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Getting Rid Of Hydrogen Sulfide | Earth Wise

December 20, 2022 By EarthWise Leave a Comment

Hydrogen sulfide gas produces the characteristic smell of rotten eggs, sewers, stockyards, and landfills.  The petroleum industry produces thousands of tons of the stuff each year as a byproduct of the processes that remove sulfur from petroleum, natural gas, coal, and other products.  The industry faces substantial fines for emitting hydrogen sulfide, but remediation is expensive.

Researchers at Rice University have developed a method for turning hydrogen sulfide into hydrogen gas and sulfur in a single step.  Called plasmonic photocatalysis, it not only gets rid of an undesirable substance, it does so by producing valuable byproducts.

The established way of getting rid of hydrogen sulfide is called the Claus process.  It requires multiple steps, including some that require combustion chambers heated to 1,500 degrees Fahrenheit.  The end product is sulfur and water.

The Rice University process gets all of its energy from light.  A surface of grains of silicon dioxide is dotted with tiny gold nanoparticles.  These particles interact strongly with a specific wavelength of visible light and cause plasmonic reactions that create short-lived, high-energy electrons that drive the catalysis of hydrogen sulfide.  Given that the process requires only visible light and no external heating, it should be relatively straightforward to scale up using solar energy or very efficient LED lamps.

The new hydrogen sulfide remediation technology has been licensed by a Houston-based startup company with more than 60 employees whose founders include some of the Rice researchers.  The process may end up being efficient enough and cheap enough for cleaning up non-industrial sources of hydrogen sulfide such as sewers and animal waste.

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New catalyst can turn smelly hydrogen sulfide into a cash cow

Photo, posted July 8, 2021, courtesy of Doug Letterman via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Fuel From Coffee Grounds | Earth Wise

December 8, 2022 By EarthWise Leave a Comment

Creating fuel from coffee waste

The world drinks a lot of coffee.  Americans alone consume 400 million cups a day.  Each cup of coffee results in about half an ounce of coffee grounds.  Adding that up, this country produces over 6,000 tons of coffee grounds each day.  While coffee grounds are not particularly harmful, that is an awful lot of waste that mostly ends up in landfills or is incinerated.

Researchers at Aston University in the UK have developed a method of producing high-quality biodiesel fuel from coffee grounds.  Their study was published in the journal Renewable and Sustainable Energy Reviews.

The technique consists of growing a particular species of microalgae (Chlorella vulgaris) directly on spent coffee grounds.  The coffee grounds provide both the nutrients for the microalgae and a structure upon which it can grow.   Exposing the algae to light for 20 hours a day and dark for just four hours a day produced the best quality biodiesel.

Microalgae is well-known as a feedstock for biodiesel production.  Previously, it has been grown on materials like polyurethane foam or nylon which don’t provide any nutrients.   Using the coffee grounds as the substrate for growth means that no external nutrients are needed.

The resultant enhanced biodiesel produces minimal emissions and good engine performance and meets both US and European specifications.  This feedstock for producing biodiesel is ideal since it doesn’t require any competition with food crops and instead makes use of a widely available waste product.  The hope is that it may reduce the cutting down of palm trees to extract oil for biofuel.  In southeast Asia, this has been a major source of deforestation and increased greenhouse gas emissions.

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Aston University researchers ‘feed’ leftover coffee grounds to microalgae to produce low emission biodiesel

Photo, posted October 13, 2007, courtesy of David Joyce via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Turning Plastic Into Protein | Earth Wise

November 18, 2022 By EarthWise Leave a Comment

Turning plastic waste into food

Our planet is choking on plastic.  According to the United Nations, 79% of the 6.3 billion tons of plastic produced every year accumulates in landfills.  Half of all plastic produced is actually designed to be used just once and thrown away.  But plastic is not only accumulating on land.  In fact, the world’s oceans are projected to contain more plastic by weight than fish by the year 2050.     

According to new research, solving the plastic waste issue could help address another prominent global issue: hunger.  A multidisciplinary team of engineers, chemists, and biologists led by researchers from Michigan Tech University has developed a process to break plastics down to be recycled into useful products, including edible protein powder.

The research team’s process converts plastic into compounds using heat and a reactor that deconstructs the material’s polymer chains. The oil-like substance is then fed to a community of oil-eating bacteria.  The bacteria grow rapidly on the oily diet, producing more bacterial cells composed of roughly 55% protein.  This majority-protein byproduct is then dried out and turned into an edible powder.   The end result doesn’t look like plastic at all.  In fact, it resembles a yeast byproduct that comes from brewing beer. 

This research is funded by an award from the US Department of Defense.  The DoD often deploys soldiers in areas where access to food is challenging.  Converting plastic to protein could be part of a solution to that problem. 

While eating something that began as plastic might take some getting used to, it could be part of the solution to both plastic pollution and global hunger.

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Turning Trash Into Treasure: The Plastic to Protein Powder Solution

Beat Plastic Pollution

Photo, posted February 2, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Greening Halloween | Earth Wise

October 26, 2022 By EarthWise Leave a Comment

According to the National Retail Federation, Halloween participation is expected to return to pre-pandemic levels this year.  Spending on Halloween festivities by the 69% of Americans who celebrate is expected to add up to $10.6 billion in 2022 – or more than $100 per person – reaching a new record high. 

Halloween generates a mind-boggling amount of waste.  Picture all the flimsy single-use costumes, plastic candy wrappers, mass-produced decorations, and so on.  Here are some tricks to treat you to a greener holiday.

Our first trick is to invest in quality costumes.  Mass-produced (and often single use) costumes leave the largest carbon footprint from Halloween.  They are often made from unsustainable materials, manufactured in countries with poor labor standards, and too many end up in landfills by mid-November. By renting, thrifting, swapping, or making your own costumes, many of the negative impacts of dressing up for the holiday can be avoided.

Our second trick is to invest in environmentally-friendly decorations and supplies.  For example, carve local pumpkins and save the seeds and flesh to eat later.  Make your own spooky decorations.  If you do buy decorations, ensure that they are durable and reusable.  And use a wicker basket, old bag, or pillowcase to trick-or-treat.

Our third trick is to pass out organic and fair trade candy.  Some of the largest candy manufacturers are major drivers of deforestation and species extinction around the globe due to their demand for sugar, palm oil, and cocoa beans.

If you’ve already spent your $100 this year, consider these changes for next year.  It’s never too late to become a superhero.

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Retail Holiday and Seasonal Trends: Halloween

Photo, posted October 14, 2007, courtesy of Brian via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Carbon Storage In Harvested Wood | Earth Wise

September 26, 2022 By EarthWise Leave a Comment

Carbon storage in harvested wood

Trees are an exceedingly important carbon sink on our planet.  For this reason, deforestation is a major contributor to climate change.  But when trees are harvested for wood products like lumber, much of the carbon in that wood continues to be stored.  Even when a wood product is discarded at the end of its useful life, it can keep storing carbon.

Over 90% of new single-family homes in the U.S. are built with wood.  Each year, about 400,000 homes, apartment buildings, and other housing units are lost to floods and other natural disasters.  Others fall apart from decay or are torn down to be replaced with newer structures.  Given how much carbon is stored in houses, it is important to understand what the future trajectory of residential structures will be.

A new study by the USDA Forest Service published in the journal PLOS ONE looks at the future of harvested wood products in residential structures.  According to the study, wood products in these structures will continue to increase the country’s carbon storage for the next 50 years. 

Even after residential structures reach the end of their useful life and much of the materials end up in landfills (which is typical in this country), the wood products do not immediately release their carbon.  It may take decades for that to happen.

The study looked at various scenarios for future home construction.  Although housing starts are projected to decline in the future, residential housing and the need to maintain existing structures are projected to continue to increase carbon storage in wood products for the next several decades.

The role of trees as a carbon sink does not end when they are harvested for their wood.

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Carbon Storage in Harvested Wood Products

Photo, posted January 27, 2022, courtesy of Luke McKernan via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio

Who Can Solve The Plastic Waste Problem? | Earth Wise

June 21, 2022 By EarthWise Leave a Comment

Plastic packaging waste is a global problem.  It collects in the oceans, breaks down into microplastics, which are consumed by fish and in turn by people who eat the fish.  Only 14.5% of U.S. plastic waste is recycled.  Most of it ends up in landfills, where is remains undegraded for hundreds of years. 

A new international study explored the global patterns of plastic packaging waste.  The study found that three countries – the U.S., Brazil, and China – are the top suppliers of waste.  In terms of supply, the Americas generate 41% of the world’s production of plastic waste, Europe 24%, and Asia 21%.

That’s the plastics supply.  As far as the consumers actually creating waste are concerned, the Americas represent 36% of the world’s packaging consumption, Asia 26%, and Europe 23%.

Packaging high-protein food such as meat, fish, and dairy is a major contributor to the waste problem.  Plastic for this purpose is hard to replace and international exports exacerbate the problem, accounting for about 25% of plastic packaging waste.

International agreements typically focus on restrictions and fees on production.  But that mostly creates strong incentives to simply relocate polluting activities to developing countries, which is a zero-sum game.  There need to be incentives for consumers to reduce plastic use such as taxes on waste management, refunds on returning bottles, single-use plastic bans, and so on.

Who can solve the plastic waste problem?  Everyone along the supply chain as well as the final consumers have to be part of the solution for reducing plastic waste.

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Producers and consumers must share burden of global plastic packaging waste

Photo, posted March 29, 2022, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Recycling Shingles | Earth Wise

May 27, 2022 By EarthWise Leave a Comment

A process to recycle asphalt shingles

Every year in the US, about 13 million tons of asphalt material is removed from old roofs to be replaced with new shingles.  Only about 10% of that is recycled for use in paving and various roadway projects.  The other 12 million tons of asphalt ends up in landfills where it takes a very long time to break down.

GAF, the largest roofing manufacturer in North America, has developed a shingle recycling process for which it has received three patents.  The process involves grinding torn-off shingles into a refined material which can then be introduced into the shingle manufacturing process.  The material – referred to as RAS for recycled asphalt shingles – has the potential to significantly reduce the amount of virgin asphalt needed to make new shingles.

Tests by GAF reclaimed upwards of 90% of the waste shingle material and produced new shingles containing up to 15% recycled content.  Underwriters Laboratories certified the shingles containing RAS material with regard to their safety and effectiveness.  The GAF process opens to door to creating a circular, sustainable economy for asphalt used for roofing shingles.

Roofs play an important role in the transition to a green economy.  Apart from recycling asphalt shingles, there are increasing options for solar shingles, which take the place of both traditional asphalt shingles and ordinary solar panels by integrating them into a single roofing product.  There are also so-called green roofs, which replace conventional roofing materials with a contained green space atop a building. Such roofs provide stormwater management, cooling, and an interesting aesthetic.

All aspects of buildings play important roles in our environment – even their roofs.

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5 Ways Roofers Can Celebrate Earth Day, Everyday

Photo, posted April 15, 2012, courtesy of Robert Taylor via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Capturing Methane To Feed Fish | Earth Wise

December 30, 2021 By EarthWise Leave a Comment

Using captured methane as food for fish

Methane in the atmosphere is an extremely potent greenhouse gas.  Its warming potential is about 85 times that of carbon dioxide over a 20-year period.  It also worsens air quality by increasing atmospheric ozone.  Many human activities add methane to the atmosphere, notably emissions from landfills and oil and gas facilities.

Capturing methane from these sources for subsequent use is currently uneconomical but new research from Stanford University analyzes the market for using the methane to feed bacteria to produce fishmeal.

Methane-consuming bacteria called methanotrophs can be grown in chilled, water-filled bioreactors containing pressurized methane, oxygen, and nutrients.  The bacteria produce a protein-rich biomass that can be used as fishmeal in aquaculture.  This could offset demand for fishmeal made from small fish or plant-based feeds that require land, water, and fertilizer.

Some companies already do this using natural gas provided by utility pipelines, but it would be far better for the environment to use methane emitted at large landfills, wastewater treatment plants, and oil and gas facilities.

Consumption of seafood has more than quadrupled since 1960, depleting wild fish stocks.  Farmed fish now provide half of all the animal-sourced seafood we eat.

The Stanford research analyzed the cost of methanotrophic fishmeal production under various scenarios and found it to be very competitive with and in some cases considerably cheaper than current market prices for fishmeal. 

According to the study, this process could profitably supply total global demand for fishmeal with methane captured in the U.S. alone.

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Stanford researchers reveal how to turn a global warming liability into a profitable food security solution

Photo, posted April 30, 2017, courtesy of Artur Rydzewski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Nanoplastics In The Air | Earth Wise

December 17, 2021 By EarthWise Leave a Comment

Austria, Silvretta mountains

The world is awash in plastic.  Discarded plastic litters our roadways, woodlands, and beaches.  It piles up in landfills.  Plastic enters the oceans by the millions of tons.  And plastic is finding its way even to remote and supposedly pristine parts of the world.

A team of researchers has found nanoplastics at the isolated high-altitude Sonnblick Observatory in the Austrian Alps.  This is the first time the particles were found in the area.  The researchers were looking for certain organic particles and only found the nanoplastics by chance.

The detected plastic particles were less than 200 nanometers in size, about one hundredth the width of a human hair.  It is highly unlikely that such particles originated in remote Alpine areas.

The researchers were looking for organic particles by taking samples of snow or ice, evaporating them, and then burning the residue to detect and analyze the vapors.  They described the detection method as essentially like a mechanical nose.  In this case, the nose smelled burning plastics in the form of polypropylene and polyethylene terephthalate.

Looking into the issue, the researchers found a strong correlation between high concentrations of nanoplastics and winds coming from the direction of major European cities – especially Frankfurt and the industrial Ruhr area of Germany, but also the Netherlands, Paris, and even London.

Modeling supports the idea that nanoplastics are transported by air from distant urban places.  This is particularly worrisome because it means that there are likely hotspots of nanoplastics in our cities and in the air that we are breathing.  Plastics appear to be everywhere.

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Nanoplastics found in the Alps, transported by air from Frankfurt, Paris and London

Photo, posted July 1, 2013, courtesy of Robert J. Heath via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Infinitely Recyclable Plastic | Earth Wise

May 25, 2021 By EarthWise 1 Comment

Making an infinitely recyclable plastic

The glut of plastics is one of the world’s most challenging environmental problems.  The average American generates over 200 pounds of plastic waste each year and most of that ends up in landfills.  Researchers around the globe continue to work on potential solutions to the plastic waste problem.

Two years ago, scientists at Lawrence Berkeley National Laboratory announced the invention of a new plastic that could be an answer to the plastic waste problem.  The material is called polydiketoenamine or PDK and it differs from traditional plastics in a very important way:  it can be recycled indefinitely with no loss in quality because it can easily be broken down into its constituent component monomers and be used to make brand new plastic.

Only a small percentage of plastics are currently recycled.  When many plastics are melted down together, the polymers are mixed with a slew of incompatible additives, resulting in a new material with much lower quality than newly produced plastic.  As a result, less than 10% of plastic is recycled more than once.

Recently, the Berkeley Lab researchers released a study that shows what could be accomplished if manufacturers began using PDKs on a large scale.  They determined that PDK-based plastic could quickly become commercially competitive with conventional plastics and, furthermore, would get less expensive and more sustainable as time goes on.

PDK is starting to draw interest from companies needing to source plastic.  The best initial application for PDKs are markets where manufacturers have the most access to products at the end of their lifespans such as in the automobile industry and consumer electronics.  Making plastics part of a circular economy is a challenging task.

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The Future Looks Bright for Infinitely Recyclable Plastic

Photo, posted April 19, 2021, courtesy of Ivan Radic via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Breaking Down Polystyrene | Earth Wise

April 20, 2021 By EarthWise Leave a Comment

Scientists have developed a way to break down polystyrene

The proliferation of global plastic waste continues to be a growing problem for the world.  Hundreds of millions of tons of plastics are produced each year and most of it is used once and then discarded.  The properties that make plastics so attractive – durability and chemical stability – make it difficult to do anything with discarded plastics other than deposit them in landfills – where they don’t easily degrade over time – or burn them, which dumps carbon dioxide and various hazardous gases into the atmosphere.

Polystyrene is one of the most widely used plastics.  It is found in foam packaging materials, disposable food containers, plastic cutlery, storage containers, and many other places. 

Recycling plastics like polystyrene is generally not economically feasible.  Sorting plastics by type is time and labor intensive and the chemical processes required to break down plastics into usable precursor materials require significant energy input and the use of toxic solvents.

Recently, a team of scientists at Ames Laboratory in Iowa has developed a process based on ball-milling that deconstructs commercial polystyrene in a single step, at room temperature, in ambient atmosphere, and in the absence of harmful solvents.

Ball-milling is a technique that places materials in a milling vial with metal ball bearings which is then agitated to initiate a chemical reaction.  This approach is known as mechanochemistry.

The method represents an important breakthrough that enables dismantling of a polymer that includes its chemical breakdown without requiring solvents or the high temperatures generally needed to thermally decompose it.  This discovery opens up new avenues for low-temperature recovery of monomers from polymer-based systems that include composites and laminates.  It could be a very useful weapon in the battle against plastic waste.

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Polystyrene waste is everywhere, and it’s not biodegradable. Scientists just found a way to break it down.

Photo, posted December 11, 2010, courtesy of Warrenski via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Paving With Plastic | Earth Wise

March 25, 2021 By EarthWise Leave a Comment

Using plastic waste as pavement

The country of Ghana has an ambitious plan to recycle and reuse as much plastic waste as it produces each year (which is over a million tons) by 2030.  As part of this plan, they have started to pave roads in Accra, the capital city, with asphalt containing a slurry of used plastics – shredded and melted bags, bottles, and snack wraps.  Only a quarter of Ghana’s roads are currently paved, so waste plastic has many opportunities for use in paving.

Plastic roads first appeared in India two decades ago.  There are now over 60,000 miles of them in that country.  Several countries have only recently built their first plastic roads including South Africa, Vietnam, Mexico, the Philippines, and the United States.

Studies have shown that roads containing waste plastic have the potential to perform as well or better than traditional roads.  They can last longer, can tolerate wide temperature swings better, are stronger and more durable, and are more resistant to water damage, cracking, and potholes.

Ordinarily, asphalt for roads consists of 90 to 95% aggregate – typically some mixture of gravel, sand, and limestone – and 5 to 10% bitumen, which is a black gooey substance extracted from crude oil that binds the aggregate together.  Plastic-enhanced roads replace varying amounts of the bitumen (often as little as 4-10%, but sometimes much more), with plastic that is actually a stronger binding agent.

Plastic roads reduce the amount of bitumen in roads, thereby reducing carbon emissions.  The plastics are not heated enough to release gases and the roads do not appear to shed microplastics.  Plastic roads will not solve the world’s plastic waste problem, but they can help by diverting lots of plastic from landfills.

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How Paving with Plastic Could Make a Dent in the Global Waste Problem

Photo, posted June 4, 2010, courtesy of Sustainable Initiatives Fund Trust via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Compost And Landfills | Earth Wise

January 19, 2021 By EarthWise Leave a Comment

the importance of landscaping

Composting is popular as a way to keep solid waste out of landfills and many people turn much of their kitchen waste into rich soil amendments.   Cities and towns across the country have composting programs that collect waste from residents to produce large quantities of compost rather than adding the waste to landfills.  A new study from North Carolina State University looked into the environmental benefits of actually using compost at landfills.

Most municipal composting programs require that the compost they produce gets used “beneficially”.  The new research shows that using compost as an alternative daily cover at landfills is competitive and often superior to the use of compost as a soil amendment in terms of its environmental benefits.

Landfills apply a layer of daily cover to reduce odors, reduce windblown debris, and keep vermin out of landfill waste.  Federal regulations require six inches of soil as a daily cover.

Compost from food waste in particular is not always suitable for soil amendment in gardens and agricultural fields because it often contains broken glass and other contaminants.

The North Carolina State study looked at the environmental impact of using compost as daily cover in landfills compared with its use as a soil amendment.  They looked at global warming potential, acidification potential, eutrophication (which is the amount of nutrients released to ground and surface water), cumulative energy demand, and the depletion of resources.

The study concluded that using compost as landfill daily cover is environmentally superior with regard to eutrophication, acidification, and global warming potential.  On the other hand, soil amendment was better in terms of resource depletion and cumulative energy demand.

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Applying Compost to Landfills Could Have Environmental Benefits

Photo, posted April 22, 2008, courtesy of Alachua County via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Electronic Waste On The Decline | Earth Wise

January 6, 2021 By EarthWise Leave a Comment

Electronic waste is declining

A new study published in the Journal of Industrial Ecology has found that the total mass of electronic waste generated by Americans has been declining since 2015.  Given that electronic devices are playing an ever-growing role in our lives, this finding seems rather surprising.  It also seems like pretty good news, but the underlying facts should dampen our level of enthusiasm.

The main reason for the decline is the disappearance of large, bulky cathode-ray tube televisions and computer monitors.  Since about 10 years ago, CRT displays have been on the decline in the waste stream, thereby leading to an overall decline in total e-waste mass.

Many state regulations with respect to e-waste recycling have targets based on product mass.  The regulations were typically designed to keep electronics with high levels of lead and mercury out of landfills.

At present, the more pertinent concern is how to recover valuable elements like cobalt (from lithium-ion batteries) and indium (from flat-panel displays).  These elements are not so environmentally toxic, but rather are relatively scarce in the earth’s crust. 

The main conclusion to be drawn from the declining mass of electronic waste is not that we are necessarily winning the battle against generating it but rather that e-waste is changing and regulations concerning it need to be rethought.  Focusing regulations on capturing critical elements not only would have significant economic benefits but also would be important in addressing geopolitical uncertainties that potentially could threaten what could be termed the mineral security of the U.S.

E-waste recycling is regulated at the state level and only half the states have e-waste recycling laws.  It may be time for more uniform policies across the country.

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Electronic Waste on the Decline, New Study Finds

Photo, posted January 22, 2013, courtesy of Thorsten Hartmann via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Getting Value From Plastic Waste | Earth Wise

November 30, 2020 By EarthWise Leave a Comment

Extracting value from plastic waste

To date, the world has produced more than five billion tons of plastic and is making more all the time.  Based on the way things are currently done, most of that will end up in landfills or in the natural environment.  By 2050, the amount of plastic is expected to exceed 13 billion tons.   This is one of the world’s biggest environmental problems.

Recently, an international collaboration by universities and institutions in the UK, China, and Saudi Arabia has developed a method of converting plastic waste into hydrogen gas and high-value solid carbon.

The technique was achieved with a new type of catalysis that uses microwaves to activate catalyst particles that effectively strip hydrogen from plastic polymers.  The work was recently published in the journal Nature Catalysis and details how the researchers mixed mechanically pulverized plastic particles with a microwave-susceptor catalyst of iron oxide and aluminum oxide.  That mixture was then subjected to microwave treatment and yielded a large volume of hydrogen gas and a residue of carbonaceous material, most of which was identified as carbon nanotubes.

The process is more rapid than most methods for dealing with plastic waste and can extract over 97% of the hydrogen in plastic without producing any carbon dioxide emissions. 

The new method represents an attractive potential solution to the problem of plastic waste.  Instead of polluting the planet, plastics could become a valuable feedstock for producing clean hydrogen fuel as well as valuable carbon materials.  Proponents of the so-called hydrogen economy have continued to seek a green and economical way to produce hydrogen.  This new work might be just what they are looking for.

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Turning plastic waste into hydrogen and high-value carbons

Photo, posted April 21, 2007, courtesy of Redwin Law via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Sustainable Flip-Flops | Earth Wise

September 9, 2020 By EarthWise Leave a Comment

Sustainable technologies

Flip-flops are the world’s most popular shoe.  They are lightweight, comfortable, affordable, and durable.  In fact, the global market for flip-flops is expected to reach a whopping $23.8 billion by the year 2025. 

But the popularity comes with a price.  Flip-flops account for a troubling percentage of plastic waste that ends up in our landfills and oceans.  As a result, demand for alternatives is compelling researchers to develop more sustainable versions of the popular footwear.

Scientists at the University of California San Diego have spent years working on this issue, and recently announced a breakthrough.  According to a study recently published in Bioresource Technology Reports, the research team has formulated polyurethane foams – made from algae oil – to meet commercial specifications for mid-sole shoes and the foot-bed of flip-flops.   In other words, the scientists have created sustainable, biodegradable, and consumer-ready materials that could replace plastics in some footwear. 

The UC San Diego scientists collaborated with Algenesis Materials – a technology startup – on the research.  Together, they worked to not only create the shoes, but to degrade them as well.  The team tested their customized foams by immersing them in traditional compost and soil.  The algae-based materials degraded after just 16 weeks.  

The life of any material should be proportionate to the life of the product.  The researchers point out that it doesn’t make sense to create a product that will last 500 years if it’ll only be used for a year or two. 

The research team is currently working on production details with its manufacturing partners.  The creation of biodegradable flip-flops that meet commercial footwear standards could eliminate tons of plastic waste from the environment.   

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New science behind algae-based flip-flops

Flip Flops Market Size Worth $23.8 Billion by 2025

Photo, posted December 12, 2019, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Preserving Produce With Eggs | Earth Wise

July 17, 2020 By EarthWise Leave a Comment

Using eggs to preserve produce

Researchers at Brown University have developed an inexpensive coating to protect fruits and vegetables that is made from eggs that would otherwise be wasted.  The micron-thick coating solves problems for the produce and its consumers as well as for the environment.

The coating relies on eggs that never reach the market.  The U.S. produces more than 7 billion eggs a year.  The supply chain rejects about 3% of them, typically because of shell damage, which means that more than 200 million eggs end up in landfills.

The coating is mostly made from egg, the rest consisting of nanoscale cellulose extracted from wood, a tiny amount of curcumin (the main active ingredient in turmeric that has antimicrobial properties), and a bit of glycerol for added elasticity.  The coating is applied to produce by spraying or dipping.  It shows a remarkable ability to resist rotting for an extended period comparable to standard coatings like wax, but without their shortcomings.

Along with being edible, the coating retards dehydration, provides antimicrobial protection, and is largely impermeable to both water vapor to prevent dehydration and to gas to prevent premature ripening.  The coating is entirely natural, and it washes off with water.  So, anyone sensitive to the coating, such as someone with an egg allergy, can easily eliminate it.

Lab tests of the coating studied its effects on strawberries, avocados, bananas and other fruits.  All were seen to maintain their freshness far longer than uncoated produce.

The researchers are continuing to refine the coating.  They are also considering other source materials.  They chose egg proteins because there are so many wasted eggs, but it may be possible to make use of plant proteins instead to address the needs of vegan consumers.

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Egg-based coating preserves fresh produce

Photo, posted July 13, 2012, courtesy of Liz West via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Plant-Based Bottles | Earth Wise

June 30, 2020 By EarthWise Leave a Comment

Single-use plastic soda and water bottles are a real problem.  Every year, billions of them are produced – comprising nearly 300 million tons of plastic that mostly ends up in landfills or in the ocean.   This discarded plastic ends up on remote islands, in the snow atop mountains, and in trenches in the deepest parts of ocean.

There has been increasing pressure on beverage companies to put an end to this environmental disaster, but the convenience and economy of disposable bottles is just too attractive.

These bottles are made of plastic derived from oil and once they are produced, they take decades or even centuries to decompose.  Recycling them is a not-starter because it is cheaper to just make new ones.

A possible solution has emerged.  A Dutch company called Avantium has found a way to take plant sugars and transform them into a plastic capable of standing up to carbonated beverages like soda and beer but that will also break down in as little as a year in a composter or 3 years if left exposed to the elements.

Coca Cola and Carlsberg are working with Avantium to develop new drink packaging based on their material that could be in stores as soon as 2023.  The new packaging would be quite different from what we use today.  Instead of a clear or tinted bottle, beverages would come inside a cardboard container with a liner made of plant-based plastic.

It may take a while for people to get used to the change, but we have already managed to get used to milk, juice and other liquids coming in cardboard containers instead of glass or plastic bottles.  The benefits to the planet would make the effort well worthwhile.

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Plant-Based Bottles Could Degrade In One Year

Photo courtesy of Avantium.

Earth Wise is a production of WAMC Northeast Public Radio.

Concrete Production And Diminishing Coal Burning | Earth Wise

June 5, 2020 By EarthWise Leave a Comment

electricity generation and concrete production

Coal burning is still one of the primary means of generating electricity in the United States, but its use is diminishing and doing so fairly rapidly.  The coal burning process produces residual, incombustible materials.  One of them is fly ash, which is composed of fine, glassy, rounded particles rich in silicon, aluminum, calcium, and iron oxides.  Fly ash is captured from coal plant flue gas by precipitators and bag filters. It turns out that two-thirds of this fly ash is not dumped into landfills or impoundments, but rather is put to use.

Because of its chemical and physical characteristics, fly ash can substitute for a portion of portland cement in concrete.  Using this byproduct material in making cement actually reduces its cost. Beyond cost, the addition of fly ash as a so-called supplementary cementitious material or SCM improves concrete’s long-term strength and reduces porosity and permeability.  It reduces the risk of thermal cracking and provides good long-term mechanical properties.

The amount of fly ash used in concrete products increased by 5% between 2011 and 2017 while the amount produced dropped by 36%.  Concrete production continues to increase steadily while fly ash production is steadily dropping.

Therefore, the concrete industry is looking for alternative sources of SCM.  The most obvious is the approximately 1/3 of fly ash that hasn’t been used to make concrete.  Much of that is landfilled or ponded onsite at power plants.  So, opportunities exist for excavating or dredging and recovering these materials.

As coal burning goes away, concrete manufacturing needs to make some changes.

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What Does the Changing Face of Electricity Production Mean for Concrete?

Photo, posted February 16, 2017, courtesy of Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

Environmental Injustice And the Coronavirus | Earth Wise

May 29, 2020 By EarthWise Leave a Comment

Environmental Injustice and coronavirus

Cities and towns across the United States continue to wrestle with the devastating impacts of the COVID-19 pandemic and none have been hit harder than low-income and minority communities.  Places like Detroit, Chicago, and St. James Parish in Louisiana have suffered from decades of economic inequality and pollution in their poorest neighborhoods and many of these same places have experienced some of the highest mortality rates from the virus.

Recent studies have shown a link between high levels of pollution and the risk of death from COVID-19.  Pollution of various kinds are higher in low-income communities and communities of color.  Such communities don’t have a strong political voice so that laws and environmental regulations are not enforced like there are in white, higher-income communities.  Thus, these communities have highways, landfills, factories, chemical facilities, paper mills, and other pollution sources that communities with economic power – and therefore political power – manage to avoid.

People living in low-income communities and communities of color tend to have higher rates of underlying health conditions like diabetes, heart disease, and asthma.  They have less healthy diets – more fast food and fewer grocery stores.  Part of the reason these communities have a higher risk of mortality from COVID-19 infection is that many people have reduced lung capacity as a result of exposure to pollutants.

The Trump administration has been suspending enforcement of environmental regulations during the pandemic.  Communities already affected by environmental injustice will bear the brunt of this decision.  Groups like nursing home populations, meat packers, prisoners and the poor are suddenly highly visible.  COVID-19 is exposing the real differences between the Haves and the Have-Nots in this country.

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Connecting the Dots Between Environmental Injustice and the Coronavirus

Photo, posted May 2, 2006, courtesy of Sean Benham via Flickr.

Earth Wise is a production of WAMC Northeast Public Radio.

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