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PFAS and groundwater

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Per- and polyfluoroalkyl chemicals, more commonly known as PFAS, are a family of human-made chemicals that have been manufactured and used in a variety of industries since the 1940s.  They provide water-resistance, oil-resistance, dirt-resistance, and corrosion-resistance to a wide range of products, including food wrappers and packaging, clothing, dental floss, nonstick cookware, textiles, and electronics.

Exposure to PFAS has been linked to birth defects, thyroid disease, liver disease, kidney disease, and cancer.  These chemicals do not break down in the environment and therefore, over time, become concentrated in plants, animals, and people. 

According to a new first-of-its kind study by scientists at the U.S. Geological Survey, more than 20% of the U.S. population could be drinking groundwater contaminated with PFAS.  The study, which was recently published in the journal Science, found that those living in the Eastern U.S. are particularly likely to be exposed.

The study is the first to report national estimates of PFAS in untreated groundwater that supplies drinking water to private and public wells. The USGS research also provides the first estimate of the total number of Americans – anywhere from 71 to 95 million – who might be exposed to this contamination.

The researchers note that their estimates merely measure the existence of PFAS – before the water has undergone any treatment or filtering – meaning that, while they may be present, they may be at very low levels. 

To find a link to the detailed USGS map showing the probability of PFAS groundwater contamination in your region, visit our website: EarthWiseRadio.org.

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PFAS in US Groundwater Interactive Dashboard

Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

Photo, posted January 12, 2008, courtesy of Andrew Kraker via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Forever chemicals in water

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So-called forever chemicals are pervasive in a wide range of products.  These are man-made substances called per- and polyfluoroalkyls or PFAS.  They get their unfortunate nickname because the chemical bonds in them are so strong that the compounds don’t break down for hundreds or even thousands of years.

PFAS compounds are used in makeup, dental floss, nonstick pans, food wrappers, pesticides, stain-resistant fabrics and carpets, firefighting foams, and more.  High level exposure to some of these chemicals has been linked to a variety of health problems include high cholesterol, liver and immune system damage, pregnancy problems, and kidney and testicular cancer.

A recent study published in the journal Nature Geoscience has found that PFAS chemicals are showing up in water around the world.  The study looked at more than 45,000 water samples and found that about 31% of ground water tested that wasn’t even near any obvious source of PFAS contamination had levels of the chemicals that are considered harmful to human health by the EPA.  About 16% of surface water samples – streams, rivers, ponds, and lakes – also not near any known source, had similar hazardous PFAS levels.

The EPA has now imposed strict new drinking water limits for six types of PFAS.  Going forward, water systems are required to monitor for these chemicals and remove them if they are found above allowable levels.  The new rules make the United States one of the strictest countries in the world in terms of regulating PFAS in water.

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EPA puts limits on ‘forever chemicals’ in drinking water

Photo, posted May 5, 2020, courtesy of Brandon Shaw via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Tracking down PFAS toxins

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PFAS – per- and polyfluoralkyl substances – are a group of organic compounds that have been extensively used to provide water-, oil-, and dirt-resistance to a wide range of products ranging from non-stick pans, clothing, and packaging to paint, car polish, and fire-suppressant foam.  Exposure to specific PFAS compounds is associated with multiple adverse health effects, including altered immune and thyroid function, liver disease, kidney disease, poor reproductive and developmental outcomes, and cancer.  PFAS compounds do not break down in the environment and therefore, over time, become concentrated in plants, animals, and people.

Government agencies such as the EPA in this country and the EU have set strict limits for allowable levels of PFAS in drinking water.  Testing water for the trace amounts of PFAS that constitute the limits is time-consuming and expensive and requires complex equipment and experienced personnel.

Researchers at MIT have now introduced a technique for making a portable, inexpensive test that can easily and selectively detect PFAS in water samples.  The test makes use of a special polymer containing fluorinated dye molecules that cause the polymer to fluoresce red.  If PFAS are present in the sample, they enter the polymer and displace the dye molecules and switches off the red fluorescence. 

The new technique is suitable for on-site detection in highly contaminated regions.  Detecting smaller concentrations can be achieved with sufficient precision after pre-concentrating the samples using the process of solid-phase extraction.

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Tracking down Environmental Toxins

Photo, posted October 16, 2021, courtesy of Nenad Stojkovic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Cleaning Up Forever Chemicals | Earth Wise

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PFAS, per- and polyfluoroalkyl substances, are chemical pollutants that threaten human health and ecosystem sustainability.  They are used in a wide range of applications including food wrappers and packaging, dental floss, firefighting foam, nonstick cookware, textiles, and electronics.  Over decades, these manufactured chemicals have leached into our soil, air, and water.  Chemical bonds in PFAS molecules are some of the strongest known, so the substances do not degrade easily in the environment.

Studies have shown that at certain levels, PFAS chemicals can be harmful to humans and wildlife and have been associated with a wide variety of health problems.

Currently, the primary way to dispose of PFAS chemicals is to burn them, which is an expensive multistep process.  Even trace levels are toxic, so when they occur in water in low amounts, they need to be concentrated in order to be destroyed.

Researchers at Texas A&M University have developed a novel bioremediation technology for cleaning up PFAS.  It uses a plant-derived material to absorb the PFAS which is then eliminated by microbial fungi that literally eat the forever chemicals.

The sustainable plant material serves as a framework to adsorb the PFAS.  That material containing the adsorbed PFAS serves as food for the fungus.  Once the fungus has eaten it, the PFAS is gone. 

The EPA has established a nationwide program to monitor the occurrence and levels of PFAS in public water systems and is considering adding PFAS threshold levels to drinking water standards.  If this happens, the technology developed at Texas A&M may become an essential part of municipal water systems.

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Texas A&M AgriLife develops new bioremediation material to clean up ‘forever chemicals’

Photo, posted August 10, 2013, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Green Bills Pass In New York | Earth Wise

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In late July, the two houses of the New York legislature passed a number of environmental bills covering a wide range of topics.

These included a bill to add protected status for streams that support fisheries and non-contact recreation.  A second bill bans the use of PFAS in food packaging.  A third bill classifies all wastes resulting from oil and gas exploration, development, extraction or production as hazardous waste, closing a previous loophole in the law.

A fourth bill requires water works corporations with more than 1,000 service connections to post their annual water supply statements online, thereby providing transparency and openness to water quality data.  A fifth bill expands protections for endangered species to protect them from environmental rollbacks by the federal government.

A sixth bill prohibits non-electric vehicles from parking in spaces designated for electric vehicle charging, thereby establishing penalties for this practice that is often done for spite.  A seventh bill bans the use of glyphosate – the herbicide found in Roundup and other products – on state property.

An eighth bill reduces the use of road salt in the Adirondacks.  A ninth bill requires supermarkets to make good faith efforts to donate edible excess food to qualifying entities such as food pantries, food banks, or similar entities.   A tenth bill bans certain uses of trichloroethylene or TCE, including as a vapor degreaser, an intermediate chemical to produce other chemicals, a refrigerant, or an extraction solvent.

When signed by the governor, these ten pieces of legislation will help protect New York’s environment, water, and health.  It was a busy session for green legislation.

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Several Green Bills Pass in State Legislature

Photo, posted September 12, 2018, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Destroying Forever Chemicals | Earth Wise

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PFAS, short for poly and perfluoroalkyl substances, have been used in commercial products since the 1940s.  There are more than 4,000 different chemicals in the class.   Some of the most commonly used PFAS chemicals, like PFOS and PFOA, have long half-lives, which has earned them the moniker “forever chemicals.” 

These dangerous chemicals have not been manufactured in the U.S. since the early 2000s, but they can still be found in various imported goods.  PFAS chemicals have been linked to cancer, birth defects, thyroid disease, and liver damage.  These forever chemicals linger in the environment and scientists have found them in the blood of virtually all Americans.

Researchers at Rice University have recently discovered an efficient catalyst for destroying PFAS forever chemicals.  Unexpectedly, the catalyst was actually in the control group in a study they were performing.

The study, published in the journal Environmental Science and Technology Letters, found that boron nitride, acting as a light-activated catalyst, destroyed PFOA at a faster clip than any previously reported photocatalyst.

The catalyst, boron nitride powder, is a commercially available synthetic mineral that is widely used in makeup, skincare products, thermal pastes for cooling computer chips, and various other industrial products.  The discovery began with dozens of failed experiments on a variety of more promising PFAS catalysts.  But along the way, they found that the boron nitride control material repeatedly yielded positive results.

The research has already attracted the attention of industrial partners seeking to develop off-grid water treatment systems that both protect human lives and support sustainable economic development.

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Boron nitride destroys PFAS ‘forever’ chemicals PFOA, GenX

Photo, posted April 9, 2009, courtesy of Rex Roof via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

PFAS In The Food Chain | Earth Wise

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Per- and polyfluoroalkyl substances (PFAS) are a family of human-made chemicals that have been manufactured and used in a variety of industries around the globe.  PFOA and PFOS have been the most extensively produced and the most extensively studied of these chemicals. 

Exposure to PFAS has been linked to a host of adverse health effects, including thyroid hormone disruption and cancer.

PFAS compounds can be found in such things as non-stick cookware, stain-resistant carpets, water-repellent outdoor gear, and food packaging, like fast food wrappers and microwave popcorn bags. 

According to a new study, researchers from North Carolina State University have found PFAS substances in every step of the Yadkin-Pee Dee River food chain, even though the river doesn’t have a known industrial input of these compounds. 

The team collected water, sediment, algae, plant, insect, fish, crayfish, and mollusk samples at five sites along the river and analyzed them for 14 different PFAS compounds.  Nearly every sample tested contained PFAS compounds.  Biofilm contained the largest concentrations of 10 of the 14 PFAS compounds measured.  Insects, which primarily eat biofilm, had the greatest accumulation of PFAS compounds of all the living taxa the researchers sampled. 

When PFAS compounds are present at every step of the food chain, the compounds accumulate at each step leading to greater concentrations in animals that sit higher on the food chain – including humans.  This is known as biomagnification. 

Studies like this that reveal how prevalent PFAS can be within ecosystems without an industrial input highlight the need for further research into how these compounds affect the environment and human health.

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PFAS present throughout the Yadkin-Pee Dee river food chain

Photo, posted May 24, 2011, courtesy of the U.S. Fish and Wildlife Service via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Forever Chemicals

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One of the toughest classes of pollutants are per- and polyfluoralkyl substances, or PFAS, as they are known.  PFAS are often called “forever chemicals” because they are extremely long-lasting and difficult to clean up.  They are found in household products including non-stick pans, dental floss, water-repellent fabrics, and many others.  They can be found extensively in U.S. waterways and soil.

PFAS move through the food chain, accumulating in humans at levels that scientists say can cause adverse health effects.  While these have not been definitively proven, there is evidence that higher cholesterol levels, cancer, thyroid disruption, and low infant birth rates are all associated with PFAS ingestion.

PFAS are difficult to get rid of because their carbon-fluorine covalent bonds are some of the strongest in organic chemistry.  Researchers at Princeton University have been studying a process known as Feammox in which ammonium breaks down in acidic, iron-rich soils in New Jersey wetlands and similar locations.  They found that this reaction takes place when a bacterium called Acidimicrobium A6 is present.

Using gene-sequencing techniques, they found that the microbe has characteristics that could help break down carbon-fluorine bonds, and therefore break down PFAS.  In tests using microbe-loaded soil samples, they found that the bacterium removed 60% of PFAS pollutants within 60 days.

The research has been published in the journal Environmental Science and Technology and the team is now testing the bacterium’s effectiveness over different time-spans in lab conditions before testing it in the field.

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New Jersey Soil Microbe Shown to Break Down ‘Forever Chemicals’

Photo, posted November 9, 2017, courtesy of the Department of Environmental Quality via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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