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Plastic From Sunlight | Earth Wise

March 13, 2023 By EarthWise Leave a Comment

Photosynthesis is the process that plants use to turn water, carbon dioxide, and energy from sunlight into plant biomass. It provides humans and much of animal life with food. Photosynthesis is also nature’s way of reducing the amount of carbon dioxide in the atmosphere. The CO2 is not directly stored in plants but rather is combined into organic compounds.

Researchers across the globe are trying to find effective ways to mimic photosynthesis. One version of artificial photosynthesis seeks to take carbon dioxide and combine it into organic compounds that can be used as raw materials for various kinds of manufacturing.

A research team in Japan has found a way to synthesize fumaric acid from carbon dioxide using sunlight to power the process. Fumaric acid is a chemical typically synthesized from petroleum and is used as a raw material for making biodegradable plastics such as polybutylene succinate.

Much of artificial photosynthesis research is aimed at using solar energy to convert carbon dioxide directly into a fuel rather than a raw material. Such solar fuels can be produced by a variety of means including thermochemical (using the sun’s heat to drive chemical reactions), photochemical (using the sun’s light to drive chemical reactions), and electrochemical (using solar-generated electricity to drive chemical reactions.) These approaches generally involve the use of specialized catalysts to drive the desired chemical reactions.

One way or another, what techniques for artificial photosynthesis have in common is trying to imitate what plant life on Earth has been doing for millions of years.

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Artificial photosynthesis uses sunlight to make biodegradable plastic

Photo, posted June 14, 2017, courtesy of Alex Holyake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Figuring Out Photosynthesis | Earth Wise

March 16, 2020 By EarthWise Leave a Comment

Plants have been harnessing the sun’s energy for hundreds of millions of years. Algae and photosynthetic bacteria have been doing the same for even longer, all with remarkable efficiency and resiliency.

People have used the energy of the sun in one way or another for millennia, but only recently have we gotten sophisticated about it by using devices like solar panels and sensors. And we still have a long way to go to get anywhere close to the efficiency of plants. It’s no wonder, then, that scientists have long sought to understand exactly how photosynthesis works.

Scientists from the U.S. Department of Energy’s (DOE) Argonne National Laboratory, and collaborators at Washington University in St. Louis, recently solved a critical part of the age-old mystery of photosynthesis, studying the initial, ultra-fast events through which photosynthetic proteins capture light and use it to initiate a series of electron transfer reactions. Electrons in plants have two possible pathways to travel but only use one.

But as a result of their efforts, the scientists are now closer than ever to being able to design electron transfer systems in which they can send an electron down a pathway of their choosing.

By gaining the ability to harness the flow of energy, it may be possible to incorporate new design principles in non-biological energy systems. This could allow us to greatly improve the efficiency of many solar-powered devices, potentially making them far smaller. Understanding the intricacies of photosynthesis creates a tremendous opportunity to open up completely new disciplines of light-driven biochemical reactions, perhaps even ones that haven’t been envisioned by nature.

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Scientists unravel mystery of photosynthesis

Photo, posted June 14, 2017, courtesy of Alex Holyoake via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaner Air Saves Lives

September 25, 2019 By EarthWise Leave a Comment

A new study by Columbia University has concluded that lower air pollution levels saved an estimated 5,660 lives in New York State in 2012, compared to 2002 mortality levels.

The study looked at New York State levels of the specific type of pollution known as fine particulate matter, referred to as PM2.5. These microscopic particulates are a mixture of solid particles and liquid droplets that either come from burning fuel or are formed in the atmosphere as a result of complex reactions of chemicals such as sulfur dioxide and nitrogen oxides from power plants, industries, and automobiles.

Long-term exposure to PM2.5 can lead to respiratory and cardiovascular problems.

The study looked at extensive amounts of data to analyze trends in PM2.5 levels across New York State. The data showed that PM2.5 levels dropped by 28 to 37% between 2002 and 2012. This was a result of continued progress in cleaner vehicles, the reduction of high sulfur-dioxide emitting coal-burning power plants, and other air pollution reduction programs. They calculated that this amount of reduction in PM2.5 reduced the air pollution mortality burden for New York State residents by 67% – from 8,410 premature deaths in 2002 to 2,750 deaths in 2012.

The study provides evidence that emission controls on air pollutants – which were initiated by the Clean Air Act of 1970 and later expanded in 1990 – have improved public health across New York State. According to the researchers, the study is a key step to documenting the health benefits from cleaner air.

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Air Pollution Cuts Are Saving Lives in New York State

Photo, posted June 29, 2014, courtesy of Paul Comstock via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Coal To Fight Climate Change

April 19, 2019 By EarthWise Leave a Comment

Coal is the most harmful fossil fuel for the environment and, furthermore, for human health. Its use has stubbornly persisted because it is so plentiful and, therefore, cheap. As a result, a big part of efforts to fight climate change is finding a way to remove the carbon dioxide dumped into the atmosphere by the combustion of coal.

Researchers at the Royal Melbourne Institute of Technology in Australia have developed a remarkable technology that in effect reverses the process that has led to soaring CO2 levels in the atmosphere. They have found a way to pull carbon dioxide from the atmosphere and turn it into coal, after which it can be stored cheaply and safely underground.

Most previous carbon capture and storage technologies have focused on compressing carbon dioxide gas into a liquid form and then pumping it into rock formations. Such techniques are rather expensive, require lots of energy, and pose risks that the liquid CO2 could escape from its underground storage sites. More recently, research on solid metal catalysts has led to the possibility of turning CO2 into solid carbon, but most of these reactions require very high temperatures and use a lot of energy.

The new technique developed at RMIT uses a new class of catalysts based on metal alloys. With a small jolt of electricity applied at room temperature, CO2 can be converted into solid carbon – basically, coal.

If this technique can be industrialized economically, it would be like turning back the clock by taking carbon dioxide that entered the atmosphere by the combustion of coal and turning it back into coal and putting it back underground. It seems like excellent environmental justice.

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Scientists Turn Atmospheric CO2 Into Coal

Photo, posted March 16, 2015, courtesy of Will Fisher via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Liquid Fuel From The Sun

February 21, 2019 By EarthWise Leave a Comment

Most forms of energy we use ultimately come from the sun in one way or another. Even fossil fuels are the end product of millions of years of plant life that captured solar energy. The advantage fossil fuels have over direct solar power is that they are, in fact, fuels and therefore can be stored for use when needed.

Scientists in Sweden have now developed a specialized fluid that absorbs some of the sun’s energy, holds it for months or even years, and then releases it when needed. This solar thermal fuel is like a rechargeable battery for heat rather than electricity.

The special fluid is pumped through transparent tubes where ultraviolet light from the sun excites its molecules into an energized state. A compound called norbornadiene is converted into quadricyclane. The quadricyclane is a quite stable substance until it is passed over a cobalt-based catalyst, which causes it to turn back into norbornadiene and release copious amounts of heat.

Such a solar thermal fuel could be stored in uninsulated tanks in homes or factories or piped or trucked to where it was needed. It could then be used for water heaters, dishwashers, or clothes driers. The room temperature fluid quickly warms to about 183 degrees when passed over the catalyst, plenty warm enough for heating a home or office. Both the fuel and the catalyst are damaged very little by the reactions, so the process can be recycled many times.

There is much development work needed to optimize shelf life, energy density, good recyclability and other properties before this technology can be commercialized but there are at least 15 groups around the world now studying this intriguing way to get liquid fuel from the sun.

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Scientists transform sunlight into a liquid fuel that can be stored for 18 years

Photo, posted August 17, 2009, courtesy of Hiromichi Torihara via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.