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solvents

Removing nanoplastics from water

September 26, 2024 By EarthWise Leave a Comment

Plastic pollution is a growing problem for people and for the environment in multiple ways.  When plastics break down over time, they can form small particles called microplastics – bits smaller than sesame seeds – and these, in turn, can break down into even smaller pieces called nanoplastics.  They are too small to be seen with the naked eye and can enter the body’s cells and tissues.

Recent studies have shown that nanoplastics are increasingly showing up in bottled water.  In fact, measurements on several popular brands of bottled water found an average of nearly a quarter million tiny pieces of plastic in a single liter of bottled water.

The health effects of ingesting all of this plastic are not really known, but they are unlikely to be anything good.  Finding a way of avoiding this contamination of the beverages we drink is a pressing need.

Researchers at the University of Missouri have created a new liquid-based solution that eliminates more than 98% of microscopic plastic particles from water.  The method makes use of water-repelling solvents made from safe, non-toxic natural ingredients. A small amount of this designer solvent absorbs plastic particles from a large volume of water.

The solvent sits on the water’s surface.  When mixed with the water, it absorbs the plastic and eventually comes back to the surface carrying the plastic leaving behind clean, plastic -free water.

Ultimately, the hope is to scale up the process so it can be applied to increasingly large amounts of water – even lakes and, eventually, oceans.  There is work to be done, but it is a potential way to address an increasingly worrisome and pervasive form of pollution.

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Mizzou scientists achieve more than 98% efficiency removing nanoplastics from water

Photo, posted August 9, 2012, courtesy of Enid Martindale via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Breaking Down Polystyrene | Earth Wise

April 20, 2021 By EarthWise Leave a Comment

Scientists have developed a way to break down polystyrene

The proliferation of global plastic waste continues to be a growing problem for the world.  Hundreds of millions of tons of plastics are produced each year and most of it is used once and then discarded.  The properties that make plastics so attractive – durability and chemical stability – make it difficult to do anything with discarded plastics other than deposit them in landfills – where they don’t easily degrade over time – or burn them, which dumps carbon dioxide and various hazardous gases into the atmosphere.

Polystyrene is one of the most widely used plastics.  It is found in foam packaging materials, disposable food containers, plastic cutlery, storage containers, and many other places. 

Recycling plastics like polystyrene is generally not economically feasible.  Sorting plastics by type is time and labor intensive and the chemical processes required to break down plastics into usable precursor materials require significant energy input and the use of toxic solvents.

Recently, a team of scientists at Ames Laboratory in Iowa has developed a process based on ball-milling that deconstructs commercial polystyrene in a single step, at room temperature, in ambient atmosphere, and in the absence of harmful solvents.

Ball-milling is a technique that places materials in a milling vial with metal ball bearings which is then agitated to initiate a chemical reaction.  This approach is known as mechanochemistry.

The method represents an important breakthrough that enables dismantling of a polymer that includes its chemical breakdown without requiring solvents or the high temperatures generally needed to thermally decompose it.  This discovery opens up new avenues for low-temperature recovery of monomers from polymer-based systems that include composites and laminates.  It could be a very useful weapon in the battle against plastic waste.

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Polystyrene waste is everywhere, and it’s not biodegradable. Scientists just found a way to break it down.

Photo, posted December 11, 2010, courtesy of Warrenski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Nanotech Water Purification | Earth Wise

July 14, 2020 By EarthWise Leave a Comment

Ultrathin nanosheets separate ions from water

We have occasionally talked about metal-organic frameworks, which are organic-inorganic hybrid crystalline structures that have a microscopic cage-like structure.  MOFs have been under development for a diverse set of applications including gas storage and separation, liquid purification, energy storage, catalysis, and sensing.

For the first time, an international research team, led by researchers from Monash University in Australia, has created an ultrathin porous membrane based on MOF technology that can completely separate potentially harmful ions, such as lead and mercury, from water.

This innovation could enhance water desalination and transform even the dirtiest water into something potable for millions of people around the world.  The new membrane performed steadily in tests for more than 750 hours using only limited energy.

The technology uses water-stable monolayer aluminum-based MOFs just a millionth of a millimeter in thickness.  These are essentially two-dimensional structures.  The ultrathin membrane is permeable to water – it achieves maximum porosity – but rejects nearly 100 percent of ions.  It has been a daunting challenge to fabricate ultra-thin MOFs for water-based processing.  Most previous membranes were too thick and unstable in water. 

Most existing ion separation membrane technologies are based on polymers and have the limitation that they have limited selectivity.  They don’t reject all unwanted ions.

The new membrane technology has great potential based on its precise and fast ion separation and could be ideal for a variety of filtration applications such as gas separation and separation of organic solvents such as paint.  Such membranes might also be used to remove harmful carcinogens from the atmosphere.

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Ultrathin nanosheets separate ions from water

Photo courtesy of Monash University.

Earth Wise is a production of WAMC Northeast Public Radio.

Mass Production Of Biodegradable Plastic  

October 17, 2017 By EarthWise 1 Comment

https://earthwiseradio.org/wp-content/uploads/2017/10/EW-10-17-17-Mass-Production-of-Biodegradable-Plastic.mp3

Plastic pollution is a major problem for the world’s oceans and non-biodegradable plastics continue to fill the planet’s landfills and litter the landscape.   There are many approaches to making plant-derived, biodegradable plastics but most of these materials do not offer the resistance to heat and moisture that is characteristic of petroleum-based plastics.

[Read more…] about Mass Production Of Biodegradable Plastic  

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