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Concrete And Carbon | Earth Wise

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After water, concrete is the world’s second most consumed material.  It is the cornerstone of modern infrastructure.  Its production accounts for 8% of global carbon dioxide emissions.  The carbon dioxide is a result of chemical reactions in its manufacture and from the energy required to fuel the reactions.

About half of the emissions associated with concrete come from burning fossil fuels to heat up the mixture of limestone and clay that ultimately becomes ordinary Portland cement.  These emissions could eventually be eliminated by using renewable-generated electricity to provide the necessary heat.  However, the other half of the emissions is inherent in the chemical process.

When the minerals are heated to temperatures above 2500 degrees Fahrenheit, a chemical reaction occurs producing a substance called clinker (which is mostly calcium silicates) and carbon dioxide.  The carbon dioxide escapes into the air.

Portland cement is then mixed with water, sand, and gravel to produce concrete.  The concrete is somewhat alkaline and naturally absorbs carbon dioxide albeit slowly.  Over time, these reactions weaken the concrete and corrode reinforcing rebar.

Researchers at MIT have discovered that the simple addition of sodium bicarbonate (aka baking soda) to the concrete mixture accelerates the early-stage mineralization of carbon dioxide, enough to make a real dent in concrete’s carbon footprint.  In addition, the resulting concrete sets much more quickly.  It forms a new composite phase that doubles the mechanical performance of early-stage concrete.

The goal is to provide much greener, and possibly even carbon-negative construction materials, turning concrete from being a problem to part of a solution.

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New additives could turn concrete into an effective carbon sink

Photo, posted April 4, 2009, courtesy of PSNH via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Energy From Rice Straw | Earth Wise

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Rice straw is produced as a byproduct of rice production.  Globally, as much as a billion tons of rice straw is produced each year, three-quarters of it in Asia.  Straw incorporation in soil for fertilization is not practical in most places because with multiple crops per year, there is not enough time for the material to decompose and become good fertilizer.  As a result, open-field straw burning is increasingly the standard practice.

Scientists at Aston University in Birmingham in the UK are embarking on a project to convert rice straw in Indonesia into low-cost energy on a commercial scale.

Indonesia produces 100 million tons of rice waste each year, of which 60% is burned in open fields, causing air pollution. 

The Aston researchers are developing a biomass conversion process based on pyrolysis.  This involves heating the rice straw to high temperatures over 900 degrees Fahrenheit to break it down, producing vapor and solid products.  Both of these things can be used to generate electricity.

A new combustion engine designed by a company called Carnot Limited is capable of converting 70% of the thermal energy extracted from the rice straw into electricity.

Energy extracted in this way could help low and middle-income countries to create their own locally generated energy, thereby reducing emissions, creating jobs, and improving human health.   The biomass electricity is predicted to be cheaper than solar, geothermal, wind, coal, or even subsidized gas-generated power.

The Aston University project will help develop a business model that could support companies and communities to produce local, cheap energy in Indonesia and other countries with biomass capacity. 

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Aston University to help power Indonesia with affordable energy made from rice straw

Photo, posted September 11, 2006, courtesy of Kristen McQuillin via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Colorful Solar Panels | Earth Wise

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More and more buildings and public spaces are incorporating solar panels and not only just on rooftops.  Some buildings are incorporating power-generating structures all over their facades.

Using solar panels in this way puts some design constraints on buildings because solar panels are typically a deep black color.  This is because solar panels need to absorb light and making them any other color decreases their ability to do so and generate power.  But the problem is that people don’t necessarily want a black building.

One alternative to traditional solar panel design is to use structural sources of color that include microscopic shapes that only reflect specific light frequencies, like the scales on butterfly wings.  But this approach generally leads to iridescence – which might not be what is wanted – and is often quite expensive to implement.

A team of researchers at a university in Shanghai has now demonstrated a way to give solar panels color that is easy and inexpensive to apply and that does not reduce their ability to produce energy efficiently.

The technique involves spraying a thin layer of a material called a photonic glass onto the surface of solar cells.  The photonic glass is made of a thin, disorderly layer of dielectric microscopic zinc sulfide spheres.  Even though most light can pass through the photonic glass, certain colors are reflected back, depending on the sizes of the spheres.  By varying that size, the researchers created solar panels that were blue, green, or purple with only a very small drop in solar panel efficiency.

The solar panels made this way maintained their color and performance under durability testing.  With this new technology, there may soon be colorful solar panels on our buildings.

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Colorful solar panels could make the technology more attractive

Photo, posted December 15, 2021, courtesy of Pete via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

A Cheap Material For Carbon Capture | Earth Wise

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The recently passed Inflation Reduction Act includes significant support for carbon capture technologies. Eliminating fossil fuel burning is essential for halting climate change, but in the interim, methods for capturing emissions of carbon dioxide and either storing it or turning it into usable products are increasingly necessary.

There are a variety of techniques being developed for carbon capture but at this point, none of them are commercially viable.  The best technique in use today involves piping flue gases through chemicals called liquid amines, which bind CO2.  The process requires large amounts of energy to release the bound carbon dioxide so it can be concentrated and stored.  As a result, it is complicated and expensive.

Researchers at UC Berkeley, Stanford, and Texas A&M University have developed a carbon capture method using melamine, which is an inexpensive polymer used to make Formica, as well as low-cost dinnerware, industrial coatings, and other plastics.  Porous melamine itself adsorbs CO2 to a limited extent.  But the researchers discovered that adsorption could be much improved by adding the chemical DETA (diethylenetriamine) to bind the CO2.  In addition, adding cyanuric acid increased the melamine pore size and radically improved CO2 capture efficiency even more.

The result is a material that is more efficient even than exotic carbon capture materials like metalorganic frameworks and is much cheaper and easier to make. The researchers aim to design equipment that can used in industrial facilities, attached to buildings and other structures, or even to the tailpipes of gas-powered vehicles.

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A simple, cheap material for carbon capture, perhaps from tailpipes

Photo, posted June 10, 2006, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Cleaning Up Forever Chemicals | Earth Wise

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PFAS, per- and polyfluoroalkyl substances, are chemical pollutants that threaten human health and ecosystem sustainability.  They are used in a wide range of applications including food wrappers and packaging, dental floss, firefighting foam, nonstick cookware, textiles, and electronics.  Over decades, these manufactured chemicals have leached into our soil, air, and water.  Chemical bonds in PFAS molecules are some of the strongest known, so the substances do not degrade easily in the environment.

Studies have shown that at certain levels, PFAS chemicals can be harmful to humans and wildlife and have been associated with a wide variety of health problems.

Currently, the primary way to dispose of PFAS chemicals is to burn them, which is an expensive multistep process.  Even trace levels are toxic, so when they occur in water in low amounts, they need to be concentrated in order to be destroyed.

Researchers at Texas A&M University have developed a novel bioremediation technology for cleaning up PFAS.  It uses a plant-derived material to absorb the PFAS which is then eliminated by microbial fungi that literally eat the forever chemicals.

The sustainable plant material serves as a framework to adsorb the PFAS.  That material containing the adsorbed PFAS serves as food for the fungus.  Once the fungus has eaten it, the PFAS is gone. 

The EPA has established a nationwide program to monitor the occurrence and levels of PFAS in public water systems and is considering adding PFAS threshold levels to drinking water standards.  If this happens, the technology developed at Texas A&M may become an essential part of municipal water systems.

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Texas A&M AgriLife develops new bioremediation material to clean up ‘forever chemicals’

Photo, posted August 10, 2013, courtesy of Mike Mozart via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Better Way To Recycle Plastic | Earth Wise

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The current state of plastic recycling is not very effective.  Plastic recycling is only able to replace 15-20% of the fossil-fuel-derived raw material needed to produce society’s demand for plastic.

Researchers at Chalmers University in Sweden have now demonstrated how the carbon content in mixed waste could be used to replace all of the fossil raw materials in the production of new plastic.  In principle, their technology could completely eliminate the climate impact of plastic materials.

According to the researchers, there are enough carbon atoms in waste to meet the needs of all global plastic production.

The Chalmers process is based on thermochemical technology and involves heating waste to 1100-1500 degrees Fahrenheit.  The waste is thereby vaporized and when hydrogen is added, becomes a carbon-based substance that can replace the fossil-fuel building blocks of plastic.  The method does not require sorting the waste materials.  Different types of waste, such as old plastic products and even paper cups, with or without food residues, can be fed into the recycling reactors.  The researchers are now developing the techniques required to utilize their recycling technology in the same factories in which plastic products are currently being made from fossil oil or gas.

The principle of the process is inspired by the natural carbon cycle in which plants break down into carbon dioxide when they wither and die, and then photosynthesis uses carbon dioxide and solar energy to grow new plants.

Producing new plastics would no longer require petroleum or other fossil fuels as raw materials.  If the energy needed to drive the recycling reactors is taken from renewable sources, plastics could become the basis of a sustainable and circular economy.

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Pioneering recycling turns mixed waste into premium plastics with no climate impact

Photo, posted August 10, 2013, courtesy of Lisa Risager via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Storing Sunshine To Make Electricity On Demand | Earth Wise

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Researchers at Chalmers University in Sweden have developed an entirely new way of capturing and storing energy from sunlight.  The system is called the Molecular Thermal Energy Storage System or MOST.  It is based on a specially designed molecule that changes shape when it is exposed to sunshine.

The molecule is composed of carbon, hydrogen, and nitrogen.  When sunlight hits it, it changes into an energy-rich isomer – a molecule made up of the same atoms but arranged together in a different way.  That isomer is stable and can be stored for many years.  When a specially designed catalyst is applied, the stored energy is released in the form of heat and the molecule returns to its original form and can be reused. 

The Chalmers researchers sent some of the energy-laden isomer to researchers in China who used it to operate a micron-thin thermoelectric generator, which used the heat released by the isomer material to generate electricity.  The generator is an ultra-thin chip that could be integrated into electronics such as headphones, smart watches, and telephones.  It is currently only at the proof-of-concept stage, but the results are quite promising.  The integration with the MOST technology provides a way that solar energy can generate electricity regardless of weather, time of day, season, or geographical location.  The results of the study were recently published in the journal Cell Reports Physical Science.

In effect, for this demonstration, Swedish sunshine was sent to the other side of the world and converted into electricity in China. The ultimate goal of this research is to create self-charging electronics that uses stored solar energy on demand.

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Converting solar energy to electricity on demand

Photo, posted March 11, 2013, courtesy of Steve Slater via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A New “Wonder Material” | Earth Wise

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Graphene is a form of carbon made of single-atom-thick layers. It has many remarkable properties and researchers around the world continue to investigate its use in multiple applications.

In 2019, a new material composed of single-atom-thick layers was produced for the first time.  It is phosphorene nanoribbons or PNRs, which are ribbon-like strands of two-dimensional phosphorous.  These materials are tiny ribbons that can be a single atomic layer thick and less than 100 atoms wide but millions of atoms long.  They are comparable in aspect ratio to the cables that span the Golden Gate Bridge.   Theoretical studies have predicted how PNR properties could benefit all sorts of devices, including batteries, biomedical sensors, thermoelectric devices, nanoelectronics, and quantum computers. 

As an example, nanoribbons have great potential to create faster-charging batteries because they can hold more ions than can be stored in conventional battery materials.

Recently, for the first time, a team of researchers led by Imperial College London and University College London researchers has used PNRs to significantly improve the efficiency of a device.  The device is a new kind of solar cell, and it represents the first demonstration that this new wonder material might actually live up to its hype.

The researchers incorporated PNRs into solar cells made from perovskites.  The resultant devices had an efficiency above 21%, which is comparable to traditional silicon solar cells.  Apart from the measured results, the team was able to experimentally verify the mechanism by which the PNRs enhanced the improved efficiency.

Further studies using PNRs in devices will allow researchers to discover more mechanisms for how they can improve performance.

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‘Wonder material’ phosphorene nanoribbons live up to hype in first demonstration

Photo, posted October 6, 2010, courtesy of Alexander AlUS / CORE-Materials via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

A Smart Heat-Blocking Window | Earth Wise

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An international research team led by Nanyang Technological University in Singapore has invented a ‘smart’ window material that controls the transmission of heat without blocking the view through the window.  The technology could help reduce the amount of energy needed to cool and heat buildings.

The new material can be the basis of an electrochromic window that can block or pass infrared radiation at the flick of a switch.  Current electrochromic windows can be darkened when switched on and are found in many ‘green’ buildings as well as in many car mirrors.  But these windows are only effective in blocking visible light so infrared radiation – meaning heat – still passes through them.

The new coating material blocks up to 70% of infrared radiation when switched on but still allows up to 90% of visible light to pass through.  The material is a specifically designed composite nanostructure and utilizes advanced materials including titanium dioxide, tungsten trioxide, neodymium, niobium, and tin oxide.  It is intended to be coated onto glass window panels and be activated by electricity when needed.  The material was put through rigorous on-off cycles to assess its stability and durability and it appears to offer superior performance in that regard compared with current electrochromic technology.

The researchers also created a switchable system that helps control conducted heat, which is the heat from the external environment.

The combination of the two technologies could result in smart windows that control two types of heat transmission:  infrared radiation and conduction heat.  Such technology could help conserve energy used for the heating and cooling of buildings and could contribute to the future design of sustainable green buildings.

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Scientists invent ‘smart’ window material that blocks rays without blocking views

Photo, posted March 11, 2016, courtesy of Open Grid Scheduler via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Reducing Emissions From Cement Manufacturing | Earth Wise

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Cement is the basic ingredient of concrete, which is the most widely used construction material in the world.  About 8% of global carbon dioxide emissions are associated with cement production.

More than half of these emissions come from making clinker, which is a major component of cement produced by heating ground limestone and clay to a temperature of over 2500 degrees Fahrenheit.  Some of the emissions come from burning fossil fuels to heat the materials, but much of them come from the chemical reaction that creates the clinker.

The Portland Cement Association, which represents 92% of US cement manufacturing capacity, has recently released its “Roadmap to Carbon Neutrality”, which lays out a plan to reach carbon net zero across the cement and concrete value chain by 2050.

The plan includes the greater use of alternative fuels to reduce emissions from energy use.  It also involves the adoption of newer versions of cement such as Portland limestone cement, which reduces CO2 levels.  The industry has already reduced emissions by some shifting to Portland limestone cement, but it still only represents a small fraction of cement production.

The most significant strategy would be the adoption of carbon capture, utilization, and storage (or CCUS) technologies.  The idea is to capture the CO2 generated in the production of clinker and inject it into the fresh concrete.  It would actually be permanently sequestered in the concrete and would not be released even if a structure is demolished in the future.

It will take a combination of technologies and initiatives for the cement industry to reduce its emissions.  Fortunately, the industry appears to be committed to that goal.

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US cement manufacturers release their road map to carbon neutrality by 2050

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Transparent Wood | Earth Wise

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In recent years, there have been efforts to change the nature of wood to give it new properties.  People have demonstrated so-called augmented wood with integrated electronics, energy storage capabilities, and other properties.  Several different groups of researchers have developed wood that is actually transparent.

In 2016, researchers at KTH Royal Institute of Technology in Stockholm demonstrated transparent wood made by selectively extracting lignin – the substance that makes up the cell walls of wood -and replacing it with a polymer.  The result is a new material that is weatherproof, fairly fire resistant, stronger than wood, lighter than wood, and transparent.

When the lignin is removed from wood, the empty pores left behind need to be filled with something that restores the wood’s strength.  The early versions of transparent wood used polymethyl methacrylate – essentially acrylic plastic – for this purpose.  But that material is made from petroleum, so it is not an environmentally desirable approach.

Recently, the KTH researchers have successfully tested an eco-friendly alternative:  limonene acrylate, which is a monomer made from renewable citrus, such as peel waste that can be recycled from the orange juice industry.

There are many potential applications for transparent wood as a structural material.  These include load-bearing windows, skylights, and semi-transparent facades that are strong and thermally insulating and yet permit light to enter. 

Transparent wood would be a very attractive material for many applications in that it comes from renewable sources and offers excellent mechanical properties including strength, toughness, low density, and low thermal conductivity.

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Citrus derivative makes transparent wood 100 percent renewable

Photo, posted October 12, 2018, courtesy of Mussi Katz via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Improving Solar Cells With Human Hair | Earth Wise

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Researchers at the Queensland University of Technology in Australia have been able to improve the performance of perovskite solar cells using material made from human hair.

Perovskite solar cells are an up-and-coming technology that offers the possibility of making solar cells less expensive, more efficient, and flexible so that there could be solar-powered clothing, backpacks, or even tents for camping.  While the technology has been shown to be as effective in converting sunlight to electricity as currently available silicon technology, it faces problems with stability and durability.

The Australian research centered on the use of carbon nanodots to improve perovskite solar cell performance.  The nanodots were created in a rather unique way.  The carbon came from hair scraps from a Brisbane barbershop that were first broken down and then burned at nearly 500 degrees Fahrenheit. 

By adding a solution of the carbon nanodots into the process of making the perovskites, the dots formed a wave-like layer in which the perovskite crystals in the cells are surrounded by the carbon dots.  It serves as a protective layer, essentially a kind of armor, for the active portions of the material.

The result was solar cells with a higher power conversion efficiency and greater stability.  The researchers did not explain why they chose human hair as the source of carbon, but it does make for an interesting sidelight to the promising research.

Perovskite solar cells could be very important for spacecraft applications where reducing weight is paramount.  But in order to be able to use them for this purpose, perovskite solar cells will need to be able to cope with the extreme radiation and temperature variations in space.

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Carbon dots from human hair boost solar cells

Photo, posted October 3, 2009, courtesy of Arktoi via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Infinitely Recyclable Plastic | Earth Wise

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The glut of plastics is one of the world’s most challenging environmental problems.  The average American generates over 200 pounds of plastic waste each year and most of that ends up in landfills.  Researchers around the globe continue to work on potential solutions to the plastic waste problem.

Two years ago, scientists at Lawrence Berkeley National Laboratory announced the invention of a new plastic that could be an answer to the plastic waste problem.  The material is called polydiketoenamine or PDK and it differs from traditional plastics in a very important way:  it can be recycled indefinitely with no loss in quality because it can easily be broken down into its constituent component monomers and be used to make brand new plastic.

Only a small percentage of plastics are currently recycled.  When many plastics are melted down together, the polymers are mixed with a slew of incompatible additives, resulting in a new material with much lower quality than newly produced plastic.  As a result, less than 10% of plastic is recycled more than once.

Recently, the Berkeley Lab researchers released a study that shows what could be accomplished if manufacturers began using PDKs on a large scale.  They determined that PDK-based plastic could quickly become commercially competitive with conventional plastics and, furthermore, would get less expensive and more sustainable as time goes on.

PDK is starting to draw interest from companies needing to source plastic.  The best initial application for PDKs are markets where manufacturers have the most access to products at the end of their lifespans such as in the automobile industry and consumer electronics.  Making plastics part of a circular economy is a challenging task.

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The Future Looks Bright for Infinitely Recyclable Plastic

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Superstrong Nanofibers | Earth Wise

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Self-assembly is a ubiquitous process in the natural world that leads to the formation of the DNA double helix, the creation of cell membranes, and to many other structures.   Scientists and engineers have been working to design new molecules that assemble themselves in water for the purpose of making nanostructures for biomedical applications such as drug delivery or tissue engineering.  For the most part, the materials created in this way have been chemically unstable and tended to degrade rapidly, especially when the water is removed.

A team at MIT recently published a paper describing a new class of small molecules they have designed that spontaneously assemble into nanoribbons with unprecedented strength and that retain their structure outside of water.

The material is modeled after a cell membrane.  Its outer part is hydrophilic (it likes to be in water) and its inner part is hydrophobic (it tries to avoid water.)  This configuration drives the self-assembly to create a specific nanostructure and by choosing the appropriate chemicals to form the structures, the result was nanoribbons in the form of long threads that could be dried and handled.  The resultant material in many ways resembles Kevlar.   In particular, the threads could hold 200 times their own weight and have extraordinarily high surface areas.  The fibers are stronger than steel and the high surface-to-mass ratio offers promise for miniaturizing technologies for such applications as pulling heavy-metal contaminants out of water and for use in electronic devices and batteries.

The goal of the research is to tune the internal state of matter to create exceptionally strong molecular nanostructures.  The potential for important new applications is considerable and exciting.

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Researchers construct molecular nanofibers that are stronger than steel

Photo, posted June 19, 2007, courtesy of Andrew Hitchcock via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Generating Hydrogen From Poor-Quality Water | Earth Wise

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Hydrogen could be the basis of a complete energy system.  It could be stored and transported and could be used to power vehicles and to generate electricity in power plants.  Proponents of the so-called hydrogen economy contend that hydrogen is the best solution to the global energy challenge.  But among the challenges faced by a hydrogen economy is the development of an efficient and green method to produce hydrogen.

The primary carbon-free method of producing hydrogen is to break down water into its constituent elements – hydrogen and oxygen.  This can be done in a number of ways, notably by using electricity in a process called electrolysis.  A method that seems particularly attractive is to use sunlight as the energy source that breaks down the water molecule.

While there is an abundance of water on our planet, only some of it is suitable for people to drink and consume in other ways.    Much of the accessible water on earth is salty or polluted.  So, a technique to obtain hydrogen from water ideally should work with water that is otherwise of little use to people.

Researchers in Russia and the Czech Republic have recently developed a new material that efficiently generates hydrogen molecules by exposing water – even saltwater or polluted water – to sunlight. 

The new material is a three-layer structure composed of a thin film of gold, an ultra-thin layer of platinum, and a metal-organic framework or MOF of chromium compounds and organic molecules.  The MOF layer acts as a filter that gets rid of impurities.

Experiments have demonstrated that 100 square centimeters of the material can generate half a liter of hydrogen in an hour.  The researchers continue to improve the material and increase its efficiency over a broad range of the solar spectrum.

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New Material Can Generate Hydrogen from Salt and Polluted Water

Photo courtesy of Tomsk Polytechnic University.

Earth Wise is a production of WAMC Northeast Public Radio.

A Fabric To Keep You Cool | Earth Wise

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About 10% of all electricity consumption in the U.S. is devoted to keeping us cool with air conditioning and other methods.  Researchers at two universities in Shanghai, China have developed a new material that can be made into clothing that cools the wearer without using any electricity.

The new fabric transfers heat, allows moisture to evaporate from the skin, and repels water.  Cooling off a person’s body is much more efficient than cooling off an entire room or a building.  There have been textiles and types of clothing designed to perform the cooling function, but most of those have disadvantages.  These include some combination of poor cooling capacity, high energy consumption, complex and time-consuming manufacturing, and high cost.

The researchers wanted to develop a personal cooling fabric that can efficiently transfer heat away from the body while at the same time being breathable, water resistant and easy to make.

The new fabric is made by electrospinning an ordinary polyurethane polymer with a water-repelling fluorinated version of polyurethane polymer along with a thermally conductive filler composed of boron nitride nanosheets.  The resultant material is a nanofibrous membrane that repels water from the outside but has large enough pores to allow sweat to evaporate from the skin and air to circulate. 

Tests of the membrane demonstrated higher thermal conductivity than other conventional or high-tech fabrics.  Used in clothing, the material would be more effective than previous fabrics in conducting heat away from the body. It may be possible to beat the heat without turning on the AC.   These membranes could also be useful for solar energy collection, seawater desalination, and thermal management of electronic devices.

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New fabric could help keep you cool in the summer, even without A/C

Photo courtesy of the American Chemical Society on Youtube.

Earth Wise is a production of WAMC Northeast Public Radio.

Plastic From Algae | Earth Wise

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Many researchers consider algae to be one of the best renewable resources for replacing fossil fuels and even as a food source.  The green microalgae Nannochloropsis salina is already a common source of omega-3 fatty acids that are sold as dietary supplements.  As a result, that algae strain is already grown on a large scale for the production of omega-3 products.

A group of researchers at UC San Diego has developed a way to make use of the waste stream from that production to create plastics and other useful products.  Currently, when the algae is processed to extract the omega-3 oil, leftover oils comprising more than 70% of the starting material are either thrown away or burned. 

The UCSD team has developed a process to purify and convert this waste stream into azelaic acid, which is a building block for flexible polyurethanes.   These materials have all kinds of commercial applications from flip-flops and running shoe soles to mattresses and yoga mats.

By analogy to the use of animals by native American tribes, the researchers wanted to “use the whole buffalo” in their solution for algae processing waste and therefore figured out how to convert heptanoic acid – another substance in the algae waste stream – into a food flavoring and fragrance.  The flavoring molecule is valued at over $500 per kilogram.

The work, published in the journal Green Chemistry, demonstrates that an algae-source waste stream has both the practical and economic potential to support production of polyurethanes.  The team is already working with shoe companies to commercialize the technology.  With mounting concern over petroleum-based plastic waste, renewable plastic made from algae is an attractive alternative.

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Researchers Turn Algae Leftovers into Renewable Products with Flare

Photo, posted November 8, 2006, courtesy of Adam Moore via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plants Paying For Biofuels | Earth Wise

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Biofuels are an important element in broader strategies to replace petroleum in transportation fuels like gasoline, diesel, and jet fuel.  The idea is that biofuels recycle carbon by getting it from growing plants rather than from fossil sources.  The biggest problem with biofuels is that they cost more than conventional petroleum fuels, so there is economic incentive to keep burning the fossil fuels.

One strategy to make biofuels cost competitive is to have the plants provide additional economic benefits beyond being a feedstock for fuel.  This in principle can be done by engineering plants to produce valuable chemical compounds, or bioproducts, as they grow.  Bioproducts include such things as flavoring agents and fragrances as well as biodegradable plastic.  These bioproducts can be extracted from the plants and then the remaining plant material can be converted to fuel. 

Researchers at Lawrence Berkeley National Laboratory recently published a study to determine what quantities of bioproducts plants need to produce to result in cost-effective biofuel production.

The study looked at a compound called limonene, which is used for flavoring and fragrance.  They calculated that if this compound was accumulated at 0.6% of the biomass dry weight, it would offer net economic benefits to biorefineries.  This corresponds to recovering 130 pounds of limonene from 10 tons of sorghum on an acre of land.

Such quantities are completely practical but, on the other hand, none of these substances are needed in huge quantities. Just six refineries could supply the world with limonene.  So, fuel crops would need to be engineered to produce a broad range of bioproducts to enable a viable cost-effective biofuel industry.

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Making Biofuels Cheaper by Putting Plants to Work

Photo, posted September 28, 2019, courtesy of Michele Dorsey Walfred via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Harvesting Blue Energy | Earth Wise

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There are various ways to generate renewable energy from the world’s oceans, most obviously from the power of tides and waves.  But there is also an oceanic energy source called osmotic or “blue” energy.  Osmotic energy uses the differences in pressure and salinity between freshwater and saltwater to generate electricity. 

When freshwater and saltwater are mixed together, large amounts of energy are released. If the freshwater and seawater are then separated via a semi-permeable membrane, the freshwater will pass through the membrane and dilute the saltwater due to the chemical potential difference. This process is called osmosis. If the salt ions are captured completely by the membrane, the passing of water through the membrane will create a pressure known as osmotic pressure. This pressure can be used to generate electricity by using it to drive a turbine.  This has been demonstrated to work as far back as the 1970s, but the materials we have to use are not adequate to withstand ocean conditions over the long term and tend to break down quickly in the water.

New research, published in the journal Joule, looked to living organisms for inspiration to develop an improved osmotic energy system.  Scientists from the U.S. and Australia combined multiple materials to mimic the kind of high-performance membranes that are found in living organisms.  They created a hybrid membrane made from aramid microfibers (like those used in Kevlar) and boron nitride.  The new material provides both the flexibility of cartilage and the strength and stability of bone.

The researchers believe that the low cost and high stability of the new hybrid membrane will allow it to succeed in volatile marine environments.  They also expect the technology will be both efficient and scalable. 

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Inspired by the Tissues of Living Organisms, Researchers Take One Step Closer to Harvesting “Blue Energy”

Photo, posted February 14, 2017, courtesy of Marian May via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Emissions-Free Cement

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The production of cement – which is the world’s leading construction material – is a major source of greenhouse gas emissions, accounting for about 8% of global man-made emissions. 

Cement production produces carbon dioxide in two ways:  from a key chemical process and from burning fuel to produce the cement.  The process of making “clinker” – the key constituent of cement – emits the largest amount of CO2.  Raw materials, mainly limestone and clay – are fed into huge kilns and heated to over 2,500 degrees Fahrenheit, requiring lots of fossil fuel.  This calcination process splits the material into calcium oxide and CO2.  The so-called clinker is then mixed with gypsum and limestone to produce cement.

A team of researchers at MIT has come up with a new way of manufacturing cement that greatly reduces the carbon emissions.  The new process makes use of an electrolyzer, where a battery is hooked up to two electrodes in water producing oxygen at one electrode and hydrogen at the other.  The oxygen-evolving electrode produces acid and the hydrogen-evolving electrode produces a base.  In the new process, pulverized limestone is dissolved in the acid at one electrode and calcium hydroxide precipitates out as a solid at the other.

High-purity carbon dioxide is released at the acid electrode, but it can be easily captured for further use such as the production of liquid fuels or even in carbonated beverages and dry ice.  The new approach could eliminate the use of fossil fuels in the heating process, substituting electricity generated from renewable sources. 

The process looks to be scalable and represents a possible approach to greatly reducing one of the perhaps lesser known but nevertheless very significant sources of greenhouse gas emissions.

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New approach suggests path to emissions-free cement

Photo, posted March 26, 2014, courtesy of Michael Coghlan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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