refrigerants

Are today’s refrigerants safe?

March 21, 2025 By EarthWise Leave a Comment

Refrigeration is based on heat transfer mediums that absorb heat from the area being cooled and transfer it to the outside environment.

The earliest refrigerants were dangerous substances like ammonia. In the 1930s, chlorofluorocarbons (CFCs) like Freon became the standard refrigerant for use in refrigeration systems and even in aerosol cans. When these substances were found to be depleting the earth’s ozone layer, the Montreal Protocol dictated their phaseout and by the mid-1990s, CFCs were largely replaced by hydrofluorocarbons (HFCs).

HFCs don’t deplete the ozone layer, but they were eventually determined to be potent greenhouse gases, thousands of times more planet-warming than carbon dioxide. As a result, the global phaseout of HFCs began in 2016, and have been increasingly replaced by hydrofluoroolefins (HFOs), which are considered a more environmentally-friendly alternative to all their predecessors.

Trying to not be surprised by additional unpleasant discoveries about refrigerants, researchers are studying the potential environmental impacts of HFOs. Researchers at the University of New South Wales in Australia have found that HFOs can break down in the atmosphere and that some small amounts of the resultant products are in fact fluoroforms, which are the HFC with the greatest global warming potential and can stay in the atmosphere for up to 200 years.

That only a small amount of HFC gets into the atmosphere is good, but nevertheless it reveals that the consequences of replacing widely-used chemicals are not a simple matter to determine.

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Are our refrigerants safe? The lingering questions about the chemicals keeping us cool

Photo, posted July 19, 2021, courtesy of Vernon Air Conditioning via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Propane Refrigerants | Earth Wise

September 20, 2022 By EarthWise Leave a Comment

About 10% of the world’s total electricity supply is used for air conditioning. If current temperature trends continue, the energy demands for space cooling will more than triple by the year 2050. Air conditioning is a double threat to the environment. Apart from using lots of energy, ACs also make use of halogenated refrigerants that are extremely powerful greenhouse gases.

The most common space cooling appliances are split-air conditioners, which use an indoor unit and an outdoor unit connected by pipes. These split ACS mostly utilize HCFC-22 and HFC-410 as refrigerants, which have global warming potential scores as high as 2,256 – meaning they trap 2,256 times more heat than carbon dioxide.

A study by the International Institute of Applied Systems Analysis in Austria has shown that propane is a far better choice as an air conditioning refrigerant. Its global warming potential is actually less than 1 meaning it traps less heat than carbon dioxide. According to the study, if air conditioners switched to propane refrigerants, the world would avoid about a tenth of a degree Celsius of additional warming, which is a significant contribution to meeting the goals of the Paris climate agreement.

Propane-based split-ACs are already available commercially in China and India. Elsewhere, many national regulations prohibit their use, primarily due to codes restricting the use of refrigerants with higher flammability. Given the increasingly urgent need for climate action, it seems to be time to reconsider regulations on refrigerants.

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Propane — a solution for more sustainable air conditioning

Photo, posted March 24, 2021, courtesy of Phyxter Home Services via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Climate-Friendly Refrigerants

March 29, 2017 By EarthWise

In 1988, President Reagan signed the Montreal Protocol, which banned CFC refrigerants like Freon in air conditioners and refrigerators. The chlorofluorocarbons were the cause of a giant hole in the ozone layer, which has been shrinking ever since the ban. Unfortunately, the chemicals that replaced CFCs – hydrofluorocarbons or HFCs – have their own major problem: they are a seriously bad greenhouse gas, far worse than carbon dioxide. Last fall, an international agreement was reached by over 170 countries to reduce and eventually replace HFCs, which included 100 developing countries like China and India where air conditioning use is growing fastest.