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Cleaning Up Forever Chemicals | Earth Wise

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PFAS, per- and polyfluoroalkyl substances, are chemical pollutants that threaten human health and ecosystem sustainability.  They are used in a wide range of applications including food wrappers and packaging, dental floss, firefighting foam, nonstick cookware, textiles, and electronics.  Over decades, these manufactured chemicals have leached into our soil, air, and water.  Chemical bonds in PFAS molecules are some of the strongest known, so the substances do not degrade easily in the environment.

Studies have shown that at certain levels, PFAS chemicals can be harmful to humans and wildlife and have been associated with a wide variety of health problems.

Currently, the primary way to dispose of PFAS chemicals is to burn them, which is an expensive multistep process.  Even trace levels are toxic, so when they occur in water in low amounts, they need to be concentrated in order to be destroyed.

Researchers at Texas A&M University have developed a novel bioremediation technology for cleaning up PFAS.  It uses a plant-derived material to absorb the PFAS which is then eliminated by microbial fungi that literally eat the forever chemicals.

The sustainable plant material serves as a framework to adsorb the PFAS.  That material containing the adsorbed PFAS serves as food for the fungus.  Once the fungus has eaten it, the PFAS is gone. 

The EPA has established a nationwide program to monitor the occurrence and levels of PFAS in public water systems and is considering adding PFAS threshold levels to drinking water standards.  If this happens, the technology developed at Texas A&M may become an essential part of municipal water systems.

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Texas A&M AgriLife develops new bioremediation material to clean up ‘forever chemicals’

Photo, posted August 10, 2013, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Removing Lead From Water With Beer Yeast | Earth Wise

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Lead and other heavy metals in water are a serious global problem that is worsening because of electronic waste and discharges from mining operations.  In the U.S., over 12,000 miles of waterways are impacted by mine-drainage water that is rich in heavy metals.

Lead in particular is highly toxic, especially to children.  The European Union established a standard for allowable lead in drinking water of only 5 parts per billion.  In the US, the EPA has declared that no level of lead at all is safe.

Researchers at MIT have recently discovered that inactive yeast can be effective as an inexpensive, abundant, and simple material for removing lead contamination from drinking water supplies.  The MIT study shows that the method works even at parts-per-billion levels of contamination.

The method is called biosorption, in which inactive biological material is used to remove heavy metals from water.  Previously, it has been studied at parts-per-million contaminant levels, but the MIT study shows that it works at much lower levels as well.

The team studied a type of yeast widely used in brewing.   The yeast cells used are inactive and desiccated and require no special care.  Such yeast is abundantly available as a waste product from beer brewing and various other fermentation-based industrial processes. 

The researchers estimate that to clean a water supply for a city the size of Boston would require about 20 tons of yeast a day, or 7,000 tons a year.  That seems like a lot, but one single brewery, the Boston Beer Company, generates 20,000 tons a year of surplus yeast that is no longer useful for fermentation.

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Could used beer yeast be the solution to heavy metal contamination in water?

Photo, posted September 5, 2017, courtesy of Allagash Brewing via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Sunscreen And Coral Reefs | Earth Wise

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The dangers of overexposure to UV solar radiation have led to the extensive production and use of sunscreen products.  It is generally understood that many of the chemical compounds used in sunscreen products have toxic effects on marine organisms, but research in this area is relatively limited.

There are estimates that as many as 82,000 kinds of chemicals from personal care products have made their way into the world’s oceans.  In 2015, it was estimated that around 14,000 tons of sunscreen are ending up in the world’s coral reefs per year and causing irreparable damage.

Eighty-five percent of the Caribbean’s coral reefs died before the turn of the century, not as a result of global warming, but because of pollution.  Oxybenzone and octinoxate are two of the common sunscreen ingredients that are most toxic to corals.  Preservatives like parabens are also toxic.

There are much safer sunscreens such as those based on zinc oxide or titanium oxide.  In some places, such eco-friendly sunscreens are mandatory.  Sunscreens with SPF values above 30 contain a higher percentage of chemicals and have been shown to not really provide any more protection than SPF 30 products.

Apart from the choice of sunscreen product, if one really wants to reduce the negative impact sunscreen has on reefs and marine life, wearing sun-protective clothing such as rash-guards will allow the use of much less sunscreen and therefore result in less of it entering the ocean.

Products that can help protect against the harmful effects of UV radiation on human health are extremely important, but it is also important to identify and quantify the risks associated with these products to reef ecosystems.

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How to Know If Your Sunscreen Is Killing Coral Reefs — and the Brands to Try Instead

Impacts of sunscreen on coral reefs needs urgent attention, say scientists

Photo, posted January 11, 2015, courtesy of Elch Korallen via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Turning Wood Into Plastic | Earth Wise

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Plastic pollution is particularly pernicious because plastics can take hundreds of years to degrade in the environment.  For this reason, researchers across the globe search for ways to shift from petrochemical plastics to ones that are biodegradable.

Producing biodegradable plastics is challenging both from the standpoint of the methods needed and from the results obtained.  Producing them often requires toxic chemicals and can be very expensive.  The materials that emerge often do not have the durability and strength of conventional plastics and can be unstable when exposed to moisture.

Researchers at the Yale School of the Environment have developed a process of decomposing the porous matrix of natural wood into a slurry that can be formed into a biodegradable plastic.  The material shows high mechanical strength, stability when holding liquids, and is resistant to the effects of ultraviolet light.  Along with all these favorable properties, the material can be recycled or safely biodegraded in the natural environment.

The slurry mixture is created by taking wood powder – a processing residue usually discarded in lumber mills – and deconstructing it with a biodegradable and recyclable solvent.  The resulting mixture has a high solid content and high viscosity and can be casted and rolled without breaking.

The researchers conducted a comprehensive life cycle assessment to test the environmental impacts of the bioplastic compared with conventional plastics.  Sheets of it were buried in soil and observed to fracture after two weeks and completely degrade after three months.  The material can also be broken back down into the slurry by mechanical stirring.

The remaining topic to investigate is the potential impact on forests if the manufacturing of this bioplastic is scaled up.

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Turning wood into plastic

Photo, posted October 12, 2016, courtesy of the US Forest Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Polystyrene | Earth Wise

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The proliferation of global plastic waste continues to be a growing problem for the world.  Hundreds of millions of tons of plastics are produced each year and most of it is used once and then discarded.  The properties that make plastics so attractive – durability and chemical stability – make it difficult to do anything with discarded plastics other than deposit them in landfills – where they don’t easily degrade over time – or burn them, which dumps carbon dioxide and various hazardous gases into the atmosphere.

Polystyrene is one of the most widely used plastics.  It is found in foam packaging materials, disposable food containers, plastic cutlery, storage containers, and many other places. 

Recycling plastics like polystyrene is generally not economically feasible.  Sorting plastics by type is time and labor intensive and the chemical processes required to break down plastics into usable precursor materials require significant energy input and the use of toxic solvents.

Recently, a team of scientists at Ames Laboratory in Iowa has developed a process based on ball-milling that deconstructs commercial polystyrene in a single step, at room temperature, in ambient atmosphere, and in the absence of harmful solvents.

Ball-milling is a technique that places materials in a milling vial with metal ball bearings which is then agitated to initiate a chemical reaction.  This approach is known as mechanochemistry.

The method represents an important breakthrough that enables dismantling of a polymer that includes its chemical breakdown without requiring solvents or the high temperatures generally needed to thermally decompose it.  This discovery opens up new avenues for low-temperature recovery of monomers from polymer-based systems that include composites and laminates.  It could be a very useful weapon in the battle against plastic waste.

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Polystyrene waste is everywhere, and it’s not biodegradable. Scientists just found a way to break it down.

Photo, posted December 11, 2010, courtesy of Warrenski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Livestock Expansion And Global Pandemics | Earth Wise

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The domestication of cows, pigs, chickens, and other animals as livestock for their meat, milk, and eggs was historically revolutionary.  It boosted food security by giving people a readily-available means of feeding themselves as opposed to more traditional methods such as hunting and fishing. 

But animal agriculture has plenty of drawbacks.  The industrialization of animal agriculture has led to horrendous conditions.  Animals are kept in huge quantities and packed together with little regard for their health and welfare.  This approach to agriculture is simply designed to maximize production while minimizing costs. 

With its chemical inputs and toxic outputs, intensive animal agriculture is also a major threat to the environment.  In fact, it’s a major driver of habitat degradation and biodiversity loss all around the globe.   

But it’s not just animals and the planet that pay a price.  Humans have inherited several lethal pathogens from livestock over the years, including the influenza virus that likely jumped to humans from poultry.

According to a study recently published in Biological Conservation,  there is a connection between the global increase in the emergence of infectious diseases and epidemics, the accelerated loss of biodiversity, and the expansion of livestock.  In the study, the research team from the Institute of Evolution Sciences of Montpellier cross referenced databases on human and animal health, livestock expansion, and biodiversity loss between 1960-2019.  The team found that the number of epidemics identified in humans increased in correlation with both biodiversity loss and livestock expansion. 

In the era of COVID-19, it’s important to understand how global livestock expansion directly threatens both human health and the health of the planet. 

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Livestock expansion is a factor in global pandemics

Photo, posted July 22, 2018, courtesy of Artem Beliakin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Controlling Malaria Without Chemicals

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Nearly half of the world’s population lives in areas vulnerable to malaria.  The disease kills roughly 450,000 people each year, most of them children and pregnant women.  Malaria is spread by Anopheles mosquitoes and, over time, the mosquitoes have been developing resistance to the chemical insecticides that are used to control them.  In addition, there is great concern about the toxic side effects of the chemicals used on the mosquitoes.

About 30 years ago, scientists identified a type of bacteria that kills Anopheles, but the mechanism was not understood.  As a result, the bacteria could not be replicated or used as an alternative to chemical insecticides.

But now, an international research team, headed by researchers at UC Riverside, has identified the neurotoxin produced by the bacteria and has determined how it kills Anopheles.  The work is described in a paper published in Nature Communications.

It took the team 10 years to achieve a breakthrough in understanding the bacteria.  Modern gene sequencing techniques were the key.

While many neurotoxins target vertebrates and are highly toxic to humans, the neurotoxin that kills Anopheles mosquitoes does not affect humans, vertebrates, fish, or even other insects.  Known as PMP1, the substance is not even toxic to mice when given by direct injection.

The team has applied for a patent on this discovery and hopes to find partners to help them develop the bacteria-based insecticide.

There is a high likelihood that PMP1 actually evolved to kill the Anopheles mosquito.  This finding opens the door to new avenues of research into other environmentally friendly insecticides that would be targeted at other disease-spreading pests.

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Controlling deadly malaria without chemicals

Photo, posted June 9, 2018, courtesy of Mario Yardanov via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Concerns About Dam Safety

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The United States has a total of 91,000 dams of various sizes and types.  Many of them are aging and sorely in need of repairs.  All that maintenance would add up to tens of billions of dollars.  Experts are increasingly worried that as extreme precipitation events become increasingly common, dams are increasingly at risk of failure, threatening lives and posing environmental risks.

In 2017, Oroville Dam in California – the tallest dam in the country – nearly collapsed.  That incident forced the evacuation of 190,000 people and cost the state of California $1.1 billion in repairs.  California is considered one of the nation’s leading states in dam safety management and yet the partial disintegration of Oroville’s two spillways during a heavy rainstorm was not anticipated.

So far, federal and state dam safety officials have not been able to get disinterested state legislatures and the U.S. Congress to fork up the money needed for repairs to the nation’s aging dam infrastructure.

Th American Society of Civil Engineers gave the nation’s dams a D grade on the latest infrastructure report card.  They estimate that the cost of rehabilitating dams whose failure would threaten human life at nearly $45 billion, and the cost of fixing all dams in need of repair at more than $64 billion.

Scientists say the likelihood of dam failures – which not only threaten lives but also release toxic sediments trapped in reservoirs behind many dams – will increase as extreme precipitation events become more frequent in a warming world.  Apart from about 1,500 dams owned by federal agencies, regulating dam safety is primarily the responsibility of the states.  So far, states have not applied remotely sufficient resources to a growing problem.

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In an Era of Extreme Weather, Concerns Grow Over Dam Safety

Photo, posted August 20, 2014, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

High-Tide Flooding And Pollution

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Global sea levels are steadily rising.  They are up 8 inches in the past century and now increasing at an average of 1.3 inches per decade.  As a result, the incidence of high-tide “sunny day” flooding is on the rise, especially along the U.S. East Coast.

Norfolk Virginia experienced fewer than 2 days of high-tide flooding a year in the 1960s; it had 14 in 2017.  Up and down the East Coast, flood days have increased by factors of 5 and more.

This has led to a form of pollution that hasn’t gathered much attention in the past:  when these floodwaters recede, they can carry debris, toxic pollutants and excess nutrients into rivers, bays, and oceans.

In the aftermath of high-tide flooding in Norfolk, Chesapeake Bay was littered with tipped-over garbage cans, tossed-away hamburgers, oil, dirty diapers, pet waste and all manner of other things.  Water that comes up on the landscape takes everything back into the river or ocean with it.

Analysis of tidal flooding along the Lafayette River in Norfolk indicated that just one morning of tidal flooding poured nearly the entire EPA annual allocation of nitrogen runoff for the river – nearly 2,000 pounds – into Chesapeake Bay.  The effects of excess nitrogen in the water are well-known and responsible for the toxic algal blooms that endanger aquatic life as well as human health.

According to the National Oceanic and Atmospheric Administration, high-tide flooding frequency along the southeastern coast of the U.S. rose 160% since 2000.  With the expected continuing rises in sea level, NOAA projects that as many as 85 days of high-tide flooding will occur along the coast by the year 2050.  It’s a big problem.

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As High-Tide Flooding Worsens, More Pollution Is Washing to the Sea

Photo, posted September 20, 2018, courtesy of SC National Guard via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Protection From Toxic Algae

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Toxic algal blooms have been a growing problem in recent years associated with warming waters and nutrient-rich agricultural runoff in lakes, rivers, and oceans.  In 2014, an algal bloom in Lake Erie left half a million residents of Toledo, Ohio without safe drinking water for three days.

The most common toxic substance released by algal blooms in the lake is called microcystin, which is closely linked to liver cancer and other diseases.  Toxicologists measure microcystin and other contaminants using the metric of parts per billion.  The EPA recommends that young children not drink water containing more than 0.3 parts per billion and adults no more than 1.6 parts per billion of microcystin.

Scientists at the University of Toledo have been working on developing a biofilter that uses naturally occurring Lake Erie bacteria to remove microcystin released by algal blooms and thereby reduce or eliminate the use of chlorine and other chemicals.

They have successfully isolated a number of types of bacteria that degrade microcystin toxin at a daily rate of up to 19 parts per billion.  To their knowledge, such bacteria have not been previously used to fight algal blooms in other parts of the world.  Based on the recorded toxin levels in Lake Erie in recent years, the bacteria would be able to effectively remove microcystin from water supplies.  None of the 13 bacterial isolates they found have any association with human disease so their use in future water-purifying biofilters should not pose a public health concern.

The researchers are now developing and testing biofilters, which are water filters containing the specialized bacteria that will degrade the toxins from lake water as it flows through the filter.

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Scientists advance new technology to protect drinking water from Lake Erie algal toxins

Photo, posted April 30, 2014, courtesy of NOAA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Hacking Photosynthesis

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There is an enzyme known as RuBisCo that is involved in carbon fixation, the process plants use to convert carbon dioxide into sugar molecules.  The RuBisCo molecule is inside the leaves of most plants and is probably the most abundant protein in the world.

RuBisCo picks up carbon dioxide from the air and uses energy from the sun to turn the carbon into sugar molecules.  This process of photosynthesis is pretty much the foundation of life on Earth.

Wonderful as it is, the process is not perfect.  RuBisCo is not very selective in grabbing molecules from the air.  It picks up oxygen as well as CO2 and it produces a toxic compound when it does that.

Plants operate a whole other complicated chemical process to deal with this toxic byproduct and uses up a lot of energy along the way, leaving less energy for making leaves or food that we can eat.

A research program at the University of Illinois called Realizing Increased Photosynthetic Efficiency (or RIPE) has been trying to correct this problem; they have been trying to hack photosynthesis.  And they may well have succeeded.

Using genetic modification on tobacco plants, they have shut down the existing detoxification process and set up a much more efficient new one.  The result is super plants that grow faster and up to 40% bigger.

The next step is to get it to work on plants that people actually rely upon for food, like tomatoes, soybeans and black-eyed peas (which are a staple food crop in sub-Saharan Africa where food is scarce.)

It will be years before we know if the process can really produce more food and be safe, but it may end up leading to a major increase in crop productivity.

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Scientists Have ‘Hacked Photosynthesis’ In Search Of More Productive Crops

Photo, posted June 10, 2013, courtesy of Boon Hong Seto via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Fumes From Gas Stations

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A study by environmental health scientists at Columbia University examined the release of vapors from gas station vent pipes and found that emissions were 10 times higher than the estimates used to establish setback regulations that determine how close schools, playgrounds, and parks can be to the facilities.

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Hippo Waste And Fish

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Agricultural and sewage pollution can cause low-oxygen conditions and fish kills in rivers. A new study published in Nature Communications reports that hippo waste can have a similar effect in Africa’s Mara River, which passes through the world renowned Maasai Mara National Reserve of Kenya and is home to more than 4,000 hippos.

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Infinitely Recyclable Plastic

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Less than 10% of discarded plastic is recycled.  This is one of the major reasons that plastic waste is such a threat to the environment.  There are many challenges to recycling plastics.  For one thing, there are many different types of plastic and if they are melted together, they tend to phase-separate like oil and water and the resultant substance is structurally weak.  Sorting plastics by type is not a simple task.   More generally, it is very difficult to produce plastic with its original properties from recycled feedstock.  So recycled plastics generally end up being useful in only more limited applications.

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Is It Time to Ban Neonics?

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Neonicotinoids (or ‘neonics’ for short) are a class of insecticides chemically related to nicotine.  In fact, the name ‘neonicotinoid’ literally means “new nicotine-like insecticide.”  And like nicotine, neonics act on certain kinds of receptors in the nerve synapse.  Most corn, soy, and wheat seeds planted today are coated with neonics, which is reportedly 5,000 to 10,000 times more toxic than DDT. 

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The Chinese War On Pollution

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For years, China has been struggling with some of the worst air pollution in the world.  According to the European Union, only 1% of the country’s half a billion city dwellers were considered safe because almost all of its major cities were covered with what was described as a toxic grey cloud.

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Turning Biofuel Waste Into Valuable Chemicals

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When biofuels are made, tough plant material is left over as waste.  The material is lignin, which is a main component of plant cell walls that gives plants their structural integrity.  Lignin is made up of many valuable compounds, but taking it apart to extract them is very difficult.

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Is A Real Christmas Tree Or A Fake One Better for the Planet? 

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For many, the Christmas tree is a quintessential part of the holiday season.  According to the American Christmas Tree Association, 81% of Christmas trees Americans decorated in 2016 were artificial.  But are artificial trees really the better option for the environment?

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