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Minerals from seawater

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There are about 18,000 desalination plants around the world that take in 23 trillion gallons of water each year.  The plants produce more than 37 billion gallons of brine – enough to fill 50,000 Olympic-size swimming pools – every day.  Disposing of this brine is an ongoing challenge.  Dumping it into the ocean can damage marine ecosystems.  Inland desalination plants either bury this waste or inject it into wells, adding further cost and complexity to the already expensive process of desalination.

According to researchers at Oregon State University, this waste brine contains large amounts of copper, zinc, magnesium, lithium, and other valuable metals.  A company in Oakland, California called Magrathea Metals has started producing modest amounts of magnesium from waste brine in its pilot projects.  With support from the U.S. Defense Department, it is building a larger-scale facility to produce hundreds of tons of the metal over two to four years. 

Most of the world’s magnesium supply comes from China, where producing it requires burning lots of coal and utilizing lots of labor.  Magrathea’s brine mining makes use of off-peak wind and solar energy and is much less labor intensive.

No large-scale brine mining operations currently exist and when there are some, they might end up having negative environmental impacts.  But in principle, the process should produce valuable metals without the massive land disturbance, acid-mine drainage, and other pollution associated with traditional mining.  Brine mining could turn a growing waste problem into a valuable resource.

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In Seawater, Researchers See an Untapped Bounty of Critical Metals

Photo, posted February 18, 2017, courtesy of Jacob Vanderheyden via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Adirondack lakes becoming inhospitable for trout

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A combination of the warming climate and the phenomenon of lake browning are making the bottom of most lakes in New York’s Adirondack Mountains unlivable for cold water fish – such as trout, salmon, and whitefish – in the summer.

Lake browning occurs when dissolved organic matter from forests turns the water tea-brown.  Browning is the legacy of a century of acid rain and subsequently the fact that forest soils have suffered reduced capacity to absorb weak organic acids, leading to more dissolved plant matter flowing into lakes.  Climate change has increased the frequency of extreme precipitation events and the length of growing seasons, leading to more runoff of organic matter.

Browner water traps more of the sun’s heat at the top of the lake and blocks the sun’s rays from reaching deeper.  The result of the browning is lakes that are either too warm or too deoxygenated to support trout populations.

A study of 1,467 Adirondack lakes by Cornell University researchers found that only about 5% of them may continue to maintain water that is cold and oxygenated enough to support cold-water fish.

Deeper lakes fare much better because they have so much water that their oxygen is hard to deplete, but only 1% of all Adirondack lakes are deeper than 30 meters.  Another 4% are very clear because the influx of cold water outpaces the expansion of low-oxygen zones and limits the effects of browning.

The study urges the protection of as many lakes as possible from species invasions, nutrient and salt pollution, and other forms of environmental degradation. 

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Most Adirondack lakes will likely become unsuitable for trout

Photo, posted July 17, 2011, courtesy of Lida via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A giant underground battery

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Two up-and-coming energy technologies are coming together near a tiny town in central Utah.  Outside of the town of Delta, population 3,600, two caverns, each as deep as the Empire State Building, are being created from an underground salt formation to be used to store hydrogen gas.  The gas will be used as a fuel in a new electricity generation plant.

The plant will replace an aging local coal-fired power plant.  The new plant will burn a mixture of natural gas and hydrogen – green hydrogen produced without emitting greenhouse gases. To produce the hydrogen, the facility will operate 40 giant electrolyzers that will use excess solar and wind power generated at times of low demand to split water molecules into hydrogen and oxygen.

The caverns were created by a process called solution mining in which high-pressure water is pumped down into salt deposits that are dissolved. The resulting caverns are 200 feet in diameter and 1,200 deep and lie 3,000 to 4,000 feet below the surface.  Hydrogen cannot escape through the thick salt layers.

The amount of energy that can be stored in the form of hydrogen fuel in these caverns is massive – far more than all the battery storage installed in the U.S. to date.  Chevron has a majority stake in one of the projects and will supply the natural gas.  The facility is expected to go online in 2025.

While this will produce far fewer emissions than existing coal plants, it is not carbon-free.  Currently, turbine technology cannot operate with pure hydrogen fuel.  The Delta plant will run on only 30% hydrogen.  The hope is that turbine technology will improve in the future and permit operation on pure hydrogen.

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A Huge Underground Battery Is Coming to a Tiny Utah Town

Photo, posted September 9, 2013, courtesy of Scott via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Sodium-ion batteries

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The transition away from fossil fuels is driving a rapidly increasing need for batteries.  Both electric vehicles and energy storage for the electric grid are enormous consumers of batteries.  At present, lithium-ion batteries are almost universally used for these purposes.  They have been getting better all the time and cheaper all the time and are likely to be the answer for the foreseeable future.  But they are not perfect.

Lithium is only found in a relatively small number of places and mining and extracting it is fairly expensive and environmentally unfriendly.  Lithium-ion batteries also frequently contain cobalt, which has its own set of problems.  There are also safety issues related to the flammability of lithium-ion batteries. 

As a result, there continue to be numerous efforts to identify and develop alternative battery technologies.  One of these is sodium-ion batteries, which are similar in many ways to lithium-ion batteries but in which sodium replaces lithium as the cathode material.

Sodium is extremely common – it’s found in ordinary salt – and sodium-ion batteries have a high energy density and are easy to produce.  They should have a long lifetime and have a more benign environmental impact than lithium-ion.  Many companies and researchers are working on sodium-ion batteries and are making good progress.

A study by Chalmers University in Sweden looked at the potential for sodium-ion batteries and found that the batteries are particularly promising for use in energy storage even in their current state of development and could eventually be used in cars.  Whether sodium-ion batteries can be good enough and cheap enough quickly enough to give lithium-ion a run for its money remains to be seen.

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Resource-efficient and climate-friendly with sodium-ion batteries

Photo, posted March 12, 2013, courtesy of Chris Hunkeler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Ending plastic separation anxiety

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Petroleum-based plastics are one of the biggest environmental problems we face.  They mostly end up in landfills – or worse, in the oceans and elsewhere in the environment – and they basically don’t decompose over time.  Bio-based plastics were invented to help solve the plastic waste crisis.  These materials do break down in the environment providing a potential solution to the problem.  But it turns out that they can actually make plastic waste management even more challenging.

The problem is that bioplastics look and feel so similar to conventional plastics that they get mixed in with the petroleum-based plastics rather than ending up in composters, where they can break down as designed.

Mixtures of conventional and bioplastics end up in recycling streams where they get shredded and melted down, resulting in materials that are of very poor quality for making functional products.  The only solution is to try to separate the different plastics at recycling facilities, which is difficult and expensive to do.

Scientists at Lawrence Berkeley National Laboratory, the Joint BioEnergy Institute, and the incubator company X have invented a simple “one pot” process to break down mixtures of different types of plastic using naturally derived salt solutions and specialized microbes and then produce a new type of biodegradable polymer that can be made into fresh commodity products.

The team is experimenting with various catalysts to find the optimum way to break down polymers at the lowest cost and are modeling how their processes can work at the large scales of real-world recycling facilities. Chemical recycling of plastics is a hot topic but has been difficult to make happen economically at the commercial scale.

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Putting an End to Plastic Separation Anxiety

Photo, posted November 28, 2016, courtesy of Leonard J Matthews via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

The end of a supergiant iceberg

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In 2017, a supergiant iceberg known as A-68 calved from the Larsen C ice shelf in Antarctica. In 2020, it drifted close to South Georgia, a British island in the South Atlantic Ocean, and then began to break up.  This iceberg was enormous – nearly the size of Delaware.  When it started to break up, it released huge quantities of fresh, cold meltwater in a relatively small region.

Scientists from the British Antarctic Survey and the University of Sheffield have studied how the melting iceberg has affected the temperature and the salinity of the ocean surface in the area.  They found that the water near the surface was 8 degrees Fahrenheit colder than normal and the water only had about two-thirds of its normal saltiness.

The effects from the melted iceberg eventually extended well beyond South Georgia as the colder, less-salty water was carried by ocean currents to form a long plume that stretched more than 600 miles across the South Atlantic.  It also took several months to disappear.

The calving of this massive iceberg provided a unique opportunity for scientists to study the impact of iceberg melting on surface ocean conditions.  A-68 was one of the largest and most studied of all icebergs.  The study has shown that each individual melting giant iceberg can have widespread and long-lasting impacts on ocean conditions, which has consequences for the plant and animal life that lives there.

Climate change is likely to lead to more giant iceberg calving in the future.  It is important to monitor these events to assess their future impacts on ocean circulation, biology, and even seafloor geology.

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Supergiant iceberg makes surrounding ocean surface colder and less salty

Photo, posted October 24, 2018, courtesy of Jefferson Beck / NASA via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Harvesting Water From The Air | Earth Wise

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Engineers at MIT have created a superabsorbent material that can soak up significant amounts of moisture from the air, even in desert-like conditions.

The material is a transparent, rubbery substance made from hydrogel, which is a naturally absorbent material that is already widely used in disposable diapers.  The MIT researchers enhanced the absorbency of hydrogel by infusing it with lithium chloride, which is a type of salt that is a powerful desiccant.

They found that they could infuse hydrogel with more salt than was possible in previous studies.  Earlier studies soaked hydrogels in salty water and waited 24 to 48 hours for the salt to infuse into the gels.  Not much salt ended up in the gels and the material’s ability to absorb water vapor didn’t change much.  In contrast, the MIT researchers let the hydrogels soak up the salt for 30 days and found that far more salt was absorbed into the gel.  The result was that the salt-laden gel could then absorb and retain unprecedented amounts of moisture, even under very dry conditions.

Under very dry conditions of 30% relative humidity, the gels captured 1.79 grams of water per gram of material.  Deserts at night have those levels of relative humidity, so the material is capable of generating water in the desert.

The new material can be made quickly and at large scale.  It could be used as a passive water harvester, particularly in desert and drought-prone regions.  It could continuously absorb water vapor from the air which could then be condensed into drinking water.  The material could also be used in air conditioners as an energy-saving, dehumidifying element.

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This salty gel could harvest water from desert air

Photo, posted July 26, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Water For Arizona | Earth Wise

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The Phoenix area is the fastest growing region in the country.  Arizona’s two major sources of water – groundwater and the Colorado River – are dwindling from drought, climate change, and overuse.  Officials in the state are considering a radical plan to construct a desalination plant off the Mexican coast that will take the salt out of seawater, and then pipe that water hundreds of miles, much of it uphill, to Phoenix.

The project is the brainchild of the Israeli company, IDE, which is one of the world’s largest desalination companies.  IDE has asked Arizona to sign a 100-year contract to buy water from the project. 

There are multiple complications surrounding the plan.  Desalination plants are common in California, Texas, and Florida, and in more than 100 other countries.  But the Arizona project is unusual because of the distance involved and because the state is landlocked.  The water would have to travel 200 miles and climb 2,000 feet along the way.

There is also the issue of waste brine, which is a major output of desalination plants.  In this case, the brine would flood the northern Gulf of California, potentially threatening a productive fishery.  In addition, the pipeline, as well as electrical transmission lines, would have to go through the Organ Pipe Cactus National Monument, a UNESCO biosphere reserve.

The plant would be located in Puerto Peñasco, a struggling town with its own water problems.

With booming home construction going on in the Phoenix area, the need for more water continues to grow.  Whether this plan will be approved by Arizona and by Mexico remains to be seen.

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Arizona, Low on Water, Weighs Taking It From the Sea. In Mexico.

Photo, posted September 26, 2008, courtesy of Dan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Salt Marshes And Climate Change | Earth Wise

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Salt marshes are coastal wetlands that are flooded and drained by salt water brought in and out by the tides. These low-lying wetlands are also sometimes called tidal marshes because they occur in the zone between low and high tides. These wetlands are some of the most biologically productive ecosystems on Earth.

Cape Cod’s beautiful salt marshes are as important as they are iconic.  They act as carbon sinks, protect coastal development from storm surge, play an outsized role in nitrogen cycling, and provide critical habitats for many fish, shellfish, and coastal birds.

According to scientists from the Marine Biological Laboratory in Woods Hole, Massachusetts, more than 90% of salt marshes around the world are likely to be underwater by the end of the century. 

Since 1971, scientists from the Marine Biological Laboratory have mapped vegetative cover in Great Sippewissett Marsh in Falmouth, Massachusetts, to examine whether increased nitrogen in the environment would impact species of marsh grass.  Because of the length of the study, the researchers were also able to investigate the impacts of climate change on the ecosystem, especially those driven by accelerating sea level rise. 

The research team found that increased nitrogen favored higher levels of vegetation and accretion of the marsh surface.  However, the researchers found that salt marshes will not be able to outpace the submergence from global sea level rise – no matter how much nitrogen is applied.

Sea level rise is the biggest threat to salt marshes around the world.  Mitigating some of these projected losses is critical in order for salt marshes to continue to provide their important ecosystem services for people and the planet.  

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Most of the World’s Salt Marshes Could Succumb to Sea Level Rise by Turn of Century

Photo, posted September 27, 2011, courtesy of Chris M Morris via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Self-Deicing Roads | Earth Wise

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Driving on snowy or icy roads can be pretty dangerous.  That is why roads are salted or coated with sand to provide traction in icy weather.  But excessive use of these substances is bad for the environment and sometimes a storm will blow in before the roads can be coated.

In a paper published in the American Chemical Society Journal ACS Omega, researchers in China describe a method of adding microcapsules filled with a chloride-free salt mixture to the asphalt with which roads are paved.  The idea is to provide the road itself with long-term snow melting capabilities.

The researchers prepared a sodium-acetate salt and combined it with a surfactant, silicon dioxide, sodium bicarbonate, and blast furnace slag, which is a waste product from power plants.  The substances were reduced to a fine powder and then coated with a polymer solution to form tiny microcapsules.  The microcapsules were then used to replace some of the standard mineral filler in asphalt.

Lab experiments showed that the special additive lowered the freezing point of water on the asphalt to -6 degrees Fahrenheit.   The researchers estimated that a 2-inch-thick layer of the anti-icing asphalt would be effective at melting snow for seven or eight years.  A real-world pilot test of the coating on a highway offramp showed that it melted snow that fell on the road whereas an uncoated road required snow removal operations.

According to the researchers, given the cost of materials used for the coating and its potential useful lifetime, it could be a practical and economic enhancement for wintertime snow and ice removal.  Maybe we’ll someday have roads that can fairly often deice themselves. 

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Keeping drivers safe with a road that can melt snow, ice on its own

Photo, posted April 8, 2007, courtesy of the Oregon Department of Transportation via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Great Salt Lake In Danger | Earth Wise

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Utah’s Great Salt Lake has been plagued by excessive water use and extensive drought conditions.  As of January, the lake dropped to record-low water levels, losing 73% of its water and exposing 60% of its lakebed. According to scientists, the lake could disappear entirely within five years.

Great Salt Lake is what is known as a “terminal lake,” which means that it is fed only by rain, snow, and runoff and has no rivers that take water to the ocean.  As a result, salt and minerals build up over time.  With so much salt in the water, only brine flies and shrimp can survive in it.  The unique ecosystem supports 10 million migratory birds.  As the lake continues to dry up, the water is becoming too salty for even algae and microbes to survive.  With shallow mud replacing previous shallow water, the nests of the 80,000 white pelicans that annually come to the lake are endangered by predators that can simply walk over to the eggs.

The historic low water levels have exposed 800 square miles of lakebed.  This lakebed holds centuries of natural and manmade toxins like mercury, arsenic, and selenium.  The exposed mud ultimately turns to dust that is carried off into the air.  This is contributing to what is already some of the worst winter air pollution in the nation.  Scientists warn that the unfolding ecological disaster may become a human health disaster.

State officials and university researchers have formed a “Great Salt Lake Strike Team” looking for ways to get more water to the lake.  There are a number of so-called moonshot proposals to save the lake.  It remains to be seen what will be done, but the clock is ticking.

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Great Salt Lake will disappear in 5 years without massive ‘emergency rescue,’ scientists say

Scientists fear a Great Toxic Dustbowl could soon emerge from the Great Salt Lake

Photo, posted September 19, 2009, courtesy of John Morgan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Food For The Future | Earth Wise

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Researchers predict that climate change will negatively impact most staple food crops, including rice, corn, and soybeans.  Therefore, climate resilient food crops – those that are salt, drought, and heat resilient – will have an important role to play in global food security.  Examples of climate resilient crops include quinoa, kernza, amaranth, millet, and tepary beans.    

According to a new study by researchers from Northwestern University, breadfruit – a starchy tree fruit native to the Pacific Islands – will be relatively unaffected by climate change.  Because breadfruit is climate resilient and well-suited to grow in regions with high levels of food insecurity, the research team suggests breadfruit could be a part of the solution to global hunger.

While it has ”fruit” in its name, breadfruit is more like a potato.  It’s starchy and seedless, and is closely related to jackfruit.  Breadfruit is nutrient-rich, and high in fiber, vitamins, and minerals.  It can be steamed, roasted, fried, fermented, and even turned into flour.  People in tropical regions around the world have been eating breadfruit for thousands of years. 

In the study, which was recently published in the journal PLOS Climate, researchers determined the climate conditions necessary to cultivate breadfruit and then looked at how these conditions are predicted to change in the future.  They examined two future climate scenarios: one that reflects high greenhouse-gas emissions and another in which emissions stabilize.

In both scenarios, the regions suitable for breadfruit cultivation were mostly unaffected.  Additionally, the researchers identified new suitable land where breadfruit cultivation could expand.   

As the climate continues to change, breadfruit might soon be on a table near you.

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Climate-resilient breadfruit might be the food of the future

Photo, posted August 11, 2007, courtesy of Malcolm Manners via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

The Scourge Of Salt | Earth Wise

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Rising seas are increasing saltwater intrusion on land and rising temperatures are causing greater evaporation.   The result is mounting levels of salt in waters and in soils.

Rising sea levels cause salty ocean water to push further into river deltas.  There is already a surge in saltiness across all inhabited continents.   Seawater works its way further upstream when dams hold back water.  Pumps that remove fresh water from underground sources for irrigation and drinking supplies add to the problem.  In dry regions, irrigation systems delivering water to crops increasingly bring salt onto fields.

People add to the problem by pouring saline drainage water from mines into rivers and by using salt to de-ice roads in the winter.

A modeling study pinpointed hotspots for climate change-induced salinization in numerous locations including the U.S. Southwest, wide areas of Australia, Mexico, South Africa, Brazil, central India, northern China, and more.

Some ecosystems are adapted to saline environments but major alterations in the balance between saline and fresh water is creating growing problems for ecosystems, lake fisheries, crop growing, and even human health.

The damage caused by salt is likely to be so severe that salinization will become a major cause of environmental refugees when the land they live on can no longer sustain them. 

Salt will be a growing threat to the world’s food supplies, especially where farmers depend on artificial irrigation.  About a third of the world’s food is grown in irrigated fields, and a fifth of those fields are deemed to already be salt-contaminated.  Ultimately, only a halt to climate change will be capable of combatting the scourge of salt.

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Salt Scourge: The Dual Threat of Warming and Rising Salinity

Photo, posted June 3, 2017, courtesy of Jason Jacobs via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Humans And Microplastics | Earth Wise

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While plastic comes in all different shapes and sizes, those that are less than five millimeters in length are called microplastics.  Primary sources of microplastics include microfibers from clothing, microbeads, and plastic pellets (known as nurdles).  Secondary sources of microplastics come from larger plastic debris, like bottles and bags, that degrades into smaller bits over time. 

Microplastic pollution can be found everywhere on earth, from the top of the tallest mountains to the bottom of the deepest oceans.  Microplastics are in the food we eat, the water we drink, and the air we breathe. 

According to research recently published in the journal Exposure & Health, humans ingest an average of five grams of plastic particles per week. This is roughly equivalent to the weight of a credit card.  The plastic particles are trafficked in via food, such as seafood and salt in particular, as well as water.  In fact, those who rely on plastic bottled water for their drinking needs ingest an additional 1,700 plastic particles each week.   

Microplastics have also been detected in human blood for the first time.  According to new research recently published in the journal Environment International, scientists detected microplastics in nearly 80% of the people they tested. 

Half of the blood samples contained PET plastic, which is commonly used for drinking bottles.  One third of the blood samples contained polystyrene plastic, which is often used for food packaging.  One quarter of the blood samples contained polyethylene plastic, which is used to make things like shopping bags and detergent bottles. 

With plastic production predicted to double by 2040, more research is urgently needed to understand how ingesting microplastics affects human health.

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Health risk due to micro- and nanoplastics in food

Microplastics found in human blood for first time

Discovery and quantification of plastic particle pollution in human blood

Photo, posted November 3, 2012, courtesy of Laura via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Lake Tuz Is Disappearing | Earth Wise

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Lake Tuz is Turkey’s second-largest lake and one of the world’s largest hypersaline lakes.  Its high salt content makes it an ideal breeding ground for some migratory bird species, including flamingos, which are often present there in huge numbers in the spring and summer.

Now, Lake Tuz rarely spans an area much larger than a puddle. In some summers, it completely dries up.  It did so this past summer, which resulted in the deaths of thousands of flamingos.

According to experts, Lake Tuz is a victim of climate change-induced drought, which has hit the region hard, and decades of harmful agricultural policies that exhausted the underground water supply.

Water in this region has become increasingly scarce.  The Mediterranean Basin has already seen more frequent and intense droughts, and is considered a climate change hotspot. 

According to new research, which was recently published in the journal Regional Environmental Change, Lake Tuz generally contained enough water in August for the lake to be considered permanent up until 2000.  But between 2001 and 2016, something shifted.  Water spanned less than 20% of the lake in every August except for one, and droughts became more frequent and intense. And in some years, the lake completely dried up.   

What caused this change?  According to the research team, Lake Tuz’s decline coincided with the excessive use of groundwater and surface water resources responsible for feeding the lake.  Some streams were rerouted for agricultural purposes, while others were dammed.  And when surface water sources dwindled, people turned to groundwater that historically fed the springs in Lake Tuz. 

Lake Tuz may be on the brink of extinction. 

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Impact of climate variability on the surface of Lake Tuz (Turkey), 1985–2016

Disappearing Lake Tuz

Photo, posted August 16, 2021, courtesy of Godot via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Wind Farms Slowing Each Other Down | Earth Wise

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Offshore wind is booming in Europe.  The expansion of wind energy in the German Bight and Baltic Sea has been especially dramatic.  At this point, there are about 8 gigawatts of wind turbines in German waters, the equivalent of about 8 nuclear power plants.  But space in this region is limited so that wind farms are sometimes built very close to one another.

A team of researchers from the Helmholtz Center Hereon, a major German research institute, has found that wind speeds downstream from large windfarms are significantly slowed down.  In a study published in the journal Nature Scientific Reports, they found that this braking effect can result in astonishingly large-scale lowering of wind speeds.

On average, the regions of lowered wind can extend 20-30 miles and, under certain weather conditions, can even extend up to 60 miles.  As a result, the output of a neighboring wind farm located within this distance can be reduced by 20 to 25 percent.

These wake effects are weather dependent.  During stable weather conditions, which are typically the case in the spring in German waters, the effects can be especially large.  During stormy times, such as in November and December, the atmosphere is so mixed that the wind farm wake effects are relatively small.

Based on their modeling, it is clear that if wind farms are planned to be located close together, these wake effects need to be taken into account.  The researchers next want to investigate the effects that reduced wind speeds have on life in the sea.  Ocean winds affect salt and oxygen content, temperatures, and nutrients in the water.  It is important to find out how reduced winds might affect marine ecosystems.

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Are wind farms slowing each other down?

Photo, posted November 23, 2011, courtesy of David J Laporte via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Understanding How To Enhance Desalination | Earth Wise

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Desalination is the process of removing mineral components – notably salt – from saline water, generally seawater.  Over 16,000 desalination plants operate across 177 countries, generating 25 billion gallons of fresh water each year.  Currently, desalination accounts for about 1% of the world’s drinking water.

The leading process for desalination in terms of installed capacity as well as new installations is reverse osmosis that makes use of a thin-film composite membrane based on ultra-thin polyamide.

Despite the fact that these membranes are widely used for desalination, they are actually rather poorly understood.  It has not been known exactly how water moves through them.  As a result, much of the progress made on the technology over the decades has been essentially based on guesswork.

A team of researchers at the University of Texas, Austin has used advanced microscopy techniques to solve some of the mysteries of reverse osmosis membranes.  By mapping membranes at very high resolution – less than half the diameter of a DNA strand – they gained a much better understanding of what makes a membrane better at reverse osmosis.

They found that desalination membranes are inconsistent in mass distribution and density and that these inconsistencies can impair membrane performance.  It turns out that inconsistencies and dead zones in membranes play a bigger role than membrane thickness.  By making the membranes more uniform in density at the nanoscale, they were able to increase desalination efficiency 30 to 40 percent, therefore cleaning more water with less energy and at lower cost.

Producing fresh water is not just essential for public health, it is also crucial for use in agriculture and energy production.

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Nanoscale control of internal inhomogeneity enhances water transport in desalination membranes

Photo, posted February 13, 2017, courtesy of Jacob Vanderheyden via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Using CO2 To Convert Seawater Into Drinking Water | Earth Wise

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A chemist at the University of Copenhagen has invented a technology that uses carbon dioxide to convert seawater into drinking water within minutes.  This desalination technology has the potential to replace electricity with CO2 and be used in survival gear and in large-scale industrial plants in places where people don’t have clean drinking water.

Over 800 million people worldwide lack access to clean drinking water and that number is growing rapidly.  Seawater is a vital source of drinking water in many parts of the world, but desalination faces the major challenge of being highly energy intensive.  Desalination plants use huge amounts of fossil fuel-generated electricity and therefore contribute to climate change.

The Copenhagen technology is reminiscent of a SodaStream machine.  Carbon dioxide is added to water, initiating a chemical reaction.  But instead of using it for bubbly carbonation, it is used to separate salt from water.  It works by adding a chemical called CO2-responsive diamine to saltwater.  The diamine compound binds with the added CO2 and acts as a sponge to absorb the salt, which can then be separated.  The entire process takes one to ten minutes.  Once the CO2 is removed, the salt is released again, allowing the diamine to be reused for several more rounds of desalination.

In the laboratory, the method removed 99.6% of the salt in seawater.  The technology is still being developed to lower its price and optimize the recycling process.  It is also being tested on a small scale in the form of water bottles fitted with special filters that can be used in lifeboats or in other outdoor settings.  Ultimately, it could be used to greatly reduce the energy consumption of desalination plants.

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Chemist uses CO2 to convert seawater into drinking water

Photo, posted January 10, 2015, courtesy of Daniel Orth via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Lake George Health Report

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The Offshore Chemistry Program, run by the Darrin Fresh Water Institute at RPI, has been monitoring the deep waters of Lake George in New York for 40 years.  Lake George, nicknamed the Queen of American Lakes, is famed for the transparency of its water and a new report on the health of the lake reveals that it is doing rather well.

According to the report, although concentrations of chemicals and pollutants like salt and nutrients have increased in the deep waters of Lake George, they are still too low to harm the ecosystem at those depths.

The Offshore Chemistry Program studies the lake as part of a collaboration between RPI, IBM Research, and the FUND for Lake George that is called the Jefferson Project.  This long-term commitment provides a wealth of information over time matched by few lake studies in the world.

The recent results show that levels of salt, the nutrient orthophosphate, and chlorophyll have increased substantially over time, but none are yet at a level that will cause harm.

Orthophosphate occurs naturally, but most likely the higher levels are due to improperly functioning septic systems, failing wastewater treatment systems, and stormwater runoff.  The orthophosphate most likely triggered the increase in chlorophyll, which probably is associated with increased density of chlorophyll in individual algal cells, rather than an increase in total algal mass in the lake.

Overall, the results demonstrate the continuing resilience of Lake George to a growing array of stressors.  In nearly 40 years of human activities, the lake has changed in a number of ways, but the changes have so far been relatively small.  With such careful monitoring, we can hope to keep them that way.

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Four Decades of Data Sounds Early Warning on Lake George

Photo, posted September 24, 2009, courtesy of GPA Photo Archive via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Another Problem For Coral Reefs

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Coral reefs around the world have been suffering in recent years from warming ocean temperatures as well as from increasing ocean acidification.  Corals are very sensitive organisms that can only tolerate relatively slight changes in their environment.  Thus, the majority of reef-building corals are found in tropical and subtropical waters with favorable conditions.

New research has confirmed that drastic changes in ocean salinity from, for example, severe freshwater flooding, provoke similar stress responses in corals as the heating that has resulted in freshwater bleaching and, eventually, coral death.

The coast of northeast Queensland in Australia has experienced abnormal monsoon-related freshwater flooding that caused extreme and sudden changes in the ocean salt concentration.  In places, nearshore reefs were exposed to water with only half the normal ocean salinity.  The result has been a shock response in corals that prevents normal cell function.  Unlike their response to heat stress, corals exposed to reduced salinity experience a complete collapse of their internal cellular protein balance.

The central Great Barrier Reef has actually been relatively free from mass thermal bleaching events this Australian summer, but many coastal reefs instead have been battling dramatic changes in water conditions as a result of massive plumes of floodwater.

The wild weather in Australia is undoubtedly associated with the changing climate and this new research shows that it is leading to yet another threat to the world’s coral reefs.  With the frequency and severity of heavy rainfall and runoff events predicted to continue to increase over the next few decades, proactive measures to increase the resiliency of coral reefs are needed more than ever.

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Reduced salinity of seawater wreaks havoc on coral chemistry

Photo, posted December 12, 2010, courtesy of Gareth Williams via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

WAMC Northeast Public Radio

WAMC/Northeast Public Radio is a regional public radio network serving parts of seven northeastern states (more...)