calcium

A better way to extract lithium

December 10, 2024 By EarthWise Leave a Comment

Lithium is the critical component in the batteries that power phones and computers, electric cars, and the systems that store energy generated by solar and wind farms. Lithium is not particularly rare, but it is difficult and often environmentally harmful to extract from where it is found.

Traditional ore sources are increasingly difficult and expensive to mine. The largest known deposits of lithium are in natural brines – the salty water found in geothermal environments. These brines also contain other ions like sodium, potassium, magnesium, and calcium, and efficiently separating out the lithium is extremely challenging.

Traditional separation techniques consume large amounts of energy and produce chemical waste, particularly hazardous chlorine gas. These techniques typically suffer from poor selectivity; that is, the process is interfered with by the other ions present in natural brines.

A team of researchers at Rice University has developed a three-chamber electrochemical reactor that improves the selectivity and efficiency of lithium extraction from brines. The middle chamber of the reactor contains a specialized membrane that acts as a barrier to chloride ions, preventing them from getting to the electrode area where they can form chlorine gas.

The new reactor has achieved a lithium purity rate of 97.5%, which means the setup can effectively separate lithium from other ions in the brine and allow the production of high-quality lithium hydroxide, the key material for battery manufacturing.

The Rice University reactor design has the potential to be a game changer for lithium extraction from geothermal brines.

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‘Game changer’ in lithium extraction: Rice researchers develop novel electrochemical reactor

Photo, posted October 21, 2023, courtesy of Simaron via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon-Negative Concrete | Earth Wise

June 6, 2023 By EarthWise Leave a Comment

Concrete is a mainstay of modern civilization. The world produces more than 4 billion tons of it each year and the process requires high temperatures, mostly obtained by burning fossil fuels. The chemical reactions that produce concrete also produce large amounts of carbon dioxide. In all, cement production is responsible for about 8% of total global carbon emissions by human activities.

This situation is the impetus for a wide range of research activities aimed at reducing the environmental impact of concrete production. Researchers at Washington State University have recently developed a way of making carbon-negative concrete: a recipe for concrete that absorbs large amounts of carbon dioxide.

There have been attempts in the past to add biochar to concrete. Biochar is a type of charcoal made from organic waste that sucks up carbon dioxide from the air. In earlier attempts, even adding 3% of biochar would dramatically reduce the strength of the concrete.

The WSU researchers found that treating biochar with concrete washout wastewater makes it possible to add much more biochar to concrete without reducing its strength. Mixing it with biochar adds calcium, which induces the formation of the mineral calcite, which in turn strengthens the concrete.

The researchers were able to add up to 30% biochar to their cement mixture. Within a month, the resultant concrete was comparable in strength to ordinary concrete. But at the same time, the biochar was able to absorb up to 23% of its weight in carbon dioxide from the air. The new concrete is potentially the most environmentally friendly concrete ever developed.

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Researchers develop carbon-negative concrete

Photo, posted January 31, 2012, courtesy of Michael J. Nevins / U.S. Army Corps of Engineers via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Carbon Into Stone | Earth Wise

January 31, 2023 By EarthWise Leave a Comment

A start-up company in Oman called 44.01 was recently awarded a $1.2 million Earthshot Prize by Prince William of the U.K. The company, whose name corresponds to the molecular weight of carbon dioxide, is working on speeding up natural chemical reactions that take carbon from the air and lock it into solid mineral form.

The company’s location in Oman is no random occurrence. The mountains of northern Oman and along the coast of the United Arab Emirates are the site of a huge block of oceanic crust and upper mantle that was thrust upward some 96 million years ago. The tilted mass of rock is over 200 miles long and is the largest surface exposure of the Earth’s mantle in the world.

This type of rock, called peridotite, is rich in olivine and pyroxene, which react with water and carbon dioxide to form calcium-based minerals like serpentine and calcite that permanently lock in carbon. Other kinds of rock also are capable of carbon-storing mineralization, but this mantle rock is the most effective for the purpose. It only exists at the Earth’s surface in a few places, including Papua New Guinea and some spots in California and Oregon.

The 44.1 company is planning to use solar-powered direct air capture devices to remove CO₂ from the air, use it to produce carbonated water, and inject the water into the reactive rocks. The company will operate a couple of pilot systems during 2023. Ultimately, the company believes it can scale up the process to be able to permanently sequester as much as a billion tons of CO₂ a year by the year 2040 without needing to inject the gas into deep caverns or find other places to store it.

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With Major Prize, a Project to Turn Carbon Emissions to Stone Gains Momentum

Photo, posted August 10, 2018, courtesy of JM McBeth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Rock Dust And Carbon | Earth Wise

May 25, 2022 By EarthWise Leave a Comment

According to a new study by Cardiff University in the UK, Britain could achieve nearly half of the carbon removal needed to meet its climate goals by adding basalt rock dust to crop fields. The process is known as enhanced weathering and has been the subject of ongoing research in the U.S. at Cornell University and the University of California, as well as in the UK, Canada, and Australia.

Adding rock dust to agricultural lands speeds up the chemical reactions that lock up carbon in soil. Basalt contains magnesium, calcium, and silica, among other components. When basalt is pulverized and applied to soils, magnesium and calcium are released and dissolve in water as it moves through the soil. The minerals in the soil react with the water, and the carbon that would otherwise end up in the atmosphere instead forms bicarbonates, which can hang around in water for thousands of years. It can also eventually make its way to the oceans where it precipitates out as limestone and can stay on the seafloor for millions of years.

Basalt is a waste stream byproduct of mining and manufacturing and is found all over the world. Mining waste is the largest waste stream in the world, so there is no shortage.

According to the U.N. Intergovernmental Panel on Climate Change, applying rock dust to agricultural lands on a global basis could theoretically remove 2 to 4 billion tons of carbon dioxide from the air each year, which is between 34-68% of the global greenhouse gas emissions produced by agriculture annually.

The added rock dust would in fact be good for the soil and for crops. Whether the economics of producing and transporting it make sense remains to be determined.

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Adding Rock Dust to Farmland Could Get UK Almost Halfway to Its Carbon Removal Goal

Photo, posted April 24, 2011, courtesy of the State of Israel via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Concrete Production And Diminishing Coal Burning | Earth Wise

June 5, 2020 By EarthWise Leave a Comment

Coal burning is still one of the primary means of generating electricity in the United States, but its use is diminishing and doing so fairly rapidly. The coal burning process produces residual, incombustible materials. One of them is fly ash, which is composed of fine, glassy, rounded particles rich in silicon, aluminum, calcium, and iron oxides. Fly ash is captured from coal plant flue gas by precipitators and bag filters. It turns out that two-thirds of this fly ash is not dumped into landfills or impoundments, but rather is put to use.

Because of its chemical and physical characteristics, fly ash can substitute for a portion of portland cement in concrete. Using this byproduct material in making cement actually reduces its cost. Beyond cost, the addition of fly ash as a so-called supplementary cementitious material or SCM improves concrete’s long-term strength and reduces porosity and permeability. It reduces the risk of thermal cracking and provides good long-term mechanical properties.

The amount of fly ash used in concrete products increased by 5% between 2011 and 2017 while the amount produced dropped by 36%. Concrete production continues to increase steadily while fly ash production is steadily dropping.

Therefore, the concrete industry is looking for alternative sources of SCM. The most obvious is the approximately 1/3 of fly ash that hasn’t been used to make concrete. Much of that is landfilled or ponded onsite at power plants. So, opportunities exist for excavating or dredging and recovering these materials.

As coal burning goes away, concrete manufacturing needs to make some changes.

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What Does the Changing Face of Electricity Production Mean for Concrete?

Photo, posted February 16, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Catching Kelp In Maine

September 6, 2016 By WAMC WEB

Farming, forestry, mining and recreation are the primary vocations in rural America. In coastal areas like Maine, fishing joins the list. And for Maine, commercial fishing has long been a major engine for the economy.

Breeding Super Corals

October 19, 2015 By EarthWise

The world’s coral reefs are increasingly threatened by the changing climate. Both warmer ocean temperatures and increasing ocean acidification are damaging coral populations and endangering the very existence of coral reefs.