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Getting Value From Plastic Waste | Earth Wise

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To date, the world has produced more than five billion tons of plastic and is making more all the time.  Based on the way things are currently done, most of that will end up in landfills or in the natural environment.  By 2050, the amount of plastic is expected to exceed 13 billion tons.   This is one of the world’s biggest environmental problems.

Recently, an international collaboration by universities and institutions in the UK, China, and Saudi Arabia has developed a method of converting plastic waste into hydrogen gas and high-value solid carbon.

The technique was achieved with a new type of catalysis that uses microwaves to activate catalyst particles that effectively strip hydrogen from plastic polymers.  The work was recently published in the journal Nature Catalysis and details how the researchers mixed mechanically pulverized plastic particles with a microwave-susceptor catalyst of iron oxide and aluminum oxide.  That mixture was then subjected to microwave treatment and yielded a large volume of hydrogen gas and a residue of carbonaceous material, most of which was identified as carbon nanotubes.

The process is more rapid than most methods for dealing with plastic waste and can extract over 97% of the hydrogen in plastic without producing any carbon dioxide emissions. 

The new method represents an attractive potential solution to the problem of plastic waste.  Instead of polluting the planet, plastics could become a valuable feedstock for producing clean hydrogen fuel as well as valuable carbon materials.  Proponents of the so-called hydrogen economy have continued to seek a green and economical way to produce hydrogen.  This new work might be just what they are looking for.

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Turning plastic waste into hydrogen and high-value carbons

Photo, posted April 21, 2007, courtesy of Redwin Law via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Sustainable Flip-Flops | Earth Wise

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Flip-flops are the world’s most popular shoe.  They are lightweight, comfortable, affordable, and durable.  In fact, the global market for flip-flops is expected to reach a whopping $23.8 billion by the year 2025. 

But the popularity comes with a price.  Flip-flops account for a troubling percentage of plastic waste that ends up in our landfills and oceans.  As a result, demand for alternatives is compelling researchers to develop more sustainable versions of the popular footwear.

Scientists at the University of California San Diego have spent years working on this issue, and recently announced a breakthrough.  According to a study recently published in Bioresource Technology Reports, the research team has formulated polyurethane foams – made from algae oil – to meet commercial specifications for mid-sole shoes and the foot-bed of flip-flops.   In other words, the scientists have created sustainable, biodegradable, and consumer-ready materials that could replace plastics in some footwear. 

The UC San Diego scientists collaborated with Algenesis Materials – a technology startup – on the research.  Together, they worked to not only create the shoes, but to degrade them as well.  The team tested their customized foams by immersing them in traditional compost and soil.  The algae-based materials degraded after just 16 weeks.  

The life of any material should be proportionate to the life of the product.  The researchers point out that it doesn’t make sense to create a product that will last 500 years if it’ll only be used for a year or two. 

The research team is currently working on production details with its manufacturing partners.  The creation of biodegradable flip-flops that meet commercial footwear standards could eliminate tons of plastic waste from the environment.   

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New science behind algae-based flip-flops

Flip Flops Market Size Worth $23.8 Billion by 2025

Photo, posted December 12, 2019, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Preserving Produce With Eggs | Earth Wise

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Researchers at Brown University have developed an inexpensive coating to protect fruits and vegetables that is made from eggs that would otherwise be wasted.  The micron-thick coating solves problems for the produce and its consumers as well as for the environment.

The coating relies on eggs that never reach the market.  The U.S. produces more than 7 billion eggs a year.  The supply chain rejects about 3% of them, typically because of shell damage, which means that more than 200 million eggs end up in landfills.

The coating is mostly made from egg, the rest consisting of nanoscale cellulose extracted from wood, a tiny amount of curcumin (the main active ingredient in turmeric that has antimicrobial properties), and a bit of glycerol for added elasticity.  The coating is applied to produce by spraying or dipping.  It shows a remarkable ability to resist rotting for an extended period comparable to standard coatings like wax, but without their shortcomings.

Along with being edible, the coating retards dehydration, provides antimicrobial protection, and is largely impermeable to both water vapor to prevent dehydration and to gas to prevent premature ripening.  The coating is entirely natural, and it washes off with water.  So, anyone sensitive to the coating, such as someone with an egg allergy, can easily eliminate it.

Lab tests of the coating studied its effects on strawberries, avocados, bananas and other fruits.  All were seen to maintain their freshness far longer than uncoated produce.

The researchers are continuing to refine the coating.  They are also considering other source materials.  They chose egg proteins because there are so many wasted eggs, but it may be possible to make use of plant proteins instead to address the needs of vegan consumers.

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Egg-based coating preserves fresh produce

Photo, posted July 13, 2012, courtesy of Liz West via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Bottles | Earth Wise

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Single-use plastic soda and water bottles are a real problem.  Every year, billions of them are produced – comprising nearly 300 million tons of plastic that mostly ends up in landfills or in the ocean.   This discarded plastic ends up on remote islands, in the snow atop mountains, and in trenches in the deepest parts of ocean.

There has been increasing pressure on beverage companies to put an end to this environmental disaster, but the convenience and economy of disposable bottles is just too attractive.

These bottles are made of plastic derived from oil and once they are produced, they take decades or even centuries to decompose.  Recycling them is a not-starter because it is cheaper to just make new ones.

A possible solution has emerged.  A Dutch company called Avantium has found a way to take plant sugars and transform them into a plastic capable of standing up to carbonated beverages like soda and beer but that will also break down in as little as a year in a composter or 3 years if left exposed to the elements.

Coca Cola and Carlsberg are working with Avantium to develop new drink packaging based on their material that could be in stores as soon as 2023.  The new packaging would be quite different from what we use today.  Instead of a clear or tinted bottle, beverages would come inside a cardboard container with a liner made of plant-based plastic.

It may take a while for people to get used to the change, but we have already managed to get used to milk, juice and other liquids coming in cardboard containers instead of glass or plastic bottles.  The benefits to the planet would make the effort well worthwhile.

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Plant-Based Bottles Could Degrade In One Year

Photo courtesy of Avantium.

Earth Wise is a production of WAMC Northeast Public Radio.

Concrete Production And Diminishing Coal Burning | Earth Wise

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Coal burning is still one of the primary means of generating electricity in the United States, but its use is diminishing and doing so fairly rapidly.  The coal burning process produces residual, incombustible materials.  One of them is fly ash, which is composed of fine, glassy, rounded particles rich in silicon, aluminum, calcium, and iron oxides.  Fly ash is captured from coal plant flue gas by precipitators and bag filters. It turns out that two-thirds of this fly ash is not dumped into landfills or impoundments, but rather is put to use.

Because of its chemical and physical characteristics, fly ash can substitute for a portion of portland cement in concrete.  Using this byproduct material in making cement actually reduces its cost. Beyond cost, the addition of fly ash as a so-called supplementary cementitious material or SCM improves concrete’s long-term strength and reduces porosity and permeability.  It reduces the risk of thermal cracking and provides good long-term mechanical properties.

The amount of fly ash used in concrete products increased by 5% between 2011 and 2017 while the amount produced dropped by 36%.  Concrete production continues to increase steadily while fly ash production is steadily dropping.

Therefore, the concrete industry is looking for alternative sources of SCM.  The most obvious is the approximately 1/3 of fly ash that hasn’t been used to make concrete.  Much of that is landfilled or ponded onsite at power plants.  So, opportunities exist for excavating or dredging and recovering these materials.

As coal burning goes away, concrete manufacturing needs to make some changes.

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What Does the Changing Face of Electricity Production Mean for Concrete?

Photo, posted February 16, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Environmental Injustice And the Coronavirus | Earth Wise

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Cities and towns across the United States continue to wrestle with the devastating impacts of the COVID-19 pandemic and none have been hit harder than low-income and minority communities.  Places like Detroit, Chicago, and St. James Parish in Louisiana have suffered from decades of economic inequality and pollution in their poorest neighborhoods and many of these same places have experienced some of the highest mortality rates from the virus.

Recent studies have shown a link between high levels of pollution and the risk of death from COVID-19.  Pollution of various kinds are higher in low-income communities and communities of color.  Such communities don’t have a strong political voice so that laws and environmental regulations are not enforced like there are in white, higher-income communities.  Thus, these communities have highways, landfills, factories, chemical facilities, paper mills, and other pollution sources that communities with economic power – and therefore political power – manage to avoid.

People living in low-income communities and communities of color tend to have higher rates of underlying health conditions like diabetes, heart disease, and asthma.  They have less healthy diets – more fast food and fewer grocery stores.  Part of the reason these communities have a higher risk of mortality from COVID-19 infection is that many people have reduced lung capacity as a result of exposure to pollutants.

The Trump administration has been suspending enforcement of environmental regulations during the pandemic.  Communities already affected by environmental injustice will bear the brunt of this decision.  Groups like nursing home populations, meat packers, prisoners and the poor are suddenly highly visible.  COVID-19 is exposing the real differences between the Haves and the Have-Nots in this country.

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Connecting the Dots Between Environmental Injustice and the Coronavirus

Photo, posted May 2, 2006, courtesy of Sean Benham via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Renewable Natural Gas

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Small-scale biogas systems have collected methane from landfills, sewage plants, and farms for decades.  Here in the US, biogas is finally catching up with modern techniques with the advent of third-party operators introducing more sophisticated technology to capture methane and pump it directly into pipelines.

Renewable methane or natural gas represents a significant mostly unexploited source of energy.  Examples include the vast amounts methane generated by manure from some of the 2,300 hog farms in eastern North Carolina, biodigesters that can turn clusters of large California dairy farms into energy hubs, as well as diverting food waste from landfills and transforming it into vehicle and heating fuels.

According to a 2014 EPA study, the U.S. could support at least 13,000 biogas facilities, fed by manure, landfill gas, and biosolids from sewage treatment plants.  Those facilities could produce over 650 billion cubic feet of biogas per year – enough renewable energy to power 3 million homes.

A study by the World Resources Institute estimated that the 50 million tons of organic waste sent to landfills or incinerated every year in the U.S. has the energy content of 6 billion gallons of diesel fuel, amounting to 15% of all diesel consumed by heavy-duty trucks and buses.

Utilizing all that biogas could help lower greenhouse gas emissions from some of the most difficult sectors to decarbonize – transportation, industry, and heating buildings.  In addition, ramped up renewable gas could keep organic waste out of landfills and prevent manure runoff into rivers and water supplies.

Renewable natural gas could be the next big thing in green energy.

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Could Renewable Natural Gas Be the Next Big Thing in Green Energy?

Photo, posted June 19, 2013, courtesy of Alan Levine via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plastic-Eating Mushrooms

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Plastic waste has become one of the most pressing environmental issues in the world.  Whether it is about drinking straws, grocery bags, or six-pack rings, getting rid of plastic items in the waste stream is a major focus of attention for more and more people.

A really promising way to deal with all the plastic ending up in landfills has grown out of research that was being conducted in the Amazon rain forest in 2012.  Back then, a group of students from Yale University discovered a fungus that eats only polyurethane.  It is a mushroom known as Pestalotiopsis microspore and it not only can survive exclusively on the plastic, but it can do it in anaerobic (that is, oxygen-free) environments.  Thus, these plastic-eating mushrooms could potentially thrive at the bottom of landfills.

More recently, other studies have identified additional mushroom species that can eat plastic.  Some of them are common, such as the oyster mushroom, which itself is edible.  In 2018, the first ever State of the World’s Fungi symposium took place in London.  The event focused on multiple applications for mushrooms, including their use as building materials, their ability to remove pollutants from soil, and their capacity to enable the conversion of waste into biofuels.

Under controlled conditions, it takes just a few weeks for plastic-eating mushrooms to start breaking down plastics.  After a few months, all that is left are puffy white mushrooms which, even if they are not used for anything themselves, can be composted and turned into soil.

So far, there has been relatively little exploitation of mushrooms for improving the environment, but they may well be a big help in dealing with the growing problem of plastic waste.

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Scientists discovered a mushroom that eats plastic, and believe it could clean our landfills

Photo, posted August 12, 2014, courtesy of Tim Sheerman-Chase via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

China And Plastic Waste

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In January 2018, China enacted its “National Sword” policy which banned the import of most plastics and other materials headed for that country’s recycling processors.  Those processors had handled nearly half of the world’s recyclable waste for the past quarter century.  China took this step because the deluge of soiled and contaminated materials was overwhelming its processing facilities and creating yet another environmental problem for the country, this time not even of its own making.

Prior to China’s ban, 95% of the plastics collected for recycling in the European Union and 70% in the U.S. were sold and shipped to Chinese processors.  A combination of favorable rates for shipping in cargo vessels that carried Chinese goods abroad and low Chinese labor rates made it a very profitable enterprise.

Before China’s ban, only 9% of globally discarded plastics were being recycled and 12% were burned.  The rest ended up in landfills or simply dumped into the environment.  Over the coming decade, as many as 11 million tons of plastic will have to find a new place to be processed or otherwise disposed of.  There is already evidence that plastic waste is accumulating in countries that are dependent on exporting.  In many places, including a number of American cities, there are curtailed collections and new restrictions on what kinds of plastics are accepted.

Some experts are hopeful that China’s ban might actually have an upside if it leads to better solutions for managing the world’s waste.  North America and Europe need to expand processing capabilities and manufacturers need to make their products more easily recyclable.  Mostly, the Chinese ban should be a wake-up call to the world on the need to greatly reduce single-use plastics.

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Piling Up: How China’s Ban on Importing Waste Has Stalled Global Recycling

Photo, posted August 8, 2017, courtesy of Sino-German Urbanisation Partnership via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Designing Plastic To Fall Apart

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In the 1940s and 1950s, synthetic polymers became very popular.  These man-made materials were designed to be cheap and durable and soon began replacing metals and glass in everything from automobiles and airplanes to bottles and dishes.

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Greening Halloween

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According to the National Retail Federation, 179 million Americans are expected to spend $9.1 billion – or nearly $84 per person – on Halloween festivities this year, reaching a new record high.  But it’s not just our wallets that take a beating.  The planet also pays quite a price. 

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A Ton Of Plastic Per Person

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A study by the American Association for the Advancement of Science has produced an estimate of the total amount of plastic manufactured worldwide since the 1950s.  The researchers then measured that data against statistics on recycling, incineration and discard rates.  The results are sobering.

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Wasting Less Food

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We have talked about the problem of food waste before.  About 40% of the food produced in the United States goes to waste, which is a truly shameful statistic.  According to a Business for Social Responsibility study on the subject, about 44% of the food that goes into landfills comes from homes.  About a third comes from the food service industry.

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Worms That Eat Plastic

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Plastics clogging up our landfills and polluting our oceans are a scourge of modern life and we struggle with ways to combat this growing problem.  The biggest issue is that most plastics are simply not biodegradable.   Polyethylene, the common plastic found in shopping bags and numerous other products, takes between 100 and 400 years to degrade in a landfill.

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Renewable Energy Projects In The Northeast

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The seven northeastern U.S. states that make up the Regional Greenhouse Gas Initiative have all set ambitious emissions reduction goals and renewable energy targets that will be difficult to meet.   For example, New York has the goal of getting 50% of its electricity from renewable sources by the year 2030.

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Greening Vacations

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According to the United Nations World Tourism Organization, more than one billion international tourists travel the world each year.  Tourism has become a powerful and transformative force for many millions of people.  But all this travel is not as positive for the planet.  To that end, the luxury travel network Virtuoso assembled a short, simple list everyone can follow to reduce the environmental impact of their travel. 

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The Methane Riddle

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Most of the blame for climate change has been placed on the growing levels of carbon dioxide in the atmosphere, but methane also plays a major role.  Estimates are that about 1/5 of greenhouse effect warming is caused by methane in the atmosphere.  There is far less of it than carbon dioxide, but methane is tremendously more effective at trapping heat.

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Too Much Waste

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As the world’s population grows and becomes more urban and affluent, the amount of solid waste we produce grows and grows.  Over the past century, the total amount has risen tenfold.  By 2025, the world-wide total is expected to double again. The average person in the United States throws away their body weight in garbage every month. 

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