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Bio-based products on the rise

January 30, 2024 By EarthWise Leave a Comment

There is a growing global movement working towards replacing conventional synthetic products – ones that are toxic to make or use, difficult to recycle, and have large carbon footprints – with products made from plants, trees, or fungi that can be safely returned to the earth at the end of their useful life.  This so-called bioeconomy is in its infant stages, but there is increasing interest in turning successful research into manufactured products.

One example is nylon.  Nylon was created in the 1930s by DuPont.  It has been used and continues to be used in a wide range of products.  The problem with it is that it is made from petroleum, it doesn’t biodegrade, and producing it generates nitrous oxide, which is a problematic greenhouse gas.

A San Diego-based company called Genomatica has developed a plant-based nylon using biosynthesis, a process in which a genetically engineered microorganism ferments plant sugars to create a chemical intermediate that can be turned into the nylon-6 polymer, and then into textiles. 

The impetus for developing bio-based products includes the growing public disgust at the mounting environmental toll of plastic, not the least of which is that people and animals are increasingly ingesting it.  Coupled with this, there is a rapidly-growing torrent of funding, especially in the US and Europe, aimed at accelerating the transition away from products that are non-biodegradable, toxic, and that produce carbon emissions.   Last September saw the launch of the National Biotechnology and Biomanufacturing Initiative which will support research and development on such topics as the use of sustainable biomass and waste resources to make non-toxic, bio-based fuels, chemicals, and fertilizers.

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From Lab to Market: Bio-Based Products Are Gaining Momentum

Photo, posted May 27, 2010, courtesy of André C via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Converting A Toxin Into An Industrial Chemical | Earth Wise

January 16, 2020 By EarthWise Leave a Comment

Converting toxin into industrial chemical

Nitrogen dioxide is a prominent air pollutant produced by internal combustion engines burning fossil fuels as well as by a variety of industrial processes.  It is a toxic material associated with a number of respiratory illnesses. 

Researchers at the University of Manchester in the UK along with an international team of scientists have developed a new advanced material that can convert nitrogen dioxide from an exhaust gas stream into useful industrial chemical using only water and air.

The material is a metal-organic framework (or MOF) that provides a selective, fully reversible, and repeatable capability to capture nitrogen dioxide.  MOFs are tiny three-dimensional structures that are porous and can trap gases inside as though there were tiny cages.  MOFs have enormous amounts of surface area for their size.  One gram of material can have a surface area as large as a football field.

The material, named MOF-520, can capture nitrogen dioxide at ambient temperatures and pressures and even at low concentration and during flow in the presence of moisture, sulfur dioxide, and carbon dioxide.  Such conditions are typical of the exhaust of internal combustion engines. In fact, the process works best at the typical temperature of automobile exhausts.

Once the nitrogen oxide is absorbed, treating the material with water in air converts it into nitric acid and restores the MOF for additional use.  Nitric acid is the basis of a multi-billion dollar industry with uses including agricultural fertilizers, rocket propellant, and nylon.  Thus, there is great potential for recouping the costs of using the MOF technology and even profiting from it.

It would be great to convert a toxic pollutant into valuable industrial chemicals.

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Clean air research converts toxic air pollutant into industrial chemical

Photo courtesy of the University of Manchester.

Earth Wise is a production of WAMC Northeast Public Radio.

Making Biofuel Cost Effective

June 14, 2017 By EarthWise

https://earthwiseradio.org/wp-content/uploads/2017/06/EW-06-14-17-Making-Biofuel-Cost-Effective.mp3

Biofuels are considered to be a sustainable alternative to fossil fuels.  However, they are generally more expensive than competing fossil fuels.   Government subsidies, such as we have for ethanol in this country, have been necessary to make biofuels competitive in the marketplace.

[Read more…] about Making Biofuel Cost Effective

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