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metal organic frameworks

Water from thin air

September 6, 2024 By EarthWise Leave a Comment

Creating drinking water from thin air

The Earth’s atmosphere contains enormous amounts of water.  Being able to efficiently and economically extract some of it to provide drinking water would be extremely beneficial to the billions of people across the globe who face chronic water shortages.

There are existing technologies for atmospheric water harvesting – or AWH.  But there are downsides associated with size, cost, and efficiency.   A new device developed by mechanical engineering researchers at the University of Utah has the potential to provide a new drinking water source in arid places.

The device is a compact, rapid-cycling, fuel-fired AWH device.  It relies on adsorbent materials that draw water molecules out of non-humid air and then applies heat to release those molecules into liquid form.

Hygroscopic materials are those that have an affinity for water and soak it up at every opportunity.  Such materials are used, for example, in disposable diapers.  The Utah device makes use of metal organic frameworks, which have enormous amounts of surface area on the molecular scale.

The initial work on the Utah device targeted a small compact water generation unit for soldiers in the field.  Instead of lugging around a large canteen filled with water, the small unit can produce water on demand.  The prototype was able to produce 5 liters of water per day per kilogram of adsorbent material.  Within three days in the field, the system outperforms packing water.  The heat required to precipitate the liquid water was provided by a standard-issue Army camping stove.

Non-military needs are the ultimate application for the device.  The researchers have applied for a patent for what they hope will be a potential solution to a persistent global problem.

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Producing water out of thin air

Photo, posted August 9, 2012, courtesy of Enid Martindale via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Cheap Material For Carbon Capture | Earth Wise

September 12, 2022 By EarthWise Leave a Comment

The recently passed Inflation Reduction Act includes significant support for carbon capture technologies. Eliminating fossil fuel burning is essential for halting climate change, but in the interim, methods for capturing emissions of carbon dioxide and either storing it or turning it into usable products are increasingly necessary.

There are a variety of techniques being developed for carbon capture but at this point, none of them are commercially viable.  The best technique in use today involves piping flue gases through chemicals called liquid amines, which bind CO2.  The process requires large amounts of energy to release the bound carbon dioxide so it can be concentrated and stored.  As a result, it is complicated and expensive.

Researchers at UC Berkeley, Stanford, and Texas A&M University have developed a carbon capture method using melamine, which is an inexpensive polymer used to make Formica, as well as low-cost dinnerware, industrial coatings, and other plastics.  Porous melamine itself adsorbs CO2 to a limited extent.  But the researchers discovered that adsorption could be much improved by adding the chemical DETA (diethylenetriamine) to bind the CO2.  In addition, adding cyanuric acid increased the melamine pore size and radically improved CO2 capture efficiency even more.

The result is a material that is more efficient even than exotic carbon capture materials like metalorganic frameworks and is much cheaper and easier to make. The researchers aim to design equipment that can used in industrial facilities, attached to buildings and other structures, or even to the tailpipes of gas-powered vehicles.

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A simple, cheap material for carbon capture, perhaps from tailpipes

Photo, posted June 10, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Harvesting Water From Air | Earth Wise

May 17, 2021 By EarthWise Leave a Comment

Solving the water crisis by harvesting it from the air

Developing new technologies that harvest water from the air is a growing field of research driven by the fact that more and more people live in areas where fresh water is in short supply.  Estimates are that roughly half the world’s population lives in regions with severe freshwater shortages for at least one month each year.

We have previously discussed some of the novel approaches that researchers are taking to enhance water harvesting.  The work at UC Berkeley using metalorganic frameworks is a notable example.

One of the key problems in harvesting water from air is that many droplets that condense from water vapor in the air are too small to be collected and when they cover a surface, they can actually impede further condensation.

University of Texas at Dallas researchers have developed a novel surface that encourages tiny water droplets to move spontaneously into larger droplets.  The droplets actually self-climb along an oil, ramp-shaped meniscus.  The meniscus acts like a bridge along which microdroplets spontaneously climb upward and coalesce with larger water droplets.  They call this the coarsening droplet phenomenon.  It is enabled by a liquid lubricant with a unique hydrophilic nature.  They actually discovered the lubricant’s special properties by accident when in a lubricant test they observed smaller water droplets propel themselves into larger droplets.

Based on experimental data, the coarsening surface enhances the water harvesting rate 200% higher than other techniques.  The team continues to work on ways to use the new lubricant to make sustainable water harvesting systems that are mobile, smaller in size, lower in weight, and less expensive.  If they are successful, they will essentially be able to harvest water anywhere that has air.

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New Physical Phenomenon Aids Harvest of Water from Air

Photo, posted April 26, 2014, courtesy of Toukou Sousui via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaning And Splitting Water

December 18, 2018 By EarthWise Leave a Comment

https://earthwiseradio.org/wp-content/uploads/2018/12/EW-12-18-18-Cleaning-and-Splitting-Water.mp3

Researchers at EPFL in Lausanne, Switzerland, have developed a photocatalytic system that can be used to degrade pollutants present in water while simultaneously producing hydrogen that can be captured and put to use.

[Read more…] about Cleaning And Splitting Water

Water From Desert Air

May 7, 2018 By EarthWise Leave a Comment

https://earthwiseradio.org/wp-content/uploads/2018/05/EW-05-07-18-Water-from-Desert-Air.mp3

Last spring, we talked about a solar-powered water harvester designed to pull water out of even dry desert air.   The prototype device was described in a paper by scientists at UC Berkeley and MIT in the journal Science.

[Read more…] about Water From Desert Air

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