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electrons

Better Zinc Batteries | Earth Wise

May 17, 2023 By EarthWise Leave a Comment

The rapid growth of wind and solar power continues to drive a global quest for new battery technologies that can be used to store the energy generated by these sources when the sun isn’t shining, and the wind isn’t blowing.

For the most part, current battery energy storage systems use lithium-ion batteries – the same sort of batteries found in cellphones and electric vehicles.  There are many other battery chemistries, but they mostly have shortcomings in performance, economy, or longevity. 

Batteries store electricity in the form of chemical energy and chemical reactions convert that energy into electrical energy. Every battery has two electrodes:  the anode, from which electrons flow into external circuits, and the cathode, which receives electrons from the external circuit.  The electrolyte is the chemical medium through which the electrons flow.

One technology that has great potential is zinc-based batteries.  Zinc itself is a metal that is safe and abundant.  Batteries based on it are energy dense. However, zinc batteries have faced the challenge of having a short cycle life.  The batteries end up plating zinc on their anodes and battery performance degrades. 

A team of researchers at Oregon State University and three other universities have recently developed a new electrolyte for zinc batteries that raises the efficiency of the zinc metal anode to nearly 100% – actually slightly better than lithium-ion batteries.

Zinc batteries have a number of potential advantages over lithium-ion.  The new hybrid electrolyte developed by the researchers is non-flammable, cost-effective, and has low environmental impact.  Lithium-ion batteries rely on the supplies of relatively rare metals that are often difficult and environmentally harmful to obtain. 

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Researchers develop electrolyte enabling high efficiency of safe, sustainable zinc batteries

Photo, posted May 13, 2017, courtesy of Jeanne Menjoulet via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Community Solar On The Rise | Earth Wise

April 14, 2023 By EarthWise Leave a Comment

Community solar continues to grow

Community solar is a way for people who can’t put solar on their own roofs to still take advantage of its benefits.  Whether they can’t afford to install their own panels, have too much shade on their roof, or don’t even own a home, community solar is another way to participate in green energy.

Community solar – also called “shared solar” or “solar gardens” – is a kind of development in which consumers can subscribe to a large solar installation in their area and receive credits on their monthly utility bills for their share of the solar electricity produced.

The large majority of community solar installations are in six states:  Colorado, Illinois, Massachusetts, Minnesota, New Jersey, and New York.  After substantial growth in community solar in 2022, New York now is the national leader, thanks to initiatives by the state government and the nonprofit sector.  Some programs focus on giving low-income households access to solar.  As of last fall, New York had over 728 community solar projects online.

One should understand that electrons are indistinguishable.  The power generated by a community solar installation is not piped directly to subscribers’ homes.  It just goes into the grid.  Subscribers get credit for their share of the power, but that is essentially a matter of bookkeeping, not physics.

The federal government now has $7 billion that can be used for community solar as part of the Greenhouse Gas Reduction Fund within the Inflation Reduction Act enacted last August.  The EPA plans to award up to 60 grants to assist projects deploying residential and community solar.  Research firm Wood Mackenzie forecasts the community solar market will double by 2027.

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Community Solar Is About to Get a Surge in Federal Funding. So What Is Community Solar?

Photo, posted November 18, 2008, courtesy of the Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Electricity From Bacteria | Earth Wise

June 3, 2022 By EarthWise Leave a Comment

Producing electricity from bacteria

Microbiologists at Radboud University in the Netherlands have demonstrated in the laboratory that methane-consuming bacteria can generate electrical power.  Their study was recently published in the journal Frontiers in Microbiology.

The bacteria studied is called Candidatus Methanoperedens and in the natural environment it consumes methane in water sources that are contaminated with nitrogen including places like water-filled ditches and some lakes. The bacteria in the study make use of the nitrates in the water to break down and digest the methane. Methanogens, which are bacteria that reduce carbon dioxide to form methane, are the source of the methane in these places. 

The researchers exploited these complex interactions of bacteria to create a source of electrical power that is essentially a kind of battery with two terminals.  One of the terminals is a chemical terminal and one is a biological terminal.  They grew the bacteria on one of the electrodes where the bacteria donate electrons that result from its conversion of methane.  (Other microbiologists at the same institution had previously demonstrated electrical generation from a similar battery containing anammox bacteria that use ammonium rather than methane in their metabolic processing).

In the study, the Radboud scientists managed to convert 31% of the methane in the water into electricity but they are aiming at higher efficiencies. 

This approach represents a potential alternative to conventional biogas electricity generation.  In those installations, methane is produced by microorganisms digesting plant materials and the methane is subsequently burned to drive a turbine to generate power.  Those systems in fact have an efficiency of less than 50%.  The researchers want to determine whether microorganisms can do a better job of generating electricity from biological sources than combustion and turbines can do.

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Bacteria generate electricity from methane

Photo, posted December 3, 2008, courtesy of Martin Sutherland via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Figuring Out Photosynthesis | Earth Wise

March 16, 2020 By EarthWise Leave a Comment

unraveling the mystery of photosynthesis

Plants have been harnessing the sun’s energy for hundreds of millions of years. Algae and photosynthetic bacteria have been doing the same for even longer, all with remarkable efficiency and resiliency. 

People have used the energy of the sun in one way or another for millennia, but only recently have we gotten sophisticated about it by using devices like solar panels and sensors.  And we still have a long way to go to get anywhere close to the efficiency of plants. It’s no wonder, then, that scientists have long sought to understand exactly how photosynthesis works.

Scientists from the U.S. Department of Energy’s (DOE) Argonne National Laboratory, and collaborators at Washington University in St. Louis, recently solved a critical part of the age-old mystery of photosynthesis, studying the initial, ultra-fast events through which photosynthetic proteins capture light and use it to initiate a series of electron transfer reactions.  Electrons in plants have two possible pathways to travel but only use one.   

But as a result of their efforts, the scientists are now closer than ever to being able to design electron transfer systems in which they can send an electron down a pathway of their choosing. 

By gaining the ability to harness the flow of energy, it may be possible to incorporate new design principles in non-biological energy systems. This could allow us to greatly improve the efficiency of many solar-powered devices, potentially making them far smaller. Understanding the intricacies of photosynthesis creates a tremendous opportunity to open up completely new disciplines of light-driven biochemical reactions, perhaps even ones that haven’t been envisioned by nature.

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Scientists unravel mystery of photosynthesis

Photo, posted June 14, 2017, courtesy of Alex Holyoake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

March 7, 2019 By EarthWise 1 Comment

There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy.  Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen.  But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it.  The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants.  This membrane is an essential part of pairing the two photosystems.  It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes.  Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Electricity From A Bionic Mushroom

December 28, 2018 By EarthWise Leave a Comment

https://earthwiseradio.org/wp-content/uploads/2018/12/EW-12-28-18-Electricity-from-a-Bionic-Mushroom.mp3

In an engineering feat straight out of a weird science-fiction story, researchers at Stevens Institute of Technology in New Jersey have taken an ordinary white button mushroom and used 3D printing technology to coat it with graphene microribbons and cyanobacteria to produce a device that generates electricity.

[Read more…] about Electricity From A Bionic Mushroom

Cleaning And Splitting Water

December 18, 2018 By EarthWise Leave a Comment

https://earthwiseradio.org/wp-content/uploads/2018/12/EW-12-18-18-Cleaning-and-Splitting-Water.mp3

Researchers at EPFL in Lausanne, Switzerland, have developed a photocatalytic system that can be used to degrade pollutants present in water while simultaneously producing hydrogen that can be captured and put to use.

[Read more…] about Cleaning And Splitting Water

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