cycle

Better Zinc Batteries | Earth Wise

May 17, 2023 By EarthWise Leave a Comment

The rapid growth of wind and solar power continues to drive a global quest for new battery technologies that can be used to store the energy generated by these sources when the sun isn’t shining, and the wind isn’t blowing.

For the most part, current battery energy storage systems use lithium-ion batteries – the same sort of batteries found in cellphones and electric vehicles. There are many other battery chemistries, but they mostly have shortcomings in performance, economy, or longevity.

Batteries store electricity in the form of chemical energy and chemical reactions convert that energy into electrical energy. Every battery has two electrodes: the anode, from which electrons flow into external circuits, and the cathode, which receives electrons from the external circuit. The electrolyte is the chemical medium through which the electrons flow.

One technology that has great potential is zinc-based batteries. Zinc itself is a metal that is safe and abundant. Batteries based on it are energy dense. However, zinc batteries have faced the challenge of having a short cycle life. The batteries end up plating zinc on their anodes and battery performance degrades.

A team of researchers at Oregon State University and three other universities have recently developed a new electrolyte for zinc batteries that raises the efficiency of the zinc metal anode to nearly 100% – actually slightly better than lithium-ion batteries.

Zinc batteries have a number of potential advantages over lithium-ion. The new hybrid electrolyte developed by the researchers is non-flammable, cost-effective, and has low environmental impact. Lithium-ion batteries rely on the supplies of relatively rare metals that are often difficult and environmentally harmful to obtain.

**********

Web Links

Researchers develop electrolyte enabling high efficiency of safe, sustainable zinc batteries

Photo, posted May 13, 2017, courtesy of Jeanne Menjoulet via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A New Method of Refrigeration | Earth Wise

February 10, 2023 By EarthWise Leave a Comment

Salting roads before winter storms is a familiar sight in the Northeast. The purpose is to change the temperature at which ice can form on the road. The underlying concept has formed the basis of a new method of refrigeration that has been dubbed “ionocaloric cooling.”

It is described in a paper published in the journal Science by researchers at the Lawrence Berkeley National Laboratory. The method takes advantage of how energy in the form of heat is either stored or released when a material changes phase – such as water changing from ice to liquid and vice versa. Melting absorbs heat from the surroundings while freezing releases heat. An ionocaloric refrigerator makes use of this phase and temperature change using an electrical current to add or remove ions provided from a chemical salt.

The potential is to make use of this refrigeration cycle instead of the vapor compression systems in present-day refrigerators, which make use of refrigerant gases that are greenhouse gases, many of which very powerful ones. The goal is to come up with a system that makes things cold, works efficiently, is safe, and doesn’t harm the environment.

There are a number of alternative refrigeration systems under development that make use of a variety of mechanisms including magnetism, pressure, physical stretching, and electric fields. Ionocaloric cooling uses ions to drive solid-to-liquid phase changes.

Apart from some very promising theoretical calculations of the system’s potential, the researchers have also demonstrated the technique experimentally. They have received a provisional patent for the technology and are continuing to work on prototypes to demonstrate its capabilities and amenability to scaling up.

**********

Web Links

Berkeley Lab Scientists Develop a Cool New Method of Refrigeration

Photo, posted October 29, 2021, courtesy of Branden Frederick via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cleaning Up Urban Rivers With Nature’s Tools | Earth Wise

October 7, 2022 By EarthWise Leave a Comment

Fifty years after the passage of the Clean Water Act, urban waterways across the United States are continuing their comeback and are showing increasing signs of life. A strategy that is being adopted in many places is to use natural restoration techniques focused on bolstering plants and wildlife to improve water quality.

A nonprofit called the Upstream Alliance has focused on public access, clean water, and coastal resilience in the Delaware, Hudson, and Chesapeake watersheds. Working with the Center for Aquatic Sciences and with support from the EPA and the National Fish and Wildlife Foundation, the alliance has been repopulating areas of an estuary of the Delaware River near Camden, New Jersey with wild celery grass, which is a plant vital to freshwater ecosystems.

In many places, scientists, nonprofits, academic institutions, and state agencies are focusing on organisms like bivalves (typically oysters and mussels) along with aquatic plants to help nature restore fragile ecosystems, improve water quality, and increase resilience.

Bivalves and aquatic vegetation improve water clarity by grounding suspended particles, which allows more light to penetrate. These organisms also cycle nutrients both by absorbing them as food and by making them more available to other organisms.

Underwater restoration projects have been underway in New York Harbor for more than a decade, where the Billion Oyster Project has engaged 10,000 volunteers and 6,000 students.

The hope is that bringing back bivalves and aquatic plants can create a lasting foundation for entire ecosystems. It is restoring nature’s ability to keep itself clean.

**********

Web Links

How Using Nature’s Tools Is Helping to Clean Up Urban Rivers

Photo, posted December 19, 2019, courtesy of Scott via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A New Way To Remove CO2 From The Air

December 13, 2019 By EarthWise Leave a Comment

Researchers at MIT have developed a new way of removing carbon dioxide from a stream of air that could be a powerful tool in the battle against climate change. The new system can pull carbon dioxide out of almost any concentration level of the gas, even including the roughly 400 parts per million level currently found in the atmosphere.

The technique is described in a new paper in the journal Energy and Environmental Science and is based on passing air through a stack of electrochemical plates. The device is essentially a large battery that absorbs carbon dioxide from the air passing over its electrodes as it is being charged up, and then releases the gas as it is being discharged.

To use it, the device would simply alternate between charging and discharging. Fresh air or some other feed gas would be blown through the system during the charging cycle and then pure, concentrated carbon dioxide would be blown out during discharging.

The specialized battery uses electrodes coated with a compound called polyanthraquinone, which is composited with carbon nanotubes. These unique electrodes have a binary affinity to carbon dioxide, which means that they either strongly want to capture carbon dioxide or not at all, depending upon whether the device is charging or discharging.

Carbon dioxide is important in many industries such as soft drinks and greenhouse agriculture. With this device, the stuff could literally be pulled out of the air. And, of course, in power plants where exhaust gas is dumped into the air, these novel electrochemical cells could be used to prevent the emission of CO2 into the atmosphere. At the right price, this could be a game changer.

**********

Web Links

MIT engineers develop a new way to remove carbon dioxide from air

Photo, posted August 9, 2007, courtesy of William Clifford via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

How Much CO2 Can The Oceans Hold?

May 2, 2019 By EarthWise Leave a Comment

The carbon dioxide that enters the atmosphere doesn’t necessarily stay there. As part of the natural carbon cycle, much of it goes into plants, soil and, very significantly, the ocean. In fact, the world’s oceans are a sink for human-generated carbon dioxide without which the extent of global climate change would be far worse.

Oceans takes up CO2 in two steps: first the CO2 dissolves in the surface water. Then, the ocean’s overturning circulation distributes it. Currents and mixing processes transport the dissolved CO2 from the surface deep into the ocean’s interior, where it accumulates over time.

A long-standing priority for climate researchers is to determine how much of the CO2 we produce is being absorbed by the oceans and, ultimately, how much can they hold?

An international team of scientists has recently provided some answers. As reported in Science, the researchers have determined that the oceans have taken up from the atmosphere as much as 37 billion tons of human-made carbon between 1994 and 2007. This figure corresponds to nearly a third of all the anthropogenic CO2 emitted during that time.

Furthermore, they found that the percentage of CO2 taken up by the oceans has remained relatively stable compared to the preceding 200 years even as the absolute quantity has increased. So, evidently, the oceans’ capacity for carbon dioxide has not yet been saturated.

That’s the good news. The bad news is that putting all that CO2 into the oceans has a steep price: the dissolved CO2 acidifies the water. The consequences for a wide range of marine life including coral reefs are serious and getting worse. We need to drastically reduce carbon emissions.

**********

Web Links

Ocean sink for human-made carbon dioxide measured

Photo, posted November 5, 2018, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Speed Breeding Of Crops

January 4, 2019 By EarthWise Leave a Comment

A technique pioneered by NASA for the purpose of growing plants extra-terrestrially is now being applied here on earth to fast-track improvements in a range of crops. The technique, known as speed breeding, has been adapted for use by British and Australian researchers on a scale ranging from vast greenhouses to desktop growth chambers.

Speed breeding uses enhanced LED lighting and day-long regimes of up to 22 hours to optimize photosynthesis and promote rapid growth of crops. By speeding up the breeding cycle of plants,it is possible, for example, to grow six generations of wheat in a year compared with two generations using traditional breeding methods.

With shortened breeding cycles, genetic improvements such as yield gain, disease resistance and climate resistance can be fast-tracked in crops such as wheat, barley, chickpeas, various Brassica species, oil seed rape and peas.

The ability to do this in compact desktop chambers permits cutting-edge research to be performed inexpensively before being scaled up to large greenhouses.

Crop development is an increasingly important activity and speed breeding is increasingly attractive in light of the opposition in some quarters to modern gene-editing techniques to create GMO crops. Speed breeding allows crop improvements via anon-GMO route.

The new technique is already being applied in Australia, which is experiencing one of the worst droughts on record. It is being used to rapidly cycle genetic improvements to make crops more drought resilient.

Generation time in most plant species is a major bottleneck in applied research programs and breeding. Speed breeding can greatly reduce this bottleneck, allowing scientists to respond more quickly to emerging diseases, the changing climate and increased demand for specific plant traits.

**********