks from the same rivers.  Their analysis of all the macroinvertebrates on the items’ surfaces found that the surfaces of plastic waste items had nearly four times the diversity of the small animals as did the rocks.  In addition, the more complex the plastic’s surface was, the higher the diversity.

The growing abundance of plastic waste coincides with a decline in natural habitat features in urban rivers.  This is a result of increasing amounts of sedimentation from development that blankets riverbeds in silt and sand, restricting the supply and movement of rocks, fallen tree branches, and aquatic plants.

Clearly litter can serve as a place for various species to colonize, but trash is not a good environment for them.  Trash can release toxic chemicals and entangle animals.  Microplastics pose risks for the animals if ingested.

Estimates are that between 1.15 and 2.41 million tons of plastic waste enter the ocean every year from rivers around the world.  Natural habitats have become rare in urban rivers.  River ecosystems built around piles of trash are not a good thing.

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As Plastic Pollution in Rivers Gets Worse, Species Are Increasingly Living on Litter

Photo, posted August 17, 2010, courtesy of Renee_McGurk via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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