Earth Wise

A look at our changing environment.

You are here: Home / Archives for toxic

toxic

Better blue LEDs

By Leave a Comment

LEDs have become the standard source of energy-efficient lighting.  They make use of semiconductors to turn electricity into light.  Depending upon the materials used to make them, LEDs produce different colors.  In the early 1990s, the first blue LEDs were discovered, ultimately earning the Nobel Prize in physics, and enabling LEDs to produce white light, which is essential for general lighting applications.

Blue LEDs have shortcomings.  Some have issues with stability, scalability, cost, efficiency, complexity in manufacturing, or have environmental concerns because of the use of toxic components. 

Researchers at Rutgers University in collaboration with scientists at several other institutions have found a way to make blue LEDs more efficient and sustainable.  These LEDs use a new type of hybrid material that is a combination of copper iodide with organic molecules.  The impressive performance of these LEDs was achieved through an innovative technique called dual interfacial hydrogen-bond passivation.  This new manufacturing technique boosts the performance of LEDs by a factor of four.

The material has several advantages.  It has a very high photoluminescence quantum yield, which means that it converts nearly all the photoenergy it receives into blue light.  The LEDs last longer than many others and they work well in larger-scale applications, maintaining high efficiency.  The materials are eco-friendly and cost-effective.

According to the researchers, this new approach could be a versatile strategy for generating high-performance LEDs that can pave the way for better, brighter, and longer-lasting LEDs.

**********

Web Links

Scientists Develop Deep-Blue LEDs Expected to Greatly Enhance General Lighting

Photo, posted February 1, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Biochar and poultry farm pollution

By Leave a Comment

Poultry farms are a significant source of air and water pollution.  In the US, they are the largest source of ammonia emissions, followed by dairy and non-dairy cattle farms. Poultry farms emit over two million tons of ammonia per year. Ammonia is not directly produced or excreted by the birds but is a common by-product of poultry wastes.

Poultry manure is a rich source of phosphate and large amounts of it are used in agricultural land as an organic fertilizer.  This poses an environmental risk when phosphates are washed into rivers and streams by rainwater. Phosphates lead to the proliferation of algae, harming other aquatic life and resulting in toxic conditions.

Researchers at the UK Centre for Ecology & Hydrology are investigating the use of biochar as a means of reducing air and water pollution from poultry farms in the UK.  Biochar is produced by heating biomass – typically wood – to high temperatures in the absence of oxygen.  The resultant material is effective at absorbing nutrients and other substances.

In laboratory experiments, adding biochar to birds’ bedding has been shown to reduce ammonia emissions from droppings by 58%.  The biochar binds ammonium to its surface, preventing release into the atmosphere as ammonia gas.

Modified biochars are also proven to be highly efficient at adsorbing phosphorous.  Adding a cost-effective biochar to poultry manure fertilizer could support the safe use of an important and otherwise renewable fertilizer.  The biochar binds phosphates in the manure to its surface, preventing leaching and run-off into waterways.

**********

Web Links

Biochar could help restore River Wye

Photo, posted May 15, 2023, courtesy of Ark. Agricultural Experiment Station via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Toxic algae and West Coast marine life

By Leave a Comment

Over the first several months of this year, hundreds of sea lions, dolphins, and seabirds have fallen ill or died after eating sardines or anchovies that had been feeding on an algal bloom along the California coast since winter.  The biotoxin in the algae accumulates in the feeder fish.

Two cases of whales dying from the biotoxin have been confirmed by two nonprofit organizations tasked with testing dead mammals.  These were a humpback that washed ashore in Huntington Beach in January and a minke whale found dead in Long Beach in April.

This is the fourth year a row that California has experienced major algal blooms.  Warmer waters are causing blooms to be bigger and more damaging than they have been before.  They enter into new areas and contaminate the food web for longer.  The warmer waters accelerate algae growth that is further fueled by nutrients that rise to the surface from deeper colder waters driven by winds that blow parallel to the coast.  This year’s algae event started earlier than usual and is lasting longer than normal.

More than a dozen animal rescue and rehabilitation groups that form NOAA’s West Coast Marine Mammal Stranding Network are providing resources to try to respond to the situation.  At the Marine Mammal Care Center in Los Angeles, more than 80 sea lions and seals were being treated for domoic acid poisoning, the result of ingesting algae neurotoxin.  Since February, it has cared for more than 300 poisoned animals.

Marine mammals are sentinel species for humans who also consume seafood.  The West Coast ocean ecosystem is currently filled with toxins.

**********

Web Links

California Toxic Algal Bloom Blamed for Months-long Marine Life Poisoning

Photo, posted March 26, 2025, courtesy of Marnee Jill via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Tracking atmospheric mercury

By Leave a Comment

Atmospheric mercury is a toxic pollutant released into the air from natural sources—such as volcanoes and wildfires—and from human activities like coal burning and gold mining.  Once in the atmosphere, mercury can travel long distances before settling onto land or into water, transforming into toxic forms that threaten ecosystems and human health.

But tracking atmospheric mercury is a costly and challenging endeavor, requiring specialized equipment and trained personnel. Active monitors, which pump air to collect mercury, are expensive and need electricity, while passive samplers, using activated charcoal for remote areas, cost up to $100 each.

Researchers from Cornell University have found a cheap method for tracking toxic atmospheric mercury near gold mining sites throughout the Global South: wild fig trees.  In the study, which was conducted in the Peruvian Amazon and recently published in the journal Frontiers in Environmental Science, the research team found that the rings in wild fig trees can serve as natural archives of atmospheric mercury, capturing and preserving historical pollution levels over time.

The technique itself is not actually new.  Previous studies have used tree rings to track mercury pollution from coal combustion, particularly in Canada. But the research team wanted to test this method in regions of the Global South, where mercury emissions from gold mining are widespread.

According to the research team, wild fig trees might soon serve as an important biomonitoring tool, helping scientists better understand how mercury disperses across landscapes and through time.

**********

Web Links

Tree rings track atmospheric mercury cheaply

Photo, posted November 13, 2012, courtesy of Steve Kessler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fighting fires with man-made wind

By Leave a Comment

Researchers at Ohio State University have developed a new portable tool that may help firefighters battle blazes more efficiently and with less risk.

Traditional firefighting methods include chemical foams – which are toxic – and the use of hydrants, which can strain water resources.  The recent fires in Southern California demonstrated the need for efficient fire suppression methods.  The new device works to suppress flames using conductive aerosols, which are small particles that can direct electricity.

The device uses vortex rings – small donut-shaped bands of air – that transform the aerosol particles into short pulses of wind that convert nearby oxygen into ozone.  This accelerated airflow generates rapid turbulence, which disrupts the natural combustion process and quickly extinguishes the target fire.

The device resembles a small bucket, attached to an arm brace.  Firefighters would aim the bucket toward the fire, and it would use bursts of compressed air to deliver aerosols in an electric arc to fight the fire.

Testing identified a coarse copper solution for the vortex ring material and simulations showed that the device would succeed in suppressing fires.  They then worked on optimizing the power and range of the device.

Depending on the size of the fire and number of firefighters, it is likely that several of the devices would be required in a real emergency.  According to the developers, the design of the vortex launcher is actually very simple and is very scalable.  The device is maneuverable in tight spaces and could be taken through doors and indoor environments.  Vortex rings can carry chemical payloads over longer distances than other methods, making firefighters safe by staying further from flames. 

**********

Web Links

New device uses electrically assisted wind to fight fires

Photo, posted November 12, 2024, courtesy of the USDA Forest Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fighting harmful algal blooms with harmful algal blooms

By Leave a Comment

Harmful algal blooms – HABs – occur when colonies of algae grow out of control and produce toxic or harmful effects on people, marine life, and birds.  HABs occur naturally but their frequency and intensity are often associated with increased nutrient loading (mainly phosphorous and nitrogen) in bodies of water that is the result of runoff from sources like lawncare and agriculture.

Researchers at Florida Atlantic University have developed a technique for transforming cyanobacteria – also known as blue-green algae and a prime HAB material – into an effective material for removing phosphorous from water.

Their process converts blue-green algal biomass – essentially hazardous waste – into a custom-made adsorbent material that can pull harmful phosphorous from water.  The algae is first quickly heated up using microwaves and then it is modified by adding lanthanum chloride. 

The study took blue-green algae from Florida’s Lake Okeechobee, synthesized the adsorbent material in minutes, and using only small amounts of it could remove 90% of the phosphorous present in only half an hour.  It worked perfectly well in the presence of natural organic matter.  Using the harmful algae itself to prevent algal growth in bodies of water is an innovative way to reduce its further occurrence.

Phosphorous is a major contributor to the occurrence of harmful algal blooms, which can lead to toxic water conditions, loss of aquatic life, and significant economic losses for the fishing and tourism industries.  This technique could prove to be an essential tool for managing the growing problem of nutrient pollution.

**********

Web Links

FAU Engineering Develops New Weapon Against Harmful Algal Blooms

Photo, posted October 27, 2010, courtesy of Jennifer L. Graham / U.S. Geological Survey via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A new way to help purify water

By Leave a Comment

Engineers at the University of Michigan and Rice University have developed a new technology for removing boron from seawater, an important step in turning seawater into safe drinking water.

Boron is a natural component of seawater that remains a toxic contaminant in drinking water after conventional filters remove salts from seawater.  The boron levels in seawater are about twice as high as the World Health Organization’s most lenient limits for safe drinking water and 5 to 12 times higher than what many agricultural plants can tolerate.

Boron passes through the reverse osmosis membranes used in desalination plants in the form of boric acid.  To remove it, the desalination plants normally add a base to the treated water that causes the boric acid to become negatively charged.  An additional membrane then removes the charged boron, and an acid is then added to neutralize the water.  All of this is expensive and complicated.

The new technology uses electrodes that remove boron by trapping it inside pores studded with oxygen-containing structures that bind with boron but let other ions pass through.  Capturing boron with electrodes enables treatment plants to avoid the need for a second stage of reverse osmosis.

Global desalination capacity reached 95 million cubic meters a day in 2019.  The new membranes could save nearly $7 billion a year.  Such savings could make seawater a more accessible source of drinking water for a thirsty world.  Freshwater supplies are expected to meet only 40% of the world’s demand by 2030.

**********

Web Links

New water purification technology helps turn seawater into drinking water without tons of chemicals

Photo, posted August 21, 2018, courtesy of Alachua County via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Mining with plants

By Leave a Comment

Plants absorb nutrients and minerals from the soil as they grow and incorporate them into their leaves and stems.  Such plants can be used to remove toxic elements from soil.  Cleaning soil in this way is called phytoremediation. 

Researchers at the University of Massachusetts Amherst are trying to go beyond phytoremediation and do phytomining, in which hyperaccumulated minerals from the soil can be harvested from plants for use in industrial or manufacturing applications.

One mineral that is critically needed for modern technology is nickel.  There are trace amounts of nickel in nearly one million acres of topsoil in the US, making the soil inhospitable for most crops, but the economics and environmental impact of extracting it make doing it impractical. 

A common plant, Alyssum murale, is a nickel hyperaccumulator; in fact, up to 3% of the plant’s biomass can be made up of nickel.  But the plant is slow-growing and difficult to manage and is also considered an invasive species

Another common plant, Camelina sativa, does not have the downsides associated with Alyssum and is also a rich source of valuable biofuel.  The Amherst researchers are working to determine which genes and proteins are responsible for Alyssum’s nickel hyperaccumulation and hope to genetically engineer Camelina sativa to have the same ability.

The researchers believe there is enough nickel in barren soil in the US to supply 50 years of phytomining.  It wouldn’t supply all the nickel the economy needs, but it could account for 20 to 30 percent of the projected demand.

**********

Web Links

Scientists at UMass Amherst Engineer Plant-based Method of ‘Precious’ Mineral Mining

Photo, posted July 10, 2017, courtesy of Matt Lavin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Artificial plants to clean indoor air

By Leave a Comment

The average American spends about 90% of their time indoors breathing the air in our workplaces, homes, or schools.  The quality of this air affects our overall health and well- being.  Indoor air quality is an issue because many sources can generate toxic materials, including building materials, carpets, and more.  But high levels of carbon dioxide are a health hazard themselves. Indoor CO2 levels can often be 5 to 10 times higher than the already heightened levels in the atmosphere. 

Many of us make use of air purification systems, which can be expensive, cumbersome, and require frequent cleaning and filter replacements.

Researchers at Binghamton University in New York are working to develop artificial plants that consume carbon dioxide, give off oxygen, and, as a bonus, generate a little electricity. These artificial plants make use of the artificial light in the indoor environment to drive photosynthesis.  They achieve a 90% reduction in carbon dioxide levels, which is far more than natural plants can achieve.

The Binghamton researchers had been working on bacteria-powered biobatteries for various applications, but they repurposed the work into a new idea for artificial plants.  The artificial plants have “leaves” containing a biological solar cell and photosynthetic bacteria.  Their first plant had five leaves and demonstrated promising carbon dioxide capture rates and oxygen generation.  It also produced a little electricity.  If its generating capacity can be improved, it might also be useful for charging cell phones or other practical applications.

**********

Web Links

Binghamton researchers develop artificial plants that purify indoor air, generate electricity

Photo, posted October 13, 2012, courtesy of F. D. Richards via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Emissions and the Great Salt Lake

By Leave a Comment

The Great Salt Lake in Utah has been described as a puddle of its former self.  The lake’s size fluctuates naturally with seasonal and long-term weather patterns, but the lake has been experiencing decline for decades as Utahans take water out of the rivers and streams that once fed the lake.  Over recent decades, the lake has lost 73% of its water and 60% of its surface area.

For years, scientists and environmental leaders have warned that the Great Salt Lake is headed toward a catastrophic decline.  Recent research has found that the lake’s desiccating shores are becoming a significant source of greenhouse gas emissions.  Scientists have calculated that the dried-out portions of the lakebed released about 4.1 million tons of carbon dioxide and other greenhouse gases in 2020.

The recent study, published in the journal One Earth, suggests that the Great Salt Lake – which is largest saltwater lake in the Western Hemisphere – as well as other shrinking saline lakes around the world could become major contributors of climate-warming emissions.

The shrinking back of the water has exposed a dusty lakebed that is laced with arsenic, mercury, lead, and other toxic substances.  Some are naturally occurring, and others are the residue of mining activity in the region.  These substances threaten to increase rates of respiratory conditions, heart and lung disease, and cancers.

As the lake shrinks, it is becoming saltier and uninhabitable to native flies and brine shrimp and may increasingly become unable to support the 10 million migratory birds and wildlife that frequent it.

The new research about greenhouse gas emissions just adds to a dire list of environmental consequences brought on by the lake’s steep decline.

**********

Web Links

Shrinking Great Salt Lake Becoming Source of Heat-Trapping Gas

Photo, posted January 20, 2020, courtesy of Matthew Dillon via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Biofuel refineries and toxic pollution

By Leave a Comment

There have been decades of government support for renewable, crop-based fuels – primarily corn ethanol.  In fact, it is a required component of gasoline sold in this country.  The biofuels industry has long claimed ethanol to be a clean, greener alternative to petroleum. 

There have been arguments all along that the environmental benefits of corn ethanol are dubious at best because of the energy required to produce the stuff.  There are also issues related to burning a food crop instead of feeding it to people and that the conversion of grasslands and forests to produce it releases massive amounts of carbon.

Recently, another serious concern has emerged.  A new review of industry data has found that the country’s biofuel refineries, mostly located in the Midwest, produce large amounts of toxic air pollutants, in some cases ever more than from their petroleum counterparts.

Emissions data from the country’s 275 ethanol, biodiesel, and renewable diesel plants revealed that they release carcinogenic formaldehyde as well as other potentially dangerous substances including acetaldehyde, hexane, and acrolein.  In 2022, biofuel refineries released 12.9 million pounds of hazardous air pollutants, compared to 14.9 million pounds emitted by oil refineries, and the biofuel plants actually emitted more of the four chemicals just mentioned than petroleum refineries did.

The broad use of crop ethanol is the result of intensive industry lobbying.  Ethanol plants are even exempt from some air pollution permitting requirements.  Perhaps the time has come to revisit its pervasive and mandated use.

**********

Web Links

Biofuel Refineries Are Releasing Toxic Air Pollutants in Farm Communities Across the US

Photo, posted February 27, 2021, courtesy of Sue Thompson via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Car tires in your salad

By Leave a Comment

There seems to be no end to the types of pollution we have introduced into the environment.  One that has only recently started to gain attention is pollution caused by vehicle tires. 

Through normal wear and tear, as vehicles drive along roadways, their tires cast off countless bits of rubber.  These particles can linger in the atmosphere or can be washed down sewage drains and into waterways.  In the water, these particles leach compounds that are toxic to wildlife.

Tires contain various chemical additives that prevent them from cracking and degrading along with various metals and other materials added to rubber and artificial rubber.  Some of these additives are acutely toxic or even carcinogenic.

A recent study by researchers at the University of Vienna tested leafy vegetables that were grown in Switzerland, Spain, and Italy, and were sold in Swiss supermarkets.  The study also tested vegetables harvested directly from Israeli farmlands.

Tire ingredients were found in 11 out of 15 samples gathered from Swiss supermarkets and 9 out of 13 samples collected from Israeli fields.  Among these are 6PPD, a tire additive that has been identified as the cause of the extensive deaths of coho salmon on the US West Coast.

The researchers say that farmers may be introducing tire additives by irrigating crops with treated wastewater or by using sewage sludge as fertilizer.  Airborne tire particles may also be settling on farm soil.

The concentration of tire particles found in the leafy vegetables are relatively low, but it is troubling that we are eating dangerous chemicals used to improve the quality of tires.

**********

Web Links

Leafy Vegetables Found to Contain Tire Additives

Photo, posted October 14, 2014, courtesy of Green Mountain Girls Farm via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Beware of the blob

By Leave a Comment

For the past 10 years, there have been several occurrences of a vast expanse of ocean stretching from Alaska to California in which water temperatures are as much as 7 degrees Fahrenheit warmer than normal.  Known jocularly as “the Blob,” the phenomenon can last for several years and decimates fish stocks, starves seabirds, creates blooms of toxic algae, prevents salmon from returning to rivers, and displaces sea lions and whales.

Until recently, there was no accepted explanation for this abrupt ocean heating.  Climate change, even combined with natural cycles like El Niños, is not enough to account for it.

In depth analysis by an international team of researchers has found that the extraordinary heating is the result of a dramatic cleanup of Chinese air pollution.  The decline of smog particles, which to some extent shield the planet from the sun’s rays, has accelerated warming and set off a chain of atmospheric events across the Pacific, essentially cooking the ocean.

This is an example of what can be called the pollution paradox in which global warming is actually increased when air pollution is reduced.  Reduced air pollution on the US West Coast has even been identified as a factor contributing to increased wildfires.  However, air pollution causes more than 4 million premature deaths from cancers and respiratory and cardiovascular diseases each year. 

Nobody thinks that we should stop cleaning up the air to slow down global warming.  The only viable solution is to reduce greenhouse gas emissions as rapidly as possible.

**********

Web Links

Pollution Paradox: How Cleaning Up Smog Drives Ocean Warming

Photo, posted December 18, 2017, courtesy of SGUP via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Storing carbon underground and abandoned wells

By Leave a Comment

Using government support in the form of subsidies and tax credits, energy companies and others are planning to capture millions of tons of industrial carbon dioxide emissions and pipe the greenhouse gas into underground storage.  It is a strategy enthusiastically supported by the fossil fuel industry because it allows them to keep burning the stuff.

There are currently 69 projects being reviewed by federal and state regulators seeking to store CO2 underground.  The sorts of places where carbon dioxide can be injected are geologic zones containing porous rock formations which, in no way coincidentally, are the same places where oil and gas deposits are found.  As a result, these places are studded with abandoned wells that have accumulated over the past century.

In Louisiana, there are about 120,000 abandoned wells that overlie geological zones that could store carbon dioxide.  Environmental watchdog groups have identified numerous abandoned wells within a few miles of proposed storage sites.

The problem is that abandoned wells leak – even ones that have been plugged – and many haven’t been.  The question is how much leakage will occur and what will be the consequences of the leakage.  In Texas, pumping oilfield wastewater into abandoned wells has led to geysers of toxic water, artificial saline lakes, and earthquakes.

Underground carbon dioxide sequestering on a scale large enough to really matter will have to extend to very large areas.  For example, injecting 100 million tons per year could create a pressurized zone as large as 100 miles.  How large a problem this might create from abandoned wells in the zone is not at all clear but cannot be ignored.

**********

Web Links

Companies Are Poised to Inject Millions of Tons of Carbon Underground. Will It Stay Put?

Photo, posted December 3, 2023, courtesy of Jason Woodhead via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Mercury in tuna

By Leave a Comment

Mercury is found throughout the ocean, and there is at least some of it in any fish one might eat. It is an element found naturally in the environment, but it is also a byproduct of manmade pollution. Generally speaking, bigger fish tend to have higher mercury levels than smaller ones, because they are higher up in the food chain. The more small fish those big fish eat, the more mercury builds up in their bodies.  Tuna aren’t the biggest fish in the ocean, but they are very common in many people’s diets.

Increased mercury levels are a result of human activities like burning coal and mining which release methylmercury into the air.  It then finds its way into the oceans in rainwater.  Methylmercury is a particularly toxic chemical that affects the nervous system.  Environmental protection policies in recent decades have helped to reduce mercury pollution.

However, a recent study by French researchers looked at the mercury levels in tuna over the past 50 years.  They found that the levels have basically not changed since 1971.  As a result, they are calling for more restrictive environmental policies to further lower mercury pollution levels.

The researchers explained that the lowering of mercury airborne levels to date has not necessarily been ineffective.  They theorized that the static levels in tuna may be caused by the upward mixing of “legacy” mercury from deeper ocean water into the shallower depths where tropical tuna swim and feed.  It could very well take decades to dramatically reduce ocean mercury levels. 

Meanwhile, mercury content in tuna varies considerably by tuna type and source and there are both better and worse choices out there.  Consumers should learn the facts.

**********

Web Links

Mercury levels in tuna remain nearly unchanged since 1971, study says

Photo, posted November 7, 2015, courtesy of Mussi Katz via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Red mud and steel

By Leave a Comment

Most of us have never heard of red mud.  Otherwise known as bauxite residue, it is an industrial waste product generated by the most common process by which aluminum is made and the world produces 200 million tons of red mud each year.  The stuff is a significant environmental hazard being extremely alkaline and corrosive. Most of it ends up in large landfills and the costs associated with disposing of red mud are substantial.

Red mud is red because it contains large amounts of iron oxide, often as much as 60% of it.  Scientists at the Max-Planck Institute in Germany have developed a method for producing steel from red mud that is much less carbon intensive than traditional steel production and that is economically viable.

The scientists melt the red mud in an electric furnace powered in part by green hydrogen.  Running the furnace this way, even when using electricity from only partially renewable sources, results in far fewer greenhouse gas emissions as well as economic benefits.  In the furnace, liquid iron separates from the other liquid oxides and can be extracted easily.  The resultant iron is so pure that it can processed directly into steel.  The remaining metal oxides are no longer corrosive, and they solidify into a glass-like material that can have practical uses in construction.

There are 4 billion tons of red mud that have accumulated worldwide to date.  According to the researchers, their process could produce over 700 million tons of green steel from it, potentially saving 1.6 billion tons of carbon dioxide emissions. 

**********

Web Links

Green steel from toxic red mud

Photo, posted September 7, 2021, courtesy of Healthy Gulf via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Bio-based products on the rise

By Leave a Comment

There is a growing global movement working towards replacing conventional synthetic products – ones that are toxic to make or use, difficult to recycle, and have large carbon footprints – with products made from plants, trees, or fungi that can be safely returned to the earth at the end of their useful life.  This so-called bioeconomy is in its infant stages, but there is increasing interest in turning successful research into manufactured products.

One example is nylon.  Nylon was created in the 1930s by DuPont.  It has been used and continues to be used in a wide range of products.  The problem with it is that it is made from petroleum, it doesn’t biodegrade, and producing it generates nitrous oxide, which is a problematic greenhouse gas.

A San Diego-based company called Genomatica has developed a plant-based nylon using biosynthesis, a process in which a genetically engineered microorganism ferments plant sugars to create a chemical intermediate that can be turned into the nylon-6 polymer, and then into textiles. 

The impetus for developing bio-based products includes the growing public disgust at the mounting environmental toll of plastic, not the least of which is that people and animals are increasingly ingesting it.  Coupled with this, there is a rapidly-growing torrent of funding, especially in the US and Europe, aimed at accelerating the transition away from products that are non-biodegradable, toxic, and that produce carbon emissions.   Last September saw the launch of the National Biotechnology and Biomanufacturing Initiative which will support research and development on such topics as the use of sustainable biomass and waste resources to make non-toxic, bio-based fuels, chemicals, and fertilizers.

**********

Web Links

From Lab to Market: Bio-Based Products Are Gaining Momentum

Photo, posted May 27, 2010, courtesy of André C via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Action on the toxic chemical from tires

By Leave a Comment

Since the 1990s, populations of coho salmon in streams and urban creeks up and down the West Coast have been dying in large numbers.  Scientists at the University of Washington began studying the mysterious deaths and it took years to figure out what was going on.  They analyzed water samples from urban creeks and found that chemicals from vehicle tires were present.  By soaking tires in water, they found that more than 2,000 chemicals were present.  It took three years to narrow down the suspect list to one chemical:  a toxin called 6PPD-quinone, which is produced when the common tire preservative 6PPD mixes with oxygen.  It is that chemical that was responsible for the salmon die-off.

6PPD-quinone is toxic enough to quickly kill some fish.  Studies showed that concentrations of the chemical in stormwater were found to be lethal for coho salmon following exposures lasting only a few hours.

Despite the discovery, the tire industry has continued to use the chemical in its products.  The industry says 6PPD is an antioxidant and antiozonant that helps prevent degradation and cracking of tires in the environment and is essential for the performance and safety of vehicles.

Last year, California regulators directed the tire industry to seek out substitutes for 6PPD.  The U.S. Tire Manufacturers Association pledged to investigate possible safer alternatives to the chemical.

In November, spurred by a petition by West Coast tribes whose lifeways depend on coho salmon, the EPA said it will study the impact of 6PPD with an eye to potentially banning its use. 

**********

Web Links

After Salmon Deaths, EPA Takes Aim at Toxic Chemical Issuing from Car Tires

Photo, posted May 31, 2021, courtesy of Chris Yarzab via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Electricity from chicken feathers

By Leave a Comment

The food industry generates enormous amounts of waste and by-products.  Each year, 40 million tons of chicken feathers are incinerated, causing adverse environmental effects.  Not only does it release large amounts of carbon dioxide but also produces toxic gases such as sulfur dioxide.

Researchers at ETH Zurich in Switzerland and Nanyang Technological University in Singapore have developed a way to put chicken feathers to good use by using them to make fuel cells more cost-effective and sustainable.

Using a simple and environmentally friendly process, they extract the keratin from the feathers.  Keratin is the protein that helps form hair, nails, the outer layer of skin, and feathers.  The extracted keratin is then converted into ultra-fine fibers known as amyloid fibrils.  The keratin fibrils are used in the membrane of a fuel cell.

Fuel cells generate clean energy from hydrogen and oxygen with only heat and water as byproducts.  At the heart of every fuel cell is a semipermeable membrane that allows protons to pass through but blocks electrons, thereby producing an electric current.  Fuel cells are the primary way hydrogen is used to directly generate electricity.  Hydrogen cars run on fuel cells.

Conventional fuel cells typically use membranes made from highly toxic chemicals.  The new ETH membranes essentially replace these toxic substances with biological keratin. 

The researchers are investigating how stable and durable their keratin membrane is and to improve it if necessary.  The team has already applied for a joint patent and is looking for partners and investors to further develop the technology and bring it to market.

**********

Web Links

Generating clean electricity with chicken feathers

Photo, posted July 10, 2016, courtesy of Matthew Bellemare via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Megafires and ecosystems

By Leave a Comment

Wildfires are a natural phenomenon.  They have occurred long before there were people around.  Ecosystems adapt to fires and some species can benefit from them or even depend upon them.  But in recent times, fires have been intensifying and increasing in frequency and they are beginning to outstrip nature’s ability to bounce back from them.

So-called megafires – ones that dwarf typical wildfires in size – have an immediate ecological toll.  They kill individual plants and animals that might have survived smaller fires. 

Over millennia, many species of plants and animals have evolved to adapt to periodic fires.  They are especially sensitive to smoke and take protective action in a timely fashion. Others take advantage of food sources that arise when trees burn.

But even species that capitalize on burned-out areas of forests require oases of healthy woodland for at least part of their activities.  When fires are too widespread, such oases are too few and far between.

Animals that survive fires must find food, water, and shelter in the aftermath.  And all air-breathing animals are going to be impacted by smoke exposure because the chemicals in smoke are toxic to them as well as to people.

In places like Canada’s Northwest Territories, repeated fires have transformed some forests, eliminating dominant tree species and replacing them with others whose light seeds were carried on the wind.

Scientists have estimated that increased global fire activity could push more than 1,000 threatened plant and animal species closer to extinction.  Changing fire patterns are transforming landscapes and utterly remaking ecosystems.

**********

Web Links

How Megafires Are Remaking the World

Photo, posted December 19, 2022, courtesy of Brian Pippin/USFWS via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)