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Recycling lithium-ion batteries

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Lithium-ion batteries are used to power computers and cellphones and, increasingly, vehicles.  The batteries contain lithium as well as various other valuable metals such as nickel, cobalt, copper, and manganese.  Like other batteries, lithium-ion batteries have a finite lifetime before they can no longer perform their intended function.

Recycling lithium-ion batteries to recover their critical metals is an alternative to mining those metals.  A recent study by Stanford University analyzed the environmental impact of obtaining those metals using lithium-ion battery recycling compared with mining.  They found that the recycling process is associated with less than half of the greenhouse gas emissions of conventional mining.  The process uses about one-fourth of the water and energy of mining new metals.  North America’s largest industrial-scale lithium-ion battery recycling facility is Redwood Materials, located in Nevada, which uses a clean energy mix that includes hydropower, geothermal, and solar power.

These calculated advantages are associated with recycling batteries that have been in use.  The advantages are even greater for recycling scrap:  defective material from battery manufacturers.

The advantages of recycling are dependent on the sources of electricity at the recycling plant and the availability of fresh water. 

At present, the U.S. recycles about half of its available lithium-ion batteries.  By comparison, 99% of lead-acid batteries (like those found in cars and trucks) have been recycled for decades.  As the supply of used lithium-ion batteries continues to increase, it is important for the availability of industrial-scale battery recycling to keep pace. 

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Recycling lithium-ion batteries delivers significant environmental benefits

Photo, posted May 7, 2020, courtesy of Mark Vletter via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A better way to extract lithium

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Lithium is the critical component in the batteries that power phones and computers, electric cars, and the systems that store energy generated by solar and wind farms.  Lithium is not particularly rare, but it is difficult and often environmentally harmful to extract from where it is found.

Traditional ore sources are increasingly difficult and expensive to mine.  The largest known deposits of lithium are in natural brines – the salty water found in geothermal environments.  These brines also contain other ions like sodium, potassium, magnesium, and calcium, and efficiently separating out the lithium is extremely challenging.

Traditional separation techniques consume large amounts of energy and produce chemical waste, particularly hazardous chlorine gas.  These techniques typically suffer from poor selectivity; that is, the process is interfered with by the other ions present in natural brines.

A team of researchers at Rice University has developed a three-chamber electrochemical reactor that improves the selectivity and efficiency of lithium extraction from brines.  The middle chamber of the reactor contains a specialized membrane that acts as a barrier to chloride ions, preventing them from getting to the electrode area where they can form chlorine gas.

The new reactor has achieved a lithium purity rate of 97.5%, which means the setup can effectively separate lithium from other ions in the brine and allow the production of high-quality lithium hydroxide, the key material for battery manufacturing. 

The Rice University reactor design has the potential to be a game changer for lithium extraction from geothermal brines.

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‘Game changer’ in lithium extraction: Rice researchers develop novel electrochemical reactor

Photo, posted October 21, 2023, courtesy of Simaron via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium in Arkansas

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Lithium is the critical raw material in the batteries that power electric cars as well as cell phones, computers, and other gadgets.  The stuff has been nicknamed “white gold” for good reason.  Chile and Australia are the world’s largest producers of the metal, which is mostly extracted from brine in evaporation ponds.  The majority of it is then processed in China.  The energy industry has been increasingly working to produce the raw materials needed to produce lithium-ion batteries in the United States and process those materials domestically.  There are multiple projects at various stages across the country.

Researchers at the US Geological Survey and the Arkansas state government recently announced that they have discovered a vast trove of lithium in an underground brine reservoir in Arkansas.

With a combination of water testing and machine learning, the researchers determined that there could be 5 to as much as 19 million tons of lithium in the geological area called the Smackover Formation.  This is more than enough to meet all the world’s demand for it.

Several companies – including Exxon Mobil, which is covering its bets on the future of oil as an energy source – are developing projects in Arkansas to produce lithium.  If these companies can develop and scale up economical new ways to extract lithium from salty water, the region in Arkansas could become the lithium capital of the world.

Energy and mining companies have produced oil, gas, and other natural resources in the Smackover Formation, which extends from Texas to Florida.  The same brines have long been the source of other valuable substances. 

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Arkansas May Have Vast Lithium Reserves, Researchers Say

Photo, posted May 22, 2020, courtesy of the European Space Agency via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Minerals from seawater

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There are about 18,000 desalination plants around the world that take in 23 trillion gallons of water each year.  The plants produce more than 37 billion gallons of brine – enough to fill 50,000 Olympic-size swimming pools – every day.  Disposing of this brine is an ongoing challenge.  Dumping it into the ocean can damage marine ecosystems.  Inland desalination plants either bury this waste or inject it into wells, adding further cost and complexity to the already expensive process of desalination.

According to researchers at Oregon State University, this waste brine contains large amounts of copper, zinc, magnesium, lithium, and other valuable metals.  A company in Oakland, California called Magrathea Metals has started producing modest amounts of magnesium from waste brine in its pilot projects.  With support from the U.S. Defense Department, it is building a larger-scale facility to produce hundreds of tons of the metal over two to four years. 

Most of the world’s magnesium supply comes from China, where producing it requires burning lots of coal and utilizing lots of labor.  Magrathea’s brine mining makes use of off-peak wind and solar energy and is much less labor intensive.

No large-scale brine mining operations currently exist and when there are some, they might end up having negative environmental impacts.  But in principle, the process should produce valuable metals without the massive land disturbance, acid-mine drainage, and other pollution associated with traditional mining.  Brine mining could turn a growing waste problem into a valuable resource.

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In Seawater, Researchers See an Untapped Bounty of Critical Metals

Photo, posted February 18, 2017, courtesy of Jacob Vanderheyden via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium in Arkansas

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There are more and more electric cars on the road and utilities are installing record amounts of battery storage to back up solar and wind power generation.  Both of these things currently use lithium-ion batteries so the need for them keeps growing.

There is actually plenty of lithium in the world.  Sources of more than 100 million tons have been identified, which is enough to meet the projected needs for decades.  But lithium is not easy, cheap, or environmentally friendly to extract.  It is either blasted out of rocks that are then roasted at 2000-degree temperatures, or it is extracted from brine in places like the high Andes where it leaves behind toxic residues.  Ramping up lithium production could greatly diminish the environmental benefits derived from green technologies.

A technique called direct lithium extraction, or DLE, may be a possible solution.  The lithium is pulled out of brine while leaving other dissolved compounds behind.  It is being tested in many places around the world and appears to offer the lowest negative impacts of available extraction technologies.

The Salton Sea area in California has rich deposits of lithium and is a good candidate for DLE.  But conditions may be even better in Arkansas whose Smackover Formation is a brine-rich expanse of limestone. 

The area was a productive oil field a hundred years ago and then undertook brine-processing in the 1950s to extract bromine.  So, the area already has industrial infrastructure and no new land would need to be cleared.

The former oil fields of Arkansas may become an important domestic source of lithium.

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In Rush for Lithium, Miners Turn to the Oil Fields of Arkansas

Photo, posted February 26, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Sodium-ion batteries

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The transition away from fossil fuels is driving a rapidly increasing need for batteries.  Both electric vehicles and energy storage for the electric grid are enormous consumers of batteries.  At present, lithium-ion batteries are almost universally used for these purposes.  They have been getting better all the time and cheaper all the time and are likely to be the answer for the foreseeable future.  But they are not perfect.

Lithium is only found in a relatively small number of places and mining and extracting it is fairly expensive and environmentally unfriendly.  Lithium-ion batteries also frequently contain cobalt, which has its own set of problems.  There are also safety issues related to the flammability of lithium-ion batteries. 

As a result, there continue to be numerous efforts to identify and develop alternative battery technologies.  One of these is sodium-ion batteries, which are similar in many ways to lithium-ion batteries but in which sodium replaces lithium as the cathode material.

Sodium is extremely common – it’s found in ordinary salt – and sodium-ion batteries have a high energy density and are easy to produce.  They should have a long lifetime and have a more benign environmental impact than lithium-ion.  Many companies and researchers are working on sodium-ion batteries and are making good progress.

A study by Chalmers University in Sweden looked at the potential for sodium-ion batteries and found that the batteries are particularly promising for use in energy storage even in their current state of development and could eventually be used in cars.  Whether sodium-ion batteries can be good enough and cheap enough quickly enough to give lithium-ion a run for its money remains to be seen.

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Resource-efficient and climate-friendly with sodium-ion batteries

Photo, posted March 12, 2013, courtesy of Chris Hunkeler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Huge American Lithium Discovery | Earth Wise

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Human history has often been described in terms of a succession of metal ages:  the copper age, the bronze age, and the iron age.  In many ways, we have now entered the lithium age.  The light metal goes into the batteries that power smartphones, electric vehicles, and massive storage banks for the power grid.  Lithium has become a critical strategic resource.

As it stands now, the U.S. gets most of its lithium from imports from Australia and South America.  Major lithium sources are not commonplace; in 2022 there were only 45 lithium mines in the world.  Many of the known deposits are not in North America but in Chile, Bolivia, Argentina, China, and Australia.  The current largest known lithium deposits lie beneath the salt flats of Bolivia.

Lithium Americas Corporation, a company dedicated to advancing lithium projects to the stage of production, funded research over the past decade that has identified vast deposits of lithium-rich clay in a dormant volcanic crater along the Nevada-Oregon border.  The McDermitt Caldera is estimated to hold between 20 and 40 million tons of lithium, which would make it the largest deposit in the world.

There are many questions still to answer.  It is not clear how easy it will be to extract lithium from the clay, in particular how expensive or carbon-intensive it will be.  There are also political complexities since the area where the lithium deposit was found is considered to be unceded ancestral land for both the Paiute and Shoshone tribes.

Apart from a dearth of domestic sources of lithium, the US also lags well behind China in lithium processing capabilities.  The country has catching up to do in the new lithium age.

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America Just Hit the Lithium Jackpot

Photo, posted April 19, 2020, courtesy of Ken Lund via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium In The Salton Sea | Earth Wise

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The Salton Sea is a shallow, landlocked, extremely salty body of water in the southern end of California.  It was formed from an inflow of water from the Colorado River in 1905 in the aftermath of a collapse of a canal during spring floods.  At one time, it was a thriving tourist destination and site of real estate speculation.  It was also a crucial habitat for migratory birds and various aquatic species.

Over the past 20 years, the Salton Sea has become increasingly desiccated and polluted with agricultural runoff and waste.  Rising salinity and the shrinking water supply from the Colorado River has made it uninhabitable for many species.

Recently, the Salton Sea has attracted new attention because of untouched lithium deposits located beneath its shores.  The general area has acquired the moniker “Lithium Valley” and has become a place where major energy companies are exploring advanced mining techniques such as Direct Lithium Extraction (DLE).  This new technique enables lithium to be captured from brine deposits without resource-intensive open-pit mining or evaporation pond processes.

Lithium is crucial for making the batteries that power electric vehicles.  DLE mining has attracted large investments from billionaires like Warren Buffet, Bill Gates, and Jeff Bezos. 

Lithium mining has generated major controversies because of its potential to damage the environment.  Whether the new mining techniques can avoid these problems and tap into the potential resources near the Salton Sea remains to be seen.  According to experts, the aquifers near the Salton Sea hold enough lithium to supply close to 40% of the global demand.

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As Companies Eye Massive Lithium Deposits in California’s Salton Sea, Locals Anticipate a Mixed Bag

Photo, posted October 28, 2021, courtesy of Christian Collins via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Big Oil And Big Lithium | Earth Wise

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The world’s big oil companies have worked pretty hard to prolong society’s dependence on petroleum.  When there are trillions of dollars at stake, there is plenty of motivation.  But those companies do see the writing on the wall.

An Exxon Mobil-funded study last year estimated that light-duty vehicle demand for combustion engine fuels could peak in 2025 and that electric vehicles of various types could grow to more than 50% of new car sales by 2050.  This is pretty pessimistic compared with most other surveys, but it is still a big number.  Exxon also projected that the global fleet of EVs could reach 420 million by 2040.

As a result of all this, Exxon is preparing for a future far less dependent on gasoline by drilling for lithium rather than oil.  The company recently purchased mining rights to a sizable chunk of Arkansas land for over $100 million from which it aims to produce lithium for electric car batteries.

Exxon’s consultants estimated that the 120,000 acres in the Smackover formation of southern Arkansas could have as much as 4 million tons of lithium carbonate, enough to power 50 million cars and trucks. 

Exxon plans to spend $17 billion through 2027 on cutting carbon emissions and developing low carbon technologies.  Other large oil producers have also been looking at the lithium business.  At the same time, some large oil companies like BP and Shell are investing in renewable energy.

The prospect of EVs dominating transportation in the coming decades is a strong incentive for oil-and-gas companies to adapt their businesses to the new world.

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Exxon Joins Hunt for Lithium in Bet on EV Boom

Photo, posted August 16, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Falling Lithium Prices | Earth Wise

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Lithium, the key element in the batteries that power electric cars, as well as smartphones, tablets, and laptop computers, is sometimes called white gold.  Over time, the price of the metal has gone up and up.  But recently, and surprisingly, the price of lithium has actually gone down, helping to make electric vehicles more affordable.

Over the first couple of months of this year, the price of lithium has dropped by nearly 20%.  The price of cobalt, another important component of vehicle batteries, has fallen by more than half.  Even copper, another battery material, has seen its price drop by 18%.

Many analysts predicted that prices of these commodities would stay high or even climb higher.  The reason for the decline, as well as whether it is likely to persist, is the subject of much debate.

Some experts believe that the price drops are a result of demand not being as high as expected, perhaps related to slowing sales growth of EVs in Europe and China after certain subsidies expired.  Other industry experts said that the drop was a result of new mines and processing plants providing additional supply sooner than was thought possible.

Despite the price drops, mining and processing lithium remains an extraordinarily profitable business.  It costs from $5,000 to $8,000 to produce a ton of lithium that sells for ten times that amount.  With such fat profit margins, there is no shortage of banks and investors eager to finance lithium mining and processing projects.  Such profit margins are probably not sustainable and that will likely result in more reasonable prices over time.

There is plenty of lithium in the world.  The huge demand for it is a recent phenomenon and the world is still working out how to meet that demand.

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Falling Lithium Prices Are Making Electric Cars More Affordable

Photo, posted January 9, 2023, courtesy of Phillip Pessar via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Electric Cars Getting Cheaper | Earth Wise

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A sticking point for buying electric cars has always been that they are typically more expensive than equivalent gasoline-powered cars.  But increasing competition, government incentives, and falling prices for lithium and other battery materials is changing the equation.  In fact, the tipping point when electric cars are as cheap or even cheaper than internal combustion cars is likely to happen this year for many cars and, in fact, has already happened for some.

Battery production is ramping up for Tesla, General Motors, Ford, and others, creating cost savings from mass production. Companies manufacturing batteries in the United States are receiving government subsidies as part of a drive to establish a domestic supply chain and reduce dependence on China.  Before anyone cries foul, it should be noted that globally, oil companies received a trillion dollars in subsidies last year.  The Inflation Reduction Act is making it cheaper for automakers to build electric cars (provided they do it in the United States using US materials) and cheaper for consumers to buy them because of tax credits.

Multiple companies have lowered the price of their electric vehicles in recent months, including both the Tesla Model 3 and Model Y, which are the best-selling electric cars in the United States. GM’s electric Equinox crossover will start at about $30,000, which is still about $3,400 more than the gas-powered version.  But once the electric vehicle tax credit is figured in, it will actually be cheaper.

Electric cars are already cheaper to own and operate because of the much lower cost of powering with electricity instead of gas as well as the greatly reduced maintenance costs for the vehicles.  Once the purchase price of these cars is less than that of gas-powered cars, the economics becomes a no-brainer.

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Electric Vehicles Could Match Gasoline Cars on Price This Year

Photo, posted May 11, 2021, courtesy of Chris Yarzab via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Mining Metals From Water | Earth Wise

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Researchers at the Department of Energy’s Pacific Northwest National Laboratory in Richland, Washington are working with industry to develop a method of extracting valuable materials from various sources of water.  The technique is the 21st-century equivalent of panning for gold in rivers and streams.

The patent-pending technology makes use of magnetic nanoparticles that are surrounded by an absorbent shell that latches on to specific materials of interest that are found in certain water sources.  These sources could include water in geothermal power plants (known as geothermal brines), water pulled from the subsurface during oil or gas production, or possibly effluents from desalination plants.  Extracting valuable materials from geothermal brines could greatly enhance the economics of geothermal power plants.

The initial focus of the development is on lithium, which is an essential element in many high-technology applications, especially in the batteries that power cell phones, computers, and electric cars.  The global market for lithium is projected to reach over $8 billion a year by 2028 and very little of it is currently produced in the United States.

The tiny particles are added to the water and any lithium is drawn out of the water and is bound to them.  Using magnets, the nanoparticles can be readily collected.  Once the particles are no longer suspended in liquid, the lithium can easily be extracted, and the nanoparticles can be reused.

PNNL is developing the technology in partnership with a company called Moselle Technology as well as with other commercial partners.  This new technology offers the promise of extracting critical materials in a quick, cost-effective manner.

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Tri-Cities Scientists “Magically” Mining Metals From Water

Photo, posted June 4, 2012, courtesy of Tom Shockey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

An Iron-Air Battery Plant | Earth Wise

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Lithium-ion batteries are the standard energy source for electric vehicles, and they are also the dominant technology for storing energy in the electric grid.  However, they are not the only game in town.  There are other battery technologies that have various potential advantages over lithium-ion and some of them are getting the chance to show what they can do.

One is the iron-air battery.  Unlike lithium-ion batteries that require expensive and strategically challenging materials like lithium, cobalt, nickel, and graphite, iron-air batteries make use of one of the most common elements in the earth’s crust.

Iron-air batteries operate on a principle known as “reversible rusting”.  When discharging, the battery takes in oxygen from the air and converts iron into rust.  While charging, electrical current converts rust back into iron and the battery releases oxygen.  Batteries consist of a slab of iron, a water-based electrolyte, and a membrane that feeds a controlled stream of air into the battery. 

A Massachusetts-based company called Form Energy is building a $760 million iron-air battery storage facility in the city of Weirton in West Virginia.  Investment financing along with a $290 million government incentive package is paying for the facility. 

The facility is designed to address the need for long-duration energy storage and will be capable of storing electricity for 100 hours at competitive prices.  The battery modules will be about the size of a side-by-side washer/dryer and will contain a stack of 50 3-foot-tall cells.  Such batteries are too big and heavy for use in cars but will be cheaper and higher-capacity than equivalent lithium-ion battery systems.

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Form Energy selects West Virginia for its first iron-air battery plant

Photo credit: Form Energy

Earth Wise is a production of WAMC Northeast Public Radio

The Race For EV Batteries | Earth Wise

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Lithium-ion batteries have been the power source for electric vehicles since 2008, when the Tesla Roadster was introduced.  They took over for nickel-metal hydride batteries that powered most hybrid electric cars such as the Prius.  Lithium-ion batteries store much more energy for a battery of a given weight, which leads to greater driving range.

But lithium-ion is not an ideal solution.  The batteries depend on critical materials that are obtained by hacking into mountains, utilizing scarce desert groundwater, and in some cases, making use of child labor. Many materials depend on countries with whom economic ties have complicated geopolitical consequences.

State and federal mandates and incentives are pushing auto companies to prioritize electric vehicles in their future plans.  The Inflation Reduction Act in particular provides credits and other incentives for both consumers and manufacturers to electrify. So, sources for EV batteries are a key issue.

The Department of Energy is funding 20 different companies with $2.8 billion to bolster the production and processing of critical minerals in the U.S.  The goal is to bring the electric vehicle supply chain onshore to the greatest extent possible.  Some of the work involves redesigning lithium-ion batteries to reduce or eliminate problematic materials such as cobalt.  Other efforts seek to find domestic sources of critical materials such as lithium without causing serious environmental problems.

Given all this, it is no surprise that academic and industrial researchers are also exploring a wide variety of alternative battery technologies. 

The future of transportation is electrification and the race for EV batteries is on.

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For U.S. Companies, the Race for the New EV Battery Is On

Photo, posted August 27, 2021, courtesy of Ron Frazier via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium Mining And Andes Ecosystems | Earth Wise

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A remote region in the high Andes straddling the borders between Argentina, Bolivia, and Chile has become known as the Lithium Triangle.   The area has become the focus of a global rush for lithium to make batteries for electric cars.  The global demand for lithium is expected to quadruple by 2030 to 2.6 million tons a year.

According to the U.S. Geological Survey, more than half of the world’s lithium reserves are dissolved in ancient underground water within the Lithium Triangle.  The cheapest way to extract the lithium is to pump the underground water to the surface and evaporate it in the sun to concentrate the lithium carbonate contained in it.

Every ton of lithium carbonate extracted using this cheap, low-tech method dissipates into the air about half a million gallons of water that is vital to the arid high Andes.  The process lowers water tables and has the potential to dry up lakes, wetlands, springs, and rivers.  Hydrologists and conservationists say the lithium rush in Argentina is likely to turn the region’s delicate ecosystems to deserts.

The global drive for green vehicles to fight climate change has the potential to be an ecological disaster in this remote region of South America and for the indigenous people who live there.

The environmental impacts are not an inevitable price for the transition to electric vehicles.  First of all, there are alternatives to lithium.  Both zinc and nickel are potential substitutes in rechargeable batteries.  But, there are also ways of obtaining lithium that are less destructive than evaporating the metal from saline ecosystems.  It is up to battery manufacturers, automakers, and financiers to start demanding lithium from sources that are less environmentally destructive.

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Why the Rush to Mine Lithium Could Dry Up the High Andes

Photo, posted September 25, 2015, courtesy of Nuno Luciano via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Lithium-Sulfur Batteries | Earth Wise

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The growing use of electric vehicles as well as energy storage systems has created a major focus on the batteries for these applications.  Lithium-ion batteries dominate these applications and the demand for the materials needed to manufacture them continues to grow.

The raw materials for these batteries include not only lithium, but also can include nickel, manganese, and cobalt. 

Sulfur has been a desirable alternative for use in lithium-based batteries for quite a while because it is an abundant element and can be extracted in ways that are safe and environmentally friendly.  However, previous attempts to create lithium batteries that combine sulfur cathodes and the standard carbonate electrolytes used in lithium-ion batteries have not been successful because of irreversible chemical reactions between intermediate sulfur products and the electrolytes.

A group of chemical engineers at Drexel University has now found a way to introduce sulfur into lithium-ion batteries that solves the stability problem and also has major performance advantages.  The new batteries have three times the capacity of conventional lithium-ion batteries, and last more than 4,000 recharges, which is also a substantial improvement.

The new battery technology involves creating a stable form of sulfur called monoclinic gamma sulfur by depositing the sulfur on carbon nanofibers.   Previously, this sulfur phase was only observed at high temperatures and was only stable for 20 or 30 minutes.  This chemical phase of sulfur does not react with carbonate electrolytes and therefore produces a battery that is chemically stable over time.

 Incorporating this sulfur into battery cathodes results in a better battery that doesn’t need any cobalt, nickel, or manganese.  It could be the next big thing in electric vehicle batteries.

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Breakthrough in Cathode Chemistry Clears Path for Lithium-Sulfur Batteries’ Commercial Viability

Photo, posted April 5, 2022, courtesy of Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

The Race For American Lithium Mining | Earth Wise

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The auto industry is making a massive transition from gas-powered cars to electric cars.  The exploding electric vehicle market has set off what some call a global battery arms race.  Battery manufacturers are urgently trying to source the raw materials needed to make batteries, which presently include cobalt, nickel, graphite, and lithium.  There is encouraging progress in reducing and even eliminating cobalt and nickel from electric car batteries, but so far lithium seems to be essential.

The International Energy Agency has named lithium as the mineral for which there is the fastest growing demand in the world.  Estimates are that if the world is to meet the global climate targets set by the Paris Agreement, at least 40 times more lithium will be needed in 2040 compared with today.

According to the US Geological Survey, the US has about 9 million tons of lithium, which puts it in the top 5 most lithium-rich countries in the world.  Despite this, our country mines and processes only 1% of global lithium output.  Most of the rest comes from China, Chile, and Australia.  Being dependent upon these foreign sources is a serious concern for national security.

There is only one operational lithium mine in the US at present.  Multiple companies are pressing to get more mining projects in operation, including sites in North Carolina and Nevada.  But there are serious environmental problems associated with lithium mining and there is considerable local opposition to establishing the mines.

The US wants to be a leader in the global race to build the batteries that will power the green transition but it is a complicated situation that combines both undeniably important benefits as well as very real dangers.

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Powering electric cars: the race to mine lithium in America’s backyard

Photo, posted January 18, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Iron Flow Batteries | Earth Wise

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Lithium-ion batteries power computers, cell phones, and increasingly, automobiles.  They started out being rather expensive but have become dramatically cheaper over the last decade, with prices dropping about 90%.  Batteries are needed to store clean power from wind and solar generation and lithium-ion batteries are increasingly being used for that purpose as well.

Utility-scale energy storage requires substantial battery installations and battery cost is still very much an inhibiting factor in the widespread adoption of the technology.  Lithium-ion battery costs continue to drop but because they require expensive materials like lithium and cobalt, there are limits to how low their prices are likely to get.

As a result, researchers have continued to seek ways to produce batteries made out of cheaper materials.  Among the more promising technologies are flow batteries, which are rechargeable batteries in which electrolyte flows through electrochemical cells from tanks. 

Flow batteries are much larger than lithium-ion batteries and include physical pumps to move electrolytes.  They typically are sold inside shipping containers.  Clearly, such batteries are not suitable for use in vehicles, much less in consumer electronics.  Nevertheless, they represent a practical option for grid storage.

A company called ESS has developed an iron flow battery suitable for utility energy storage.  Clean energy firm CSB Energy plans to install iron flow batteries at several solar projects across the U.S. that will store enough energy to provide power 50,000 homes for a day.  According to ESS, the iron-based batteries should sell for about half the price of lithium-ion batteries by 2025 and be able to store energy for longer periods.

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New Iron-Based Batteries Offer an Alternative to Lithium

Photo, posted March 21, 2021, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Busting Electric Vehicle Myths | Earth Wise

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From the early days of hybrid vehicles right on through the current booming market for electric cars, there has been the contention by some people that these cars are responsible for comparable or even greater amounts of greenhouse gas emissions over their product lifetimes.  The arguments generally centered around the carbon costs of creating batteries for the cars as well as the emissions associated with generating the electricity used to charge them.

A new study published by the International Council for Clean Transportation reports a life cycle assessment (or LCA) that considers every source of carbon generated from the cradle to the grave of the vehicle.

Included in the assessment are the mining costs of the lithium to make batteries, the transportation of batteries across the world by container ship, the end-of-life burden, the mix of energy generation in various places around the world, and so on.

The results of the analysis are that even in India and China, which are the biggest burners of coal and oil on earth, it still results in lower emissions to drive an EV instead of an internal combustion vehicle.

Lifetime emissions of today’s average medium-size EVs are lower than comparable gasoline cars by 66-69% in Europe, 60-68% in the US, 37-45% in China, and 19-34% in India.  As electricity generation continues to further decarbonize, all these numbers will only get better.  While it is somewhat more carbon-intensive to manufacture an EV, it doesn’t take very long in the car’s life to come out ahead owning one.

Early skeptics of EVs and hybrids had more legitimate concerns a decade or so ago, but the advantages of these vehicles are now unambiguous.

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One of the Biggest Myths About EVs is Busted in New Study

Photo, posted December 30, 2020, courtesy of Chris Yarzab via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Minerals And Metals For A Low-Carbon Future | Earth Wise

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For the past century, economies and geopolitics have largely been driven by our insatiable appetite for oil and fossil fuels in general.  As we gradually make the transition to a low-carbon energy future, the focus on oil will shift to sustainable supplies of essential minerals and elements.

The use of solar panels, batteries, electric vehicle motors, wind turbines, and fuel cells is growing rapidly around the world.  These technologies make use of cobalt, copper, lithium, cadmium, and various rare earth elements.  The need for any one of these things may diminish if alternatives are found, but there will continue to be a growing reliance on multiple substances whose physical and chemical properties are essential to the function of modern devices and technologies.

In some cases, global supplies of particular minerals and elements are dominated by a particular country, are facing social and environmental conflicts, or face other market issues.  Shortages of any of them could create economic problems and derail progress much as the oil-related energy crises of the past have.

The world faces challenges in managing the demand for low-carbon technology minerals as well as limiting the environmental and public health damage that might be associated with their extraction and processing.  Expanded use of recycling and reuse of rare minerals will be essential.

As the relatively easy sources of these materials become exhausted, other resources will become more attractive.  These include various valuable ecosystems, oceanic deposits, and even space-based reserves.

Ushering in the low-carbon future is not a simple matter and will require responsible actions by the world’s governments and industries. In undoing the damage from the oil age, we must avoid new damage from the low-carbon age.

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Sustainable supply of minerals and metals key to a low-carbon energy future

Photo, posted March 13, 2015, courtesy of Joyce Cory via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)