argonne national laboratory

Figuring Out Photosynthesis | Earth Wise

March 16, 2020 By EarthWise Leave a Comment

Plants have been harnessing the sun’s energy for hundreds of millions of years. Algae and photosynthetic bacteria have been doing the same for even longer, all with remarkable efficiency and resiliency.

People have used the energy of the sun in one way or another for millennia, but only recently have we gotten sophisticated about it by using devices like solar panels and sensors. And we still have a long way to go to get anywhere close to the efficiency of plants. It’s no wonder, then, that scientists have long sought to understand exactly how photosynthesis works.

Scientists from the U.S. Department of Energy’s (DOE) Argonne National Laboratory, and collaborators at Washington University in St. Louis, recently solved a critical part of the age-old mystery of photosynthesis, studying the initial, ultra-fast events through which photosynthetic proteins capture light and use it to initiate a series of electron transfer reactions. Electrons in plants have two possible pathways to travel but only use one.

But as a result of their efforts, the scientists are now closer than ever to being able to design electron transfer systems in which they can send an electron down a pathway of their choosing.

By gaining the ability to harness the flow of energy, it may be possible to incorporate new design principles in non-biological energy systems. This could allow us to greatly improve the efficiency of many solar-powered devices, potentially making them far smaller. Understanding the intricacies of photosynthesis creates a tremendous opportunity to open up completely new disciplines of light-driven biochemical reactions, perhaps even ones that haven’t been envisioned by nature.

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Scientists unravel mystery of photosynthesis

Photo, posted June 14, 2017, courtesy of Alex Holyoake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Lighting Up Batteries

December 24, 2019 By EarthWise 2 Comments

One of the things that hampers the adoption of electric vehicles is range anxiety. Drivers worry that they will run out of charge before they get to the closest charging station. Range anxiety has lessened considerably in recent years as electric cars have incorporated larger and larger battery packs yielding driving ranges well over two hundred and even over three hundred miles.

With these extended driving ranges, drivers then turn their attention to how long it takes to charge. Tesla’s Superchargers have gotten to the point where a car can add 75 miles of charge in 5 minutes and 200 miles in less than half an hour. Fast charging systems are improving the charge times for other electric models as well.

Nevertheless, drivers would ideally like to reduce charging times to as little as possible in order to provide the convenience experienced in gasoline cars.

Researchers at Argonne National Laboratory have reported a mechanism for speeding up the charging of lithium-ion batteries for electric vehicles. By exposing the battery cathode to a beam of concentrated light, the charging time can be reduced by a factor of two or more. If this could be commercialized, it could be a real game changer for electric vehicles.

The research used specially crafted lithium-ion cells with transparent quartz windows. Shining white light into the windows caused a semiconductor material known as LMO to change its charge state and drive the charging reaction more quickly in the lithium ions of the battery.

Using this photo-assisted technology in vehicle batteries would require substantial redesign that would allow concentrated light to illuminate battery electrodes during charging. How practical that is remains to be seen, but the payoff would be substantial.

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Shedding new light on the charging of lithium-ion batteries

Photo, posted June 30, 2018, courtesy of Open Grid Scheduler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Trash Into Treasure

December 12, 2019 By EarthWise Leave a Comment

Every year, 380 million tons of plastic are created worldwide, and that number continues to grow. Furthermore, more than 75% of these materials are discarded after one use. Much of it ends up in oceans and waterways, harming wildlife and spreading toxins.

Recycling most plastics is difficult because while they can be melted and reprocessed, the resultant material is not as structurally strong as the original material. Thus, plastics are often down-cycled such as turning plastic bottles into molded park benches.

Researchers at Northwestern University, Argonne National Laboratory, and Ames Laboratory have developed a new method for upcycling abundant, seemingly low-value plastics into high-quality liquid products, such as motor oils, lubricants, detergents, and even cosmetics. The catalytic method could remove plastic pollution from the environment and contribute to a circular economy.

Plastics don’t degrade when disposed of because they have very strong carbon-carbon bonds. Instead they just break into smaller bits, known as microplastics. The researchers viewed these strong bonds as an opportunity rather than a problem.

The new technique actually recoups the high energy that holds these bonds together by catalytically converting polyethylene molecules into value-added commercial products. The catalyst consists of platinum nanoparticles deposited onto perovskite nanocubes. Under moderate pressure and temperature, the catalyst cleaves the carbon-carbon bonds in plastic to produce high-quality liquid hydrocarbons.

The researchers believe these findings could lead to a future in which we can continue to benefit from plastic materials but do so in a way that is sustainable and less harmful to the environment.

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Turning plastic trash into treasure

Photo, posted August 15, 2012, courtesy of Emilian Robert Vicol via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hydrogen From Water And Sun

March 7, 2019 By EarthWise 1 Comment

There are research efforts around the world seeking ways to produce hydrogen starting from water and using clean energy. Finding an economical and scalable way to do this is a key to the so-called hydrogen economy.

A recent study at Argonne National Laboratory makes use of a chemical reaction pathway central to plant biology to create a process that converts water into hydrogen using energy from the sun.

The process combines two membrane-bound protein complexes to perform the conversion of water molecules into hydrogen and oxygen.

The first protein complex, which the researchers call Photosystem I, is a membrane protein that uses energy from light to feed electrons to an inorganic catalyst that makes hydrogen. But this represents only half of the overall process.

A second protein complex that they call Photosystem II uses energy from light to split water and take electrons from it. The electrons are then fed to Photosystem I.

The two protein complexes are embedded in thylakoid membranes, which are like those found inside the oxygen-creating chloroplasts in plants. This membrane is an essential part of pairing the two photosystems. It supports both of the photosystems and provides a pathway for transferring electrons between the proteins.

The researchers also make use of a synthetic catalyst made from nickel or cobalt that replaces expensive platinum catalysts used in conventional water-splitting schemes. Combining the light-triggered transport of electrons with the synthetic catalyst results in what the researchers call the “Z-scheme”, an adaptation of photosynthesis to produce hydrogen.

The next step is to incorporate the scheme into a living system which the researchers hope will lead to a practical system for hydrogen production.

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Discovery adapts natural membrane to make hydrogen fuel from water

Photo, posted December 25, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.