acidic

Reducing emissions from ocean shipping

August 13, 2025 By EarthWise Leave a Comment

Ocean shipping is a significant contributor to global carbon emissions, accounting for about 3% of the total. It is a key part of international trade, moving goods like electronics, automobiles, and oil. It relies on fossil fuels, and, without significant changes, shipping’s emissions could more than double by 2050. Ocean shipping is one of the world’s most difficult to decarbonize industrial sectors.

Scientists at the University of Southern California and Caltech, collaborating with a startup company called Calcarea, have developed a shipboard system that could remove up to half of the carbon dioxide emitted by shipping vessels. The system is fairly simple and scalable.

The process mimics a natural chemical reaction that takes place in the ocean. As a cargo ship moves through seawater, the CO2 from the ship’s exhaust is absorbed into water that is pumped onboard. This makes the water more acidic. The treated water is then passed through a bed of limestone, where it reacts with the rock to form bicarbonate, which is a stable compound that already exists naturally in seawater. The treated seawater, now stripped of the carbon dioxide, is dumped back into the ocean.

Sophisticated ocean modeling examined what would happen when the bicarbonate-rich water is released back into the sea over a hypothetical 10-year period. The model showed a negligible impact on ocean pH and chemistry.

The researchers estimate that widespread adoption of the technique could reduce shipping-related carbon dioxide emissions by 50%. The startup company Calcarea is working to bring the technology to market and is in early discussions with commercial shippers.

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USC technology may reduce shipping emissions by half

Photo, posted November 14, 2017, courtesy of Bernard Spragg via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Marine carbon dioxide removal

May 23, 2024 By EarthWise Leave a Comment

About 30% of the carbon dioxide emitted by human activity is absorbed by the oceans. As a result, they are getting warmer and more acidic, and the currents that help shape global weather are shifting. To try to reduce global warming, people want to be able to store even more carbon dioxide in the oceans without the negative effects of doing so.

There are multiple efforts across the globe to achieve effective marine carbon dioxide removal. Some are based on sinking carbon-rich materials to the bottom of the sea. This is the marine equivalent of capturing CO2 from the air and storing it underground. Other efforts involve increasing the alkalinity of the ocean, which increases its ability to chemically react with carbon dioxide as well as lowers its acidity, which is desirable in many ways.

Running Tide, a U.S.-based company, has been dumping thousands of tons of wood-industry waste 190 miles off the coast of Iceland. The company has also been experimenting with dumping algae and kelp and sinking it deep below the ocean. Such materials on land either get burned or decay, in both cases releasing CO2 into the atmosphere. On the deep-sea bottom, the carbon is trapped.

Other efforts involve pumping seawater through electrodialysis filter systems to remove excess acidity or adding alkaline rocks to increase water alkalinity.

All of these efforts are a form of geoengineering, and like proposed ideas to cool the atmosphere, pose potential risks. There is no silver bullet to solve the climate crisis. It will take a combination of many solutions to address the issue of excess carbon dioxide in the atmosphere. Marine carbon dioxide removal is one of the solutions that may play a role.

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Scientists Are Trying to Coax the Ocean to Absorb More CO2

Photo, posted February 22, 2018, courtesy of Bobbie Halchishak/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Ocean Oxygen Levels And The Future Of Fish | Earth Wise

June 23, 2023 By EarthWise Leave a Comment

Climate change is creating a cascade of effects in the world’s oceans. Not only are ocean temperatures on the rise, but oceans are becoming more acidic, and oxygen deprived. The warming temperatures and acidification have grabbed headlines and prompted academic research. Declining oxygen levels have not garnered as much attention. But they spell bad news for fish.

Oxygen levels in the world’s oceans have dropped over 2% between 1960 and 2010 and are expected to decline up to 7% over the next century. There are places in the northeast Pacific that have lost more than 15% of their oxygen. There are a growing number of “oxygen minimum zones” where big fish cannot survive but jellyfish can.

Oceans are losing oxygen for several reasons. First, warmer water can hold less dissolved gas than colder water. (This is why warm soda is flatter than cold soda.) Deeper in the ocean, oxygen levels are governed by currents that mix oxygen-rich surface water from above. Melting ice in the warming polar regions add fresh, less-dense water that resists downward mixing in key regions. Finally, increasing amounts of ocean bacteria in warming waters gobble up oxygen creating dead zones in the ocean.

In many places, fish species that cannot cope with lower oxygen levels are migrating from their usual homes, resulting in a decline in species diversity. Our future oceans – warmer and oxygen-deprived – will not only hold fewer kinds of fish, but also smaller fish and even more greenhouse-gas producing bacteria.

Climate change is bad news for fish and for the more than 3 billion people in the world who depend on seafood as a significant source of protein.

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As Ocean Oxygen Levels Dip, Fish Face an Uncertain Future

Photo, posted January 10, 2022, courtesy of Willy Goldsmith via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Pulling Carbon Dioxide Out Of Seawater | Earth Wise

April 17, 2023 By EarthWise Leave a Comment

The world’s largest sink for carbon dioxide from the atmosphere is the ocean. The world’s oceans soak up 30-40% of all the gas produced by human activities. Dissolving carbon dioxide in water produces carbonic acid. This is the reason that oceans are becoming increasingly acidic, which is causing serious damage to ocean ecosystems.

There are many efforts underway aimed at directly removing carbon dioxide from the air as a way to mitigate the effects of ongoing emissions. But another possibility is to remove CO2 directly from ocean water. Existing methods for doing it involve the use of expensive membranes and complex chemicals. The economics of such methods are quite unfavorable.

Recently, a team of researchers at MIT has identified what they claim is a truly efficient and inexpensive removal mechanism. It involves a reversible process based on membrane-free electrochemical cells. Electrodes in the cells release protons that are introduced to seawater which drive the release of carbon dioxide dissolved in the water. The carbon dioxide can be collected and the processed water ends up being alkaline.

Running this process at a site that is already collecting seawater – such as at a desalination plant – would be an effective way to collect carbon dioxide as well as help mitigate ocean acidification.

Once the carbon dioxide is removed from the water, it still needs to be disposed of, just as is the case for other carbon removal processes. It could be turned into useful chemicals or it could be stored in underground caverns. But this approach is fairly unique in that the carbon dioxide has already been captured by the ocean. The issue remains what to do with it.

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How to pull carbon dioxide out of seawater

Photo, posted January 19, 2016, courtesy of Judy Dean via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Some Good News For The Great Barrier Reef | Earth Wise

September 5, 2022 By EarthWise Leave a Comment

It seems like there has been nothing but dire news from Australia’s Great Barrier Reef. Earlier this year, there was yet another mass bleaching event – the fourth in seven years and the first ever to strike during a cooler La Niña phase in the Pacific. But this bleaching event was less severe than other recent ones, which makes it possible for parts of the reef to bounce back.

In particular, in the northern and central stretches of the reef, scientists have recorded the most extensive coral cover seen in 36 years of study. In areas where coral cover has expanded, it is mostly fast-growing Acropora corals driving the growth. That isn’t the best outcome, given that Acropora are particularly vulnerable to strong waves, highly susceptible to bleaching, and are the preferred target of crown-of-thorns starfish.

Those creatures are a major problem for the Great Barrier Reef. In contrast to the upper stretches of the reef, the southern third actually saw coral cover drop from 38 to 34 percent over the course of the past year. Scientists blame the decline on an outbreak of crown-of-thorns starfish, which prey on corals. The starfish grow faster and eat more in warmer, more acidic waters. Carbon emissions are both raising ocean temperatures and turning waters more acidic.

The large increases in hard coral cover in the reef are certainly good news, but it is important to understand that they can be quickly negated by disturbance on reefs where Acropora corals predominate. Warming temperatures and mass bleaching events continue to pose a critical threat to all reefs, especially when there are crown-of-thorns starfish outbreaks and increasing frequency of tropical cyclones.

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Parts of Great Barrier Reef See Most Extensive Coral Cover In 36 Years

Photo, posted July 15, 2019, courtesy of Kenneth Lu via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Sea Urchins And Climate Change | Earth Wise

August 1, 2022 By EarthWise Leave a Comment

There is a thriving population of black sea urchins in bubbling volcanic vents off the coast of Ishia, a small island in the Gulf of Naples. The oceanic environment there is very acidic, high in carbon dioxide, and very warm. The environment represents a proxy for what is gradually happening to oceans around the world.

Researchers from the University of Sydney have determined that the ability of sea urchins to prosper in such an environment means that these animals, which are already abundant in the Mediterranean Sea are likely to spread further afield as oceans continue to warm and become more acidic. The Mediterranean Sea is warming 20% faster than the global average.

Sea urchins are already an environmental problem in many places around the world. When their numbers increase disproportionately, they decimate kelp forests and algae, leading to the demise of other species that depend on these things for food or shelter. The result is something called an urchin barren, which is a rocky, sandy, urchin-filled seafloor devoid of other life.

Urchin barrens are increasingly common in many places, including the east coast of Australia and the coastline in the Americas stretching from Nova Scotia to Chile.

In Australia, for example, sea urchin populations have multiplied, and their range has expanded considerably, overgrazing kelp and damaging abalone and lobster farms.

Tests run by the Sydney researchers found that it is difficult to stress sea urchins. They appear to tolerate conditions that other creatures simply cannot. The only real positive is that understanding the urchins’ remarkable survival abilities might offer insights into adaptations that other animals might need in order to survive as the oceans become warmer and more acidic.

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Colonising sea urchins can withstand hot, acidic seas

Photo, posted January 31, 2010, courtesy of Anna Barnett via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Protecting Bees From Pesticides | Earth Wise

July 15, 2021 By EarthWise Leave a Comment

Studies have shown that the wax and pollen in 98% of beehives in the U.S. are contaminated with an average of six pesticides. These substances lower bees’ immunity to devastating varroa mites and other pathogens. By some estimates, pesticides cause beekeepers to lose about a third of their hives every year on average.

Researchers at Cornell University have developed a new technology that effectively protects bees from insecticides. The insecticide antidote delivery method is now the basis of a new company called Beemunity.

The Cornell researchers developed a uniform pollen-sized microparticle filled with enzymes that detoxify organophosphate insecticides before they are absorbed and can harm bees. Organophosphate insecticides account for about a third of the insecticides on the market. The microparticles have a protective casing that allows the enzymes to move past the bees’ crop (basically the stomach), which is acidic and would otherwise break them down. The safeguarded enzymes then enter the midgut, where digestion occurs and where toxins and nutrients are absorbed. There the enzymes act to break down and detoxify the organophosphate insecticides.

In experimental tests, bees that were fed the enzyme-filled microparticles had a 100% survival rate after exposure to the insecticide malathion. Unprotected control bees died within days.

The Cornell work appears to represent a low-cost, scalable solution to the insecticide toxicity issue and may help to protect essential pollinators.

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Pollen-sized technology protects bees from deadly insecticides

Photo, posted January 30, 2020, courtesy of George Tan via Flick.

Earth Wise is a production of WAMC Northeast Public Radio.

Ocean Acidification And Mass Extinction

November 26, 2019 By EarthWise Leave a Comment

Since the industrial revolution, the concentration of carbon dioxide in the atmosphere has increased due to the burning of fossil fuels and land use changes. The ocean absorbs about 30% of the CO2 that is released in the atmosphere. As the levels of atmospheric CO2 increase, so do the levels in the ocean.

When CO2 is absorbed by the ocean, a series of chemical reactions occur, resulting in seawater becoming more acidic. Ocean acidification threatens calcifying organisms, such as clams and corals, as well as other marine animals, like fish. When these organisms are at risk, the entire marine ecosystem may also be at risk.

In fact, according to research recently published in the journal Proceedings of the National Academy of Sciences, fossil evidence from 66 million years ago has revealed that ocean acidification can cause the mass extinction of marine life. Researchers analyzed seashells in sediment laid down shortly after a giant meteorite hit earth. This strike wiped out the dinosaurs and 75% of marine species. Chemical analysis of the shells revealed a sharp drop in the PH of the ocean over hundreds of years after the meteorite strike. The meteorite impact vaporized rocks, causing carbonic acid and sulphuric acid to rain down, acidifying the ocean. The strike also resulted in mass die-off of plants on land, increasing atmospheric CO2.

Researchers found that the pH dropped by 0.25 pH units in the 100 to 1,000 years after the meteorite strike. Alarmingly, scientists expect the pH of the ocean to drop by 0.4 pH units by 2100 if our carbon emissions continue as projected.

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Ocean acidification can cause mass extinctions, fossils reveal

Photo, posted March 16, 2017, courtesy of Zachary Martin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Pine Barrens Threatened

September 29, 2017 By EarthWise Leave a Comment

Pine barrens occur throughout the northeastern U.S. from New Jersey to Maine. They are plant communities that occur on dry, acidic, infertile soils dominated by grasses, forbs, low shrubs, and small to medium-sized pines. The Pine Bush Preserve in Albany, New York is one of the larger inland pine barrens in the country.