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A green battery from industrial waste

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Flow batteries are rechargeable batteries in which liquid electrolytes flow through one or more chemical cells from one or more tanks.  The electrolytes are redox pairs, that is, chemical compounds that can reversibly undergo reduction and oxidation reactions.  The most common redox electrolytes include elements like vanadium, chromium, iron, zinc, and bromine.  Flow batteries can provide large amounts of both electrical power and stored energy based on the size of the electrolyte tanks.  As a result, they can be scaled up far more readily than other battery technologies. 

Flow batteries are safe, stable, long-lasting, and their electrolytes can easily be refilled.  They have significant potential for use in utility-scale storage for renewable energy systems.

Researchers at Northwestern University have developed a redox flow battery based on an organic industrial-scale waste product.  The material – triphenylphosphine oxide or TPPO – is produced in the thousands of tons each year.  It is byproduct of producing a variety of substances including some vitamins, pharmaceuticals, agrochemicals, and other bulk chemicals.  For the most part, TPPO is of little use and must be carefully discarded.

The current market for redox flow batteries is very small but is expected to grow over time as the need for utility-scale energy storage continues to expand.  A battery technology based on a waste material that is already produced in high volume and that must otherwise be disposed of with caution would have significant advantages.

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Green battery discovery turns trash into treasure

Photo, posted January 12, 2015, courtesy of California Energy Commission via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Climate change and Antarctic meteorites

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Researchers from Switzerland and Belgium have investigated the effects of the warming climate on access to meteorites in Antarctica.  Meteorites are of great scientific interest because they provide unique information about the makeup of our solar system.  Of all the meteorites that people have found, 62.6% of them were found in Antarctica.

Why is this?  It is not because more meteorites land in Antarctica.  Statistically, they can land anywhere on earth.  Most end up in the ocean since the world’s oceans cover 70% of the planet. 

Meteorites in Antarctica are more visible because environmental conditions are favorable for their preservation and their visibility.  The arid and cold Antarctic environment helps to preserve meteorites and the lack of rocks and contrast with ice makes spotting meteorites much easier.  The flow of ice sheets tends to concentrate meteorites in so-called meteorite stranding zones where the dark colored space rocks can be easily detected.

There are an estimated 300,000 to 800,000 meteorites in Antarctica.  When meteorites warm up, they can transfer heat to the ice, which locally melts.  Eventually, the meteorites sink beneath the surface.  A recent study using satellite imagery, climate model projections, and AI predicts that for every tenth of a degree of increase in global air temperature, an average of 9,000 meteorites in Antarctica will disappear from the surface and will no longer be able to be found. 

The study estimates that a quarter of Antarctic meteorites will be lost to glacial melt by 2050.  If warming continues to accelerate, closer to three-quarters of the meteorites on the continent will be lost. 

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Climate change threatens Antarctic meteorites

Photo, posted April 21, 2005, courtesy of Kevin Walsh via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

El Paso’s Water Future | Earth Wise

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El Paso, Texas is part of the Paso del Norte region, which includes Ciudad Juarez in Mexico and Las Cruces, New Mexico.  The population on both sides of the border is booming, approaching 3 million people.  The region’s primary water source is the Rio Grande River.  But that river is declining.

Rising temperatures and decreasing rainfall have led to diminishing flow in the river.  Eighty percent of the river’s flow has historically been diverted to agriculture, but the reduced flow of the Rio Grande has forced many farmers to reduce planting or change to less water-hungry crops.  The river is expected to continue to decrease its flow as time goes by.

The city of El Paso gets 40% of its water supply directly from the Rio Grande.  Urban water authorities in the region are scrambling to find ways to provide cities with alternative supplies of water.

El Paso now gets some of its water from a desalination plant, which is the world’s largest inland municipal desalination plant.  The water comes from brackish groundwater rather than from the sea.  The briny waste from the plant is piped to an injection well many miles way and is permanently stored 4,000 feet underground.

El Paso continues to seek new water sources and reduce its water use.  It gets much of its water from wells drilled in nearby aquifers.  It is working to make this use of groundwater more sustainable.  The city recycles used residential water through its so-called purple pipe system, which cleans up waste water and delivers it for non-potable use on golf courses and park lawns. 

Like many places in the increasingly dry west, El Paso’s water future is uncertain. 

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As Rio Grande Shrinks, El Paso Plans for Uncertain Water Future

Photo, posted April 29, 2018, courtesy of R. Baire via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pumped Hydro Storage In Switzerland | Earth Wise

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Pumped hydro energy storage is still by far the largest form of energy storage in the world, representing more than 90% of storage capacity worldwide.  The theory behind it is simple.  Water is pumped into an upper reservoir (that is, one at a higher elevation), and when electricity is needed, the water is allowed to flow downhill to power turbines and then is collected in a lower reservoir.   When there is excess electricity, it is used to pump water back uphill for use later.

Pumped hydro installations can’t be built just anywhere.  Geography and hydrology have to be suitable, which means high voltage transmission lines need to be constructed to link electricity sources like wind and solar farms with the storage location.  But in those situations where pumped hydro makes sense, it is a great solution to the energy storage problem.

Switzerland has just completed one of the largest pumped hydro facilities in the world.  The Nant de Drance installation makes use of the Emosson reservoir, which is an artificial lake built high in the Alps near the French border.  Over the past 14 years, 10 miles of tunnels have been dug into the mountains to connect the Emosson reservoir to the Vieux Emosson reservoir to the south.

In between the two reservoirs is a giant underground cavern where six of the largest water-driven turbines in the world are spun from the water rushing down from above.  The turbines have a capacity of 900 megawatts, making Nant de Drance one of the most powerful generating plants in Europe.  In terms of storage capacity, the installation has a maximum capacity of 20 gigawatt-hours, and can store that energy indefinitely, which is challenging for other storage technologies.

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14 Years In The Making, 20 GWh Pumped Hydro Storage Facility Comes To Switzerland (With Video)

Photo, posted September 7, 2009, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Antarctic Ice Collapse | Earth Wise

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In Antarctica, a huge chunk of the Larsen B Ice Shelf collapsed suddenly and spectacularly in January.

The Larsen Ice Shelf is located on the northeastern side of the Antarctic Peninsula on the Weddell Sea.  It was formed over the course of more than 12,000 years.  The Weddell Sea used to be a completely frozen body of water.  The famous Ernest Shackleton expedition in 1915 was trapped in its ice.  But the Antarctic Peninsula has been steadily warming in recent decades.

The Larsen A Ice shelf collapsed in 1995 and the 1,250-square-mile Larsen B Ice Shelf collapsed in 2002.  After that event, a portion of the detached ice shelf refroze in 2011 and was attached to the Scar Inlet Ice Shelf.  The refrozen ice was called the Larsen B embayment.

In January, the embayment broke apart, taking with it a portion of the Scar Inlet Ice Shelf.  It disintegrated within a matter of days.  The combined Larsen Ice Shelves – called A, B, C, and D – once extended along a 1000-mile stretch of the eastern Antarctic Peninsula.  Since 1995, it has shrunk from 33,000 square miles to 26,000 square miles.

These ice shelves float on the ocean, so their loss does not actually increase global sea levels.   However, the shelves act as dams that hold back glaciers located on the land behind them.  The loss of Antarctic ice shelves dramatically increases the rate at which glaciers flow into the sea, and that does increase global sea levels. 

Now that the sea ice from the Larsen B embayment is gone, it is likely that there will be additional inland ice losses from the newly exposed glaciers.

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Remnant of Antarctica’s Larsen B Ice Shelf Disintegrates

Photo, posted February 13, 2018, courtesy of NASA/Nathan Kurtz via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Room-Temperature Superconductor | Earth Wise

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One of the Holy Grails of science has apparently been found:  a room-temperature superconductor.   In a paper recently published in Nature, scientists from the University of Rochester and collaborators announced that they had observed superconductivity at 59 degrees Fahrenheit in an exotic material they produced in the laboratory.

Superconductivity is a phenomenon occurring in certain materials characterized by the total absence of electrical resistance.  Current flowing in a closed loop of superconducting wire can go on forever.  Superconductors have other unique characteristics as well, all of which combine to make them quite useful in a number of applications.  Superconductors are used in high-powered magnets in particle accelerators and in MRI machines.  They continue to be developed for use in electrical power transmission, energy storage, communication filters, magnetic sensors, and more.

The problem with superconductors is that they only work at very low temperatures.  For most of a century – after superconductivity was discovered in 1911 – those temperatures were very close to absolute zero:  459 degrees below zero Fahrenheit.  (In the late 1980s, so-called high-temperature superconductors were discovered.  Those materials superconduct at the temperature of liquid nitrogen:  about 320 degrees below zero).

The dream has been to find a superconductor that works at ambient temperatures.  The Rochester team has produced tiny amounts of a mysterious combination of hydrogen, carbon, and sulfur which, when subjected to extraordinarily high pressures (over 2 million atmospheres), superconducts at the temperature of a pleasant fall day.

 There is no practical value for this first room-temperature superconductor, but it proves that superconductivity can exist at ambient temperature.  Once something is shown to exist at all, there is reason to hope that it can occur in ways that are easier and more practical to attain.

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First room-temperature superconductor excites — and baffles — scientists

Photo, posted June 18, 2013, courtesy of Oak Ridge National Laboratory via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Figuring Out Photosynthesis | Earth Wise

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Plants have been harnessing the sun’s energy for hundreds of millions of years. Algae and photosynthetic bacteria have been doing the same for even longer, all with remarkable efficiency and resiliency. 

People have used the energy of the sun in one way or another for millennia, but only recently have we gotten sophisticated about it by using devices like solar panels and sensors.  And we still have a long way to go to get anywhere close to the efficiency of plants. It’s no wonder, then, that scientists have long sought to understand exactly how photosynthesis works.

Scientists from the U.S. Department of Energy’s (DOE) Argonne National Laboratory, and collaborators at Washington University in St. Louis, recently solved a critical part of the age-old mystery of photosynthesis, studying the initial, ultra-fast events through which photosynthetic proteins capture light and use it to initiate a series of electron transfer reactions.  Electrons in plants have two possible pathways to travel but only use one.   

But as a result of their efforts, the scientists are now closer than ever to being able to design electron transfer systems in which they can send an electron down a pathway of their choosing. 

By gaining the ability to harness the flow of energy, it may be possible to incorporate new design principles in non-biological energy systems. This could allow us to greatly improve the efficiency of many solar-powered devices, potentially making them far smaller. Understanding the intricacies of photosynthesis creates a tremendous opportunity to open up completely new disciplines of light-driven biochemical reactions, perhaps even ones that haven’t been envisioned by nature.

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Scientists unravel mystery of photosynthesis

Photo, posted June 14, 2017, courtesy of Alex Holyoake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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