Earth Wise

A look at our changing environment.

You are here: Home / Archives for manganese

manganese

Facemask pollution

By Leave a Comment

During the height of the Covid-19 pandemic, the global usage of disposable facemasks reached a staggering 129 billion per month. Most of these masks are manufactured from petroleum-based non-renewable plastics like polypropylene and the disposal of these masks results in serious pollution problems.  These include the loss of ecological integrity from buried waste in landfills, air pollution from increased waste incineration, and microplastic pollution. 

Recent research by engineers at Washington University in St. Louis investigated the multipronged pollution problem brought about by discarded facemasks.  The study in particular looked at the chemical changes that occur when facemasks are exposed to sunlight, water, and trace metal ions.

Masks littering the environment degrade into nanoplastics and produce reactive oxygen species.  These chemical agents interact with trace metal ions in the environment within hours.  The result is oxides of metals like manganese and iron, which can drive various biogeochemical reactions.

Abandoning and forgetting about plastics like facemasks is an unsustainable practice.  Plastics not only cause physical damage, but also introduce unpredictable and potentially dangerous chemical changes into environmental systems.

Plastic waste is a global problem that has continued to grow and become an increasingly serious threat over decades.  Understanding the nature of the effects of billions of facemasks in the environment is essential to efforts to address the challenges created by them.

**********

Web Links

Sun exposure changes chemical fate of littered face masks

Photo, posted August 21, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Recycling lithium-ion batteries

By Leave a Comment

Lithium-ion batteries are used to power computers and cellphones and, increasingly, vehicles.  The batteries contain lithium as well as various other valuable metals such as nickel, cobalt, copper, and manganese.  Like other batteries, lithium-ion batteries have a finite lifetime before they can no longer perform their intended function.

Recycling lithium-ion batteries to recover their critical metals is an alternative to mining those metals.  A recent study by Stanford University analyzed the environmental impact of obtaining those metals using lithium-ion battery recycling compared with mining.  They found that the recycling process is associated with less than half of the greenhouse gas emissions of conventional mining.  The process uses about one-fourth of the water and energy of mining new metals.  North America’s largest industrial-scale lithium-ion battery recycling facility is Redwood Materials, located in Nevada, which uses a clean energy mix that includes hydropower, geothermal, and solar power.

These calculated advantages are associated with recycling batteries that have been in use.  The advantages are even greater for recycling scrap:  defective material from battery manufacturers.

The advantages of recycling are dependent on the sources of electricity at the recycling plant and the availability of fresh water. 

At present, the U.S. recycles about half of its available lithium-ion batteries.  By comparison, 99% of lead-acid batteries (like those found in cars and trucks) have been recycled for decades.  As the supply of used lithium-ion batteries continues to increase, it is important for the availability of industrial-scale battery recycling to keep pace. 

**********

Web Links

Recycling lithium-ion batteries delivers significant environmental benefits

Photo, posted May 7, 2020, courtesy of Mark Vletter via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Deep sea mining

By Leave a Comment

Deep sea mining is the extraction of minerals from the ocean floor at depths greater than 660 feet and as much as 21,000 feet below the surface.  Active or extinct hydrothermal vents on the ocean floor create sulfide deposits which collect metals such as silver, gold, copper, manganese, cobalt, and zinc.  This forms polymetallic nodules – potato-sized rocklike deposits containing these valuable minerals.  There are literally trillions of these things scattered over wide areas of ocean floor.  The largest of these deposits are in the Pacific Ocean between Hawaii and Mexico in the Clarion Clipperton Fracture Zone.

Mining companies argue that land-based sources for valuable metals are running out and are critically needed for green technologies like batteries for electric vehicles and manufacturing solar panels and wind turbines.  They also claim that mining in the deep sea will be less environmentally damaging than land-based mining.

The deep sea is viewed by many as kind of a watery desert but there are actually diverse and rich ecosystems down there.  Most of the animals living in the depths are tiny, but that doesn’t make them any less important.  Many can live for a very long time.  Some invertebrates live for thousands of years.

There are currently no commercial deep sea mining operations underway.  Many countries have outlawed them.

The deep seas are the last mostly unexplored part of the Earth.  Deep sea mining will unquestionably be highly destructive to these environments.  We don’t really know what the impact of widespread deep sea mining might be, but the world continues to edge ever closer to allowing it to happen.

**********

Web Links

Can We Mine the World’s Deep Ocean Without Destroying It?

Photo, posted March 30, 2018, courtesy of the NOAA Office of Ocean Exploration and Research via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

By Leave a Comment

Existuje také spousta přípravků ve formě vitaminových a minerálních komplexů, které nasycují tělo všemi užitečnými zdroji pro správné fungování celého těla a sexuálního systému. Nejoblíbenější jsou dnes syntetické stimulanty, protože poskytují silný apothekeein.com a stabilní účinek, doplňky stravy a homeopatické léky se častěji používají pro prevenci problémů tohoto druhu.

The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications.  Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt. 

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly.  However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages.  The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers.   Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes.  This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

 Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese.  It could be the next big thing in electric vehicle batteries.

**********

Web Links

Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Water-Based Battery

By Leave a Comment

The transition from fossil fuel-based power plants to clean, renewable energy sources is accelerating as both wind and solar power get cheaper and increasingly become cost-competitive with traditional power sources.   The biggest stumbling block both energy sources face is that they cannot always supply power on demand but require the sun to shine and the wind to blow.

[Read more…] about A Water-Based Battery

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)