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Natural hydrogen

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Hydrogen is considered to be a potential substitute for conventional fossil fuels in applications where electricity cannot easily be used such as in blast furnaces, cement works, industrial heating, long-distance aviation, and shipping.  But most hydrogen is manufactured by separating it from methane, which is energy-intensive and produces carbon dioxide.  So-called green hydrogen is made by splitting water using electricity.  It is a carbon-free process if the electricity is from renewable sources, but it is pretty expensive.

A small community in Mali gets its electricity by burning natural hydrogen, which bubbles up from underground into a village well.  It has long been known that processes in the Earth’s crust can make hydrogen gas from water under certain circumstances.  But conventional wisdom has been that this occurrence is rare and that the hydrogen produced is either inaccessible or seeps away.

An increasing number of geoscientists now are convinced that there is actually an enormous quantity of hydrogen beneath the planet’s surface and that we just haven’t been looking for it in the right places, or at all, for that matter.  Some say that there could be trillions of tons of hydrogen, and more is being generated all the time.

Prospectors have recently been drilling for hydrogen in France, Australia, Morocco, Brazil, and in the United States, in Nebraska, Arizona, and Kansas.  Will extracting natural hydrogen be practical at the scale required and will it be economical?  The jury is still out on all of this, but if it turns out as proponents claim, natural hydrogen could be a very big deal.

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Natural Hydrogen: A Potential Clean Energy Source Beneath Our Feet

Photo, posted November 4, 2012, courtesy of Heather Paul via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

What’s Been Killing Salmon? | Earth Wise

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For decades, there have been mysterious deaths of Coho salmon.  The salmon return from the Pacific Ocean each year to spawn along the West Coast.   They can be found from Alaska all the way down into California.  After heavy rain events each fall, fish have been turning up dead in huge numbers before they spawn.  Normally, less than 1% of adult Coho die before spawning. In these mass death events, anywhere from 40% to 90% of fish can perish in affected streams.  The mysterious phenomenon has been the subject of intense research for years.

Recently, scientists announced that they may have solved the mystery.  There is a chemical antioxidant known as 6PPD that is used in the manufacture of tires around the world to make them last longer.  As tire treads break down over time, they leave behind bits of microplastics on roads.  The 6PPD in the plastic bits reacts with ozone to become another chemical:  a previously unreported substance called 6PPD-quinone.

That chemical turns out to be toxic to Coho salmon.  Researchers have found the presence of 6PPD-quinone in roadway water runoff samples taken from across the West Coast.  Based on these observations, they believe it is likely that exposure to this chemical is the main cause of the Coho salmon population decline.

Coho salmon are a favorite of sport fishermen and have great cultural significance to many Native American tribes on the West Coast.  The central California Coho population is classified as endangered and three other Coho populations are listed as threatened.

Tire industry representatives call the study results “preliminary” but say the industry is deeply committed to protecting the environment.  A safe chemical substitute for 6PPD is clearly needed.

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Salmon have been dying mysteriously on the West Coast for years. Scientists think a chemical in tires may be responsible

Photo, posted November 17, 2011, courtesy of Lynn Ketchum/Oregon State University via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Clean Gas From An Artificial Leaf

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Photosynthesis is the process used by plants, algae and certain bacteria to harness energy from sunlight and turn it into chemical energy.  It is often described as the green engine of life on earth.

For quite some time, there have been extensive research efforts around the world in the area of artificial photosynthesis.  The goal is to somehow mimic the behavior of plants in order to generate clean-burning fuels using nothing more than sunlight and the carbon dioxide in the air.

Researchers at the University of Cambridge have recently demonstrated a so-called artificial leaf that can directly produce syngas using sunlight.   Syngas is a fuel gas mixture consisting primarily of hydrogen and carbon monoxide.  Most people haven’t heard of syngas, but many products are created using it.  Being able to produce it sustainably would be a critical step to a far greener chemical and fuel industry.

The artificial leaf contains two light absorbers, similar to the molecules in plants that harvest sunlight, which are combined with a catalyst made from the naturally abundant element cobalt.  When the device is immersed in water, one light absorber uses the catalyst to produce oxygen.  The other carries out the chemical reaction that reduces carbon dioxide and water into carbon monoxide and hydrogen.  The result is the syngas mixture.

It turns out that even a rainy or overcast day provides enough light to drive the process.

Previous artificial leaf devices have mostly just produced hydrogen.  The Cambridge device produces syngas thanks to the novel combination of materials and catalysts it uses.

The researchers are now focused on finding ways to use the technology to produce a sustainable gasoline substitute.

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‘Artificial leaf’ successfully produces clean gas

Photo, posted August 15, 2014, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)