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You are here: Home / Archives for landfills

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Upcycling Plastic Waste | Earth Wise

August 23, 2023 By EarthWise Leave a Comment

People have generated 8 billion tons of plastic waste over time and less than 10% of it has been recycled.  Millions of tons of it escapes into the oceans.  Plastic piles up virtually everywhere on earth.

There are many approaches to dealing with the plastic waste problem and no one of them is a magic bullet.  Engineers at Stanford University have investigated the prospects for upcycling plastic waste for use in infrastructure like buildings and roads.

They used a mix of computer modeling, scientific research, experimental and field data to analyze the potential for using plastic waste in infrastructure.

Among their findings is that recycled glass fiber reinforced polymer composite – which is a tensile plastic commonly used in car, boat, and plane parts – is a promising material for reuse in buildings. 

Roads in which waste plastic is melted down and mixed with conventional paving materials are becoming more common around the world.  India has installed over 60,000 miles of these roads.  Studies show that roads containing waste plastic have the potential to perform better than conventional roads.  They can last longer, are more durable, can tolerate wide temperature swings, and are more resistant to water damage, cracking, and potholes.  Such roads rely less upon virgin fossil resources, which is obviously advantageous.

Upcycling plastic waste in infrastructure is attracting increasing interest because it creates value from something that is strictly a liability and may end up having regulatory advantages as societies move toward more environmentally friendly and sustainable policies.

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Can we use plastic waste to build roads, buildings, and more?

Photo, posted October 7, 2022, courtesy of the Grand Canyon National Park via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Methane Emissions And The Paris Agreement | Earth Wise

August 21, 2023 By EarthWise Leave a Comment

The Paris Agreement is a legally binding international treaty on climate change adopted at the UN Climate Change Conference in 2015.  Its goal is to strengthen the global response to climate change by committing to limit the rise in global average temperature to well below 2°C above pre-industrial levels, and pursue efforts to limit that increase to just 1.5°C. 

Achieving the goals of the Paris Agreement requires reaching net-zero carbon dioxide emissions by or around 2050, as well as deep reductions in methane and other emissions. 

According to a new study by researchers from Simon Fraser University in Canada, reductions in methane emissions are needed urgently  if we are to meet the goals of the Paris Agreement.  The study, which was recently published in the journal Nature’s Communications Earth & Environment, suggests that global warming levels could be kept below 2°C if methane mitigation efforts are initiated globally before 2030.  However, delaying methane mitigation to the year 2040 or beyond would increase the risk of exceeding 2°C, even if net-zero carbon dioxide emissions were achieved.

Methane is a potent greenhouse gas, second only to carbon dioxide in contributing to global temperature increases over the last two centuries.  However, methane is known to warm the planet 86 times more effectively than carbon dioxide over a 20-year period.

During the past 40 years, more than 60% of global methane emissions have been produced as a result of human activities, such as fossil fuel exploitation, livestock production, and waste from landfills.

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Delaying methane mitigation increases risk of breaching Paris Agreement climate goal, study finds

Photo, posted July 22, 2011, courtesy of Steven W. via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Energy From Fruit Waste | Earth Wise

June 20, 2023 By EarthWise Leave a Comment

In the Back to the Future films, Doc Brown ran his DeLorean time machine on food scraps.  It was a fun bit of science fiction.  But researchers at the University of British Columbia Okanagan in Canada are investigating the potential for using food waste to generate power.

Food waste is not a candidate to replace solar or wind power, but it could be a source of energy for powering fuel cells.  As it is, food waste represents a sustainability challenge because of its detrimental impacts on the economy and the environment.  Organic waste represents a significant fraction of the material in landfills and contributes to methane production, air pollution, and other harmful pollutants.

The UBC researchers focused on fruit waste, which is abundantly available in agricultural regions.  They have devised microbial fuel cells that convert fruit waste into electrical energy using an anaerobic anode compartment.  That is a chamber in which anaerobic microbes – ones that don’t need oxygen – utilize the organic matter to convert it into energy.  The microbes consume the fruit waste and produce water while generating bioelectricity.

It is not like the Back to the Future time machine where you can just toss in scraps of whatever is on hand.  Different types of fruits provide different results when used in the microbial fuel cell. The process works best when the food waste is separated and ground into small particles.  There is a long way to go before the technology could produce bioenergy on a commercial scale, but there is considerable potential for doing something useful with something that is currently worthless.

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UBCO researchers aim to energize fruit waste

Photo, posted July 24, 2011, courtesy of Andrew Girdwood via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Methane And Wildfires | Earth Wise

May 29, 2023 By EarthWise Leave a Comment

Wildfires release a massive amount of methane

Methane is a colorless and odorless gas that occurs abundantly in nature and is also a product of certain human activities.  It’s also a potent greenhouse gas, meaning it affects climate change by contributing to increased warming.  In fact, methane gas is known to warm the planet 86 times more effectively than carbon dioxide over a 20-year period.

According to the U.S. EPA, up to 65% of total methane emissions around the world come from the following human activities: raising livestock, leaks from natural gas systems, and waste from landfills. 

Scientists from the University of California, Riverside have discovered that wildfires are releasing a massive amount of methane gas into the atmosphere.  According to the research team, this source of methane is not currently being tracked by air quality managers in California.  And this omission could have significant implications for climate change mitigation efforts in the state. 

Methane from wildfires is nothing new.  But what is new is just how much of the stuff is being emitted.  According to the findings, which were recently detailed in the journal Atmospheric Chemistry and Physics, the amount of methane from the top 20 fires in 2020 was more than seven times greater than the average from wildfires in the previous 19 years.  Wildfires were the third largest source of methane emissions in California in 2020. 

In 2016, California passed a law requiring a 40% reduction in air pollutants contributing to global warming by 2030.  But as wildfires continue to get bigger and more intense, achieving those reduction targets will get increasingly difficult.

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Methane from megafires: more spew than we knew

Detecting Methane

Photo, posted November 30, 2015, courtesy of Daria Devyatkina via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Plastic Eating Fungus | Earth Wise

May 26, 2023 By EarthWise Leave a Comment

Researchers exploring the use of fungi to break down plastic

More than five billion tons of plastic have accumulated on land and sea including the most remote regions of the planet as well as in the bodies of animals and humans.  There is a compelling need to recycle as much plastic as possible but doing so is a major challenge. Plastic comes in many varieties and breaking it down for reuse requires different methods for each.

Polypropylene is one of the biggest challenges for recycling.  It is a very common plastic used for all sorts of products including food containers, coat hangers, plastic wrap, toys, and much more. It accounts for roughly 28% of the world’s plastic waste, but only 1% of it is recycled.

Polypropylene is seldom recycled because it generally has a short life as a packaging material, and it often becomes contaminated by other materials and plastics.  Thus, it generally ends up in landfills.

Researchers at the University of Sydney in Australia have discovered that two common strains of fungi were able to successfully biodegrade polypropylene.  The fungi species – with unavoidable Latin names of Aspergillus terreus and Engyodontium album – are typically found in soil and plants.

The researchers found that the fungi were able to break down polypropylene after it had been pre-treated with either UV light or heat, by 21% over 30 days, and by 25-27% over 90 days.  This seems rather slow but compared with the nearly endless life of polypropylene in landfills, it is a major improvement.

The hope is that methods like this could ultimately reduce the amount of plastic polluting the environment by encouraging plastic to biodegrade naturally under the appropriate conditions.

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Fungi makes meal of hard to recycle plastic

Photo, posted March 5, 2010, courtesy of Kevin Krejci via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Getting Rid Of Hydrogen Sulfide | Earth Wise

December 20, 2022 By EarthWise Leave a Comment

Hydrogen sulfide gas produces the characteristic smell of rotten eggs, sewers, stockyards, and landfills.  The petroleum industry produces thousands of tons of the stuff each year as a byproduct of the processes that remove sulfur from petroleum, natural gas, coal, and other products.  The industry faces substantial fines for emitting hydrogen sulfide, but remediation is expensive.

Researchers at Rice University have developed a method for turning hydrogen sulfide into hydrogen gas and sulfur in a single step.  Called plasmonic photocatalysis, it not only gets rid of an undesirable substance, it does so by producing valuable byproducts.

The established way of getting rid of hydrogen sulfide is called the Claus process.  It requires multiple steps, including some that require combustion chambers heated to 1,500 degrees Fahrenheit.  The end product is sulfur and water.

The Rice University process gets all of its energy from light.  A surface of grains of silicon dioxide is dotted with tiny gold nanoparticles.  These particles interact strongly with a specific wavelength of visible light and cause plasmonic reactions that create short-lived, high-energy electrons that drive the catalysis of hydrogen sulfide.  Given that the process requires only visible light and no external heating, it should be relatively straightforward to scale up using solar energy or very efficient LED lamps.

The new hydrogen sulfide remediation technology has been licensed by a Houston-based startup company with more than 60 employees whose founders include some of the Rice researchers.  The process may end up being efficient enough and cheap enough for cleaning up non-industrial sources of hydrogen sulfide such as sewers and animal waste.

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New catalyst can turn smelly hydrogen sulfide into a cash cow

Photo, posted July 8, 2021, courtesy of Doug Letterman via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fuel From Coffee Grounds | Earth Wise

December 8, 2022 By EarthWise Leave a Comment

Creating fuel from coffee waste

The world drinks a lot of coffee.  Americans alone consume 400 million cups a day.  Each cup of coffee results in about half an ounce of coffee grounds.  Adding that up, this country produces over 6,000 tons of coffee grounds each day.  While coffee grounds are not particularly harmful, that is an awful lot of waste that mostly ends up in landfills or is incinerated.

Researchers at Aston University in the UK have developed a method of producing high-quality biodiesel fuel from coffee grounds.  Their study was published in the journal Renewable and Sustainable Energy Reviews.

The technique consists of growing a particular species of microalgae (Chlorella vulgaris) directly on spent coffee grounds.  The coffee grounds provide both the nutrients for the microalgae and a structure upon which it can grow.   Exposing the algae to light for 20 hours a day and dark for just four hours a day produced the best quality biodiesel.

Microalgae is well-known as a feedstock for biodiesel production.  Previously, it has been grown on materials like polyurethane foam or nylon which don’t provide any nutrients.   Using the coffee grounds as the substrate for growth means that no external nutrients are needed.

The resultant enhanced biodiesel produces minimal emissions and good engine performance and meets both US and European specifications.  This feedstock for producing biodiesel is ideal since it doesn’t require any competition with food crops and instead makes use of a widely available waste product.  The hope is that it may reduce the cutting down of palm trees to extract oil for biofuel.  In southeast Asia, this has been a major source of deforestation and increased greenhouse gas emissions.

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Aston University researchers ‘feed’ leftover coffee grounds to microalgae to produce low emission biodiesel

Photo, posted October 13, 2007, courtesy of David Joyce via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Plastic Into Protein | Earth Wise

November 18, 2022 By EarthWise Leave a Comment

Turning plastic waste into food

Our planet is choking on plastic.  According to the United Nations, 79% of the 6.3 billion tons of plastic produced every year accumulates in landfills.  Half of all plastic produced is actually designed to be used just once and thrown away.  But plastic is not only accumulating on land.  In fact, the world’s oceans are projected to contain more plastic by weight than fish by the year 2050.     

According to new research, solving the plastic waste issue could help address another prominent global issue: hunger.  A multidisciplinary team of engineers, chemists, and biologists led by researchers from Michigan Tech University has developed a process to break plastics down to be recycled into useful products, including edible protein powder.

The research team’s process converts plastic into compounds using heat and a reactor that deconstructs the material’s polymer chains. The oil-like substance is then fed to a community of oil-eating bacteria.  The bacteria grow rapidly on the oily diet, producing more bacterial cells composed of roughly 55% protein.  This majority-protein byproduct is then dried out and turned into an edible powder.   The end result doesn’t look like plastic at all.  In fact, it resembles a yeast byproduct that comes from brewing beer. 

This research is funded by an award from the US Department of Defense.  The DoD often deploys soldiers in areas where access to food is challenging.  Converting plastic to protein could be part of a solution to that problem. 

While eating something that began as plastic might take some getting used to, it could be part of the solution to both plastic pollution and global hunger.

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Turning Trash Into Treasure: The Plastic to Protein Powder Solution

Beat Plastic Pollution

Photo, posted February 2, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Greening Halloween | Earth Wise

October 26, 2022 By EarthWise Leave a Comment

According to the National Retail Federation, Halloween participation is expected to return to pre-pandemic levels this year.  Spending on Halloween festivities by the 69% of Americans who celebrate is expected to add up to $10.6 billion in 2022 – or more than $100 per person – reaching a new record high. 

Halloween generates a mind-boggling amount of waste.  Picture all the flimsy single-use costumes, plastic candy wrappers, mass-produced decorations, and so on.  Here are some tricks to treat you to a greener holiday.

Our first trick is to invest in quality costumes.  Mass-produced (and often single use) costumes leave the largest carbon footprint from Halloween.  They are often made from unsustainable materials, manufactured in countries with poor labor standards, and too many end up in landfills by mid-November. By renting, thrifting, swapping, or making your own costumes, many of the negative impacts of dressing up for the holiday can be avoided.

Our second trick is to invest in environmentally-friendly decorations and supplies.  For example, carve local pumpkins and save the seeds and flesh to eat later.  Make your own spooky decorations.  If you do buy decorations, ensure that they are durable and reusable.  And use a wicker basket, old bag, or pillowcase to trick-or-treat.

Our third trick is to pass out organic and fair trade candy.  Some of the largest candy manufacturers are major drivers of deforestation and species extinction around the globe due to their demand for sugar, palm oil, and cocoa beans.

If you’ve already spent your $100 this year, consider these changes for next year.  It’s never too late to become a superhero.

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Retail Holiday and Seasonal Trends: Halloween

Photo, posted October 14, 2007, courtesy of Brian via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon Storage In Harvested Wood | Earth Wise

September 26, 2022 By EarthWise Leave a Comment

Carbon storage in harvested wood

Trees are an exceedingly important carbon sink on our planet.  For this reason, deforestation is a major contributor to climate change.  But when trees are harvested for wood products like lumber, much of the carbon in that wood continues to be stored.  Even when a wood product is discarded at the end of its useful life, it can keep storing carbon.

Over 90% of new single-family homes in the U.S. are built with wood.  Each year, about 400,000 homes, apartment buildings, and other housing units are lost to floods and other natural disasters.  Others fall apart from decay or are torn down to be replaced with newer structures.  Given how much carbon is stored in houses, it is important to understand what the future trajectory of residential structures will be.

A new study by the USDA Forest Service published in the journal PLOS ONE looks at the future of harvested wood products in residential structures.  According to the study, wood products in these structures will continue to increase the country’s carbon storage for the next 50 years. 

Even after residential structures reach the end of their useful life and much of the materials end up in landfills (which is typical in this country), the wood products do not immediately release their carbon.  It may take decades for that to happen.

The study looked at various scenarios for future home construction.  Although housing starts are projected to decline in the future, residential housing and the need to maintain existing structures are projected to continue to increase carbon storage in wood products for the next several decades.

The role of trees as a carbon sink does not end when they are harvested for their wood.

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Carbon Storage in Harvested Wood Products

Photo, posted January 27, 2022, courtesy of Luke McKernan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Who Can Solve The Plastic Waste Problem? | Earth Wise

June 21, 2022 By EarthWise Leave a Comment

Plastic packaging waste is a global problem.  It collects in the oceans, breaks down into microplastics, which are consumed by fish and in turn by people who eat the fish.  Only 14.5% of U.S. plastic waste is recycled.  Most of it ends up in landfills, where is remains undegraded for hundreds of years. 

A new international study explored the global patterns of plastic packaging waste.  The study found that three countries – the U.S., Brazil, and China – are the top suppliers of waste.  In terms of supply, the Americas generate 41% of the world’s production of plastic waste, Europe 24%, and Asia 21%.

That’s the plastics supply.  As far as the consumers actually creating waste are concerned, the Americas represent 36% of the world’s packaging consumption, Asia 26%, and Europe 23%.

Packaging high-protein food such as meat, fish, and dairy is a major contributor to the waste problem.  Plastic for this purpose is hard to replace and international exports exacerbate the problem, accounting for about 25% of plastic packaging waste.

International agreements typically focus on restrictions and fees on production.  But that mostly creates strong incentives to simply relocate polluting activities to developing countries, which is a zero-sum game.  There need to be incentives for consumers to reduce plastic use such as taxes on waste management, refunds on returning bottles, single-use plastic bans, and so on.

Who can solve the plastic waste problem?  Everyone along the supply chain as well as the final consumers have to be part of the solution for reducing plastic waste.

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Producers and consumers must share burden of global plastic packaging waste

Photo, posted March 29, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Recycling Shingles | Earth Wise

May 27, 2022 By EarthWise Leave a Comment

A process to recycle asphalt shingles

Every year in the US, about 13 million tons of asphalt material is removed from old roofs to be replaced with new shingles.  Only about 10% of that is recycled for use in paving and various roadway projects.  The other 12 million tons of asphalt ends up in landfills where it takes a very long time to break down.

GAF, the largest roofing manufacturer in North America, has developed a shingle recycling process for which it has received three patents.  The process involves grinding torn-off shingles into a refined material which can then be introduced into the shingle manufacturing process.  The material – referred to as RAS for recycled asphalt shingles – has the potential to significantly reduce the amount of virgin asphalt needed to make new shingles.

Tests by GAF reclaimed upwards of 90% of the waste shingle material and produced new shingles containing up to 15% recycled content.  Underwriters Laboratories certified the shingles containing RAS material with regard to their safety and effectiveness.  The GAF process opens to door to creating a circular, sustainable economy for asphalt used for roofing shingles.

Roofs play an important role in the transition to a green economy.  Apart from recycling asphalt shingles, there are increasing options for solar shingles, which take the place of both traditional asphalt shingles and ordinary solar panels by integrating them into a single roofing product.  There are also so-called green roofs, which replace conventional roofing materials with a contained green space atop a building. Such roofs provide stormwater management, cooling, and an interesting aesthetic.

All aspects of buildings play important roles in our environment – even their roofs.

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5 Ways Roofers Can Celebrate Earth Day, Everyday

Photo, posted April 15, 2012, courtesy of Robert Taylor via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Capturing Methane To Feed Fish | Earth Wise

December 30, 2021 By EarthWise Leave a Comment

Using captured methane as food for fish

Methane in the atmosphere is an extremely potent greenhouse gas.  Its warming potential is about 85 times that of carbon dioxide over a 20-year period.  It also worsens air quality by increasing atmospheric ozone.  Many human activities add methane to the atmosphere, notably emissions from landfills and oil and gas facilities.

Capturing methane from these sources for subsequent use is currently uneconomical but new research from Stanford University analyzes the market for using the methane to feed bacteria to produce fishmeal.

Methane-consuming bacteria called methanotrophs can be grown in chilled, water-filled bioreactors containing pressurized methane, oxygen, and nutrients.  The bacteria produce a protein-rich biomass that can be used as fishmeal in aquaculture.  This could offset demand for fishmeal made from small fish or plant-based feeds that require land, water, and fertilizer.

Some companies already do this using natural gas provided by utility pipelines, but it would be far better for the environment to use methane emitted at large landfills, wastewater treatment plants, and oil and gas facilities.

Consumption of seafood has more than quadrupled since 1960, depleting wild fish stocks.  Farmed fish now provide half of all the animal-sourced seafood we eat.

The Stanford research analyzed the cost of methanotrophic fishmeal production under various scenarios and found it to be very competitive with and in some cases considerably cheaper than current market prices for fishmeal. 

According to the study, this process could profitably supply total global demand for fishmeal with methane captured in the U.S. alone.

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Stanford researchers reveal how to turn a global warming liability into a profitable food security solution

Photo, posted April 30, 2017, courtesy of Artur Rydzewski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Nanoplastics In The Air | Earth Wise

December 17, 2021 By EarthWise Leave a Comment

Austria, Silvretta mountains

The world is awash in plastic.  Discarded plastic litters our roadways, woodlands, and beaches.  It piles up in landfills.  Plastic enters the oceans by the millions of tons.  And plastic is finding its way even to remote and supposedly pristine parts of the world.

A team of researchers has found nanoplastics at the isolated high-altitude Sonnblick Observatory in the Austrian Alps.  This is the first time the particles were found in the area.  The researchers were looking for certain organic particles and only found the nanoplastics by chance.

The detected plastic particles were less than 200 nanometers in size, about one hundredth the width of a human hair.  It is highly unlikely that such particles originated in remote Alpine areas.

The researchers were looking for organic particles by taking samples of snow or ice, evaporating them, and then burning the residue to detect and analyze the vapors.  They described the detection method as essentially like a mechanical nose.  In this case, the nose smelled burning plastics in the form of polypropylene and polyethylene terephthalate.

Looking into the issue, the researchers found a strong correlation between high concentrations of nanoplastics and winds coming from the direction of major European cities – especially Frankfurt and the industrial Ruhr area of Germany, but also the Netherlands, Paris, and even London.

Modeling supports the idea that nanoplastics are transported by air from distant urban places.  This is particularly worrisome because it means that there are likely hotspots of nanoplastics in our cities and in the air that we are breathing.  Plastics appear to be everywhere.

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Nanoplastics found in the Alps, transported by air from Frankfurt, Paris and London

Photo, posted July 1, 2013, courtesy of Robert J. Heath via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Infinitely Recyclable Plastic | Earth Wise

May 25, 2021 By EarthWise 1 Comment

Making an infinitely recyclable plastic

The glut of plastics is one of the world’s most challenging environmental problems.  The average American generates over 200 pounds of plastic waste each year and most of that ends up in landfills.  Researchers around the globe continue to work on potential solutions to the plastic waste problem.

Two years ago, scientists at Lawrence Berkeley National Laboratory announced the invention of a new plastic that could be an answer to the plastic waste problem.  The material is called polydiketoenamine or PDK and it differs from traditional plastics in a very important way:  it can be recycled indefinitely with no loss in quality because it can easily be broken down into its constituent component monomers and be used to make brand new plastic.

Only a small percentage of plastics are currently recycled.  When many plastics are melted down together, the polymers are mixed with a slew of incompatible additives, resulting in a new material with much lower quality than newly produced plastic.  As a result, less than 10% of plastic is recycled more than once.

Recently, the Berkeley Lab researchers released a study that shows what could be accomplished if manufacturers began using PDKs on a large scale.  They determined that PDK-based plastic could quickly become commercially competitive with conventional plastics and, furthermore, would get less expensive and more sustainable as time goes on.

PDK is starting to draw interest from companies needing to source plastic.  The best initial application for PDKs are markets where manufacturers have the most access to products at the end of their lifespans such as in the automobile industry and consumer electronics.  Making plastics part of a circular economy is a challenging task.

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The Future Looks Bright for Infinitely Recyclable Plastic

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Polystyrene | Earth Wise

April 20, 2021 By EarthWise Leave a Comment

Scientists have developed a way to break down polystyrene

The proliferation of global plastic waste continues to be a growing problem for the world.  Hundreds of millions of tons of plastics are produced each year and most of it is used once and then discarded.  The properties that make plastics so attractive – durability and chemical stability – make it difficult to do anything with discarded plastics other than deposit them in landfills – where they don’t easily degrade over time – or burn them, which dumps carbon dioxide and various hazardous gases into the atmosphere.

Polystyrene is one of the most widely used plastics.  It is found in foam packaging materials, disposable food containers, plastic cutlery, storage containers, and many other places. 

Recycling plastics like polystyrene is generally not economically feasible.  Sorting plastics by type is time and labor intensive and the chemical processes required to break down plastics into usable precursor materials require significant energy input and the use of toxic solvents.

Recently, a team of scientists at Ames Laboratory in Iowa has developed a process based on ball-milling that deconstructs commercial polystyrene in a single step, at room temperature, in ambient atmosphere, and in the absence of harmful solvents.

Ball-milling is a technique that places materials in a milling vial with metal ball bearings which is then agitated to initiate a chemical reaction.  This approach is known as mechanochemistry.

The method represents an important breakthrough that enables dismantling of a polymer that includes its chemical breakdown without requiring solvents or the high temperatures generally needed to thermally decompose it.  This discovery opens up new avenues for low-temperature recovery of monomers from polymer-based systems that include composites and laminates.  It could be a very useful weapon in the battle against plastic waste.

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Polystyrene waste is everywhere, and it’s not biodegradable. Scientists just found a way to break it down.

Photo, posted December 11, 2010, courtesy of Warrenski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Paving With Plastic | Earth Wise

March 25, 2021 By EarthWise Leave a Comment

Using plastic waste as pavement

The country of Ghana has an ambitious plan to recycle and reuse as much plastic waste as it produces each year (which is over a million tons) by 2030.  As part of this plan, they have started to pave roads in Accra, the capital city, with asphalt containing a slurry of used plastics – shredded and melted bags, bottles, and snack wraps.  Only a quarter of Ghana’s roads are currently paved, so waste plastic has many opportunities for use in paving.

Plastic roads first appeared in India two decades ago.  There are now over 60,000 miles of them in that country.  Several countries have only recently built their first plastic roads including South Africa, Vietnam, Mexico, the Philippines, and the United States.

Studies have shown that roads containing waste plastic have the potential to perform as well or better than traditional roads.  They can last longer, can tolerate wide temperature swings better, are stronger and more durable, and are more resistant to water damage, cracking, and potholes.

Ordinarily, asphalt for roads consists of 90 to 95% aggregate – typically some mixture of gravel, sand, and limestone – and 5 to 10% bitumen, which is a black gooey substance extracted from crude oil that binds the aggregate together.  Plastic-enhanced roads replace varying amounts of the bitumen (often as little as 4-10%, but sometimes much more), with plastic that is actually a stronger binding agent.

Plastic roads reduce the amount of bitumen in roads, thereby reducing carbon emissions.  The plastics are not heated enough to release gases and the roads do not appear to shed microplastics.  Plastic roads will not solve the world’s plastic waste problem, but they can help by diverting lots of plastic from landfills.

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How Paving with Plastic Could Make a Dent in the Global Waste Problem

Photo, posted June 4, 2010, courtesy of Sustainable Initiatives Fund Trust via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Compost And Landfills | Earth Wise

January 19, 2021 By EarthWise Leave a Comment

the importance of landscaping

Composting is popular as a way to keep solid waste out of landfills and many people turn much of their kitchen waste into rich soil amendments.   Cities and towns across the country have composting programs that collect waste from residents to produce large quantities of compost rather than adding the waste to landfills.  A new study from North Carolina State University looked into the environmental benefits of actually using compost at landfills.

Most municipal composting programs require that the compost they produce gets used “beneficially”.  The new research shows that using compost as an alternative daily cover at landfills is competitive and often superior to the use of compost as a soil amendment in terms of its environmental benefits.

Landfills apply a layer of daily cover to reduce odors, reduce windblown debris, and keep vermin out of landfill waste.  Federal regulations require six inches of soil as a daily cover.

Compost from food waste in particular is not always suitable for soil amendment in gardens and agricultural fields because it often contains broken glass and other contaminants.

The North Carolina State study looked at the environmental impact of using compost as daily cover in landfills compared with its use as a soil amendment.  They looked at global warming potential, acidification potential, eutrophication (which is the amount of nutrients released to ground and surface water), cumulative energy demand, and the depletion of resources.

The study concluded that using compost as landfill daily cover is environmentally superior with regard to eutrophication, acidification, and global warming potential.  On the other hand, soil amendment was better in terms of resource depletion and cumulative energy demand.

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Applying Compost to Landfills Could Have Environmental Benefits

Photo, posted April 22, 2008, courtesy of Alachua County via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Electronic Waste On The Decline | Earth Wise

January 6, 2021 By EarthWise Leave a Comment

Electronic waste is declining

A new study published in the Journal of Industrial Ecology has found that the total mass of electronic waste generated by Americans has been declining since 2015.  Given that electronic devices are playing an ever-growing role in our lives, this finding seems rather surprising.  It also seems like pretty good news, but the underlying facts should dampen our level of enthusiasm.

The main reason for the decline is the disappearance of large, bulky cathode-ray tube televisions and computer monitors.  Since about 10 years ago, CRT displays have been on the decline in the waste stream, thereby leading to an overall decline in total e-waste mass.

Many state regulations with respect to e-waste recycling have targets based on product mass.  The regulations were typically designed to keep electronics with high levels of lead and mercury out of landfills.

At present, the more pertinent concern is how to recover valuable elements like cobalt (from lithium-ion batteries) and indium (from flat-panel displays).  These elements are not so environmentally toxic, but rather are relatively scarce in the earth’s crust. 

The main conclusion to be drawn from the declining mass of electronic waste is not that we are necessarily winning the battle against generating it but rather that e-waste is changing and regulations concerning it need to be rethought.  Focusing regulations on capturing critical elements not only would have significant economic benefits but also would be important in addressing geopolitical uncertainties that potentially could threaten what could be termed the mineral security of the U.S.

E-waste recycling is regulated at the state level and only half the states have e-waste recycling laws.  It may be time for more uniform policies across the country.

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Electronic Waste on the Decline, New Study Finds

Photo, posted January 22, 2013, courtesy of Thorsten Hartmann via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Getting Value From Plastic Waste | Earth Wise

November 30, 2020 By EarthWise Leave a Comment

Extracting value from plastic waste

To date, the world has produced more than five billion tons of plastic and is making more all the time.  Based on the way things are currently done, most of that will end up in landfills or in the natural environment.  By 2050, the amount of plastic is expected to exceed 13 billion tons.   This is one of the world’s biggest environmental problems.

Recently, an international collaboration by universities and institutions in the UK, China, and Saudi Arabia has developed a method of converting plastic waste into hydrogen gas and high-value solid carbon.

The technique was achieved with a new type of catalysis that uses microwaves to activate catalyst particles that effectively strip hydrogen from plastic polymers.  The work was recently published in the journal Nature Catalysis and details how the researchers mixed mechanically pulverized plastic particles with a microwave-susceptor catalyst of iron oxide and aluminum oxide.  That mixture was then subjected to microwave treatment and yielded a large volume of hydrogen gas and a residue of carbonaceous material, most of which was identified as carbon nanotubes.

The process is more rapid than most methods for dealing with plastic waste and can extract over 97% of the hydrogen in plastic without producing any carbon dioxide emissions. 

The new method represents an attractive potential solution to the problem of plastic waste.  Instead of polluting the planet, plastics could become a valuable feedstock for producing clean hydrogen fuel as well as valuable carbon materials.  Proponents of the so-called hydrogen economy have continued to seek a green and economical way to produce hydrogen.  This new work might be just what they are looking for.

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Turning plastic waste into hydrogen and high-value carbons

Photo, posted April 21, 2007, courtesy of Redwin Law via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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